A novel discharge splicing-free ultra-highly sensitive fiber-optic temperature sensor, based on polydimethylsiloxane (PMDS) and the Vernier effect, is constructed and experimentally validated. The sensor comprises single mode fiber (SMF), hollow core fiber (HCF), and PDMS. The Vernier effect is produced by the PDMS cavity and the mixed PDMS-air cavity during fabrication. By virtue of the Vernier effect and the temperature-sensitive material PDMS, this sensor shows an exceptionally high temperature sensitivity of −4.08658 nm/℃ while maintaining an outstanding linearity of 0.99972. The repeatability and stability have been demonstrated by subjecting the sensor to three cycles of heating and cooling, each with a 24-hour interval. Furthermore, experimental results indicate that the sensor exhibits excellent resistance to microvibrations and the interference occurs inside the structure, enabling its reliable operation in harsh environments without additional package. The miniature fiber temperature sensor is easily fabricated, highly sensitive, and demonstrates exceptional stability and repeatability, serving an ideal alternative for measuring temperature in challenging conditions.