A SnO 2 multilayered gas sensor was prepared by using electrostatic agglomeration and electrostatic adhesion of aerosol particles, in order to develop a new system which enables simultaneous CH 4 and CO sensing. The multilayer consists of an initial subsensor layer for CH 4 detection and a second subsensor layer for CO detection coated on the initial layer. The initial subsensor uses a membrane prepared by electrostatic adhesion of SnO 2 whisker particles. The interior SnO 2 whisker subsensor layer has a lot of pores, which consist of several sizes distributed from 100 μm to 100 nm in diameter. The second subsensor comprises a membrane prepared by electrostatic adhesion of SnO 2-Pd composite particles. Electrostatic agglomeration enables composite particle preparation where Pd particles agglomerate onto a SnO 2 particle. The exterior subsensor layer ensures a dendrite microstructure of the SnO 2-Pd composite particles with a three-dimensional network and a uniform Pd distribution on the surface of SnO 2 core particles over the whole film. The SnO 2 multilayered sensor reveals a high selectivity to CH 4 and CO gases, which means high sensitivity to CH 4 and no response to CO of the interior subsensor, and, in turn, no response to CH 4 and high sensitivity to CO of the exterior subsensor.
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