Simple Spray Method Research Articles

Significantly enhanced corrosion resistance for Fe-based amorphous coatings via sealing treatment: Based on hybridisation and superhydrophobicity strategy

Based on the synergistic effect of hybridisation-superhydrophobicity, a simple and facile spraying method was used to achieve efficient sealing of Fe-based amorphous metallic coatings. In this paper, we employed rare-earth neodymium salts as inorganic sealant raw materials and loaded low surface energy fluorosilanes into epoxy resins to act as organic sealant raw materials. The surface structure and chemical composition of the sealing coatings were systematically characterised. The sealing mechanism as well as the anti-corrosion mechanism of the coating were investigated intensively. The results indicate that the superior corrosion resistance and self-cleaning ability of the sealed coating stems from the inorganic–organic-complex trinity effect: the corrosion inhibition effect of Nd oxide deposited during the inorganic sealing process, the shielding effect of the resin in the organic sealing, and the cross-linking and superhydrophobicity behaviour (liquid repellency effect) of the FDTES-Nd3+-Fe2+ complexes formed on the surface of the coating. This work provides valuable guidelines and insights for the design of subsequent corrosion-resistant and sealing coating.

AIEE-Active Green Fluorescence Imaging Technique for Latent Fingerprint Application.

Latent fingerprint imaging is a crucial tool for national security and crime recognition, requiring environmentally sustainable, nontoxic materials. To address this need, we have developed a green fluorescence-emitting material, THCHO, that binds effectively to latent fingerprints, enabling clear, high-resolution visualization. The solution produces strong green fluorescence that highlights fingerprint imprints with exceptional detail and contrast. The material is applicable across various substrates, making it efficient for on-site visualization. The synthesized organic conjugated material THCHO rapidly visualizes precise fingerprint substructures within 5 s using a simple spray method. It maintains high contrast and low interference across different substrates, such as glass, aluminum foil, plastic, and ironware, even in diverse backgrounds. Additionally, the THCHO material demonstrates high stability, retaining its fluorescence imaging capabilities for up to 35 days and after water washing. This is the first report of using a conjugated organic thiophene material for latent fingerprint fluorescence imaging, suggesting potential applications in other fields.

Preparation of superhydrophobic/oleophobic wood coating with fluorinated silica sol by a simple spraying method

The biomimetic construction of superhydrophobic coatings on wood surfaces significantly reduces the water absorption capacity of wood while enhancing its deformation resistance, thereby extending the service life of wooden structures. In this work, a fluorinated silica sol was prepared from alkaline silica sol and 1H,1H,2H,2H-perfluorodecyltrimethoxysilane (PFDMS), and evenly sprayed over the wood surface to effectively produce superhydrophobic/oleophobic wood specimens. The effect of the preparation procedure of fluorinated silica sol on the wettability of the coating was investigated. Acid and alkali corrosion tests were conducted to assess the chemical stability of the superhydrophobic coating, while sandpaper abrasion tests were used to evaluate its mechanical stability. The results showed that with a volume ratio of silica sol to PFDMS of 6:1 and a reaction period of 30 min, the modified wood exhibited excellent superhydrophobicity, with a water contact angle of 157.3° and an oil contact angle of 126.5°. Furthermore, the superhydrophobic coating demonstrated excellent mechanical and chemical durability, along with self-cleaning properties. These findings have significant practical implications for enhancing the performance and longevity of wood.

Facile fabrication of robust, multi-functional and superhydrophobic coatings with corrosion resistance and anti-icing performance

In this paper, a series of superhydrophobic coatings with varying n-SiO2 content were prepared using a simple one-step spray method. The coatings were characterized with SEM, XPS, electrochemical workstation, AFM, etc. The influence of n-SiO2 content on the micro-nanostructure of the coatings was investigated, as well as the elemental composition, the wettability, mechanical stability, chemical stability, and anti-icing performance. The results showed that as the n-SiO2 content increased, the wettability and anti-icing time of the coatings initially increased and then decreased. The optimal performance was achieved at an n-SiO2 content of 4.16 wt%, with a contact angle of 162.62°, a sliding angle of 4.17°, and an anti-icing time of 1095 s. Mechanical stability was improved with increasing n-SiO2 content, and the coatings lasted for 40 sandpaper abrasion cycles, 55 tape peeling cycles, and 31 icing/deicing cycles at 4.88 wt% of n-SiO2. The coatings demonstrated good chemical stability in neutral and acidic environments but failed in strongly alkaline conditions. Electrochemical tests revealed that the superhydrophobic coatings provided excellent protection, with the corrosion inhibition efficiency (η) of Q235 carbon steel reaching 99.99 % after coating compared to uncoated Q235 carbon steel.

Construction of robust superhydrophobic surfaces with electrothermal, photothermal properties using simple spraying method

In this study, robust superhydrophobic surfaces with electrothermal, photothermal properties were fabricated by simple spraying method. In more detail, multiwall carbon nanotube (MWCNT) and silica were deliberately sprayed onto the wet poly(amide imide) (PAI) surface to construct intensive conductive network with hierarchical porous structure. The composite coating showed superhydrophobic with a water contact angle (CA) of greater than 155o and sliding angle (SA) of lower than 5o, conductivity of approaching to 1 kΩ sq-1. As expected, the composite coating possessed passive anti-icing property owing to its high CA, and the freezing time at -20 °C was obviously delayed from 150 to 600 s. On the other hand, the surface temperature respectively increased by 40 °C and 35 °C under the assistance of electric (voltage of 36 V) or light (0.23 W cm-2 irradiation) power, and the active anti-icing function can still work even under a such low temperature of -15 °C. It is worth noting that the heat generated by Joule effect was fixed on the conductive surfaces, and thus the composite coating showed good thermal insulation due to the low thermal conductivity of PAI substrate (0.298 W/mK) and hierarchical porous structure of composite coating. In addition, the surfaces showed high mechanical robust and durability, and the superhydrophobic and conductive properties were nearly unaffected even they suffered from lots of tests such as sandpaper abrasion, ultrasonic treatment, strong acid or strong alkali immerse, UV irradiation, and hot water jet impacting. Therefore, this study offered a simple way to fabricate electrothermal and photothermal surfaces for practical anti-icing/de-icing applications.

Fabrication of PDMS/FA superhydrophobic coatings and its self-cleaning and anti-icing performance

Superhydrophobic coatings have garnered immense attention in recent years. Nevertheless, the creation of superhydrophobic coatings is often associated with high production costs and comparatively intricate fabrication processes. In this paper, we utilize cheap and easily available ultrafine fly ash(FA) as the main raw material to replace the expensive filler substances traditionally used for constructing rough structures, and Polydimethylsiloxane(PDMS) as a low surface energy modification to construct FA-based superhydrophobic coatings by a simple spraying method. The PDMS/FA coating surface exhibits a water contact angle(WCA) of 157.65°and a water sliding angle(WSA) of 2.00° The irregular morphology of the FA is conducive to forming a rough texture on the coating surface, which captures more air, leading to the formation of a stable air layer. Molecular dynamics (MD) simulations provide an insight into the anti-wetting mechanism of the superhydrophobic surface through an analysis of energetic and dynamic properties. PDMS/FA coatings remain superhydrophobic at 150 °C, in UV, and in varying pH environments. In addition, PDMS/FA coatings offer excellent mechanical, self-cleaning and anti-icing properties. This innovative approach to superhydrophobic coating, utilizing solid waste material as a basic material, demonstrates potential applicative value in fields such as self-cleaning and anti-icing.

Robust superhydrophobic self-cleaning coating prepared by silane modified multi-walled carbon nanotubes: A combined experimental and molecular dynamics study

As a functional material, superhydrophobic coating has been widely studied in the field of self-cleaning. However, obtaining superhydrophobic coatings with robustness through simple preparation processes remains a challenge. In this paper, a robust superhydrophobic coating is prepared based on multi-walled carbon nanotubes modified by octyltrimethoxysilane, and its performance and hydrophobic mechanism are studied by experiments and molecular dynamics simulation. The superhydrophobic coating is prepared by one-step spraying method. The coating is characterized and analyzed by scanning electron microscopy and Fourier transform infrared spectroscopy, and the properties of the coating are tested by experiments. Molecular dynamics simulation is used in the study to construct a molecular model system, and the molecular modification mechanism and coating wettability are simulated under the COMPASSII force field. The results show that octyltrimethoxysilane successfully modified carbon nanotubes, and the hydroxyl groups at the head of the molecular chain are bound to the surface of the carbon nanotubes in the form of hydrogen bonds, while the tail of the molecular chain is far away from the surface. After modification, the surface of carbon nanotubes changed from hydrophilic to hydrophobic. The prepared superhydrophobic coating not only has excellent self-cleaning properties, but also exhibits corrosion resistance to acid and alkali solutions. The coating still has superhydrophobic when the wear length is in the range of 400 cm. It can be seen that a robust superhydrophobic self-cleaning coating is successfully prepared by a simple one-step spraying method. The modification mechanism and the hydrophobic mechanism of the coating were obtained by the combination of experiment and molecular dynamics simulation, which provided theoretical support for the superhydrophobic of the coating at the micro level.

Multifunctional superhydrophobic coatings with self-cleaning and anti-fouling properties for corrosion protection of metals

Superhydrophobic coatings have self-cleaning, antifouling, and anti-corrosion properties due to their unique surface properties, but their disadvantages such as poor durability, poor mechanical properties, and complicated preparation methods severely limit their practical applications. Here, super hydrophobic coatings with high abrasion resistance and long-lasting corrosion resistance were prepared by a simple spraying method using stearic acid-modified titanium dioxide nanoparticles (TiO2), polyphenylene sulfide (PPS) as the base material, and doped polyvinylidene difluoride (PVDF). The SA-TiO2 can provide low surface energy and rough structure, and the PPS itself has high mechanical strength and corrosion resistance properties. The PVDF doping can generate cross-linking inside the coating to improve the densification and mechanical strength of the coating, while the formation of irregular micrometer-sized protrusions can play a role in protecting the nano-surface. he synergistic effect of the various components results in an excellent mechanical stability of the coating, which remains superhydrophobic after a 400 cm sanding test. In addition, the coating has excellent corrosion resistance, and the electrochemical impedance spectroscopy (EIS) results show that the impedance modulus of the coating is as high as 21.99 kΩ· cm2. The coating has a hierarchical micro-nano structure, and shows excellent mechanical and corrosion resistance, which is of great potential for practical applications.

Wood sponge with photothermal, magnetically driven, and superhydrophobic characteristics for high-viscosity oil–water separation

In this work, naturally degradable porous balsa wood was used as a raw material to prepare a highly elastic wood sponge (WS) substrate using a two-step chemical method and a freeze-drying method. The surface hydrophobic modification of Fe3O4 nanoparticles using the fluorine-free material octadecyltrimethoxysilane (C18TMS) solved the problem of agglomeration caused by the high nanoparticle surface energy. Polydopamine (PDA), hydrophobically modified Fe3O4 (C18TMS/Fe3O4), and low-surface-energy polydimethylsiloxane (PDMS) were sprayed onto WS substrates using a simple spraying method. An environmentally friendly adsorption sponge with photothermal, magnetically driven, and superhydrophobic properties was prepared for the first time using this method. The prepared sponge had a water droplet contact angle of 156.8° and exhibited excellent oil–water separation performances. Due to the addition of PDA and Fe3O4, the modified sponge exhibited excellent photothermal performance, rapidly heating to 63.4°C under a sunlight intensity of 1 kW m−2. The superhydrophobic WS prepared in this experiment provides a more environmentally friendly and low-cost way for high viscosity oil–water separation and targeted removal of oil pollution.

Robust and Superhydrophobic Polydimethylsiloxane/Ni@Ti3C2Tx Nanocomposite Coatings with Assembled Eyelash-Like Microstructure Array: A New Approach for Effective Passive Anti-Icing and Active Photothermal Deicing.

To solve the problem of ice condensation and adhesion, it is urgent to develop new anti-icing and deicing technologies. This study presented the development of a highly efficient photothermal-enhanced superhydrophobic PDMS/Ni@Ti3C2Tx composite film (m-NMPA) fabricated cost-effectively and straightforwardly. This film was fabricated utilizing PDMS as a hydrophobic agent, adhesive, and surface protector, while Ni@Ti3C2Tx as a magnetic photothermal filler innovatively. Through a simple spraying method, the filler is guided by a strong magnetic field to self-assemble into an eyelash-like microstructure array. The unique structure not only imparts superhydrophobic properties to the surface but also constructs an efficient "light-capturing" architecture. Remarkably, the m-NMPA film demonstrates outstanding superhydrophobic passive anti-icing and efficient photothermal active deicing performance without the use of fluorinated chemicals. The micro-/nanostructure of the film forms a gas layer, significantly delaying the freezing time of water. Particularly under extreme cold conditions (-30 °C), the freezing time is extended by a factor of 7.3 compared to the bare substrate. Furthermore, under sunlight exposure, surface droplets do not freeze. The excellent photothermal performance is attributed to the firm anchoring of nickel particles on the MXene surface, facilitating effective "point-to-face" photothermal synergy. The eyelash-like microarray structure enhances light-capturing capability, resulting in a high light absorption rate of 98%. Furthermore, the microstructure aids in maintaining heat at the uppermost layer of the surface, maximizing the utilization of thermal energy for ice melting and frost thawing. Under solar irradiation, the m-NMPA film can rapidly melt approximately a 4 mm thick ice layer within 558 s and expel the melted water promptly, reducing the risk of secondary icing. Additionally, the ice adhesion force on the surface of the m-NMPA film is remarkably low, with an adhesion strength of approximately 4.7 kPa for a 1 × 1 cm2 ice column. After undergoing rigorous durability tests, including xenon lamp weathering test, pressure resistance test, repeated adhesive tape testing, xenon lamp irradiation, water drop impact testing, and repeated brushing with hydrochloric acid and particles, the film's surface structure and superhydrophobic performance have remained exceptional. The photothermal superhydrophobic passive anti-icing and active deicing technology in this work rely on sustainable solar energy for efficient heat generation. It presents broad prospects for practical applications with advantages such as simple processing method, environmental friendliness, outstanding anti-icing effects, and exceptional durability.

A waterborne coating system for constructing inorganic-organic composite anti-corrosion and wear-resistant coating

In the fields of engineering and materials science, enhancing the corrosion resistance of engineered metal materials is extremely important. Most common anti-corrosion coatings often lack the capacity to resist external damages, which can lead to a failure in the coating's physical shielding effect. In this study, we have developed an all-water-based, simple one-step spray method for preparing a modified phosphate-based organic-inorganic composite coating, designated as AP-S30@Al2O3@PTFE. The nanofillers of polytetrafluoroethylene (PTFE) and alumina (Al2O3) were dispersed into inorganic binder aluminum phosphate (AP) modified by silica sol (S30). The effects of the incorporation of S30 and Al2O3 as the second hard phase on their wettability, mechanical properties, microscopic morphology, abrasion resistance, and corrosion resistance of the composite coatings were investigated. The results showed that the AP-S30@Al2O3@PTFE coating significantly improved the corrosion resistance of the metal, with the open current density decreasing from 2.285×10−5 to 1.653×10−7 mA·cm−2, and the open potential decreasing from −0.7533 to −0.2577 V. In addition, the composite coating provides a significant improvement in wear resistance. Thus, this cost-effective and eco-friendly method may offer significant contributions to the design and fabrication of strategic composite coatings, advancing their practical deployment in the protection of metal surfaces.

Oral feed-based administration of phage cocktail protects rohu fish (Labeo rohita) against Aeromonas hydrophila infection.

Aeromonas hydrophila is one of the major freshwater fish pathogens. In the current study, a cocktail of D6 and CF7 phages was given orally to Labeo rohita to assess phage survival in fish organs as well as to determine the therapeutic efficacy of phage treatment against fish mortality caused by A. hydrophila. In the phage-coated feed, prepared by simple spraying method, phage counts were quite stable for up to 2 months with a decline of ≤ 0.23 log10 and ≤ 1.66 log10 PFU/g feed during 4 oC and room temperature storage. Throughout the experimental period of 7 days, both phages could be detected in the gut of fish fed with phage-coated feed. Besides, both CF7 and D6 phages were also detected in fish kidneys indicating the ability of both the phage to cross the intestinal barrier. During challenge studies with LD50 dose of A. hydrophila, phage cocktail doses of 1 × 106 - 1 × 108 PFU/g feed prevented the mortality in L. rohita with relative percentage survival (RPS) of 8.7-65.2. When challenged with LD90 dose of A. hydrophila, an RPS value of 28.6 was obtained at a phage cocktail dose of 1 × 108 PFU/g feed. The RPS data showed that orally-fed phage cocktail protected the fish against the mortality caused by A. hydrophila in a dose-dependent manner. Simple practical approaches for phage cocktail development, medicated feed preparation and oral administration along with phage survival and protection data make the current study useful for farmer-level application.

Interlaminar performance of three nanomaterials film enhanced glass fiber reinforced polymer

The carbon nanotube (CNT) and graphene oxide are widely applied in Glass Fiber Reinforced Polymer (GFRP) to enhance interlaminar performance, even though they have an extremely expensive price. Herein, we provide a novel interlaminar toughening material: carbon black, which has a cheap price and good interlaminar properties. The relationship between different amounts of three nanomaterials and toughening efficiency is obtained through experiments (end notch bending (ENF) test) and the curves between different amounts and prices are revealed by the investigation. Moreover, a mathematical model of interlaminar performance, material consumption, and price is established, which can provide researchers with accurate, efficient, and inexpensive predictions in different application environments. On the other hand, a simple and efficient spraying method for making reinforcement layers is adopted in this research and we analyzed the microstructure strengthening mechanism of three nanomaterials by scanning electron microscopy (SEM).

MXene-Based Pressure Sensor with a Self-Healing Property for Joule Heating and Friction Sliding.

As a kind of flexible electronic device, flexible pressure sensor has attracted wide attention in medical monitoring and human-machine interaction. With the continuous deepening of research, high-sensitivity sensor is developing from single function to multi-function. However, Current multifunctional sensors lack the ability to integrate joule heating, detect sliding friction, and self-healing. Herein, a MXene/polyurethane (PU) flexible pressure sensor with a self-healing property for joule heating and friction sliding is fabricated. The MXene/PU sensitive layer with special spinosum structure is prepared by a simple spraying method. After face-to-face assembly of the sensitive layers, the MXene/PU flexible pressure sensor is obtained and showed excellent sensitivity (150.65kPa-1), fast response/recovery speed (75.5/63.9ms), and good stability (10000 cycles). Based on the self-healing property of PU, the sensor also has the ability to heal after mechanical damage. In addition, the sensor realizes the joule heating function under low voltage, and has the real-time monitoring ability of sliding objects. Combined with low cost and simple manufacturing method, the multi-functional MXene/PU flexible sensor shows a wide range of application potential in human activity monitoring, thermal management, and slip recognition.

A cost-effective photothermal superhydrophobic coating with micro- and nano-graded structures for efficient solar energy harvesting

Solar collector coatings can solve the current energy shortage and environmental pollution by converting clean solar energy into thermal energy. However, once the coating is adhered to a liquid, the performance of the solar thermal conversion will be seriously affected. Here, a cost-effective photothermal superhydrophobic coating was designed by modulating the microstructure of a highly solar-absorbing material (MCN), followed by a simple spraying method combined with polyvinylidene fluoride resin (PVDF). The MCN in the coating provides excellent photothermal conversion performance, hence, the surface temperature of the coating can be rapidly increased to 97.5 °C at 1 kW/m2. In addition, the coating achieves a water contact angle (WCA) of 155.79° due to the combined micro-nano structure of MCN and PVDF coupled with the low surface energy of PVDF. More importantly, the coating possesses excellent mechanical properties and can be applied to different substrates. This cost-effective photothermal superhydrophobic coating has promising applications in outdoor environments such as insulated tents and waterproof insulation packaging.

Preparation of superhydrophobic conductive micro/nano‐graphite/PDMS films on paper by simple spraying method

AbstractPaper‐based materials are widely used in various fields due to their advantages, such as environmental friendliness and sustainability. However, the highly hydrophilic nature of the cellulose that makes up paper‐based materials limits their use. In this paper, micron/nano‐graphite/polydimethylsiloxane (PDMS) coatings with excellent superhydrophobic and conductive properties were prepared on the surface of filter paper by a simple spraying method. A mixture of micro‐graphite and nano‐graphite was used to form a multistage rough structure on the surface of the filter paper by spraying, and the low surface energy PDMS enhanced the adhesion of the micro‐graphite and nano‐graphite on the surface of the filter paper. The results showed that the samples possessed the best superhydrophobic properties when the ratio of micro‐graphite to nano‐graphite was 1:1, at which time the contact and rolling angles of the samples were 165.4° and 3.2°, respectively. The prepared superhydrophobic samples have good bounce and self‐cleaning properties, while the samples have good mechanical stability and chemical resistance. Additionally, due to the conductivity of micro–nano‐graphite, both particle sizes closely contact the sample surface, creating a conductive network. With a 1:1 ratio of micro‐ and nano‐graphite, the coating exhibits minimal resistance at 1.89 KΩ, and the sample maintains stable conductivity even underwater. The above properties greatly extend the application range of paper‐based superhydrophobic materials.

Robust superhydrophobic coating with carbon nanotubes and silica nanoparticles in the matrix of fluorinated polyurethane

After years of research, superhydrophobic coatings have made great progress, but the complex preparation process and poor durability are still key issues that limit their practical application. Herein, we developed a room temperature cured durable superhydrophobic coating through a simple spraying method. The main polymer matrix used in this study was fluorinated polyurethane (FPU), which exhibited high hardness (5H), strong adhesion to the substrate (grade 1, GB/T 9286), and excellent hydrophobicity with a contact angle of approx. 108 ° Silica nanoparticles were found to be highly effective in enhancing the surface hydrophobicity of FPU. Nevertheless, these particles can be easily removed from the surface by even a simple touch with a finger. For enhanced durability, we incorporated carbon nanotubes (CNTs) with intertwining structures. Additionally, polydimethylsiloxane (PDMS) was utilized to facilitate the interaction between the inorganic fillers and the organic FPU matrix, owing to its inorganic Si-O skeleton and organic side chains. The so-optimised composite coating was covered with micro-/nano- particles and the hydrophobicity was enhanced greatly (contact angle of ∼165 ° and sliding angle of 5.5 °). The contact angle of the coating remained higher than 150 ° even after undergoing a range of tests. These tests included immersing in corrosive solutions for 60 h, gravel impacting for 100 cycles, water jetting for 1200 s, and abrading against sandpaper for 1000 cycles. The good chemical and mechanical durability was due to the high compactness, high hardness (4H pencil hardness), and high adherence (grade 1, GB/T 9286) of the coating. Moreover, due to the photothermal conversion effect of carbon nanotubes, the coating possessed excellent photothermal performance and showed good application prospects in anti icing / deicing.

Highly positive fluorophlogopite for enhanced power generation in triboelectric nanogenerators prepared on a flexible Ni–Cu fabric

Recent developments in triboelectric nanogenerators (TENGs) facilitate creation of sustainable, self-powered energy harvesting systems. In our study, we introduce fluorophlogopite as a positive triboelectric material with excellent electron transfer capabilities. We investigate the efficacy of a fluorophlogopite-based TENG, MgF-mica-TENG. We use a simple spray method on flexible Ni–Cu conductive fabric platforms to perform electrical analyses including open-circuit voltage (Voc), short circuit current (Isc), and peak power density using a home-made, 3D-printed, M-shaped spring setup. MgF-mica-TENG exhibited enhanced performance compared to the conventional muscovite-based TENG (Al-mica-TENG). This enhanced performance is primarily attributed to the increased surface potential of fluorophlogopite, which facilitate efficient charge transfer upon the contact of two electrodes, combined with optimized 11fabrication parameters. Based on our findings, we anticipate that MgF-mica materials can pave the way to the development of a comprehensive strategy to powering smart electronics, harnessing the abundant mechanical energy sources found in our daily surroundings.

Mn0.6Ni1.4Co2Oy micro-nano tower structure with tunable spectral selectivity interface for infrared stealth and solar selective coating application

In order to make full use of solar energy and solve the problem of functional incompatibility between solar and infrared spectra, the present work has cleverly aimed at the problem by designing Mn0.6Ni1.4Co2Oy multi-functional interface. The Mn0.6Ni1.4Co2Oy coating was obtained by a simple vacuum spraying method. It was found that the coatings prepared with the appropriate amount of MNC/resin ratio (5:5) possessed the high solar absorptivity (0.915) and low infrared emittance (0.245) at ambient temperatures, as well as excellent heat-collecting properties, which suggests that the structure of the Mn0.6Ni1.4Co2Oy is maximally preserved. Notably, the DSC results confirm that the introduction of Mn0.6Ni1.4Co2Oy into the resin can strengthen the thermal stability of the coating, which is mainly attributed to the fact that Mn0.6Ni1.4Co2Oy can effectively prevent the chain segment movement of the resin. Furthermore, the addition of low-emissivity aluminum powder further reduced the emissivity of the coating to 0.142 and the absorbance/emissivity ratio to 6.22 at room temperature. The coating demonstrated remarkable thermal stability and infrared stealth performance even at 300 °C, meeting the basic requirements of solar selective absorption. This work provides a low-cost and simple spray method for fabricating Mn0.6Ni1.4Co2Oy solar selective absorption coating with great potential in high-temperature infrared stealth applications.

Dual-Coating of Fluorinated Polydimethylsiloxane/Fluorinated SiO2 Nanoparticles for Superhydrophobic and High-Efficiency Bacteriostatic Surface.

A simple two-step spray method is used to prepare superhydrophobic and bacteriostatic surfaces, involving dual-coating with polydimethylsiloxane-normal-fluorine (PDMS-NF) or branched-fluorine (PDMS-BF) in combination with fluorinated silica nanoparticles (FSiO2 -NPs) using a spray technique. This approach has the potential to create surfaces with both water-repellent and antimicrobial properties, which could be useful in a variety of applications. It is noteworthy that the dual-coating on cotton fabric exhibited an impressive dual-scale roughness and achieved superhydrophobicity with a water contact angle of 158° and a hysteresis of less than 3°. Additionally, the coating was subjected to an ultra-high concentration of bacteria (109 CFU/mL) and was still able to inhibit more than 80 % of attachment, demonstrating its effectiveness as a bacteriostatic surface.