Simple Engineering Research Articles

Obtaining versatile Cr3+-activated phosphors with improved far-red emissions via host composition modulation

Cr3+-activated spinel-type phosphors have great potential in different application scenes due to their unique sharp and far-red (FR) emission. However, the multi-functionalization of these phosphors is still limited by their unsatisfied comprehensive properties. Herein, a simple composition engineering was used to explore versatile phosphors, using Ga3+ to substitute Al3+ to improve the optical performances of spinel LiAl5–xGaxO8:Cr3+. The substitution of Ga3+ evidently affects the crystal field environment of Cr3+ and further accounts for the luminescence optimization. Using the optimized phosphor, two sensitive thermometers based on fluorescence intensity ratio (FIR) technique were explored on account of the different temperature dependencies of 4T2→4A2 and 2E→4A2 emission and of R2 and R1 emission. The maximum relative sensitivity Sr are 1.29%/K at 323 K and 1.94%/K at 298 K, respectively, which are superior to that of the Ga3+-unsubstituted one. Besides, the Ga3+→Al3+ substitutions endow the resultant phosphors with larger atomic number (Zeff) and theoretical density, which is more conducive to improving X-ray-stimulated emission for X-ray detection. Finally, the potential applications of the developed phosphor are also reflected in plant growth and night vision surveillance, as it is shown to be capable of matching with the absorption of phytochrome PFR and visualizing objects in the dark. This contribution not only proves that the developed LiAl5–xGaxO8:Cr3+ FR phosphors are promising versatile platforms, but also provides an essential guidance for designing more novel multi-functional materials.

Sensor event sequence prediction for proactive smart home: A GPT2-based autoregressive language model approach

We propose a framework for predicting sensor event sequences (SES) in smart homes, which can proactively support residents’ activities and alert them if activities are not completed as intended. We leverage ongoing activity recognition to enhance the prediction performance, employing a GPT2-based model typically used for sentence generation. We hypothesize that the relationship between ongoing activities and SES patterns is akin to the relationship between topics and word sequence patterns in natural language processing (NLP), enabling us to apply the GPT2-based model to SES prediction. We empirically evaluated our method using two real-world datasets in which residents performed their usual daily activities. Our experimental results demonstrates that the use of the GPT2-based model significantly improves the F1 value of SES prediction from 0.461 to 0.708 compared to the state-of-the-art method, and that leveraging knowledge on ongoing activity can further improve performance to 0.837. Achieving these SES predictions using the ongoing activity recognition model required simple feature engineering and modeling, yielding a performance rate of approximately 80%.

Ligand and band engineering-induced covalent organic framework-embedded Ti32 Oxo-cluster gels-based Z-scheme heterojunction for boosting the photocatalytic degradation performance of tetracycline

Designing and synthesizing highly efficient photocatalysts with proper energy band structures, which can accelerate the degradation of antibiotics, is crucial and challenging. Herein, by introducing a simple ligand engineering strategy, we ingeniously developed a novel approach for facile synthesis of covalent organic framework (COF) embedded and oxygen vacancies (OV) in-situ doped Ti32 oxo-cluster gels-based Z-scheme heterojunction, COF@OV-Ti32-gels (CT-X). This strategy has led to a remarkable improvement in the photodegradation efficiency of tetracycline hydrochloride (TC), increasing from 15% (pure Ti32 crystals) to an impressive 93.7%. The heterojunctions, which possess modified bandgap structures due to the presence of oxygen defects, exhibit superior photo-induced charge separation efficiency compared to Ti32 without such defects. This enhanced utilization of sunlight results in highly efficient photocatalytic degradation of TC via a built-in electric field. Intriguingly, the CT-X photocatalysts, synthesized with a unique heterojunction structure, exhibit the ability to achieve full-time domain degradation of TC. Notably, CT-X can effectively degrade TC in the absence of light, and its degradation capability is significantly enhanced upon exposure to visible light. Furthermore, the superoxide radical (•O2¯) was evidenced to play a crucial role in the photocatalytic process, and the corresponding degradation mechanism was also depicted.

Interfacial Si–O–Zr bonds induced well dispersed zirconia on magnetic mesoporous silicas for enhanced tetracycline removal

Constructing recoverable materials with both high adsorption capacity and excellent photocatalytic performance towards antibiotics elimination is very meaningful and challenging in wastewater remediation. In this work, we demonstrate a simple interface engineering strategy to design well dispersed zirconia on core–shell structured magnetic mesoporous silica microspheres (MMS) for efficient removal of tetracycline hydrochloride (TC). With ultrahigh specific surface area (682.0 m2/g) and interfacial Si-O-Zr serving as active sites, the optimal sample (MMS-Zr10) exhibits enhanced TC adsorption capacity of 266.5 mg/ZrO2 g, which is 19.2-fold than that of pure ZrO2. Simultaneously, the photocatalytic degradation rate constant of TC over MMS-Zr10 in the presence of peroxydisulfate (PDS) is 12.5 times that of ZrO2 under visible light irradiation, which may be attributed to the enhanced light harvest capability and high charge separation efficiency facilitated by interfacial Zr–O–Si charge transfer channels. Furthermore, in consecutive adsorption cycles in both deionized (DI) water solution and actual wastewater, no obvious decline in TC removal % is observed. The TC adsorption is mainly governed by pore filling, hydrogen bonding and electrostatic interactions; whilst O2•−, h+, SO4•−, •OH and 1O2 species are responsible for enhanced photocatalytic degradation of TC.

Modelling and Thermographic Measurements of LED Optical Power.

This paper presents a simple engineering method for evaluating the optical power emitted by light-emitting diodes (LEDs) using infrared thermography. The method is based on the simultaneous measurement of the electrical power and temperature of an LED and a heat source (resistor) that are enclosed in the same plastic packaging under the same cooling conditions. This ensures the calculation of the optical power emitted by the LED regardless of the value of the heat transfer coefficient. The obtained result was confirmed by comparing it with the standard direct measurement method using an integrated sphere. The values of the estimated optical power using the proposed method and the integrated sphere equipped with a spectrometer were consistent with each other. The tested LED exhibited a high optical energy efficiency, reaching approximately η ≈ 30%. In addition, an uncertainty analysis of the obtained results was performed. Compact modelling based on a thermal resistor network (Rth) and a 3D-FEM analysis were performed to confirm the experimental results.

Engineering stable Cu+-Cu0 sites and oxygen defects in boron-doped copper oxide for electrocatalytic reduction of CO2 to C2+ products

Cu-based catalysts inevitably undergo surface reconstruction during the electrochemical carbon dioxide reduction reaction (CO2RR) process. Thus, it is a challenge to construct stable Cu+-Cu0 sites of Cu-based catalysts. In this study, we report a simple and facile engineering strategy for stable Cu+-Cu0 sites and oxygen defects derived from the boron-doped copper composite catalyst (B-CuxO) as an efficient CO2RR electrocatalyst. The 5 % B-CuxO exhibited 48.44 % C2+ products Faraday efficiency (FE) for 12 h at −1.0 V vs reversible hydrogen electrode (RHE) in H-cell, which was far superior to CuxO (23.85 %). Combining density functional theory (DFT) and in situ Attenuated Total Reflection Fourier Transform Infrared spectroscopy (in situ ATR-FTIR), a higher electronic depletion on the catalyst surface inhibited the electrons accumulation around Cu sites, thereby maintaining the positive charge and inhibiting the complete reduction of Cu+. Moreover, the high oxygen defects in 5 % B-CuxO could effectively activate CO2 into *CO. We emphasized that Cu+ functioned as the primary active site by facilitating adsorption and dimerization of *CO, whereas Cu0 assisted in optimizing CO2 activation.

Effectiveness of a novel composite filler to enhance phosphorus removal in constructed wetlands.

Improving the adsorption performance of wetland fillers is of great significance for enhancing pollutant removal in constructed wetlands. Currently, limited by complex preparation processes and high costs, large numbers of high adsorption fillers studied in lab are difficult to be applied in practical engineering. In this study, a newly low-cost and efficient phosphorus removal composite wetland filler (CFB) is prepared by using industrial and agriculture waste (steel slag and oyster shells) and natural ore (volcanic rock) as raw materials. The results show that phosphorus removal efficiency was largely enhanced by synergistic effects of steel slag, oyster shells, and volcanic rock, and it was mainly influenced by the proportion of each component of CFB. Based on the fitting of the classical isothermal equation, the adsorption capacity of CFB is 18.339 mg/g. The adsorption of phosphorus by CFB is endothermic and spontaneous, and there are heterogeneous surfaces and multi-layer adsorption processes, as well as pH value and temperature, are free from the influence on CFB phosphorus removal. During the practical wastewater application experiments, the phosphorus removal rate of the CFB-filled constructed wetland apparatus (CW-A) can reach 94.89% and is free from the influence on the removal of other pollutants (COD, TN, and NH3-N) by the system. Overall, the prepared CFB is of excellent decontamination effect, an extremely simple preparation process, low cost, and sound practical engineering application potential, providing new ideas and approaches for enhancing the phosphorus removal capacity and waste resource utilization of constructed wetland systems.

Application of amplified damped outrigger in seismic design of high‐rise buildings

SummaryThe application of the outrigger technology effectively improves the lateral stiffness of buildings, reduces harmful deformation, enhances the seismic resistance of structures, and contributes to the rapid development of high‐rise buildings. To improve the response speed and energy dissipation of a viscous damping outrigger under seismic excitation, a viscous damping outrigger with an amplifier was proposed, and its effectiveness was verified by combining it with the seismic design of a 149.2 m high‐rise building in an 8.5‐degree intensity area. To determine the additional damping ratio of the building structure, investigations were carried out using both the code method and energy ratio method to evaluate the contribution of the damping outrigger. The damped outrigger equivalent stiffness determination method was studied, and the simplified engineering calculation method was compared against the refined finite element analysis results for engineering design purposes. The displacement amplification technique incorporated into the viscously damped outrigger can enhance the damper response speed, and increase the energy dissipation of the damped outrigger system. The application of an enlarged damped outrigger in engineering can result in an additional damping ratio of approximately 1% while simplifying the calculation method based on the additional damping and equivalent damper cut‐line stiffness, which can be useful in engineering design.

100 years of extremum seeking: A survey

Extremum seeking (ES) is a powerful approach to the optimization and stabilization of unknown dynamic systems and is an active field of research in control theory. This paper surveys recent ES algorithm developments. ES has evolved from its origins as a simple but brilliant engineering invention in the 1922 paper of Leblanc to the breakthrough work of Krstić and Wang in 2000 in which the first general stability analysis was given, to the most recent and numerous analytical results which prove convergence for a wide range of general dynamic systems. This survey provides a thorough overview of the dynamic systems for which ES stabilization and optimization results have been provided, the various analytical methods for proving convergence, and an overview of many real world applications for which ES has been utilized in industry and at scientific laboratories.

EN Optimization strategy for system management of cold thermal energy storage (CTES) in conditions of dynamic changes in energy carrier value

In world of contemporary challenges involving the continual increase in demand for energy resources and corresponding environmental pollution, the necessity has arisen to develop and implement advanced technologies to reduce energy consumption. This calls for enhancing energy utilization efficiency and optimizing energy generation systems, taking into account the utilization of alternative and renewable energy sources. Specifically, thermal energy storage becomes crucial as an effective economic option. Thermal energy storage systems enable meeting heating or cooling needs during optimal periods when it is more energy-efficient. Traditional management methods rarely prove optimal due to fluctuating electricity tariffs, cooling loads, and ambient temperature. This leads to suboptimal achievement of maximum savings in the utilization of thermal energy storage systems. In this work, the advantages of Cold Thermal Energy Storage (CTES) systems based on Ice Thermal Energy Storage (ITES) were analysed alongside existing management strategies implemented in most enterprises and buildings utilizing ITES. A simplified engineering methodology for analysing the thermodynamic efficiency of CTES was proposed. It was determined that cold losses during exergy analysis during storage are caused by both losses through surfaces and internal exergy losses (i.e., exergy consumption due to irreversibility within the reservoir). For modern systems, exergy losses encompass both external and internal components. As an example, if the heat transfer at the external surface temperature of the storage reservoir equals the ambient temperature, external exergy losses would be zero, while total exergy losses would be entirely due to internal consumption. Conversely, if heat transfer occurs at the liquid's temperature for storage, a greater portion of exergy losses will be due to external losses. In all cases, the cumulative exergy losses, comprising internal and external exergy losses, remain constant. The implementation of CTES allows for shifting the use of electrical energy from peak to off-peak hours. During off-peak hours, electrical energy is used to charge the storage to fulfil (fully or partially) the peak demand for refrigeration equipment. Ice-based ITES has the potential to reduce maximum energy consumption, peak demand, and most importantly, the average cost of energy consumed

Achieving efficient and stable blue thermally activated delayed fluorescence organic light-emitting diodes based on four-coordinate fluoroboron emitters by simple substitution molecular engineering.

Achieving both high efficiency and high stability in blue thermally activated delayed fluorescence organic light-emitting diodes (TADF-OLEDs) is challenging for practical displays and lighting. Here, we have successfully developed a series of sky-blue to pure-blue emitting donor-acceptor (D-A) type TADF materials featuring a four-coordinated boron with 2,2'-(pyridine-2,6-diyl)diphenolate (dppy) ligands, i.e.1-8. Synergistic engineering of substituents on the phenyl bridge as well as the electronic properties and the attached positions of heteroatom N-donors not only enables fine-tuning of the emission colors, but also modulates the nature and energies of their triplet excited states that are important for the reverse intersystem crossing (RISC). Particularly for the compound with two methyl substituents on the phenyl bridge (compound 8), RISC is significantly facilitated through the vibronic coupling of the energetically close-lying triplet charge transfer (3CT) and the triplet local excited (3LE) states, when compared to analogue 7. Efficient sky-blue to pure-blue OLEDs with electroluminescence peaks (λ EL) at 460-492 nm have been obtained, in which ca. five-fold higher external quantum efficiencies (EQEs) of 18.9% have been demonstrated by 8 than that by 7. Moreover, ca. thirty times longer device operational half-lifetimes (LT50) of 9113 hours for 8 than that for 7 as well as satisfactory LT50 reaching 26 643 hours for 6 at an initial luminance of 100 cd m-2 have also been demonstrated. To the best of our knowledge, these results represent one of the best high-performance blue OLEDs based on tetracoordinated boron TADF emitters. Moreover, the design strategy presented here has provided an attractive strategy for enhancing the device performance of blue TADF-OLEDs.

Modulating the crystal packing to achieve efficient ultralong organic phosphorescence by simple methylation engineering

Simple methylation engineering strategy used to adjust the packing and UOP behavior is demonstrated. The intrinsic relationship between structure and UOP properties are investigated by combining the experimental and theoretical results.

Effects of occurrence form of soil organic matter on the Atterberg limits and thermal conductivity of clays

Abstract Because of the interfacial interactions between mineral soil particles and soil organic matter (SOM), SOM occurs in various forms in the soil, and the mineral-associated and particulate forms are fundamental. Many recent studies have concentrated on the effects of SOM content and type on the geotechnical behavior of soil. However, the influence of SOM occurrence forms is not well understood, nor is there a scientific classification standard for SOM in geotechnical engineering. The main objectives of this study were to explore the effects of SOM occurrence forms on a few physical properties of clays to develop an engineering classification standard of SOM. First, this paper reviews the interfacial interaction mechanism, factors that influence the relation between mineral soil particles and SOM, and the classification method of SOM in soil science. Three predominant clays (montmorillonite, illite, and kaolinite) were then used as the matrix, and three groups of artificial soil samples with different SOM contents (wu ranging from 0 to 50% by weight) were prepared by adding peat. A chemical extraction method was used to determine the amount of different forms of SOM. Moreover, the Atterberg limits wL (wp) and thermal conductivity λ of artificial soil samples were tested. Based on the experimental results, the relationship between the form of SOM and these physical parameters was established. The experimental results show that the wL (wp) vs wu, and λ vs wu fitted curves were not monotonic but piecewise linear and could be divided into two straight lines with different slopes; wu corresponded to the inflection point of wL (wp) vs wu, and λ vs wu curves were closer to the threshold value wu,2. Finally, a simple engineering classification method of SOM is proposed.

Investigating the Laplace Transform Method’s Efficiency to a Simple Engineering Problem

In this study, it is aimed to solve the differential equation that forms a simple engineering system and transform it into the Laplace domain, and then to investigate the effectiveness of the method used to compare the solutions with the exact solutions. For this purpose, first, the solutions of a given test function with analytical and numerical Laplace inverse transform methods (Durbin, Stehfest and Talbot) are given comparatively. Although the values obtained from these three methods overlap with each other but it is observed that the Talbot inverse transform method is more suitable than the other two methods due to its lower calculation time requirement. In addition, Talbot’s method and analytical solutions to engineering problems related to the vibratory mechanical system, heat conduction problem and a single matrix block in a fractured reservoir non-isothermal gravity drainage are numerically compared. It is understood that the Talbot inverse transform method is quite effective, and this is evident from the consistency of the numerical results and analytical results of the study. The findings show that the proposed method is very suitable and the method is easy to implement without much difficulty for solving a simple engineering problem.

Establishing the Influence of Methanol Fuelled Power Propulsion and Energy Systems on Ship Design

The adoption of alternative energy carriers is one of the key ways to meet the increasingly stricter emission regulations faced by shipping vessels from the international maritime organisation (IMO) and European Commission. To support this objective, this study examines the challenges and uncertainties associated with implementing a methanol power propulsion and energy (PPE) system on the design of a vessel. This paper argues that new fuels, such as methanol, should be treatedas disruptive innovations due, in part, to the uncertainties surrounding their implementation. Their integration causes challenges regarding systems selection, layout design, and maintaining strict safety measures. In the case of methanol, current research treats the fuel as a system conversion based on diesel fuel. This paper provides a review of the state-of-the-art on the design of methanol fuelled vessels, and identifies a research gap related to the need for a new suitable design method for the design of ships integrating future alternatively fuelled PPE systems. A design approach inspired by model-based systems engineering integrating uncertainty modelling is proposed to examine the influence of uncertainty on the design of the vessels. The impact of uncertainty on the design is investigated through a case study of a simplified engine room layout utilizing a genetic algorithm to produce layouts for variable PPE systems dimensions within a MonteCarlo simulation.

Critical role of isopotential surfaces for magnetostatic ponderomotive forces.

By producing localized wave regions at the ends of an open-field-line magnetic confinement system, ponderomotive walls can be used to differentially confine different species in the plasma. Furthermore, if the plasma is rotating, this wall can be magnetostatic in the laboratory frame, resulting in simpler engineering and better power flow. However, recent work on such magnetostatic walls has shown qualitatively different potentials than those found in the earlier, nonrotating theory. Here, using a simple slab model of a ponderomotive wall, we resolve this discrepancy. We show that the form of the ponderomotive potential in the comoving plasma frame depends on the assumption made about the electrostatic potential in the laboratory frame. If the laboratory-frame potential is unperturbed by the magnetic oscillation, one finds a parallel-polarized wave in the comoving frame, while if each field line remains equipotential throughout the perturbation region, one finds a perpendicularly polarized wave. This in turn dramatically changes the averaged ponderomotive force experienced by a charged particle along the field line, not only its scaling, but also its direction.

Development of a Simple Stirling Engine Demonstration Tool on the Subject of Thermodynamics

Purpose of the study: The aim of this research is to develop a simple Stirling engine teaching aid for the class XI thermodynamics subject at high school and determine students' responses to the teaching aid developed.
 Methodology: The research method used is research and development (R&D) ADDIE model, namely with the stages of analysis, design, development, implementation, evaluation. The instruments used in this research were media expert validation questionnaires, material expert validation, small group trials and field trials with a Likert scale. The data obtained was then analyzed quantitatively and qualitatively. The test subjects in this research were carried out using small group trials of 10 students and field trials of 30 students from three schools.
 Main Findings: Based on the results of the material expert validation analysis and media expert validation, an average of 86.5% was obtained which could be categorized as very good, then for small group trials it was obtained 91.9% and 93.1% of field trials could be categorized as very good, so that the media for simple Stirling engine teaching aids were has been developed as a whole very well to be used as a teaching aid in learning in class XI High School.
 Novelty/Originality of this study: The novelty of developing a simple Stirling engine demonstration tool for the study of thermodynamics lies in its innovative approach to making a complex subject accessible, engaging, and applicable to a wide range of learners, thereby fostering a deeper understanding and appreciation of the field.

Improved Cycle Life and Determination of Li Ion Transport Parameters in Mixed Cation Doped Ni-Rich NMC

Ni-rich Li-ion cathode materials like NMC-9.5.5 (LiNi0.9Mn0.05Co0.05O2) are of interest due to their higher energy density and limited cobalt content, aiding the transition away from critical raw materials, when compared to materials like NMC111 - 622. This has the advantage of reducing production costs while maintaining a high working voltage and capacity. However, the high nickel content of these materials can be detrimental due to disorder brought by Li+/Ni2+ cation mixing, lithium residuals, and irreversible phase changes during operation resulting in significant capacity fade during cycling. Similarly, the different synthesis methods and treatments drastically affect the morphological, structural, and electrochemical propertiesWe present a structural and electrochemical study of NMC-9.5.5 prepared at scale via a hydroxide coprecipitation synthesis in a 5 L continuous stirred reactor tank (CSTR). In this work, bulk doping and co-doping with two metal cations are investigated with a simple and scalable method to achieve mixed metal and mixed valence doped NMC-9.5.5 with the aim to further improve cycle life and stability. Additionally, the effect of bulk doping on the thermodynamic and kinetic properties of the cathode material are investigated in both half-cells and full-cells using galvanostatic intermittent titration technique (GITT) and electrical impedance spectroscopy (EIS), where a 3-electrode configuration is used to elucidate the individual electrode potentials and stoichiometries.The bulk doping of the transition metal layer was found to significantly reduce the capacity fade in the NMC-9.5.5, increasing the capacity retention after 100 cycles from 78% in the undoped material to 92% and 89% in the doped and co-doped NMC-9.5.5 half-cells. The mixed metal co-doped material was also effective in delivering a higher specific capacity than the baseline throughout the full cycling range. The improved cycling performance can be understood by the inspection of the differential capacity plots, which show a suppression of the H2-H3 irreversible phase transition in the doped material and stabilisation of the peak to a higher voltage compared to the baseline. The effect of doping on the structural stabilisation is similarly reflected in the XRD characterisation, in which the introduction of the metal cation acts to constrain the detrimental Li+/Ni2+ cation mixing due to a widening of the transition metal channel. This is also supported by the EXAFS characterisation that indicate the dopants may act to stabilise the local Ni environment. These structural changes appear to be further beneficial in facilitating improved Li ion transport properties in the doped material as evidenced by the lower charge transfer resistances during cycling and increased diffusion coefficient.This research illustrates the high capacity performance of low cobalt cathode materials thus reducing the reliance on critical materials, as well as the ability to produce Ni-rich cathode material at large scale and further stabilise its cycle life by simple structural engineering. Improved materials manufacturing processes will enable a greater understanding of the synthesis process and enable more sustainable methods of synthesis. There are also benefits for cell makers with improvement in processability and additional stabilisation knowledge for battery manufacturers, as well as the consumers that benefit from longer driving ranges and battery life in their EV’s. Figure 1

Hydrogen-Bonded Organic Framework Derived 2D N, O Co-Doped Carbon Nanobelt with Tunable Pseudocapacitive Contribution for Efficient Capacitive Deionization.

Defect engineering is recognized as an attractive method for modulating the electronic structure and physicochemical characteristics of carbon materials. Exploiting heteroatom-doped porous carbon with copious active sites has attracted great attention for capacitive deionization (CDI). However, traditional methods often rely on the utilization of additional heteroatom sources and strong corrosive activators, suffering from low doping efficiency, insufficient doping level, and potential biotoxicity. Herein, hydrogen-bonded organic frameworks (HOFs) are employed as precursors to synthesize N, O co-doped porous carbon via a simple and green reverse defect engineering strategy, achieving controllable heavy doping of heteroatoms. The N, O co-doping triggers significant pseudocapacitive contribution and the surface pore structure supports the formation of the electric double layer. Therefore, when HOF-derived N, O co-doped carbon is used as CDI electrodes, a superior salt adsorption capacity of 32.29±1.42mgg-1 and an outstanding maximum salt adsorption rate of 10.58±0.46mgg-1min-1 at 1.6V in 500mgL-1 NaCl solution are achieved, which are comparable to those of state-of-the-art carbonaceous electrodes. This work exemplifies the effectiveness of the reverse nitrogen-heavy doping strategy on improving the carbon structure, shedding light on the further development of rational designed electrode materials for CDI.

Interfacial engineering of α-Fe2O3 coupled Co3O4 heterostructures anchored on g-C3N4 structure for enhanced electrocatalytic performance in alkaline oxygen evolution reaction

Creating an efficient electrocatalytic oxygen evolution reaction (OER) by developing a low-cost, stable metal oxide nanocomposite based on earth-abundant materials is an essential and highly efficient method to meet the increasing demand for sustainable energy. For this reason, we have proposed a simple and effective interfacial engineering approach to construct a novel graphitic carbon nitride (g-C3N4) strongly coupled with α-Fe2O3 and Co3O4 as dual co-catalysts for highly active electrocatalysts (ECs) OER in a typical alkaline electrolyte. The detailed structural, chemical, and morphological characterizations were performed by various analyses. The as-synthesized g-C3N4/Co3O4/α-Fe2O3 (GCFO) nanocomposite ECs exhibited efficient and stable OER performances with low overpotentials of 359 mV to attain a 10 mA/cm2 current density and a less Tafel slope of 116 mV dec−1, resulting in better durability after 14 h of the i-t test. A strong coupling interaction was found at the interface between the g-C3N4 and the α-Fe2O3/Co3O4 heterostructure, which acts as an effective electron transport channel and exposes more catalytically active sites to explore the outstanding performances for electrocatalysis OER. These results show that a novel approach for the rational coupling of composite heterostructures could be an alternative to using noble metals for sustainable energy-related applications.