A two-colour laser technique is developed for photodetachment microscopy, by means of microwave modulation of a CW single-mode dye laser. A phase modulation regime is achieved through an electro-optical LiNbO 3 crystal excited at the frequency 1.95 GHz. The two first sidebands created are selected by rejection of the other orders through a plane Fabry–Perot interferometer. With the resulting two-colour radiation, the photodetachment microscopy technique is applied to a beam of 32S − ions. It is shown that the superposition of the two resulting interference patterns can be used as a ‘spectral vernier’ to remove the uncertainty on the electric field and absolute energy scale. Without any initial assumption on the value F of the electric field in the laser-ion interaction region, a measure of F and of the electron affinity e A of Sulfur can be obtained. Putting 16 recordings of two-colour photodetachment interferograms together, with the only condition that F be the same for all experiments, one gets e A( 32S) = 16752.978(11) cm −1, which is quite compatible, even though not as accurate, with the most recently recommended value e A( 32S) = 16752.9760(42) cm −1. A proposal is made for going from an incoherent to a coherent two-colour photodetachment scheme, which would make photodetachment interferograms sensitive to a new degree of freedom.