Single Spin Research Articles

Building a bridge between comparable and extreme mass ratio black hole binaries: A single spin precessing model for the final state

Building a bridge between comparable and extreme mass ratio black hole binaries: A single spin precessing model for the final state

Room Temperature Dynamics of an Optically Addressable Single Spin in Hexagonal Boron Nitride.

Hexagonal boron nitride (h-BN) hosts pure single-photon emitters that have shown evidence of optically detected electronic spin dynamics. However, the electrical and chemical structures of these optically addressable spins are unknown, and the nature of their spin-optical interactions remains mysterious. Here, we use time-domain optical and microwave experiments to characterize a single emitter in h-BN exhibiting room temperature optically detected magnetic resonance. Using dynamical simulations, we constrain and quantify transition rates in the model, and we design optical control protocols that optimize the signal-to-noise ratio for spin readout. This constitutes a necessary step toward quantum control of spin states in h-BN.

Trajectory-Based Time-Resolved Mechanism for Benzene Reductive Elimination from Cyclopentadienyl Mo/W Phenyl Hydride Complexes.

Calculated potential energy structures and landscapes are very often used to define the sequence of reaction steps in an organometallic reaction mechanism and interpret kinetic isotope effect (KIE) measurements. Underlying most of this structure-to-mechanism translation is the use of statistical rate theories without consideration of atomic/molecular motion. Here we report direct dynamics simulations for an organometallic benzene reductive elimination reaction, where nonstatistical intermediates and dynamic-controlled pathways were identified. Specifically, we report single spin state as well as mixed spin state quasiclassical direct dynamics trajectories in the gas phase and explicit solvent for benzene reductive elimination from Mo and W bridged cyclopentadienyl phenyl hydride complexes ([Me2Si(C5Me4)2]M(H)(Ph), M = Mo and W). Different from the energy landscape mechanistic sequence, the dynamics trajectories revealed that after the benzene C-H bond forming transition state (often called reductive coupling), σ-coordination and π-coordination intermediates are either skipped or circumvented and that there is a direct pathway to forming a spin flipped solvent caged intermediate, which occurs in just a few hundred femtoseconds. Classical molecular dynamics simulations were then used to estimate the lifetime of the caged intermediate, which is between 200 and 400 picoseconds. This indicates that when the η2-π-coordination intermediate is formed, it occurs only after the first formation of the solvent-caged intermediate. This dynamic mechanism intriguingly suggests the possibility that the solvent-caged intermediate rather than a coordination intermediate is responsible (or partially responsible) for the inverse KIE value experimentally measured for W. Additionally, this dynamic mechanism prompted us to calculate the kH/kD KIE value for the C-H bonding forming transition states of Mo and W. Surprisingly, Mo gave a normal value, while W gave an inverse value, albeit small, due to a much later transition state position.

Work and efficiency fluctuations in a quantum Otto cycle with idle levels.

We study the performance of a quantum Otto heat engine with two spins coupled by a Heisenberg interaction, taking into account not only the mean values of work and efficiency but also their fluctuations. We first show that, for this system, the output work and its fluctuations are directly related to the magnetization and magnetic susceptibility of the system at equilibrium with either heat bath. We analyze the regions where the work extraction can be done with low relative fluctuation for a given range of temperatures, while still achieving an efficiency higher than that of a single spin system heat engine. In particular, we find that, due to the presence of "idle" levels, an increase in the interspin coupling can either increase or decrease fluctuations, depending on the other parameters. In all cases, however, we find that the relative fluctuations in work or efficiency remain large, implying that this microscopic engine is not very reliable as a source of work.

Cavity QED systems for steady-state sources of Wigner-negative light

We present a theoretical investigation of optical cavity quantum electrodynamics (cavity QED) systems, as described by the driven, open Jaynes–Cummings model and some of its variants, as potential sources of steady-state Wigner-negative light. We consider temporal modes in the continuous output field from the cavity and demonstrate pronounced negativity in their Wigner distributions for experimentally relevant parameter regimes. We consider models of both single and collective atomic spin systems, and find a rich structure of Wigner-distribution negativity as the spin size is varied. We also demonstrate an effective realization of all of the models considered using just a single 87Rb atom and based upon combinations of laser- and laser-plus-cavity-driven Raman transitions between magnetic sublevels in a single ground hyperfine state.

Measurements of the Z0/γ⁎ cross section and transverse single spin asymmetry in 510 GeV p + p collisions

The differential cross section for Z0 production, measured as a function of the boson's transverse momentum (pT), provides important constraints on the evolution of the transverse momentum dependent parton distribution functions (TMDs). The transverse single spin asymmetry (TSSA) of the Z0 is sensitive to one of the polarized TMDs, the Sivers function, which is predicted to have the opposite sign in p+p→W/Z+X from that which enters in semi-inclusive deep inelastic scattering. In this Letter, the STAR Collaboration reports the first measurement of the Z0/γ⁎ differential cross section as a function of its pT in p+p collisions at a center-of-mass energy of 510 GeV, together with the Z0/γ⁎ total cross section. We also report the measurement of Z0/γ⁎ TSSA in transversely polarized p+p collisions at 510 GeV.

Exact Results for a Boundary-Driven Double Spin Chain and Resource-Efficient Remote Entanglement Stabilization

We derive an exact solution for the steady state of a setup where two XX-coupled N-qubit spin chains (with possibly nonuniform couplings) are subject to boundary Rabi drives and common boundary loss generated by a waveguide (either bidirectional or unidirectional). For a wide range of parameters, this system has a pure entangled steady state, providing a means for stabilizing remote multiqubit entanglement without the use of squeezed light. Our solution also provides insights into a single boundary-driven dissipative XX spin chain that maps to an interacting fermionic model. The nonequilibrium steady state exhibits surprising correlation effects, including an emergent pairing of hole excitations that arises from dynamically constrained hopping. Our system could be implemented in a number of experimental platforms, including circuit QED. Published by the American Physical Society 2024

A quantum coherent spin in hexagonal boron nitride at ambient conditions.

Solid-state spin-photon interfaces that combine single-photon generation and long-lived spin coherence with scalable device integration-ideally under ambient conditions-hold great promise for the implementation of quantum networks and sensors. Despite rapid progress reported across several candidate systems, those possessing quantum coherent single spins at room temperature remain extremely rare. Here we report quantum coherent control under ambient conditions of a single-photon-emitting defect spin in a layered van der Waals material, namely, hexagonal boron nitride. We identify that the carbon-related defect has a spin-triplet electronic ground-state manifold. We demonstrate that the spin coherence is predominantly governed by coupling to only a few proximal nuclei and is prolonged by decoupling protocols. Our results serve to introduce a new platform to realize a room-temperature spin qubit coupled to a multiqubit quantum register or quantum sensor with nanoscale sample proximity.

Simultaneous reweighting of Transverse Momentum Dependent distributions

The Bayesian reweighting procedure is extended to the case of multiple independent extractions of transverse momentum dependent parton distributions (TMDs). By exploiting the data on transverse single spin asymmetries, AN, for inclusive pion production in polarized proton-proton collisions measured at RHIC, we perform a simultaneous reweighting of the quark Sivers, transversity and Collins TMD functions extracted from semi-inclusive deep inelastic scattering (SIDIS) and e+e− annihilation into hadron pairs. The impact of the implementation of the Soffer bound, as well as the differences between older and newer AN data, are investigated. The agreement with AN data at large-xF values, a kinematical region complementary to those explored in SIDIS measurements, is enhanced, improving the knowledge of the polarized quark TMDs in the large-x region.

Theory of electron spin resonance in scanning tunneling microscopy

Electron spin resonance (ESR) spectroscopy in scanning tunneling microscopy (STM) has enabled probing the electronic structure of single magnetic atoms and molecules on surfaces with unprecedented energy resolution, as well as demonstrating coherent manipulation of single spins. Despite this remarkable success, the field could still be greatly advanced by a more quantitative understanding of the ESR-STM physical mechanisms. Here, we present a theory of ESR-STM that quantitatively models not only the ESR signal itself, but also the full background tunneling current, from which the ESR signal is derived. Our theory is based on a combination of Green's function techniques to describe the electron tunneling and a quantum master equation for the dynamics of the spin system along with microwave radiation interacting with both the tunneling current and the magnetic system. We show that this theory is able to quantitatively reproduce the experimental results for a spin-1/2 system (TiH molecules on MgO) across many orders of magnitude in tunneling current, providing access to the relaxation and decoherence rates that govern the spin dynamics due to intrinsic mechanisms and to the applied bias voltage. More importantly, our work establishes that (i) sizable ESR signals, which are a measure of microwave-induced changes in the junction magnetoresistance, require surprisingly high tip spin polarizations, and (ii) the coupling of the magnetization dynamics to the microwave field gives rise to the asymmetric ESR spectra often observed in this spectroscopy. Additionally, our theory provides very specific predictions for the dependence of the relaxation and decoherence times on the bias voltage and the tip-sample distance. Finally, with the help of electromagnetic simulations, we find that the transitions in our ESR-STM experiments, in which the tunnel junction is irradiated by a nearby microwave antenna, can be driven by the ac magnetic field at the junction. Published by the American Physical Society 2024

All-Electrical Driving and Probing of Dressed States in a Single Spin.

The subnanometer distance between tip and sample in a scanning tunneling microscope (STM) enables the application of very large electric fields with a strength as high as ∼1 GV/m. This has allowed for efficient electrical driving of Rabi oscillations of a single spin on a surface at a moderate radiofrequency (RF) voltage on the order of tens of millivolts. Here, we demonstrate the creation of dressed states of a single electron spin localized in the STM tunnel junction by using resonant RF driving voltages. The read-out of these dressed states was achieved all electrically by a weakly coupled probe spin. Our work highlights the strength of the atomic-scale geometry inherent to the STM that facilitates the creation and control of dressed states, which are promising for the design of atomic scale quantum devices using individual spins on surfaces.

Single-Shot Readout of a Nuclear Spin in Silicon Carbide.

Solid-state qubits with a photonic interface is very promising for quantum networks. Color centers in silicon carbide have shown excellent optical and spin coherence, even when integrated with membranes and nanostructures. Additionally, nuclear spins coupled with electron spins can serve as long-lived quantum memories. Pioneering work previously has realized the initialization of a single nuclear spin and demonstrated its entanglement with an electron spin. In this Letter, we report the first realization of single-shot readout for a nuclear spin in SiC. We obtain a deterministic nuclear spin initialization and readout fidelity of 94.95% with a measurement duration of 1ms. With a dual-step readout scheme, we obtain a readout fidelity as high as 99.03% within 0.28ms by sacrificing the success efficiency. Our Letter complements the experimental toolbox of harnessing both electron and nuclear spins in SiC for future quantum networks.

The Efficacy of Local Autologous Platelet-Rich Plasma Prepared by Single and Double Spin Methods in the Treatment of Chronic Ulcer.

Chronic nonhealing ulcers present significant challenges in diabetic, dermatological, and surgical patients. Platelet-rich plasma (PRP), enriched with bioactive factors, offers promise for wound healing enhancement. This study evaluates PRP's efficacy, prepared via single and double spin methods in nonhealing chronic ulcers. Twenty-two patients aged 18-65 years participated and100 mL of blood was drawn into citrate phosphate dextrose adenine (CPDA) bags with all aseptic precautions. PRP was prepared by single and double spin methods. Patient serum and 10% calcium gluconate were added to fibrin gel. PRP was injected around the ulcer and then dressed. Dressings were changed on the fifth, 15th, and 20th days with PRP. Evaluation occurred on day 30 using surface area and volume assessments by both methods. The single spin PRP group and double spin PRP group had 11 patientseach with hemoglobin range of 10.79±1.88 to 12.63±2.22 g/dL. Initial lesions (16.27 cm²) significantly reduced to 14.76 cm² after double spin PRP sessions (p=0.005) andInitial lesions (9.87 cm²) significantly reduced to 7.65 cm² after single spin PRP sessions (p=0.005). Platelet count differences between whole blood and PRP were significant (p<0.05). The single spin PRP method exhibited considerable improvements in healing parameters, showcasing its potential for chronic ulcer management.

A scanning probe microscope compatible with quantum sensing at ambient conditions.

We designed and built up a new type of ambient scanning probe microscope (SPM), which is fully compatible with state-of-the-art quantum sensing technology based on the nitrogen-vacancy (NV) centers in diamond. We chose a qPlus-type tuning fork (Q up to ∼4400) as the current/force sensor of SPM for its high stiffness and stability under various environments, which yields atomic resolution under scanning tunneling microscopy mode and 1.2-nm resolution under atomic force microscopy mode. The tip of SPM can be used to directly image the topography of nanoscale targets on diamond surfaces for quantum sensing and to manipulate the electrostatic environment of NV centers to enhance their sensitivity up to a single proton spin. In addition, we also demonstrated scanning magnetometry and electrometry with a spatial resolution of ∼20nm. Our new system not only paves the way for integrating atomic/molecular-scale color-center qubits onto SPM tips to produce quantum tips but also provides the possibility of fabricating color-center qubits with nanoscale or atomic precision.

Perturbative QCD contribution to transverse single spin asymmetries in the Drell-Yan process and SIDIS

In a previous publication [Benić , ], we have computed the perturbative QCD contribution to transverse single spin asymmetries (SSAs) in semi-inclusive deep inelastic scattering (SIDIS) involving the gT(x) distribution. In this paper, we first present a more efficient derivation of the asymmetries which is applicable to both transverse and longitudinal SSAs and correct some inconsistencies in our previous calculation. We then adapt the method to compute transverse SSAs in the Drell-Yan process proportional to gT(x) and its gluonic counterpart and discuss the crossing symmetry between the results for SIDIS and the Drell-Yan process. Finally, we present numerical results for various asymmetries measurable at the EIC, RHIC, COMPASS, and Fermilab (SpinQuest), including also part of the genuine twist-three corrections to gT(x) from a recent global analysis. We find that the asymmetries can reach percent-level magnitude, if the kinematics predominantly probes the large-x (valence) region of the polarized proton, but remain at subpercent levels otherwise. Published by the American Physical Society 2024

Correlation between two distant quasiparticles in separate superconducting islands mediated by a single spin

Controlled coupling between distant particles is a key requirement for the implementation of quantum information technologies. A promising platform are hybrid systems of semiconducting quantum dots coupled to superconducting islands, where the tunability of the dots is combined with the macroscopic coherence of the islands to produce states with non-local correlations, e.g. in Cooper pair splitters. Electrons in hybrid quantum dots are typically not amenable to long-distance spin alignment as they tend to be screened into a localized singlet state by bound superconducting quasiparticles. However, two quasiparticles coming from different superconductors can overscreen the quantum dot into a doublet state, leading to ferromagnetic correlations between the superconducting islands. We present experimental evidence of a stabilized overscreened state, implying correlated quasiparticles over a micrometer distance. We propose alternating chains of quantum dots and superconducting islands as a novel platform for controllable large-scale spin coupling.

Fast Quantum State Preparation and Bath Dynamics Using Non-Gaussian Variational Ansatz and Quantum Optimal Control.

Fast preparation of quantum many-body states is essential for myriad quantum algorithms and metrological applications. Here, we develop a new pathway for fast, nonadiabatic preparation of quantum many-body states that combines quantum optimal control with a variational Ansatz based on non-Gaussian states. We demonstrate our approach on the spin-boson model, a single spin interacting with the bath. We use a multipolaron Ansatz to prepare near-critical ground states. For one mode, we achieve a reduction in infidelity of up to ≈60 (≈10) times compared to linear (optimized local adiabatic) ramps; for many modes, we achieve a reduction in infidelity of up to ≈5 times compared to nonadiabatic linear ramps. Further, we show that the typical control quantity, the leakage from the variational manifold, provides only a loose bound on the state's fidelity. Instead, in analogy to the bond dimension of matrix product states, we suggest a controlled convergence criterion based on the number of polarons. Finally, motivated by the possibility of realizations in trapped ions, we study the dynamics of a system with bath properties going beyond the paradigm of (sub- and/or super-) Ohmic couplings.

Spin-encoded quantum computer near ultimate physical limits

Landauer’s bound is applicable to irreversible quantum operations. In this study, we showcased that the Doppler temperature manifests the existence of Landauer’s bound, which does not block a spin from (irreversibly) flipping with a tiny amount of energy via quantum tunneling. Verified by a spin–spin magnetic interaction experiment, this (energy) amount was determined to be only 1.25 times the theoretical value of Landauer’s bound. Based on Heisenberg’s principle, we defined information from a measuring perspective: one bit of information corresponds to the smallest error when quantifying the product of the measured energy uncertainty (ΔE\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Delta E$$\\end{document}) and the measured time duration (Δt\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Delta t$$\\end{document}). We then illustrate an optically manipulated, spin-encoded, near-Landauer-bound, near-Heisenberg-limit quantum computer that encompasses this new definition of information. This study may represent the last piece of the puzzle in understanding both quantum Landauer erasure and Heisenberg’s quantum limit since a single spin is the smallest information carrier.

Gravito-diamagnetic forces for mass independent large spatial superpositions

Creating a massive spatial quantum superposition, such as the Schrödinger cat state, where the mass and the superposition size within the range 10−19 − 10−14 kg and Δx ∼ 10 nm − 100 μm, is a challenging task. The methods employed so far rely either on wavepacket expansion or on a quantum ancilla, e.g. single spin dependent forces, which scale inversely with mass. In this paper, we present a novel approach that combines gravitational acceleration and diamagnetic repulsion to generate a large spatial superposition in a relatively short time. After first creating a modest initial spatial superposition of 1 μm, achieved through techniques such as the Stern–Gerlach (SG) apparatus, we will show that we can achieve an ∼102−103 fold improvement to the spatial superposition size (1 μm → 980 μm) between the wave packets in less than 0.02 s by using the Earth’s gravitational acceleration and then the diamagnetic repulsive scattering of the nanocrystal, neither of which depend on the object mass. Finally, the wave packet trajectories can be closed so that spatial interference fringes can be observed. Our findings highlight the potential of combining gravitational acceleration and diamagnetic repulsion to create and manipulate large spatial superpositions, offering new insights into creating macroscopic quantum superpositions.

High ODMR contrast and alignment of NV centers in microstructures grown on heteroepitaxial diamonds

Heteroepitaxial chemical vapor deposition is the most promising option to fabricate wafer-scale monocrystalline diamonds for quantum applications. Previously, we demonstrated the feasibility to manufacture functional micrometer-sized pyramids on as-grown heteroepitaxial diamond as well as their quantum optical characteristics. Due to high background signals and microfabrication challenges, these pyramids could not compete with homoepitaxially grown structures. In this study, we overcame these problems with a nominally undoped buffer layer between the heteroepitaxial substrate and the pyramidal microstructure to reduce the signal-to-noise ratio from the substrate on the spin measurements of the nitrogen-vacancy (NV) center. Moreover, the microfabrication was improved to reach a higher angle of the pyramidal side plane, corresponding to the {111} facets. These improvements lead to pyramids on which each facet contains almost purely only one of the four possible NV orientations as shown by optically detected magnetic resonance (ODMR). ODMR shows a very high contrast of 19% without an external magnet and of 13% for a single spin resonance in the presence of a magnetic field. The contrast is more than doubled compared to our previous study. The T2* dephasing time of the NV centers of the samples ranges from 0.02 to 0.16 μs. The P1 center is a single substitutional nitrogen center, and the P1 densities range from 1.8 to 5 ppm.