Single Atomic Layer Research Articles

Robustness of large-area suspended graphene under interaction with intense laser

Graphene is known as an atomically thin, transparent, highly electrically and thermally conductive, light-weight, and the strongest 2D material. We investigate disruptive application of graphene as a target of laser-driven ion acceleration. We develop large-area suspended graphene (LSG) and by transferring graphene layer by layer we control the thickness with precision down to a single atomic layer. Direct irradiations of the LSG targets generate MeV protons and carbons from sub-relativistic to relativistic laser intensities from low contrast to high contrast conditions without plasma mirror, evidently showing the durability of graphene.

Nonadiabatic quantum control of valley states in silicon

Non-adiabatic quantum effects, often experimentally observed in semiconductors nano-devices such as single-electron pumps operating at high frequencies, can result in undesirable and uncontrollable behaviour. However, when combined with the valley degree of freedom inherent to silicon, these unfavourable effects may be leveraged for quantum information processing schemes. By using an explicit time evolution of the Schrodinger equation, we study numerically non-adiabatic transitions between the two lowest valley states of an electron in a quantum dot formed in a SiGe/Si heterostructure. The presence of a single atomic layer step at the top SiGe/Si interface opens an anti-crossing in the electronic spectrum as the centre of the quantum dot is varied. We show that an electric field applied perpendicularly to the interface allows tuning of the anti-crossing energy gap. As a result, by moving the electron through this anti-crossing, and by electrically varying the energy gap, it is possible to electrically control the probabilities of the two lowest valley states.

Tuning Ferromagnetism in a Single Layer of Fe above Room Temperature.

The crystallographic and magnetic properties of an Fe monolayer (ML) grown on 2 ML Au/W(110) substrate are studied with spin-polarized low-energy electron microscopy, density functional theory, and relativistic screened Korringa–Kohn–Rostoker calculations. The single layer of iron atoms possesses hexagonal symmetry and reveals a ferromagnetic order at room temperature. We experimentally demonstrate the possibility of tuning the Curie temperature and the magnitude of magnetization of the Fe monolayer by capping with Au. Taking into account several structural models, the calculation results mostly show ferromagnetic states with enhanced magnetic moments of Fe atoms compared to their bulk value and a further increase in their value after covering with Au. The theoretically calculated Curie temperatures are in fair agreement with those obtained in the experiments. The calculations, furthermore, found evidence for the presence of frustrated isotropic Fe–Fe exchange interactions, and a discussion of the structural effects on the magnetic properties is provided herein.

A review on electro-mechanical properties of solar photovoltaic panels with graphene material

The global power demand was increasing rapidly, one of the most important global problems are Electricity demand and Energy-related CO2 emissions. World countries now focus on mass energy production in clean and green manner. So now world turned into solar power generation. It preserves natural resources and controls the environment problems. But normal solar panel have lot of issues like less efficient, land requirements, etc. silicon play major roll in PV panels manufacturing,but it cost is lightly high, efficient of power conversion is less,material strength is low and important thing is silicon is non flexible. Therefore, the PV industry wants one master material that replaces the silicon. That master materialise Graphene. Graphene is single layer (monolayer) of carbon atoms (oneallotropeofcarbon). It is thinnest material with one atom thickness and stronger than steel. 2Dmaterial and transparent, also grapheme have high electrical and thermal conductivity, low resistance. So overall efficiency of the graphene solar panel is greater than silicon or other normal solar panels. Graphene is carbon-based element, so it is eco-friendly element.

Flexoelectric effect of perovskite superlattice SrTiO<sub>3</sub>/BaTiO<sub>3</sub>

The flexoelectric effect describes the coupling of polarization to strain gradient, which has increasingly attracted interest in perovskite oxide materials. The perovskite oxide superlattice containing epitaxial relaxation or intrinsic surface tension or curvature, together with its high dielectric constant, is a highly desirable candidate for high flexoelectricity. In this work, the flexoelectric coefficients of <sup>1</sup>SrTiO<sub>3</sub>/<sup>1</sup>BaTiO<sub>3</sub> superlattice, which is composed of alternating single atomic layers of SrTiO<sub>3</sub> and BaTiO<sub>3</sub>, are systematically investigated with first principle density functional theory calculations. Various supercell sizes are used to minimize the discrepancy between the gradient values of the fixed atoms and relaxed atoms. It is found that the strain gradients of the constrained <i>A</i>-site atoms and the relaxed <i>B</i>-site atoms are almost the same when the supercell sizes are 1×1×24 for longitudinal flexoelectric coefficient, 7×1×16 for transverse flexoelectric coefficient and 3×1×28 for shear flexoelectric coefficient. Calculation results demonstrate that the transverse flexoelectric coefficient and shear flexoelectric coefficient of <sup>1</sup>SrTiO<sub>3</sub>/<sup>1</sup>BaTiO<sub>3</sub> superlattice are about one order of magnitude larger than its longitudinal flexoelectric coefficient. Even though its longitudinal flexoelectric coefficient decreases slightly compared with its constituent compounds, both transverse coefficient and shear flexoelectric coefficient are about several times higher than the counterparts of its constituent compounds, respectively. Hence, the overall flexoelectric coefficient of <sup>1</sup>SrTiO<sub>3</sub>/<sup>1</sup>BaTiO<sub>3</sub> superlattice is enhanced several times in magnitude. There exist a large number of interfaces inside the perovskite oxide superlattice with alternating single atomic layers of SrTiO<sub>3</sub> and BaTiO<sub>3</sub>, which potentially stimulate the redistribution of charge carriers, orbitals and spins of the atoms at the interface and promote the interfacial strain gradient. The stacking order of the superlattice atoms has a profound influence on the flexoelectric properties. These studies present an alternative approach to fabricating better flexoelectric materials for the applications of electromechanical equipment.

Retracted] Garment Digital Design Method Oriented to the Production Process of Graphene‐Modified Nylon Knitted Fabric

Graphene is a single‐atom‐thick layer of carbon atoms, the thinnest material ever discovered. The special single atomic layer structure of graphene makes it have many unique physical and chemical properties, and these excellent properties make graphene have a bright application prospect in the field of composite materials. The use of modern digital production technology to coordinate the management of various production departments of an enterprise can greatly reduce the input of human resources and improve the utilization of materials and equipment resources. In the process of caprolactam monomer polymerization, adding filler is a common method to strengthen and toughen nylon. The main fillers are powder fillers and fibrous materials. In order to make the fillers denatured, the fillers are usually pretreated with a silane coupling agent before modification. This research mainly discusses the digital clothing design method oriented to the production process of graphene‐modified nylon knitted fabric. The color of graphene‐modified cotton fiber is gray and black. With the increase of graphene content, the color becomes darker. Graphene has become a hotspot in materials science due to its unique two‐dimensional crystal structure and excellent mechanical, thermal, and electrical properties. In this paper, the preparation and organic modification of graphene oxide and its application in cast nylon are mainly studied. Therefore, when designing graphene‐modified cotton fiber jacquard graphene knitted fabric, the color matching has certain restrictions. The shrinking is to reduce the friction between the fibers through the appropriate concentration of the shrinking agent and improve the stretching and shrinking ability of the wool fiber. The fabric feels plump after shrinking, forming fluff, and improving the warmth retention performance. Due to the different design of the veil material, ground yarn material, and organizational structure of the fabric sample, the basic parameters of the fabric are directly different. Therefore, first perform the width, density, areal density, thickness, and raw material content ratio of the blank sample of the fabric. And wait for testing. In order to realize the digitization of styles, this research has developed a drawing system, which provides a large number of drawing tools to enable designers to draw clothing styles more accurately. The system for digital realization consists of six parts, including desktop environment, drawing tools, linear settings, curve drawing, data storage, and user interface. There are a variety of curves to choose from in computer graphics. The B3 spline curve has become the first choice due to its smoothness, no Runge phenomenon, and few saved data. When the mass fraction of graphene‐modified nylon was reduced to 18%, the inhibitory rate of Staphylococcus aureus and Escherichia coli was still greater than 80%. Nylon/modified graphene oxide nanocomposites with different filler contents were prepared by in situ polymerization with modified graphite oxide as modified filler. The effects of modified graphene oxide on the mechanical properties, wear resistance, and thermal properties of the composites were investigated. This research will promote the development of a customized platform for apparel collaborative management.

Effect of single atomic layer graphene film on the thermal stability and hydrogen permeation of Pd-coated Nb composite membrane

Pd coated Nb-base composite membranes are preferable in the fields of hydrogen permeation. However, the rapid reduction of hydrogen permeability caused by high-temperature interfacial diffusion of Pd and Nb atoms hinders their large-scale application. In this paper, a single atomic layer graphene film was used for improving the thermal stability of a hydrogen-permeable composite membrane comprising a Pd coating on the Nb substrate. First, the graphene film was transferred onto the surface of the “clean” niobium substrate. Then a thin palladium coating was deposited on it by magnetron sputtering to form the niobium/graphene/palladium (Nb/Gr/Pd) composite membrane. The interfacial stability was evaluated in the temperature range of 673–973 K under vacuum, and the hydrogen permeation behavior was studied by gas-driven permeation method at 573–823 K. The results show that the single atomic layer graphene film can effectively compress the interdiffusion of Pd coating and Nb substrate and achieve a good hydrogen permeability below 823 K. However, it would be broken due to the micro-deformation of Nb substrate, the high mobility of Pd atoms, and the grain growth at a higher temperature. Therefore, it is concluded that the single atomic layer graphene film is unsuitable as an intermediate hindering layer for Nb-based hydrogen-permeable membranes.

Multiwavelength magnetic coding of helical luminescence in ferromagnetic 2D layered CrI3

SummaryTwo-dimensional (2D) van der Waals (vdW) ferromagnets have opened new avenues for manipulating spin at the limits of single or few atomic layers, and for creating unique magneto-exciton devices through the coupling of ferromagnetic (FM) orders and excitons. However, 2D vdW ferromagnets explored so far have rarely possessed exciton behaviors; to date, FM CrI3 have been revealed to show ligand-field photoluminescence correlated with FM ordering, but typically with a broad emission peak. Here, we report a straightforward approach to realize strong coupling of narrow helical emission and FM orders in CrI3 through microsphere cavity. The resonant whispering-gallery modes (WGM) of SiO2 microspheres cause strong oscillation helical emissions with a full width at half-maximum (FWHM) of ∼5 nm under continuous wave excitation. Reversible magnetic coding of helical luminescence is realized in the range of 950–1100 nm. This work enables numerous opportunities for creating magnetic encoding lasing for photonic integrated chips.

Intracellular nanoscale architecture as a master regulator of calcium carbonate crystallization in marine microalgae

Unicellular marine microalgae are responsible for one of the largest carbon sinks on Earth. This is in part due to intracellular formation of calcium carbonate scales termed coccoliths. Traditionally, the influence of changing environmental conditions on this process has been estimated using poorly constrained analogies to crystallization mechanisms in bulk solution, yielding ambiguous predictions. Here, we elucidated the intracellular nanoscale environment of coccolith formation in the model species Pleurochrysis carterae using cryoelectron tomography. By visualizing cells at various stages of the crystallization process, we reconstructed a timeline of coccolith development. The three-dimensional data portray the native-state structural details of coccolith formation, uncovering the crystallization mechanism, and how it is spatially and temporally controlled. Most strikingly, the developing crystals are only tens of nanometers away from delimiting membranes, resulting in a highly confined volume for crystal growth. We calculate that the number of soluble ions that can be found in such a minute volume at any given time point is less than the number needed to allow the growth of a single atomic layer of the crystal and that the uptake of single protons can markedly affect nominal pH values. In such extreme confinement, the crystallization process is expected to depend primarily on the regulation of ion fluxes by the living cell, and nominal ion concentrations, such as pH, become the result, rather than a driver, of the crystallization process. These findings call for a new perspective on coccolith formation that does not rely exclusively on solution chemistry.

Pb/NiSi[formula omitted] atomic sandwich on Si(111)

Atomic sandwich consisting of single atomic layers of Pb and NiSi2 has been grown on Si(111) and its structural, electronic and transport properties have been elucidated using a set of experimental techniques, scanning tunneling microscopy, angle-resolved photoelectron spectroscopy, in situtransport and magnetotransport measurements, and density functional theory calculations. The Pb layers incorporate around 1.1 monolayers of Pb and display a melt-like 1 × 1 structure at room temperature which crystallizes into the 7 × 7-R38.2∘ (i.e., (83−35)) and “21×39” (i.e., (4−157)) structures upon cooling to low temperatures. Electronic band structure of the Pb/NiSi2/Si(111) sandwich contains two bands associated with NiSi2 and two spin-split bands associated with Pb with minor hybridization of the electrons belonging to different layers. Concerning the transport properties at low temperatures, the sandwich demonstrates a high conductance but without clear indication on superconductivity.

Silicene-Based Spin Filter With High Spin-Polarization

In this article, for the first time, we propose a silicene-based spin filter having a TFET configuration. The device portrays a voltage-dependent spin polarization and achieves a “spin polarization” as high as 98% at a minimal “operating voltage” (0.35 V). The operation of the device is based on the “spin-polarized edge states” in a silicene nanoribbon. The “spin polarization” of the output current can be tuned by modifying the bandgap of the spin-up and spin-down states via an in-plane perpendicular “electric field” generated by two “lateral gates.” The device features high spin polarization apart from its expected integration with Si-based technology. The proposed device has a simple construction, wherein a single layer of Si atoms achieves such a high value of spin polarization at a minimal operating voltage. The operation of the proposed device is demonstrated by using the first-principles quantum transport simulations.

Direct methane activation by atomically thin platinum nanolayers on two-dimensional metal carbides

Efficient and direct conversion of methane to value-added products has been a long-term challenge in shale gas applications. Here, we show that atomically thin nanolayers of Pt with a single or double atomic layer thickness, supported on a two-dimensional molybdenum titanium carbide (MXene), catalyse non-oxidative coupling of methane to ethane/ethylene (C2). Kinetic and theoretical studies, combined with in-situ spectroscopic and microscopic characterizations, demonstrate that Pt nanolayers anchored at the hexagonal close-packed sites of the MXene support can activate the first C–H bond of methane to form methyl radicals that favour desorption over further dehydrogenation and thus suppress coke deposition. At 750 °C and 7% methane conversion, the catalyst runs for 72 hours of continuous operation without deactivation and exhibits >98% selectivity towards C2 products, with a turnover frequency of 0.2–0.6 s−1. Our findings provide insights into the design of highly active and stable catalysts for methane activation and create a platform for developing atomically thin supported metal catalysts. The challenge in non-oxidative coupling of methane lies in the activation of the first C–H bond while avoiding further dehydrogenations, which lead to the formation of coke. Here, atomically thin platinum nanolayers on two-dimensional molybdenum titanium carbides are reported as a superior catalyst for this reaction owing to reduced coke formation.

Atomistic modeling to predict and improve the strength of doped Sn-Cu solder interfaces

Abstract The reliability of solder joints depends upon the strength of the interface where two materials are joined. The strengthening of solder joints has been routinely achieved via doping with other elements, though this is not yet well understood at a fundamental level, and typically accomplished by trial and error. In the present work, we have used atomistic modeling based on density functional theory (DFT) and ab initio molecular dynamics (AIMD) to study the mechanical strength of the Sn-Cu interface under various conditions. We have investigated the cleavage energy (CE) of the Sn-Cu interface, and how it changes with various dopants (Ag, Au, Bi, Cu, Ni, Zn) to determine the benefit (or detriment) to the strength of this simulated solder joint. We have also tested multiple faces of Sn ([001], [100] and [110]) as potential interfaces with Cu. Our simulations show that each of the dopants considered, except for Bi, increases the strength of the interface. In all our constructed Sn-Bi interfaces, a single atomic layer of Sn atoms deposits on the Cu and binds strongly to it. The weakest point of the interface is located between the deposited Sn layer and the remaining bulk Sn. For the undoped [001] Sn-Cu system, the cleavage energy between the Sn and Cu layers is 1.63 J/m2, whereas the cleavage energy between the deposited layer of Sn and the remaining Sn bulk is considerably lower: 0.54 J/m2; this is likely the location of joint failure, and the focus of our investigation. We observed this trend in each interface that we studied. As expected, the strength of the Sn-Cu interface can be modified with dopants; the CE of the weakest point can be increased (strengthening it) by 0.1–0.2 J/m2 when doping it with Ag, Au, Cu, Ni and Zn, though Bi results in a decrease (weakening it) by 0.15 J/m2. As a complementary method for investigating this interface, we have used AIMD to simulate a mechanically controlled break junction (MCBJ) of the solder interface by gradually increasing the separation between the two ends of the simulated junction. The process is continued until the junction completely breaks, yielding an energy vs. distance curve, which provides information about the strength of the solder joint that is similar to a stress-strain curve. We observe that, as the Sn is moved away from the Cu, there is a relatively steady increase in energy until the system begins to separate. From this separation point, the energy curve plateaus as the interaction between the two halves of the system vanishes. The location of the breaking point is in excellent accordance with our CE calculations; there is also a correlation between the CE and the amount of distance that the system must be stretched before reaching the breaking point. Furthermore, we have adapted the MCBJ method in AIMD to simulate shearing of the Sn-Cu interface. In these simulations, as opposed to moving Sn atoms away from the Cu atoms perpendicularly to the interface, we are sliding the Sn atoms laterally across the interface relative to the Cu atoms. The deposited Sn layer remains strongly bonded to the Cu surface, with most of the shearing occurring inside the bulk Sn region. The first principles nature of the methods employed makes them highly transferable and applicable to any chemical composition. These atomistic simulations provide valuable insights that can be used to design stronger solder joints based on physical understanding.

Progress in non-noble metal oxygen reduction electrocatalysts based on MOFs

<p indent=0mm>Proton exchange membrane fuel cells (PEMFCs) are favored in the field of new energy vehicles because of their cleanliness, high efficiency, quietness, high power density, low operating temperature, fast start-up and power matching. With the realization of mass production of fuel cell vehicles in many countries in the world in recent years, its large-scale promotion is imperative. However, the PEMFC cathode uses a high-load platinum (Pt)-based catalyst, which has greatly hindered the commercialization of fuel cell vehicles because of high cost. Pt is the most effective electrocatalyst for the low-temperature fuel cell cathode oxygen reduction reaction (ORR). On one hand, it can greatly reduce the amount of Pt through alloying and single-atom layer design. On the other hand, it can develop alternative high-activity and high-stability non-noble metals. The catalyst process is considered the ultimate solution. Among the many types of non-noble metal catalysts, the ORR activity and lifetime of the carbon-nitrogen-transition metal series non-noble metal catalysts are particularly worthy of attention. Non-precious metal ORR electrocatalysts based on metal organic framework materials (MOFs) have been extensively studied for their excellent properties. This paper introduces the characteristics and advantages of MOFs materials in detail and reviews the research status of carbon-nitrogen-transition metal ORR electrocatalysts based on MOFs materials at home and abroad in recent years, including Fe-based MOFs catalysts, Co-based MOFs catalysts, and bimetal MOFs catalysts. It also analyzes and forecasts the bottlenecks and challenges encountered in the research. In the future, we need to conduct in-depth research on the activity and stability of membrane electrodes.

Magnetic enhancement and nitriding process of Fe atomic layers on Si 111-7 × 7-CH3OH surface

Aim to greatly enhance the magnetic performance, room temperature nitriding experiments were implemented on the existing linear Fe clusters. Firstly, the dissociation of CH3OH adsorption process was deducted in detail, which laid a good foundation for the better use of surface quasi-potential. Further to solve the coming problems like weak linearity and low nitriding effect, atomic layers of Fe deposition are confirmed as the key to NH3 dissociation process (at room temperature). Specifically, the higher Fe atomic layer contacted by NH3, the weaker influence of surface quasi-potential. With the introduction of Ar, Fe cluster structure could be precisely controlled at single atomic layer, result in good NH3 dissociation and nitriding efficiency. Combining with magnetic performance result, the density of residual magnetization is improved from 1.5E−0.5 emu to 7.0E−0.5 emu, forming an obvious linear structure.

Borophene synthesis beyond the single-atomic-layer limit.

Synthetic two-dimensional (2D) materials have no bulk counterparts and typically exist as single atomic layers due to substrate-stabilized growth. Multilayer formation, although broadly sought for structure and property tuning, has not yet been achieved in the case of synthetic 2D boron: that is, borophene1,2. Here, we experimentally demonstrate the synthesis of an atomically well-defined borophene polymorph beyond the single-atomic-layer (SL) limit. The structure of this bilayer (BL) borophene is consistent with two covalently bonded α-phase layers (termed BL-α borophene) as evidenced from bond-resolved scanning tunnelling microscopy, non-contact atomic force microscopy and density functional theory calculations. While the electronic density of states near the Fermi level of BL-α borophene is similar to SL borophene polymorphs, field-emission resonance spectroscopy reveals distinct interfacial charge transfer doping and a heightened local work function exceeding 5 eV. The extension of borophene polymorphs beyond the SL limit significantly expands the phase space for boron-based nanomaterials.

Few-layer antimonene electrical properties

Antimonene -a single layer of antimony atoms- and its few layer forms are among the latest additions to the 2D mono-elemental materials family. Numerous predictions and experimental evidence of its remarkable properties including (opto)electronic, energetic or biomedical, among others, together with its robustness under ambient conditions, have attracted the attention of the scientific community. However, experimental evidence of its electrical properties is still lacking. Here, we characterized the electronic properties of mechanically exfoliated flakes of few-layer (FL) antimonene of different thicknesses (∼ 2–40 nm) through photoemission electron microscopy, kelvin probe force microscopy and transport measurements, which allows us to estimate a sheet resistance of ∼ 1200 Ω sq−1 and a mobility of ∼ 150 cm2V−1s−1 in ambient conditions, independent of the flake thickness. Alternatively, our theoretical calculations indicate that topologically protected surface states (TPSS) should play a key role in the electronic properties of FL antimonene, which supports our experimental findings. We anticipate our work will trigger further experimental studies on TPSS in FL antimonene thanks to its simple structure and significant stability in ambient environments.

Designing artificial two-dimensional landscapes via atomic-layer substitution

Technology advancements in history have often been propelled by material innovations. In recent years, two-dimensional (2D) materials have attracted substantial interest as an ideal platform to construct atomic-level material architectures. In this work, we design a reaction pathway steered in a very different energy landscape, in contrast to typical thermal chemical vapor deposition method in high temperature, to enable room-temperature atomic-layer substitution (RT-ALS). First-principle calculations elucidate how the RT-ALS process is overall exothermic in energy and only has a small reaction barrier, facilitating the reaction to occur at room temperature. As a result, a variety of Janus monolayer transition metal dichalcogenides with vertical dipole could be universally realized. In particular, the RT-ALS strategy can be combined with lithography and flip-transfer to enable programmable in-plane multiheterostructures with different out-of-plane crystal symmetry and electric polarization. Various characterizations have confirmed the fidelity of the precise single atomic layer conversion. Our approach for designing an artificial 2D landscape at selective locations of a single layer of atoms can lead to unique electronic, photonic, and mechanical properties previously not found in nature. This opens a new paradigm for future material design, enabling structures and properties for unexplored territories.

Trends of higher-order exchange interactions in transition metal trilayers

We present a systematic study of higher-order exchange interactions beyond the pair-wise Heisenberg exchange in transition-metal trilayers based on density functional theory calculations. We show that these terms can play an important role in magnetic trilayers composed of a single hexagonal Fe or Co atomic layer sandwiched between $4d$ and $5d$ transition-metal layers. We study the dependence of the biquadratic and the three-site and four-site four spin interaction on the band filling of the $4d$ and $5d$ layers as well as the stacking sequence, i.e. fcc vs. hcp stacking. Our calculations reveal relatively small higher-order interactions for Co based trilayers. For Fe based trilayers with a Rh or Ir layer the higher-order terms can be on the same order of magnitude as pair-wise Heisenberg exchange. The trends obtained for freestanding trilayers are used to understand the higher-order interactions in ultrathin film systems on surfaces that are experimentally accessible. It is shown that hcp Rh/Fe/Ir(111) and hcp-Rh/Fe/Rh(111) exhibit the largest values for the biquadratic and the three-site four spin interaction of all systems under study. We further demonstrate that the three-site four spin interaction is responsible for the experimentally observed change of the magnetic ground state of Rh/Fe/Ir(111) from a spin spiral (single-Q) for fcc-Rh to a 2Q state for hcp-Rh. We find similar trends for Rh/Fe/Rh(111), i.e. replacing the Ir surface by the isoelectronic Rh surface. For Rh/Co/Ir(111), we obtain a negative value for the four-site four spin interaction which will lead to a reduced stability of magnetic skyrmions which are metastable in this film at zero magnetic field. In contrast, for Pd/Fe/Ir(111), the four-site four spin interaction is positive which leads to an enhanced stability of skyrmions.

Graphene for Thermal Storage Applications: Characterization, Simulation and Modelling

In recent years, interest in the thermal properties of graphene constituents has seen rapid growth in the fields of science and engineering. The removal of heat in the continuous processes in the electronics industry has had major issues in thermal transmission in lower-dimensional assemblies. It has also shown fascinating topographies as the carbon allotropes and their derivative compounds expel heat. Numerous research articles reported within the past 15 years have demonstrated enhanced electron flexibility, exceptional thermal conductivity and mechanical behaviour, as well as excellent optical properties of graphene as a single atomic layer. This review article tries to provide a detailed summary of the heat exchange properties of graphene structures and graphene-based materials such as nanoribbons with few-layered graphene. Thermal and energy storage management systems have played a major role in the increase in marketable products in recent times. The purpose of this review is to summarize the current research on thermal properties with regard to the management and energy storage of graphene materials, focusing on characteristic properties, industrialization, modelling and simulation, and their applications in specific thermal storage systems.