COMSOL Simulation Research Articles

Optimization of ECR assisted pre-ionization in GLAST-III via Multiphysics simulation

Abstract Electron cyclotron resonance (ECR) is a common pre-ionization technique to assist ohmic startup in tokamaks. In this research, ECR assisted pre-ionization in GLAST-III tokamak is comprehensively investigated via Multiphysics 3D COMSOL simulations. Optimal conditions for ECR microwave absorption at fundamental mode are determined to achieve reliable plasma startup. The effect of filled gas pressure on the ECR plasma parameters such as plasma density and plasma temperature is thoroughly investigated in the range of 0.08–1 Pa. The results reveal that the ECR absorption of the incident microwaves is significantly enhanced at low enough filled argon pressure. The behavior of absorbed microwave power is significantly changed for different filled gas pressures. In case of high gas pressure, the microwave power is deposited locally in front of the waveguide, whereas in case of low pressure (0.08 Pa), the microwave power is uniformly deposited along the resonance layer. Moreover, the experimental investigation extends to nearly identical operating conditions, confirming the ECR absorption. The experimental data aligns with the simulation results, collectively affirming the efficacy of optimized pre-ionization in the low gas pressure scenario (0.08 Pa) within the GLAST-III tokamak.

Constructing magnetically propelled piezoelectric and pyroelectric bifunctional micromotors to boost the photocatalytic H2 production involving biomass reforming

Biomass-assisted photocatalytic water splitting for hydrogen (H2) production has attracted widespread interest, which is important for the development of green H2 energy and the high value-added utilization of biomass. Although photothermal utilization can improve solar energy conversion efficiency, the elevated temperature also enhances the likelihood of electron-hole collisions. Herein, magnetically propelled PVDF/Fe3O4@g-C3N4 spiral micromotors were constructed to easily foster the synergistic coupling of piezoelectric and pyroelectric effects, which is beneficial to enhance the directional migration of photogenerated carriers at high temperatures. With both piezo- and pyroelectric effects, the biomass glucose involved H2 production rate on PVDF/Fe3O4@g-C3N4 spiral micromotors is 42.3 μmol/h, representing a significant increase of 31.9 times compared to water splitting without these effects, and the average apparent quantum yield at ordinary pressure can reach 12.6 %. Furthermore, photoluminescence and variable-temperature electrochemistry demonstrate that the piezo-pyroelectric coupling can accelerate the separation of carriers. Meanwhile, COMSOL simulations and KPFM tests show that the built-in electric field of the sample is enhanced under the piezo-pyroelectric effect. The spiral micromotors can easily realize the synergism of piezoelectric and pyroelectric effects, which provides an effective strategy to enhance the built-in electric field and thereby improve the performance of photocatalytic H2 evolution involving biomass reforming.

Ecodesign of Kesterite Nanoparticles for Thin Film Photovoltaics at Laboratory Scale.

This manuscript investigates the efficient synthesis of copper zinc tin sulfide (CZTS) nanoparticles for CZTS thin film solar cell applications with a primary focus on environmental sustainability. Underpinning the investigation is an initial life-cycle assessment (LCA) analysis. This LCA analysis is conducted to evaluate the environmental impact of different synthesis volumes, providing crucial insights into the sustainability of the synthesis process by considering the flows of material and energy associated with the process. Life-cycle assessment results demonstrate that significant reductions to the environmental impact can be made by increasing the synthesis volume of CZTS nanoparticle ink. Using a 5-fold increase in volume can reduce all 11 investigated environmental impacts by up to 35.6%, six of these impacts demonstrating reductions >10% and the amount of global warming potential is reduced by 21.4%. Motivated by the LCA results, COMSOL simulations are employed to understand the fluid flow patterns in large-scale fabrication. Various sizes and speeds of stirrer bars are investigated in these simulations, and it is determined that a 50 mm stir bar at 200 rpm represents the optimal configuration for the synthesis process in a 500 mL flask. Subsequently, large-batch CZTS nanoparticle inks are synthesized using these parameters and compared to small-batch samples. The light absorbers are characterized using Raman spectroscopy and X-ray diffraction, confirming favorable properties with close-to-ideal elemental ratios in large-batch synthesis. Finally, solar cell devices fabricated utilizing CZTSSe absorbers from the large volume synthesis process demonstrate comparable performance to those fabricated using small-batch synthesis, with uniform power conversion efficiencies of around 5% across the substrate. This study highlights the potential of large-volume CZTS nanoparticle synthesis for efficient and environmentally friendly CZTS solar cell fabrication, contributing to the advancement of sustainable renewable energy technologies.

Ti3C2T x MXene as surface-enhanced Raman scattering substrate

The electromagnetic field enhancement mechanisms leading to surface-enhanced Raman scattering (SERS) of R6G molecules near Ti3C2T x MXene flakes of different shapes and sizes are analyzed theoretically in this paper. In COMSOL simulations for the enhancement factor (EF) of SERS, the dye molecule is modeled as a small sphere with polarizability spectrum based on experimental data. It is demonstrated, for the first time, that in the wavelength range of 500 nm – 1000 nm , the enhancement of Raman signals is largely conditioned by quadrupole surface plasmon (QSP) oscillations that induce a strong polarization of the MXene substrate. We show that the vis-NIR spectral range quadrupole SP resonances are strengthened due to interband transitions (IBTs), which provide EF values of the order of 105–107 in agreement with experimental data. The weak sensitivity of the EF to the shape and size of MXene nanoparticles (NPs) is interpreted as a consequence of the low dependence of the absorption cross-section of QSP oscillations and IBT on the geometry of the flakes. This reveals a new feature: the independence of EF on the geometry of MXene substrates, which allows to avoid the monitoring of the shape and size of flakes during their synthesis. Thus, MXene flakes can be advantageous for the easy manufacturing of universal substrates for SERS applications. The electromagnetic SERS enhancement is determined by the ‘lightning rod’ and ‘hot-spot’ effects due to the partial overlapping of the absorption spectrum of the R6G molecule with these MXene resonances.

Research on multi-velocity measurement method of solid particles based on interdigital electrostatic sensor

Abstract In gas-solid two-phase flow, the velocities of solid particles will show different distributions as the flow pattern changes, and it is a challenging task to achieve the measurement of different velocity parameters in the flow field. To obtain the velocity information of solid particles in the flow field, a novel method to achieve multi-velocity measurement of solid particles is proposed by using the spatial filtering characteristics of interdigital electrostatic sensor with variational mode decomposition (VMD). Firstly, a three-dimensional model of the interdigital electrostatic sensor is established using COMSOL simulation software. Based on its spatial dynamic sensitivity, a theoretical analysis of its spatial filtering characteristics is conducted to obtain a mathematical relationship for velocity measurement. Subsequently, the VMD decomposition method is applied to an experiment involving charged wires, with the experimental results verifying the effectiveness of VMD in achieving multi-scale decomposition of electrostatic signals. Finally, the proposed measurement method is validated on a gravity feeding device and a pneumatic conveying system. The experimental results demonstrate that the method exhibits good feasibility.

Research on the mechanism of copper removal during electromagnetic enhanced aerobic fermentation of sludge

The migration and transformation of copper during magneto electric assisted aerobic fermentation were studied by establishing a control group, a magnetic assisted group (1.4 mT), an electric assisted group (10 V), and a magneto electric assisted group. The results showed that during the aerobic fermentation process of magnetic assisted sludge, changes in pH, temperature, and microorganisms in the system promoted the dissolution of Cu2+ and its migration from solid sludge to fermentation broth. Due to the presence of an electric field, Cu2+ deposits on the cathode plate through anisotropic attraction, combined with the Lorentz force generated by the magnetic field, promoting mass transfer of copper ions and reducing the concentration of Cu2+ in the fermentation broth, resulting in a copper removal rate of up to 75 %. In addition, the COMSOL simulation results show a consistent overall trend with actual experiments, indicating that the external electric and magnetic fields have a significant inhibitory effect on the removal of heavy metals in sludge.

Spatially Confined Assembly and Immobilization of Hierarchical Nanoparticle Architectures inside Microdroplets in Magnetic Fields.

Magnetic field-directed colloidal interactions offer facile tools for assembly of structures that range from linear chains to multidimensional hierarchical architectures. While the field-driven assembly of colloidal particles has commonly been investigated in unbounded media, a knowledge gap remains concerning such assembly in confined microenvironments. Here, we investigate how confinement of ferromagnetic nanoparticles in microspheres directs their magnetic assembly into hierarchical architectures. Microdroplets from polydimethylsiloxane (PDMS) liquid precursor containing dispersed iron oxide magnetic nanoparticles (MNPs) were placed in a static magnetic field leading to the formation of organized assemblies inside the host droplets. By changing the MNP concentrations, we revealed a sequence of microstructures inside the droplets, ranging from linear chains at a low MNP loading, transitioning to a combination of chains and networked bundles, to solely 3D bundles at high MNP loading. These experimental results were analyzed with the aid of COMSOL simulations where we calculated the potential energy to identify the preferred assembly conformations. The chains at high MNP loading minimized their energy by aggregating laterally to form bundles with their MNP dipoles being out-of-registry. We cured these PDMS droplets to immobilize the assemblies by forming soft microbeads. These microbeads constitute an "interaction toolbox" with different magnetic macroscale responses, which are governed by the structuring of the MNPs and their magnetic polarizability. We show that thanks to their ability to rotate by field-induced torque under a rotating field, these microbeads can be employed in applications such as optical modulators and microrollers.

Towards Design Automation of Microfluidic Mixers: Leveraging Reinforcement Learning and Artificial Neural Networks.

Microfluidic mixers, a pivotal application of microfluidic technology, are primarily utilized for the rapid amalgamation of diverse samples within microscale devices. Given the intricacy of their design processes and the substantial expertise required from designers, the intelligent automation of microfluidic mixer design has garnered significant attention. This paper discusses an approach that integrates artificial neural networks (ANNs) with reinforcement learning techniques to automate the dimensional parameter design of microfluidic mixers. In this study, we selected two typical microfluidic mixer structures for testing and trained two neural network models, both highly precise and cost-efficient, as alternatives to traditional, time-consuming finite-element simulations using up to 10,000 sets of COMSOL simulation data. By defining effective state evaluation functions for the reinforcement learning agents, we utilized the trained agents to successfully validate the automated design of dimensional parameters for these mixer structures. The tests demonstrated that the first mixer model could be automatically optimized in just 0.129 s, and the second in 0.169 s, significantly reducing the time compared to manual design. The simulation results validated the potential of reinforcement learning techniques in the automated design of microfluidic mixers, offering a new solution in this field.

A facile superlithiophilic 3D host with a transition metal oxide heterostructure for ultrastable zero-volume-expansion lithium metal anodes

Lithium metal batteries (LMBs) are widely recognized as the candidate for next-generation energy devices due to their unprecedented capacity and low electrochemical potential. Nonetheless, their practical implementation has been hindered by the dendrite formation and unstable solid electrolyte interface (SEI). In this study, we introduce a novel approach involving the in-situ growth of a ZnO–CuO heterostructure within a crack shield construction on a three-dimensional (3D) copper foam host. Computational COMSOL simulations reveal remarkable improvements in homogenizing lithium ion flux subsequent to decoration. Through galvanostatic measurements, the Li@ZnO-CuO-CF electrode exhibits an exceptionally low 0.2 V hysteresis, no volume expansion and uniform lithium deposition in symmetry cells under a 50 mA cm−2 current density. Furthermore, the electrode retains 95.4 % initial capacity after 600 cycles at 0.5C and 85.5 % initial capacity after 220 cycles at 1 C when coupled with a LiFePO₄ (LFP) cathode. This work sheds light on the facile fabrication of practical Li metal anodes for high-energy-density LMBs.

An Anti-Scaling Strategy for Electrochemical Wastewater Treatment: Leveraging Tip-Enhanced Electric Fields.

Electrode scaling poses a critical barrier to the adoption of electrochemical processes in wastewater treatment, primarily due to electrode inactivation and increased internal reactor resistance. We introduce an antiscaling strategy using tip-enhanced electric fields to redirect scale-forming compounds (e.g., Mg(OH)2 and CaCO3) from the electrode-electrolyte interface to the bulk solution. Our study utilized Cu nanowires (Cu NW) with high-curvature nanostructures as the cathode, in contrast to Cu nanoparticles (Cu NP), Cu foil (CF), and Cu mesh (CM), to evaluate the electrochemical nitrate reduction reaction (NO3RR) performance in hard water conditions. The Cu NW/CF cathode demonstrated superior NO3RR efficiency, with an apparent rate constant (Kapp) of 1.04 h-1, significantly outperforming control electrodes under identical conditions (Kapp < 0.051 h-1). Through experimental and theoretical analysis, including COMSOL simulations, we show that the high-curvature design of Cu NW induced localized electric field enhancements, propelling OH- ions away from the electrode surface into the bulk solution, thus mitigating scale formation on the cathode. Testing with real nitrate-contaminated wastewater confirms that the Cu NW/CF cathode maintained excellent denitrification efficiency over a 60-day period. This study offers a promising perspective on preventing electrode scaling in electrochemical wastewater treatment, paving the way for more efficient and sustainable practices.

Numerical Simulation of Thermal Therapy for Melanoma in Mice.

In recent years, the progressively escalating incidence and exceptionally high fatality rate of cutaneous melanoma have drawn the attention of numerous scholars. Magnetic induction hyperthermia, as an efficacious tumor treatment modality, has been promoted and applied in the therapy of some tumors. In this paper, the melanoma atop the mice's heads was chosen as the research subject, and a magnetic induction hyperthermia approach based on Helmholtz coils as the magnetic field excitation was investigated and designed. The influence of the electromagnetic field and thermal field on organisms was addressed through modeling by COMSOL simulation software. The results showed that the maximum values of induced electric field and magnetic induction strength in mouse tumor tissues were 63.1 V/m and 8.5621 mT, respectively, which reached the threshold value of magnetic field strength required for magnetic induction hyperthermia. The maxima of the induced electric field and magnetic induction intensity in brain tissues are, respectively, 35.828 V/m and 8.57 mT. Approximately 93% of the tumor tissue can reach 42 °C, and the maximum temperature is 44.2 °C. Within this temperature range, a large quantity of tumor cells can be successfully induced to undergo apoptosis without harming normal cells, and the therapeutic effect is favorable.

Electric Field Generated at the Millisecond Pulse-Polarized Interface Facilitates the Electrolytic Conversion of SO2 into H2S.

Interfacial electric field holds significant importance in determining both the polar molecular configuration and surface coverage during electrocatalysis. This study introduces a methodology leveraging the varying electric dipole moment of SO2 under distinct interfacial electric field strengths to enhance the selectivity of the SO2 electroreduction process. This approach presented the first attempt to utilize pulsed voltage application to the Au/PTFE membrane electrode for the control of the molecular configuration and coverage of SO2 on the electrode surface. Remarkably, the modulation of pulse duration resulted in a substantial inhibition of the hydrogen evolution reaction (HER) (FEH2 < 3%) under millisecond pulse conditions (ta = 10 ms, tc = 300 ms, Ea = -0.8 V (vs Hg/Hg2SO4), Ec = -1.8 V (vs Hg/Hg2SO4)), concomitant with a noteworthy enhancement in H2S selectivity (FEH2S > 97%). A comprehensive analysis, incorporating in situ Raman spectroscopy, electrochemical quartz crystal microbalance, COMSOL simulations, and DFT calculations, corroborated the increased selectivity of H2S products was primarily associated with the inherently large dipole moment of the SO2 molecule. The enhancement of the interfacial electric field induced by millisecond pulses was instrumental in amplifying SO2 coverage, activating SO2, facilitating the formation of the pivotal intermediate product *SOH, and effectively reducing the reaction energy barrier in the SO2 reduction process. These findings provide novel insights into the influences of ion and molecular transport dynamics, as well as the temporal intricacies of competitive pathways during the SO2 electroreduction process. Moreover, it underscores the intrinsic correlation between the electric dipole moment and surface-molecule interaction of the catalyst.

The dynamic behavior and nonlinear characteristics of aircraft landing gear retraction mechanism considering atmospheric corrosion

Atmospheric corrosion poses a significant challenge for the components of aircraft exposed to prolonged harsh weather conditions, critically impacting the safety property of aircraft landing gear retraction mechanism (ALGRM). This paper focuses on the ALGRM of a specific aircraft type, presenting a new modeling and analysis approach to assess the influence of atmospheric corrosion on dynamic behavior and nonlinear characteristics of mechanism. Initially, the dynamic model of ALGRM incorporating clearance joints is established using Lagrangian method. Numerical solutions are then obtained using the Runge-Kutta method. Subsequently, COMSOL simulation software is employed to simulate the corrosion morphology of the bearing under atmospheric corrosion, integrating the corroded bearing surfaces into the dynamic model of the mechanism. Finally, the study investigates the effects of corrosion time and different bearing materials on the dynamic behavior and nonlinear characteristics of ALGRM considering atmospheric corrosion. The results indicate that as corrosion time increases, the degradation of the dynamic behavior of ALGRM becomes more pronounced, and there are significant variations for corrosion morphology of bearing made of different materials under atmospheric corrosion. The findings of this study contribute to a broader understanding of the complex interactions between the dynamic behavior of aircraft and environmental degradation, providing some insights for designing ALGRM that are more durable and adaptable to atmospheric corrosion environments.

Simulation and experimental benchmarking of a proton pencil beam scanning nozzle model for development of MR-integrated proton therapy.

MR-integrated proton therapy is under development. It consists of the unique challenge of integrating a proton pencil beam scanning (PBS) beam line nozzle with an magnetic resonance imaging (MRI) scanner. The magnetic interaction between these two components is deemed high risk as the MR images can be degraded if there is cross-talk during beam delivery and imageacquisition. To create and benchmark a self-consistent proton PBS nozzle model for empowering the next stages of MR-integrated proton therapy development, namely exploring and de-risking complete integrated prototype system designs including magnetic shielding of the PBS nozzle. Magnetic field (COMSOL ) and radiation transport (Geant4) models of a proton PBS nozzle located at OncoRay (Dresden, Germany) were developed according to the manufacturers specifications. Geant4 simulations of the PBS process were performed by using magnetic field data generated by the COMSOL simulations. In total 315 spots were simulated which consisted of a scan pattern with 5cm spot spacings and for proton energies of 70, 100, 150, 200, and 220MeV. Analysis of the simulated deflection at the beam isocenter plane was performed to determine the self-consistency of the model. The magnetic fringe field from a sub selection of 24 of the 315 spot simulations were directly compared with high precision magnetometer measurements. These focused on the maximum scanning setting of 20cm beam deflection as generated from the second scanning magnet in the PBS for a proton beam energy of 220MeV. Locations along the beam line central axis (CAX) were measured at beam isocenter and downstream of 22, 47, 72, 97, and 122cm. Horizontal off-axis positions were measured at 22cm downstream of isocenter ( 50, 100, and 150cm from CAX). The proton PBS simulations had good spatial agreement to the theoretical values in all 315 spots examined at the beam line isocenter plane (0-2.9mm differences or within 1.5% of the local spot deflection amount). Careful analysis of the experimental measurements were able to isolate the changes in magnetic fields due solely to the scanning magnet contribution, and showed 1.9 1.2 -9.4 1.2 changes over the range of measurement locations. Direct comparison with the equivalent simulations matched within the measurement apparatus and setup uncertainty in all but one measurementpoint. For the first time a robust, accurate and self-consistent model of a proton PBS nozzle assembly has been created and successfully benchmarked for the purposes of advancing MR-integrated proton therapy research. The model will enable confidence in further simulation based work on fully integrated designs including MRI scanners and PBS nozzle magnetic shielding in order to de-risk and realize the full potential of MR-integrated proton therapy.

Research and Application of New Anti-Condensation System of High-Voltage Switchgear

Abstract The drastic fluctuations in temperature and humidity in the switchgear environment can lead to condensation, posing the threat to the safe and dependable operation of power equipment. In response to the limitations of current anti-condensation measures, a new anti-condensation system for high-voltage switchgear is proposed. Firstly, this research provides an overview of the cause of condensation and the present situation of relevant prevention technologies. Secondly, a new anti-condensation system for high-voltage switchgear is presented. Drawing upon existing anti-condensation technology, this system effectively addresses prevalent issues such as high air humidity and facile condensation in high-voltage switchgear. Electric field simulation calculations, conducted using COMSOL simulation software, demonstrate that the system does not compromise the normal operation of the switchgear. Finally, practical applications show that the robust operational stability of the system. It consistently achieves precise heat dissipation and dehumidification in high-voltage switchgear, which has high application value.

Compact Q-switched vortex waveguide laser modulated by buried Ag nanoparticles in SiO2

Vortex beam, particularly pulsed vortex laser, has expanded the potential applications in optics due to their unique wave-front phase structure and the determined photon orbital angular momentum. In this study, we present a novel approach including the integration of fused silica embedded with silver nanoparticles (Ag:SiO2) into the Nd:YAG waveguide platform for achieving nanosecond vortex pulses. Using a spiral phase plate for in-cavity phase modulation, we successfully demonstrate a Q-switched vortex laser with a high repetition rate in the megahertz range and short pulse width in the nanosecond regime. Additionally, we conduct a comprehensive analysis of the near-field distributions of Ag nanoparticles with varying sizes and distributions using COMSOL simulation. This study exemplifies the integration of silica-based photonic elements for realizing a high-stability and cost-effective nanosecond vortex laser system.

SnO2 induced electrostatic polarization PVDF composite nanofibers for efficient energy harvesting and self-powered wireless monitoring /motion recognition systems

With the rapid development of the Internet of Things and flexible electronics, piezoelectric nanogenerators (PENGs) based on polyvinylidene fluoride (PVDF) have demonstrated a wide range of potential applications in wearable devices. However, there are still challenges in developing high-performance PENGs, which affect their potential applications in more scenarios. Herein, we propose a SnO2-PVDF (SP)-PENG based on low-cost and environment-friendly SnO2 nanoparticles modulated via electrospinning, achieving outstanding piezoelectric output performance. The piezoelectric output of SP-PENG is up to 49.2 V, which is 11.7 times higher than that of pure PVDF-PENG. From the theoretical perspective, the enhanced electrostatic polarization is achieved by the strengthened local electric field due to the presence of low-resistivity SnO2 in the SP fibers. The mechanism of enhanced electrostatic polarization is also declared by COMSOL simulation. Moreover, the SP-PENG exhibits excellent durability (41,600 cycles) and long-term stability (8 months). A self-powered wireless sensing-monitoring system is realized by combining SP-PENG with circuit design. The motion recognition system is accomplished by integrating an assistance of a 1D CNN-LSTM joint learning model, which is verified by an alphabetic handwriting recognition with a classification accuracy up to 100 %. This study provides significant insights for enhancing the performance of PENGs and offers valuable guidance for exploring the application of PENGs in flexible electronics and artificial intelligence.

Ultrasonically enhanced zinc powder replacement method for cobalt removal: Electrochemical behavior, numerical simulation

The zinc powder replacement method for Co removal is characterized by several challenges, such as poor mass transfer and agglomeration. To solve this problem, the ultrasonically enhanced zinc powder replacement method was developed and used to remove Co from the sulfate solution, and a 95.02% removal rate of Co was achieved under the optimized condition. Compared with conventional conditions, the removal rate increased by 24.5%. The behavior and mechanism of zinc powder replacing Co were comprehensively analyzed through electrochemistry and COMSOL Multiphysics. Chronoamperometry curves showed that after the introduction of ultrasound, the reaction current increased by approximately two times compared with the conventional condition. The cyclic voltammetry (CV) curves showed that the reduction potential of Co positively shifted, accompanied by an increase in peak current. The electrochemical impedance spectroscopy (EIS) tests showed that the nuclear transmission resistance decreased by approximately 1.6 times compared with conventional conditions. In addition, the COMSOL simulation revealed that, after the system was subjected to ultrasonic conditions, the temperature, flow rate, and sound pressure physical field increased, which accelerated the heat and mass transfer process in the solution. The removal behavior of the system was studied using scanning electron microscopy and X-ray diffraction. Ultrasonic waves decomposed the insoluble substances on the surface of zinc powder, refined the particles, and improved the removal rate of Co. This provides new insights into the ultrasound-enhanced reaction.

Experimental study on fiber-reinforced cement tailings sand-based grouting material preparation and factors influencing the grouting effect

To address the problem of permeation of tailings pond initial dams rockfill dams, fiber-reinforced cement tailings sand-based grouting (FRCTG) material, which can be used for rockfill dam reinforcement, was prepared by selecting ordinary portland cement (OPC), iron tailings sand (ITS), basalt fiber (BF), fly ash (FA) and water as the raw materials. Orthogonal tests were used to investigate the effects of the water-binder ratio (w/b) and material mass fraction on the rheological and mechanical properties of FRCTG and determine the optimum mixing ratio. Comparative analyses were performed of the grouting effect of FRCTG and pure OPC grouting materials based on concrete self-compacting tests and COMSOL simulations. Combined X-ray diffraction (XRD) and scanning electron microscopy-energy spectroscopy (SEM-EDS) microstructural characterization were used to reveal the factors influencing FRCTG mechanical properties. The results showed that when the water-binder ratio (w/b) was 0.5, ITS substitution percentage for OPC was 10 %, BF dosage was 0.2 %, BF length was 6 mm, and FA substitution percentage for OPC was 8 %, FRCTG had better rheological properties and flexural strength than pure OPC grouting materials. In addition, FRCTG self-compacting concrete also had stronger compressive strength and splitting strength. FRCTG showed a better filling capacity and diffusion effect, which preliminarily verified the feasibility of rockfill dam grouting. ITS inhibited the hydration reaction of the cementitious material and prolonged the setting time of the slurry. The interlocking structure formed by FA and hydration products indirectly enhanced the flexural strength of the grouting material. BF not only provided FRCTG reinforcement but also acted as the hydration product skeleton. FRCTG demonstrated better economic and environmental performance than traditional cement material while effectively utilizing ITS and FA solid waste.

Hierarchical NiCo2Se4 Arrays Composed of Atomically Thin Nanosheets: Simultaneous Improvements in Thermodynamics and Kinetics for Electrocatalytic Water Splitting in Neutral Media.

The inefficiency of electrocatalysts for water splitting in neutral media stems from a comprehensive impact of poor intrinsic activity, a limited number of active sites, and inadequate mass transport. Herein, hierarchical ultrathin NiCo2Se4 nanosheets are synthesized by the selenization of NiCo2O4 porous nanoneedles. Theoretical and experimental investigations reveal that the intrinsic hydrogen evolution reaction (HER) activity primarily originate from the NiCo2Se4, whereas the high oxygen evolution reaction (OER) performance is related to the NiCoOOH due to the structural reconstruction. The abundant Se and O vacancies introduced by atomically thin nanostructure modulate the electronic structure of NiCo2Se4 and NiCoOOH, thereby improving the intrinsic HER and OER activities, respectively. COMSOL simulation demonstrate the edges of extended nanosheets from the main body significantly promote the charge aggregation, boosting the reduction and oxidation current during HER/OER process. This charge aggregation effect notably exceeds the tip effect for the nanoneedle, highlighting the unique advantage of the hierarchical nanosheet structure. Benefiting from abundant vacancies and unique nanostructure, the hierarchical ultrathin nanosheet simultaneously improve the thermodynamics and kinetics of the electrocatalyst. The optimized samples display an overpotential of 92mV for HER and 214mV for OER at 100mA cm-2, significantly surpassing the performance of currently reported HER/OER catalysts in neutral media.