Single Carbon Research Articles

Enhancing capacitance performance of functional group assisted carbon quantum dots derived from turmeric plant waste

Supercapacitors have attracted significant attention in modern devices as a promising solution for electrical energy storage due to their remarkable capability to undergo rapid charge and discharge cycles. While various materials are employed in the construction of supercapacitors, carbon-based materials emerge as a predominant choice within the commercial realm. In present report, our intention is to develop an effective supercapacitor device derived from natural biomass. Therefore, we have synthesized water soluble, monodisperse and fluorescent carbon quantum dots (CQDs) from turmeric leaves (Curcuma caesia) via a single step hydrothermal carbonization. Further, the doctor blade technique was employed to coat a layer of CQDs on stainless steel substrate using PVA as a binder. We observed the functional groups associated with QDs triggers the fast diffusion of ions and transmission of electrons with conducting substrate and electrolyte and thereby effectively charge and discharge mechanism. The supercapacitor based on carbon quantum dots (CQDs) based electrode exhibits exceptional performance characteristics with a remarkable specific capacitance of 468 F/g and highest energy density of 78.6 Wh/kg, superior to the values reported for most carbon-based supercapacitors. Further, we demonstrated the light dependent capacitive enhancement by depositing a thin P3HT layer over CQDs. Moreover, CQDs-based supercapacitor achieves a maximum power density of 733.2 W/kg when operated in a 1 M KOH electrolyte solution and an excellent capacitive retention of about 80 % even after 5000 cycles.

Co-expression analysis reveals distinct alliances around two carbon fixation pathways in hydrothermal vent symbionts

Most autotrophic organisms possess a single carbon fixation pathway. The chemoautotrophic symbionts of the hydrothermal vent tubeworm Riftia pachyptila, however, possess two functional pathways: the Calvin–Benson–Bassham (CBB) and the reductive tricarboxylic acid (rTCA) cycles. How these two pathways are coordinated is unknown. Here we measured net carbon fixation rates, transcriptional/metabolic responses and transcriptional co-expression patterns of Riftia pachyptila endosymbionts by incubating tubeworms collected from the East Pacific Rise at environmental pressures, temperature and geochemistry. Results showed that rTCA and CBB transcriptional patterns varied in response to different geochemical regimes and that each pathway is allied to specific metabolic processes; the rTCA is allied to hydrogenases and dissimilatory nitrate reduction, whereas the CBB is allied to sulfide oxidation and assimilatory nitrate reduction, suggesting distinctive yet complementary roles in metabolic function. Furthermore, our network analysis implicates the rTCA and a group 1e hydrogenase as key players in the physiological response to limitation of sulfide and oxygen. Net carbon fixation rates were also exemplary, and accordingly, we propose that co-activity of CBB and rTCA may be an adaptation for maintaining high carbon fixation rates, conferring a fitness advantage in dynamic vent environments.

Beyond methane, new frontiers in anaerobic microbial hydrocarbon utilizing pathways.

Alkanes, single carbon methane to long-chain hydrocarbons (e.g. hexadecane and tetradecane), are important carbon sources to anaerobic microbial communities. In anoxic environments, archaea are known to utilize and produce methane via the methyl-coenzyme M reductase enzyme (MCR). Recent explorations of new environments, like deep sea sediments, that have coupled metagenomics and cultivation experiments revealed divergent MCRs, also referred to as alkyl-coenzyme M reductases (ACRs) in archaea, with similar mechanisms as the C1 utilizing canonical MCR mechanism. These ACR enzymes have been shown to activate other alkanes such as ethane, propane and butane for subsequent degradation. The reversibility of canonical MCRs suggests that these non-methane-activating homologues (ACRs) might have similar reversibility, perhaps mediated by undiscovered lineages that produce alkanes under certain conditions. The discovery of these alternative alkane utilization pathways holds significant promise for a breadth of potential biotechnological applications in bioremediation, energy production and climate change mitigation.

Boron-manganese-nitrogen co-doped three-dimensional porous carbon realizes superior capacitive lithium-ion storage

Three-dimensional (3D) porous carbon has sufficient specific surface area and anchor positioning points. The pore structure facilitates uniform charge distribution, and buffers volume changes during stripping. However, single carbon materials have limited theoretical capacity and short cycle life. Here, 3D porous carbon material BCN/Mn-6 (B,N and Mn co-doped porous carbon with 6 mmol Mn content) co-doped with manganese, boron and nitrogen was synthesized by heat treatment. Affective modulation of the material structure and surface functional groups was achieved by adjusting the amount of manganese doping. The metal element doping can promote the diffusion of lithium ions, and the formed vacancies and defects can be used as lithium storage sites. Nitrogen doping can improve the dispersion and stability of metals and oxides, and regulate the redox capacity. Co-doping of metals and heteroatoms synergistically improves electrical conductivity. Thus, BCN/Mn-6 exhibits excellent cycling stability (99.60 % Coulombic efficiency after 300 cycles) and specific capacity (779.9 mAh/g), and shows capacity rise. This study provides a new direction for the preparation of carbon-based electrode materials doped with heteroatoms and the study of capacitive energy storage mechanisms.

Characterization of the surface-active exopolysaccharide produced by Halomonas sp TGOS-10: Understanding its role in the formation of marine oil snow.

In this study, we characterize the exopolymer produced by Halomonas sp. strain TGOS-10 -one of the organisms found enriched in sea surface oil slicks during the Deepwater Horizon oil spill. The polymer was produced during the early stationary phase of growth in Zobell's 2216 marine medium amended with glucose. Chemical and proton NMR analysis showed it to be a relatively monodisperse, high-molecular-mass (6,440,000 g/mol) glycoprotein composed largely of protein (46.6% of total dry weight of polymer). The monosaccharide composition of the polymer is typical to that of other marine bacterial exopolymers which are generally rich in hexoses, with the notable exception that it contained mannose (commonly found in yeast) as a major monosaccharide. The polymer was found to act as an oil dispersant based on its ability to effectively emulsify pure and complex oils into stable oil emulsions-a function we suspect to be conferred by the high protein content and high ratio of total hydrophobic nonpolar to polar amino acids (52.7:11.2) of the polymer. The polymer's chemical composition, which is akin to that of other marine exopolymers also having a high protein-to-carbohydrate (P/C) content, and which have been shown to effect the rapid and non-ionic aggregation of marine gels, appears indicative of effecting marine oil snow (MOS) formation. We previously reported the strain capable of utilising aromatic hydrocarbons when supplied as single carbon sources. However, here we did not detect biodegradation of these chemicals within a complex (surrogate Macondo) oil, suggesting that the observed enrichment of this organism during the Deepwater Horizon spill may be explained by factors related to substrate availability and competition within the complex and dynamic microbial communities that were continuously evolving during that spill.

Programmable quantum emitter formation in silicon.

Silicon-based quantum emitters are candidates for large-scale qubit integration due to their single-photon emission properties and potential for spin-photon interfaces with long spin coherence times. Here, we demonstrate local writing and erasing of selected light-emitting defects using femtosecond laser pulses in combination with hydrogen-based defect activation and passivation at a single center level. By choosing forming gas (N2/H2) during thermal annealing of carbon-implanted silicon, we can select the formation of a series of hydrogen and carbon-related quantum emitters, including T and Ci centers while passivating the more common G-centers. The Ci center is a telecom S-band emitter with promising optical and spin properties that consists of a single interstitial carbon atom in the silicon lattice. Density functional theory calculations show that the Ci center brightness is enhanced by several orders of magnitude in the presence of hydrogen. Fs-laser pulses locally affect the passivation or activation of quantum emitters with hydrogen for programmable formation of selected quantum emitters.

Impedimetric Single Carbon Fiber Electrode for Ultrasensitive Detection of Staphylococcus aureus Pathogen DNAs in Breast Milk by CRISPR Technology.

This study introduces a novel biosensing approach for the detection of pathogen DNA in breast milk utilizing single carbon fiber electrodes (SCFE) enhanced with MXene nanomaterial layers. The primary innovation lies in the modification of SCFE with MXenes to increase the electrode's surface area, followed by surface activation for the immobilization of dCas9-sgRNA complexes. This modification aims to leverage the unique properties of MXenes and the selective binding capability of the CRISPR technology for efficient and specific pathogen detection. Electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) analyses were employed to characterize the electrode modifications and the immobilization process, demonstrating the successful enhancement of biosensor performance. This study further optimized the chronoimpedimetric detection method to achieve rapid, sensitive, and selective detection of Staphylococcus aureus (SAu) DNA in breast milk, with a notable detection time of 60 s in real samples. The biosensor demonstrated high selectivity and sensitivity, with a linear detection range between 50 and 6000 fM and a limit of detection (LOD) of 14.5 fM. The reproducibility and stability of the biosensor were also confirmed through multiple tests, showing promising potential for clinical and public health applications.

Cation Effects on the Adsorbed Intermediates of CO2 Electroreduction Are Systematic and Predictable.

The electrode-electrolyte interface, and in particular the nature of the cation, has considerable effects on the activity and product selectivity of the electrochemical reduction of CO2. Therefore, to improve the electrocatalysis of this challenging reaction, it is paramount to ascertain whether cation effects on adsorbed intermediates are systematic. Here, DFT calculations are used to show that the effects of K+, Na+, and Mg2+, on single carbon CO2 reduction intermediates can either be stabilizing or destabilizing depending on the metal and the adsorbate. Because systematic trends are observed, cation effects can be accurately predicted in simple terms for a wide variety of metals, cations and adsorbed species. These results are then applied to the reduction of CO2 to CO on four different catalytic surfaces (Au, Ag, Cu, Pd) and activation of weak-binding metals is consistently observed by virtue of the stabilization of the key intermediate *COOH.

Implementation of bio-inspired organic/inorganic layer structures as interphase in carbon fiber reinforced concrete

Biological materials found in nacre or glass sponges reveal specific layered organic and inorganic structures known for their fracture toughness caused by crack deflection and bridging. This work aims to bio-mimic the brick-and-mortar (BnM) structure from nacre and the layer-by-layer (LbL) structure from the glass sponge filaments to incorporate these effects into the contact zone of carbon fiber-reinforced concrete (CFRC) in order to prevent brittle composite failure. To build up BnM- and LbL-structure materials such as nanoclays, sodium water glass, and polymer dispersions were selected since they are well-established low-cost materials in building. Nanoclays were analyzed regarding their size, dispersibility and exfoliation. Montmorillonite (MMT) was used to be mixed with polymers to produce self-assembled BnM-structured films and coatings. Also, LbL-structures were formed by alternating layers of sodium water glass and polymer. Scanning electron microscopy and energy-dispersive X-ray spectroscopy were used to verify the morphology. The MMT-containing coatings demonstrated enhanced nucleation potential when exposed to cementitious eluate. Micromechanical pull-out tests on single carbon fibers with BnM- and LbL-coatings embedded in concrete demonstrate the potential to increase composite toughness. The successful implementation of the bio-inspired structures using affordable materials lays the groundwork for their scalability and integration into composite structures for building.

Field-Emission Energy Distribution of Carbon Nanotube Film and Single Tube under High Current.

A narrow energy distribution is a prominent characteristic of field-emission cold cathodes. When applied in a vacuum electronic device, the cold cathode is fabricated over a large area and works under a high current and current density. It is interesting to see the energy distribution of the field emitter under such a working situation. In this work, the energy distribution spectra of a single carbon nanotube (CNT) and a CNT film were investigated across a range of currents, spanning from low to high. A consistent result indicated that, at low current emission, the CNT film (area: 0.585 mm2) exhibited a narrow electron energy distribution as small as 0.5 eV, similar to that of a single CNT, while the energy distribution broadened with increased current and voltage, accompanied by a peak position shift. The influencing factors related to the electric field, Joule heating, Coulomb interaction, and emission site over a large area were discussed to elucidate the underlying mechanism. The results provide guidance for the electron source application of nano-materials in cold cathode devices.

Probing the Thermoelectricity in Single Carbon Nanocoil for the Design of a Nano Thermocouple

Probing the Thermoelectricity in Single Carbon Nanocoil for the Design of a Nano Thermocouple

Position-specific carbon stable isotope analysis of glyphosate: isotope fingerprinting of molecules within a mixture.

Glyphosate [N-(phosphonomethyl) glycine] is a widely used herbicide and a molecule of interest in the environmental sciences, due to its global use in agriculture and its potential impact on ecosystems. This study presents the first position-specific carbon isotope (13C/12C) analyses of glyphosates from multiple sources. In contrast to traditional isotope ratio mass spectrometry (IRMS), position-specific analysis provides 13C/12C ratios at individual carbon atom positions within a molecule, rather than an average carbon isotope ratio across a mixture or a specific compound. In this work, glyphosate in commercial herbicides was analyzed with only minimal purification, using a nuclear magnetic resonance (NMR) spectroscopy method that detects 1H nuclei with bonds to either 13C or 12C, and isolates the signals of interest from other signals in the mixture. Results demonstrate that glyphosate from different sources can have significantly different intramolecular 13C/12C distributions, which were found to be spread over a wide range, with δ13C Vienna Peedee Belemnite (VPDB) values of -28.7 to -57.9‰. In each glyphosate, the carbon with a bond to the phosphorus atom was found to be depleted in 13C compared to the carbon at the C2 position, by 4 to 10‰. Aminomethylphosphonic acid (AMPA) was analyzed for method validation; AMPA contains only a single carbon position, so the 13C/12C results provided by the NMR method could be directly compared with traditional isotope ratio mass spectrometry. The glyphosate mixtures were also analyzed by IRMS to obtain their average 13C/12C ratios, for comparison with our position-specific results. This comparison revealed that the IRMS results significantly disguise the intramolecular isotope distribution. Finally, we introduce a 31P NMR method that can provide a position-specific 13C/12C ratio for carbon positions with a C-P chemical bond, and the results obtained by 1H and 31P for C3 carbon agree with one another within their analytical uncertainty. These analytical tools for position-specific carbon isotope analysis permit the isotopic fingerprinting of target molecules within a mixture, with potential applications in a range of fields, including the environmental sciences and chemical forensics.

Magnetohydrodynamic Casson SWCNT-MWCNT/EG hybrid nanofluid flow over a stretching cylinder with Cattaneo-Christov double diffusion model

The present problem examines the flow features of a two-dimensional time-independent Casson hybrid nanofluid on a stretching cylinder with dual stratification and MHD effects. Heat and mass transfer effects are analyzed by utilizing the Cattaneo-Christov double diffusion scheme with entropy generation. Further, the energy losses due to viscous and Joulian dissipation are also considered in the problem. Due to the high thermal conductivity nature of the carbon nanotubes, which plays a crucial role in cooling systems, material sciences, electrical components and treatment of cancer cells, single and multi-walled carbon nanotube particles (SWCNT, MWCNT) are considered in the hybrid nanofluid. The carbon nanotubes are mixed with base fluid ethylene glycol (EG) to form the required hybrid nanofluid. Suitable transformations are adopted for transforming the non-linear PDEs to non-linear ODEs of the mathematical model. Then, the system of ODEs are resolved by utilizing bvp4c numerical approach in MATLAB software. The impact of the various flow pertinent parameters on the flow model are disclosed through graphs and tables and then explained elaborately. The important findings of the study reveal a reduction in the absolute value of coefficient of surface friction with the Casson and velocity slip parameters. The entropy generation rate (NG ) is diminished due to slip parameters, whereas the opposite effect is observed due to the SWCNT nanoparticle volume fraction. The thermal and mass relaxation parameters induce a significant amplification in the rates of heat and mass transport, respectively. Furthermore, it is observed that the heat and mass transfer rates of EG-based SWCNT – MWCNT hybrid nanofluid perform better than those of EG-based SWCNT nanofluid. The outcomes of the investigation exhibit an excellent agreement with the previously published results. The present analysis has applications in cancer therapy, microelectronics cooling, industrial heat generators, nuclear reactor maintenance, electrolytic condensers, and many more.

Experimental analysis of 3D printed continuous carbon/glass hybrid fiber reinforced PLA composites: Revealing synergistic mechanical properties and failure mechanisms

AbstractThis study investigates the mechanical properties of continuous carbon/glass hybrid fiber‐reinforced polylactic acid (PLA) composites (HFRC) produced through the three dimensions (3D) printing process, comparing them with single carbon fiber‐reinforced PLA composites (CFRC). Initially, composite prepreg filaments are prepared using an impregnation device, followed by fabrication using a 3D printer. The mechanical performance results reveal a 13% increase in tensile strength for HFRC compared with CFRC. Due to differing elongation rates of carbon and glass fibers, HFRC exhibits two strength peaks, while CFRC demonstrates a 37% higher bending strength than HFRC. Scanning electron microscope images indicate that the tensile failure mechanism involves fiber brittle fracture and fiber‐matrix interface debonding, while the bending failure mechanism includes fiber pullout, fiber debonding, fiber cluster buckling, and interlayer interface failure.Highlights To realize the moldless rapid manufacturing of continuous hybrid fiber‐reinforced PLA composites. The stress–strain curves of single fiber‐reinforced composites and hybrid fiber‐reinforced composites are obviously different. Elucidating the effect of single fiber/hybrid fiber in composites on mechanical properties and failure mechanism according to micro‐morphology.

Synergistic interactions between lignite and biomass during co-pyrolysis from volatile release, kinetics, and char structure

One of the most efficient techniques to achieve efficient utilization of both is coal and biomass co-pyrolysis. Despite a great deal of recent research on the co-pyrolysis process, it is still unknown how biomass affects the co-pyrolysis's synergistic effect and how volatiles interact. This study uses a thermogravimetric analyzer to examine the weight loss law of co-pyrolysis of wheat straw, rice straw, and bamboo powder with various amounts of Zhundong coal. According to the findings, there is a strong positive interaction, a mild positive interaction, and a negative interaction when three different types of biomass (wheat straw, rice straw, bamboo straw) are co-pyrolysis with Zhundong coal. The interaction between wheat straw and Zhundong coal is the strongest when the mass ratio of wheat straw to Zhundong coal is 6: 4. Using a thermogravimetric-infrared spectrometer, the changes in volatile functional groups during co-pyrolysis are investigated. It is discovered that adding wheat straw decreased the amount of CO2 produced by Zhundong coal pyrolysis. Regarding the mechanism of co-pyrolysis, the alkali and alkaline earth metals (AAEMs) on the surface of biochar catalyze the pyrolysis of Zhundong coal, while the “hydrogen donor” and “free radical donor” generated by biomass pyrolysis inhibited the cross-linking and polymerization of macromolecular volatiles produced by Zhundong coal pyrolysis. The activation energy of the mass ratio of wheat straw to Zhundong coal = 6: 4 sample is calculated by three model-free methods. The co-pyrolysis process's average activation energy is determined to be between 175.95 and 194.18 kJ/mol. Through scanning electron microscopy, it is found that the morphology of co-pyrolysis carbon is significantly different from that of single pyrolysis carbon. The porous structure of biochar promotes the secondary cracking of heavy volatiles produced by coal pyrolysis, while the cracking of volatiles further promotes the development of the pore structure of biochar.

Flow of magnetohydrodynamic blood-based hybrid nanofluids with double diffusion in the presence of Riga plate for heat optimization and drug applications

In a recent study, researchers investigated the flow behavior of Casson Hybrid nanofluids (HNFs) combination of single and multi-walled carbon nanotubes (SWCNTs), (MWCNTs) on a Riga plate for drug delivery applications. The study found that the Casson HNFs exhibited non-Newtonian behavior on the Riga plate, with the presence of nanoparticles causing an increase in viscosity and shear-thinning behavior. This rheological behavior is favorable for drug delivery applications as it improves the stability and dispersion of drug particles in the fluid. The similarity equations of the flow problem are easily tackled with the homotopy analysis method (HAM) built on fundamental homotopy mapping. In high-speed flows, Riga actuators are expected to achieve the requirements, since HNF is enhanced by modified Hartmann numbers. As the Eckert number, heat generation/absorption parameter, and thermal relaxation time parameter decrease the temperature, thermal transport increases. Furthermore, with the increments in paramount parameters, the skin friction coefficient and heat transfer rate are remarkably meliorated under higher modified Hartmann number. Furthermore, the study also found that the Casson Hybrid nanofluids showed enhanced heat transfer properties on the Riga plate, which is beneficial for localized drug delivery applications that require precise temperature control.

A new method of estimating shelterbelt carbon storage on the regional scale: Combined the single tree carbon storage with tree numbers

The carbon storage potential of planted shelterbelts was gradually recognized in recent years, but there was a lack of shelterbelt knowledge for carbon inventory analyses because of their narrow linear feature and extensive distribution. Considering its own characteristics of the shelterbelt, this paper proposed a new remote sensing model for estimating the carbon storage of farmland shelterbelt (CSBelt) based on the single tree carbon storage and tree numbers. In this model, the single tree carbon storage model was established by shelterbelt age, which could be identified from time series images. Tree numbers of each shelterbelt, as another important parameter in the CSBelt model, was detected by numbers of rows, columns, and preservation rate, which were monitored by high resolution remote sensing image and geographic information system method. Finally, overall accuracy (OA), mean absolute error (MAE), and mean error (ME) was used to validate the remotely identified data. The results showed that, the OA of the single tree carbon storage was 80.4% within the error range of 0.05 MgC/tree, the MAE was 0.036 MgC/tree, and ME was 0.020 MgC/tree; the OA of tree numbers was 71.7% within the error range of 100 trees/km, the MAE was 94 trees/km, and ME was 73 trees/km; the OA of shelterbelt carbon storage was 82.6% within the error range of 100 MgC/km, the MAE was 49.63 MgC/km, and ME was 33.78 MgC/km. Compared to other carbon storage models, this model requires fewer parameters and is not restricted by the stand conditions, which has better universality and realizability. This research is helpful for the accurate assessment of shelterbelt ecosystem carbon storage, which is of great significance for predicting climate change and formulating strategies. The results of this research will also provide data support for shelterbelt management on a regional scale.

(Bio)electrochemical system: A systematic approach from agricultural waste to sewage wastewater treatment with nutrients and hydrogen recovery

Sustainable biowaste utilization is currently an interesting research area to enhance its conversion to value-added products. Electrochemical and bioelectrochemical technologies are cracking up the fractionization of various types of waste for environmental cleanup processes. In the present study, agricultural waste-based extracted material was used to capture the nutrients and/or pollutants from the anaerobic bioelectrochemically treated sewage wastewater (SWW). Hydrogen production potential of 15.52–11.77 times higher than the single carbon source indicated efficient utilization of organic and inorganic matters by extant microorganisms in the SWW. The electrochemical hemicellulose (HC) extraction, nutrient recovery and other components like applied potential (mV), NaOH (M) and rice straw load (%) analysis were evaluated at three factors and three levels. The N/C ratio of 0.06 and the highest functionalities in the 150-mV extracted HC, confirm its suitability to trap nutrients/pollutants from wastewater. With the potential to substitute expensive adsorbents in the future, the additional advantage of HCs being useful in the recovery of ammonium ions for use in agriculture could positively impact the global food security program. The aim of the study is not only the recovery of nutrients from waste but also to unravel the clean path of waste management with possible green energy production.

Increasing single households challenges household decarbonization in Japan

In light of societal shifts such as an aging population, delayed marriages, and higher rates of divorce, there's a notable rise in solitary living, affecting society, the economy, and the environment. To understand the implications of these demographic shifts, our research examines the nexus between solo living and its broader social-environmental consequences. Using Japan, one of the countries with the highest proportion of the elderly, as a reference, we explore the temporal fluctuations, gender-specific variances, and long-term trends in carbon footprints influenced by alterations in consumption behaviors. Results indicate that housing energy and food consumption remain the dominant carbon footprint contributors across all demographic sectors. Interestingly, single households present higher carbon footprints than non-single households, with those of single females surpassing their male counterparts due to increased household energy use and expenditures on clothing and healthcare. Following the demographic shifts, single households are expected to account for approximately 31.1% of Japan's emissions from households by 2040, challenging national decarbonization efforts due to their higher per capita emissions. This highlights the imperative for bespoke strategies, especially in resource allocation and sharing, to address the solo living challenge and ensure congruence with Japan's sustainability and decarbonization goals.

Construction of multileveled and oriented micro/nano channels in Mg doped hydroxyapitite bioceramics and their effect on mimicking mechanical property of cortical bone and biological performance of cancellous bone

Drawing on the structure and components of natural bone, this study developed Mg-doped hydroxyapatite (Mg-HA) bioceramics, characterized by multileveled and oriented micro/nano channels. These channels play a critical role in ensuring both mechanical and biological properties, making bioceramics suitable for various bone defects, particularly those bearing loads. Bioceramics feature uniformly distributed nanogrooves along the microchannels. The compressive strength or fracture toughness of the Mg-HA bioceramics with micro/nano channels formed by single carbon nanotube/carbon fiber (CNT/CF) (Mg-HA(05-CNT/CF)) are comparable to those of cortical bone, attributed to a combination of strengthened compact walls and microchannels, along with a toughening mechanism involving crack pinning and deflection at nanogroove intersections. The introduction of uniform nanogrooves also enhanced the porosity by 35.4 %, while maintaining high permeability owing to the capillary action in the oriented channels. This leads to superior degradation properties, protein adsorption, and in vivo osteogenesis compared with bioceramics with only microchannels. Mg-HA(05-CNT/CF) exhibited not only high strength and toughness comparable to cortical bone, but also permeability similar to cancellous bone, enhanced cell activity, and excellent osteogenic properties. This study presents a novel approach to address the global challenge of applying HA-based bioceramics to load-bearing bone defects, potentially revolutionizing their application in tissue engineering.