Simultaneous Reduction Research Articles

Exceptional figure of merit achieved in boron-dispersed GeTe-based thermoelectric composites

GeTe is a promising p-type material with increasingly enhanced thermoelectric properties reported in recent years, demonstrating its superiority for mid-temperature applications. In this work, the thermoelectric performance of GeTe is improved by a facile composite approach. We find that incorporating a small amount of boron particles into the Bi-doped GeTe leads to significant enhancement in power factor and simultaneous reduction in thermal conductivity, through which the synergistic modulation of electrical and thermal transport properties is realized. The thermal mismatch between the boron particles and the matrix induces high-density dislocations that effectively scatter the mid-frequency phonons, accounting for a minimum lattice thermal conductivity of 0.43 Wm−1K−1 at 613 K. Furthermore, the presence of boron/GeTe interfaces modifies the interfacial potential barriers, resulting in increased Seebeck coefficient and hence enhanced power factor (25.4 μWcm−1K−2 at 300 K). Consequently, we obtain a maximum figure of merit Zmax of 4.0 × 10−3 K−1 at 613 K in the GeTe-based composites, which is the record-high value in GeTe-based thermoelectric materials and also superior to most of thermoelectric systems for mid-temperature applications. This work provides an effective way to further enhance the performance of GeTe-based thermoelectrics.

Assessing the extent and persistence of major crisis events in the crude oil market and economy: evidence from the past 30 years

This study investigates the extent and persistence of major crisis events in the crude oil market and economy and searches for general rules of event impact. Although the short-term effects of such crises may quickly become evident, their long-term implications can be challenging to uncover. To this end, we analyzed 50 major crisis events across four categories using a Proxy structural vector autoregressive (Proxy-SVAR) model. The results show that these events substantially impacted crude oil production, world crude oil prices, and inflation in China and the United States. Generally speaking, major crisis events have a more severe impact on the crude oil market, but their impact on the economy lasts longer. Notably, geopolitical conflicts have led to a sharp decline in S&P500, resulting in a simultaneous reduction in the industrial production indices of the world, China, and the US. Among the different types of crises, the financial crisis had the most prolonged impact, persisting for approximately four years. The public health emergency represented by COVID-19 resulted in a decline in actual oil prices, with its impact on the oil market continuing for over three years. Considering our findings, we suggest four policy measures to enhance economic resilience.

Engineering Single-Atom Sites with the Irving-Williams Series for the Simultaneous Co-photocatalytic CO2 Reduction and CH3CHO Oxidation.

The bonding effects between 3d transition-metal single sites and supports originate from crystal field stabilization energy (CFSE). The 3d transition-metal atoms of the spontaneous geometrical distortions, that is the Jahn-Teller effect, can alter CFSE, thereby leading to the Irving-Williams series. However, engineering single-atom sites (SASs) using the Irving-Williams series as an ideal guideline has not been reported to date. Herein, alkynyl-linked covalent phenanthroline frameworks (CPFs) with phenanthroline units are developed to anchor the desired 3d single metal ions from d5 to d10 (Mn2+, Fe3+, Co2+, Ni2+, Cu2+, and Zn2+). The Irving-Williams series was employed to accurately predict the bonding effects between 3d transition-metal atoms and phenanthroline units. To verify this, theoretical calculations and experimental results reveal that Cu-SASs/CPFs exhibits higher stability and faster charge-transfer efficiency, far surpassing other metal-SASs/CPFs. As expected, Cu-SASs/CPFs demonstrates a high photoreduction of CO2-to-CO activity (~30.3 μmol ⋅ g-1 ⋅ h-1) and an exceptional photooxidation of CH3CHO-to-CH3COOH activity (~24.7 μmol ⋅ g-1 ⋅ h-1). Interestingly, the generated *O2 - is derived from the process of CO2 reduction, thereby triggering a CH3CHO oxidation reaction. This work provides a novel design concept for designing SASs by the Irving-Williams to regulate the catalytic performances.

Integrated catalytic systems for simultaneous NOx and PM reduction: a comprehensive evaluation of synergistic performance and combustion waste energy utilization.

The global transition towards sustainable automotive vehicles has driven the demand for energy-efficient internal combustion engines with advanced aftertreatment systems capable of reducing nitrogen oxides (NOx) and particulate matter (PM) emissions. This comprehensive review explores the latest advancements in aftertreatment technologies, focusing on the synergistic integration of in-cylinder combustion strategies, such as low-temperature combustion (LTC), with post-combustion purification systems. Selective catalytic reduction (SCR), lean NOx traps (LNT), and diesel particulate filters (DPF) are critically examined, highlighting novel catalyst formulations and system configurations that enhance low-temperature performance and durability. The review also investigates the potential of energy conversion and recovery techniques, including thermoelectric generators and organic Rankine cycles, to harness waste heat from the exhaust and improve overall system efficiency. By analyzing the complex interactions between engine operating parameters, combustion kinetics, and emission formation, this study provides valuable insights into the optimization of integrated LTC-aftertreatment systems. Furthermore, the review emphasizes the importance of considering real-world driving conditions and transient operation in the development and evaluation of these technologies. The findings presented in this article lay the foundation for future research efforts aimed at overcoming the limitations of current aftertreatment systems and achieving superior emission reduction performance in advanced combustion engines, ultimately contributing to the development of sustainable and efficient automotive technologies.

Application of CFD Simulation to the Design of an Innovative Drying Chamber

Drying and sanitising equipment has been very common in industrial plants since the pandemic. These are devices that consume significant amounts of energy. The best solution is to use a drying chamber equipped with a heat pump, which allows partial recovery of the energy. In the design of the drying chamber, the drying time is important, which depends both on the parameters of the heat pump itself, and the geometry and airflow of the drying chamber. The geometry and airflow supply should be arranged to ensure a uniform distribution of velocity throughout the drying area. For this purpose, the use of CFD simulations has been proposed. A model was developed in ANSYS/FLUENT where all model parameters, including the optimal mesh density, turbulence models, etc., were determined. The model was verified on the experimental results of the basic design of the chamber. Then an innovative design was proposed that was modelled and optimised in terms of the distribution of the inlet’s perforation. The final design was made, and, at the same time, the simulation’s results were verified by measuring the velocity of airflow in the new design. Together with the optimisation of the heat pump, this made it possible to reduce the drying time by 50%, with a simultaneous reduction in the energy consumed.

Development and Performance Evaluation Experiment of a Device for Simultaneous Reduction of SOx and PM

Mitigating air pollutants such as SOx and PM emitted from ships is an important task for marine environmental protection and improving air quality. To address this, exhaust gas after-treatment devices have been introduced, but treating pollutants like SOx and PM individually poses challenges due to spatial constraints on ships. Consequently, a Total Gas Cleaning System (TGCS) capable of simultaneously reducing sulfur oxides and particulate matter has been developed. The TGCS combines a cyclone dust collector and a wet scrubber system. The cyclone dust collector is designed to maintain a certain distance from the bottom of the wet scrubber, allowing exhaust gases entering from the bottom to rise as sulfur oxides are adsorbed. Additionally, the exhaust gases descending through the space between the cyclone dust collector and the wet scrubber collide with the scrubbing solution before entering the bottom of the wet scrubber, facilitating the absorption of SOx. In this study, the efficiency of the developed TGCS was evaluated, and the reduction effects based on design parameters were investigated. Furthermore, the impact of this device on ship engines was analyzed to assess its practical applicability. Experimental results showed that increasing the volume flow rate of the cleaning solution enhanced the PM reduction effect. Particularly, when the height of the Pall ring was 1000 mm and the volume flow rate was 35 L/min, the sulfur oxide reduction effect met the standards for Sulfur Emission Control Areas (SECA). Based on these findings, suggestions for effectively controlling atmospheric pollutants from ships were made, with the expectation of contributing to the development of systems combining various after-treatment devices.

Study on the shear mechanism of horizontal joints within UVDR precast shear wall by quasi-static test and finite element analysis

This research introduced a novel precast shear wall designed to address prevalent challenges encountered in precast shear wall structures, such as issues with difficult installation, high expenses, and the uncertain quality of grouting by eliminating the connection of the vertical distributing bars. Early experimental verification of this novel structural system showcased favourable results concerning its seismic performance. Building upon this groundwork, the paper presented an elaborate horizontal joint deformation model, demonstrating its precise analysis of damage modes and interface slip in the novel structural system with high reliability. Furthermore, in an effort to enhance the damage mode of this novel precast shear wall under conditions of low axial compression ratio, the study introduced and evaluated two improvement measures through finite element parametric analysis. The findings indicated a noticeable enhancement in capacity and a simultaneous reduction in interface slip with the proposed improvement measures. Additionally, the section steel measures were more effective than the additional bars measures.

Defining Design Parameters for Controlled Rocking Braced Frames to Control Seismic Losses

ABSTRACT Controlled rocking braced frames (CRBFs) are a self-centering lateral force-resisting system aimed at reducing structural damage potential. Previous research has shown that relatively low design forces for rocking and for structural elements in CRBFs would be acceptable based on collapse fragility analysis. However, past studies have also highlighted the potential for significant story drifts and for increased demands on acceleration-sensitive nonstructural components installed in buildings with CRBFs. Therefore, while CRBFs have demonstrated acceptable performance in terms of collapse across a wide range of design options, these design options must be evaluated considering the performance of nonstructural components if the intended low-damage potential of CRBFs is to be fully realized. To address this need, this paper investigates the influence of two key design parameters on seismic losses of buildings with CRBFs, namely the response modification factor (R) for the rocking joint design and the amplification factor (γ) used to incorporate higher-mode forces into the capacity design of frame members. Three different heights of CRBF buildings are designed using different design options, with values of R ranging from 5 to 12 and with higher-mode forces considered based on two seismic intensity levels: the design earthquake (DE) and the maximum considered earthquake (MCE). Then, following an assessment of structural responses, the paper’s primary emphasis is on earthquake-induced economic losses. While the computed total expected annual losses (EALs) using various design options are remarkably similar, the distribution of losses attributed to collapse or to nonstructural components varies. The CRBFs with lower resistance to rocking exhibit greater losses attributed to collapse and to drift-sensitive nonstructural components, but this is counterbalanced by a simultaneous reduction in losses related to acceleration-sensitive nonstructural components. Furthermore, in taller CRBF buildings, using amplified higher-mode forces based on the MCE level slightly decreases total EALs compared to those using the DE level, primarily due to a reduction in collapse losses.

Synchronous influence of soil amendments on alkylmercury and methane emissions in mercury-contaminated paddy soil

Mercury (Hg) alkylation and methane (CH4) emissions pose significant global concerns. Paddy soil, due to its long-term anaerobic conditions and abundant organic matter, is hotspots for soil Hg alkylation and CH4 emissions. However, the relevance between Hg alkylation and CH4 emissions, especially their simultaneous reduction strategies, remains poorly understood. Here, we investigated the effects of biochar (BC), selenium (Se) and rice straw (RS) amendments on Hg alkylation and CH4 emissions in paddy soil, and the accumulation of Hg speciation. Results found that both BC and RS amendments significantly increased the levels of soil organic carbon (SOC) and humification index (HIX). Furthermore, BC decreased the concentrations of Hg(II), methylmercury (MeHg) and ethylmercury (EtHg) by 63.1%, 53.6% and 100% in rice grains. However, RS increased Hg(II) concentration but decreased the total Hg (THg), MeHg and EtHg concentrations in rice grains. Compared to the CK, RS significantly increased CH4 emissions, while BC decreased CH4 emissions, and Se showed no significant difference. Se amendment increased the Hg(II) and EtHg concentrations by 20.3% and 17.0% respectively, and decreased the MeHg concentration in grains by 58.3%. Both BC and RS impacted the abundance of methanogens by enhancing SOC and HIX, subsequently modulating the relevance between Hg alkylation and CH4 emissions. These findings provide insights into the relevance between Hg alkylation and CH4 emissions and propose potential mitigation mechanisms in Hg-contaminated paddy soil.

Mechanism of Biological Transport and Transformation of Copper, Cadmium, and Zinc in Water by Chlorella

This study investigates the effectiveness of Chlorella vulgaris in treating copper, cadmium, and zinc in aqueous solutions; the aim of this study was to examine the effects of various factors on the adsorption capacity of Chlorella in water. This study explored the intra- and extracellular adsorption and accumulation patterns of copper (Cu(II)), cadmium (Cd(II)), and zinc (Zn(II)), revealing their molecular response mechanisms under the most suitable conditions. The adsorption capacity of Chlorella to Cu(II), Cd(II), and Zn(II) in water was 93.63%, 73.45%, and 85.41%, respectively. The adsorption mechanism for heavy metals is governed by both intracellular and extracellular diffusion, with intracellular absorption serving as a supplement and external uptake predominating. XRD, XPS, FTIR, SEM-EDX, and TEM-EDX analyses showed that there would be the formation of precipitates such as Cu2S, CuS2, CdS, and ZnSO4. The adsorption of Cu(II) involves its simultaneous reduction to Cu(I). Moreover, specific functional groups present on the cellular surface, such as amino, carboxyl, aldehyde, and ether groups, interact with heavy metal ions. In view of its efficient heavy metal adsorption capacity and biosafety, this study recommends Chlorella as a potential biosorbent for the bioremediation and environmental treatment of heavy metal contaminated water in the future.

Shrimp shapes a resistance trait against vibriosis by memorizing the colonization resistance of intestinal microbiota.

Vibriosis is one of the most serious diseases that commonly occurs in aquatic animals, thus, shaping a steady inherited resistance trait in organisms has received the highest priority in aquaculture. Whereas, the mechanisms underlying the development of such a resistance trait are mostly elusive. In this study, we constructed vibriosis-resistant and susceptible families of the Pacific white shrimp Litopenaeus vannamei after four generations of artificial selection. Microbiome sequencing indicated that shrimp can successfully develop a colonization resistance trait against Vibrio infections. This trait was characterized by a microbial community structure with specific enrichment of a single probiotic species (namely Shewanella algae), and notably, its formation was inheritable and might be memorized by host epigenetic remodeling. Regardless of the infection status, a group of genes was specifically activated in the resistant family through disruption of complete methylation. Specifically, hypo-methylation and hyper-expression of genes related to lactate dehydrogenase (LDH) and iron homeostasis might provide rich sources of specific carbon (lactate) and ions for the colonization of S. algae, which directly results in the reduction of Vibrio load in shrimp. Lactate feeding increased the survival of shrimp, while knockdown of LDH gene decreased the survival when shrimp was infected by Vibrio pathogens. In addition, treatment of shrimp with the methyltransferase inhibitor 5-azacytidine resulted in upregulations of LDH and some protein processing genes, significant enrichment of S. algae, and simultaneous reduction of Vibrio in shrimp. Our results suggest that the colonization resistance can be memorized as epigenetic information by the host, which has played a pivotal role in vibriosis resistance. The findings of this study will aid in disease control and the selection of superior lines of shrimp with high disease resistance.

Laser-assembled conductive 3D nanozyme film-based nitrocellulose sensor for real-time detection of H2O2 released from cancer cells

In this work, a nanostructured conductive film possessing nanozyme features was straightforwardly produced via laser-assembling and integrated into complete nitrocellulose sensors; the cellulosic substrate allows to host live cells, while the nanostructured film nanozyme activity ensures the enzyme-free real-time detection of hydrogen peroxide (H2O2) released by the sames. In detail, a highly exfoliated reduced graphene oxide 3D film decorated with naked platinum nanocubes was produced using a CO2-laser plotter via the simultaneous reduction and patterning of graphene oxide and platinum cations; the nanostructured film was integrated into a nitrocellulose substrate and the complete sensor was manufactured using an affordable semi-automatic printing approach. The linear range for the direct H2O2 determination was 0.5–80 μM (R2 = 0.9943), with a limit of detection of 0.2 μM. Live cell measurements were achieved by placing the sensor in the culture medium, ensuring their adhesion on the sensors' surface; two cell lines were used as non-tumorigenic (Vero cells) and tumorigenic (SKBR3 cells) models, respectively. Real-time detection of H2O2 released by cells upon stimulation with phorbol ester was carried out; the nitrocellulose sensor returned on-site and real-time quantitative information on the H2O2 released proving useful sensitivity and selectivity, allowing to distinguish tumorigenic cells. The proposed strategy allows low-cost in-series semi-automatic production of paper-based point-of-care devices using simple benchtop instrumentation, paving the way for the easy and affordable monitoring of the cytopathology state of cancer cells.

Optimizing Elliptical Cylindrical Antenna Array for Improved Wireless Communication Using Novel PSO Algorithm

This paper presents a novel approach to optimize the thinning of an elliptical cylindrical array (ECA) composed of uniformly stimulated, isotropic antennas with the objective of achieving a directed beam characterized by a significantly reduced relative Sidelobe Level (SLL). The optimization process employs the Novel Particle Swarm Optimization (NPSO) method, which offers a fresh perspective on addressing electromagnetic optimization challenges by its ability to effectively explore solution spaces. By employing the NPSO algorithm, which emulates the collective behavior of swarming particles to search for optimal solutions, this study addresses complex optimization challenges inherent in antenna array design. This study focuses on identifying the optimal combination of ON–OFF components (use the minimum number of ON antenna elements) within the antenna array to produce a radiation pattern exhibiting the greatest decrease in SLL. Additionally, the First Null Beam Width (FNBW) is targeted for optimization without predefined values. The optimization approach also considers the effect of thinned array element spacing on the overall performance metrics. Out of total 36 elements, only 15 elements are switched ON and the remaining of the elements are OFF, so the total reduction or thinning of ECAA is 41.66%. Simulation results demonstrate that the proposed methodology enables a simultaneous reduction of more than half of the antenna array elements while achieving superior SLL minimization. This significant reduction in antenna elements not only contributes to simplifying the array design, but also enhances the array’s beamforming capabilities.

A double‐edged sword: Interim CEO and corporate social (ir)responsibility activities

AbstractEmploying an interim CEO is one of the key strategies organizations use to address urgent changes in leadership, yet there is a notable lack of attention in existing corporate governance literature regarding their impact on non‐market strategic behaviors. In an effort to bridge this gap, our study integrates institutional theory with impression management literature. Based on unbalanced panel data from Chinese non‐state‐owned listed companies from 2010 to 2019, the study finds that the succession of an interim CEO is associated with a simultaneous reduction in both corporate social responsibility (CSR) and corporate social irresponsibility (CSI) activities. The negative relationship between interim CEO and CSI activities is weaken in the context of high institutional voids. Mechanism analysis reveals that interim CEOs tend to focus more on the present and allocate more attention toward external stakeholder management strategies and low‐cost and efficiency strategies. Additional analysis indicates that in the face of negative financial performance aspirations, interim CEOs are more likely to reduce CSR activities. Similarly, when confronted with negative social performance aspirations, interim CEOs tend to decrease CSI activities to a greater extent.

Preparation of nanocellulose/reduced graphene oxide matrix loaded with cuprous oxide nanoparticles for efficient catalytic reduction of 4-nitrophenol.

The paper reports on the preparation of cellulose nanocrystals/reduced graphene oxide matrix loaded with cuprous oxide nanoparticles (CNC/rGO-Cu2O) through a simple solvothermal method and its application for 4-nitrophenol reduction to 4-aminophenol using sodium borohydride. The CNC/rGO-Cu2O nanocomposite was formed chemically by first mixing CNC and graphene oxide (GO) followed by complexation of the negatively charged functional groups of CNC/GO with Cu2+ ions and subsequent heating at 100°C. This resulted in the simultaneous reduction of GO to rGO and the formation of Cu2O nanoparticles. The as-elaborated nanocomposite was firstly characterized using different techniques such as atomic force microscopy, scanning electron microscopy, transmission electron microscopy, UV-Vis spectrophotometry, Raman spectroscopy and x-ray photoelectron spectroscopy. Then, it was successfully applied for efficient catalytic reduction of 4-nitrophenol to 4-aminophenol using sodium borohydride: the reduction was completed in about 6 min. After eight times use, the catalyst still maintained good catalytic performance. Compared to CNC/rGO, rGO/Cu2O and free Cu2O nanoparticles, the CNC/rGO-Cu2O nanocomposite exhibits higher catalytic activity even at lower copper loading.

Exploring the therapeutic potential of ethanol extract of Erythrina fusca Lour. roots as an analgesic, antipyretic, and anti-inflammatory agent in experimental animals

Erythrina fusca Lour., renowned in traditional medicine for its soothing, analgesic, anti-inflammatory, and neuroinhibitory properties, is the focus of our investigation. Expanding on its traditional applications, we assessed the analgesic, anti-inflammatory, and antipyretic characteristics of the ethanol extract from E. fusca root (REEF). Administered orally to mice at varying doses (50, 100, and 150 mg/kg for pain and fever reduction; 100, 150, and 200 mg/kg for anti-inflammatory experiments), REEF's effects were systematically evaluated through parameters such as reaction time, pain inhibition ratio, COX2 and PGE2 levels, rectal temperature, fever inhibition ratio, paw diameter, paw edema inhibition ratio, and inflammatory cytokines. Results reveal that REEF consistently reduced licking and biting time (p < 0.05) in response to formalin-induced pain in mice. Particularly noteworthy was the more pronounced reduction in COX2 and PGE2 during the late phase, with the most significant decrease observed at the 150 mg/kg REEF treatment (p < 0.05). The licking time graph substantiated the analgesic efficacy of REEF, illustrating simultaneous and sustained pain reduction over time. Moreover, REEF significantly alleviated fever (p < 0.05) in mice, with the most substantial effect observed three hours post-yeast injection. REEF not only efficiently reduced body temperature but also countered the fever-inducing effects of yeast at evaluated time points (p < 0.05). In the context of carrageenan-induced inflammation, paw swelling markedly diminished after 4 and 5 hours (p < 0.05). Notably, at the 5-hour mark, REEF treatment at 150 mg/kg dose exhibited significantly superior anti-inflammatory effects (p < 0.05). Additionally, mice treated with REEF (100, 150, and 200 mg/kg) exhibited a considerable decrease (p < 0.05) in serum concentrations of TNF-?, IL-1?, and IL-6 compared to the control treatment. The ethanol extract from Erythrina fusca roots demonstrates substantial potential for pain relief, fever reduction, and anti-inflammatory effects, positioning it as a promising herbal resource for the research and development of natural medicinal products with these therapeutic properties.

Optical properties of NiO films: Effect of nitrogen-doping, substrate temperature and band gap estimation using machine learning

In this study, nickel oxide (NiO) thin films were synthesized on glass substrates using RF magnetron sputtering with varying nitrogen (N) doping ratio and substrate temperatures to explore modifications in their structural, morphological, and optical properties. The films were prepared using a high-purity NiO target under controlled sputtering conditions. Structural analysis by X-ray diffraction revealed an improvement in crystallinity in the (200) direction with increasing N ratio. In contrast, higher N ratio led to the suppression of (111) and (220) peaks, indicating a significant influence of N on the crystal structure and orientation. The films’ thickness and morphology, examined using scanning electron microscopy and energy-dispersive X-ray spectroscopy, showed uniform and homogeneous growth with smooth surface topologies. Optical properties, assessed by UV–Vis-NIR spectrophotometry, demonstrated a decrease in transmittance and a redshift in the absorption edge with increased N doping, corresponding to a narrowing of the energy bandgap from 3.7 eV to 3.45 eV. This bandgap reduction is attributed to N incorporation substituting oxygen sites, introducing defect states within the band structure. Additionally, the impact of substrate temperature on film growth enhanced crystallinity and orientation along the (111) plane at higher temperatures, with a simultaneous reduction in film thickness due to increased adatom mobility and potential thermal decomposition. The evaluation of Kernel Ridge Regression (KRR) and Ridge Regression (RR) models revealed their effectiveness in predicting band gap values for thin films at varying substrate temperatures and thicknesses. While RR excelled in predicting a band gap of 3.6 eV for a film with a substrate temperature of 24 °C and a thickness of 112.7 nm, KRR outperformed in predicting a band gap of 3.65 eV for a film with a substrate temperature of 24 °C and a thickness of 107 nm. These findings elucidate the dual influence of N doping and substrate temperature on enhancing the functional properties of NiO thin films, promising for applications in optoelectronic devices and gas sensors.

Atomistic simulations of coherent thermoelectric transport in ultrathin pristine and decorated noble metals nanowires

Nanowires (NWs) are envisioned to be an important component of novel nanoscale electronic devices. Here, we perform atomistic simulations of coherent thermoelectric (TE) transport in free-standing ultrathin NWs of noble metals (viz. Au, Ag, Cu, Pt) cut along the [111] crystallographic direction using a non-equilibrium Greens function based first principles approach. Effect of decorating these NWs with Au or Pt atoms in an fcc environment, is also explored. Results of the calculated electronic structure show that all considered NWs, except the Pt and Pt-decorated NWs, are metallic and non-magnetic. Interestingly, Cu@Pt NW is found to be a magnetic semiconductor with an unequal band gap in ↑− and ↓−spin energy bands, while Pt NW and other Pt-decorated NWs (viz. Ag@Pt and Au@Pt) behave like a magnetic half-metal. To explore the TE potential of as-considered NWs, electrical conductance G, thermal conductance κT, and thermopower S are computed in the linear response regime. Notably, the metallic NWs exhibit a quantized G. Among these, pristine NWs show a quantized value 3G0 up to a temperature of 200 K, while Cu@Au NW preserves its quantized value 5G0 even at T exceeding 300 K. In thermal transport, valence electrons make a dominant contribution to the room-temperature κT of pristine NWs. The phononic contribution κph, however, goes up following decoration, with Pt-decorated NWs showing a pronounced increment (by a factor of ∼2). But, these NWs undergo a simultaneous reduction in the electronic contribution κel owing to half-metallic conduction, resulting in a net suppression of total thermal conductance κT. Moreover, Pt-decorated NWs show a manifold enhancement in zero-bias S, with Ag@Pt exhibiting the highest value ∼119μV/K. However, S can be augmented considerably by adjusting the chemical potential μ of electrodes, and an overall best S∼−890μV/K is found in Au NW for μ=0.575eV. In this way, TE figure of merit ZT is tunable in pristine NWs over the range 1−3.7. Correspondingly, the decorated NWs exhibit somewhat smaller S and ZT. Furthermore, spin-asymmetric electronic transport in Pt and Pt-decorated NWs results in net spin conductance Gs and spin thermopower Ss. It is found that the spin figure of merit ZsT, as high as 3.5, can be attained in Pt NW by controlling μ. Thus, noble metals NWs can be tailored for both thermoelectric and spin-thermoelectric applications. We have also investigated TE transport for the pristine NWs in the [110] direction, and found S and ZT to be comparatively much smaller. Such NWs may be useful as interconnects for low noise applications.

Cobalt nanoparticles confined nitrogen–doped carbon integrated bimetallic Co2P–VP heterostructured composite: A MOF integrated 3D arrays for catalytic water splitting

A robust electrode material with outstanding stability at high current density is crucial for the practical application of water splitting. We present an intertwined heterostructure composed of in-situ confined cobalt nanoparticles (Conp) in nitrogen-doped carbon (N–C), derived from functionalized zeolitic imidazolate framework–67 (ZIF−67), and composited with the hetero phase bimetallic cobalt vanadium phosphide (Co2P−VP) through a hydrothermal reaction, room temperature aging, and chemical vapor deposition (CVD) for simultaneous phosphidation, graphitization, and reduction. The synergistic effect generated across the multiple heterointerfaces of Co2P, VP, and Conp in the N−doped carbon on nickel foam, as the Co2P–VP@N–C/Co heterostructure, exhibits outstanding electrocatalytic performance for the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and electrochemical water splitting. The Co2P–VP@N–C/Co (+,−) alkaline electrolyzer demonstrates a low potential of 1.49 and 1.71 V to achieve current densities of 10 and 100 mA cm−2, respectively. It exhibits outstanding stability during continuous operation for 100 h at 100 mA cm−2, with 98.02 % retention. The outstanding performance is credited to the synergistic interaction and d-electronic modulation of the metallic hetero phasic Co2P–VP moiety and confined Conp in a functionalized N−doped porous carbonaceous heterostructure. Density Functional Theory (DFT) validates the regulation of electronic structure for efficient redistribution of local charges and electron transfer.

Using Optimization Algorithms to Design Phononic Barriers Protecting Monuments or Building Facades

The work compares the design of phononic structures using two types of optimization algorithms. Using the genetic algorithm and the simulated annealing algorithm, optimal layer distributions were obtained in which the phononic band gap phenomenon occurs. The mechanical wave propagating in the obtained structure, for the given frequency ranges, significantly reduces the transmitted energy, thanks to which the building facade or monument located behind the obtained barrier is exposed to much smaller vibrations, which significantly reduces damage related to long-term fatigue load. The mechanical wave propagation was modeled using the Transfer Matrix Method algorithm and the proprietary objective function allows for the reduction of wave transmission with the simultaneous reduction of high transmission peaks with small half-widths.