Silver Solution Research Articles

Synthesis, characterization, and evaluation of antibacterial properties of silver/ carboxymethyl cellulose/ bacterial cellulose/ Clitoria ternatea extract aerogel composites

Food packaging for meat, processed food, and fresh food is often equipped with adsorbent pads to regulate moisture. However, most adsorbents are derived from synthetic polymer materials. There has been increasing demand for functional packaging materials that are not only durable, cost-effective, and well-designed, but also capable of extending the product shelf-life. Butterfly pea (Clitoria ternatea L.) flowers and silver nanoparticles have been reported to exhibit antibacterial activity in several studies. This study aimed to synthesize novel aerogel composites made of carboxymethyl cellulose (CMC), bacterial cellulose (BC), and C. ternatea flower extracts as adsorbent material in food packaging. BC was used as a reinforcing agent. The composites were synthesized by reacting silver solution and carboxymethyl cellulose, and then adding bacterial cellulose and C. ternatea extracts. Three different ratios of C. ternatea extract i.e. 0.5 %, 1 % and 2 % were used in this study (AT1, AT2, AT3). These aerogel composites were tested against four pathogenic bacteria i.e. Staphylococcus aureus, Eschericia coli, Pseudomonas aeruginosa, and Salmonella Typhimurium using disk diffusion and microdilution methods. The aerogel composites were characterized using X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray fluorescence (XRF), Fourier-transform infrared (FTIR) spectroscopy, and color analysis. The results showed that AT3 had good antibacterial activity against P. aeruginosa, S. Typhimurium, and S. aureus with inhibition zones of 10.14 mm, 11.63 mm, and 7.69 mm, respectively, while composite AT2 had good inhibition against E. coli with the value of 9.82 mm. Equipped with good antibacterial activity, these aerogel composites have excellent potential to be used as adsorbent pads in food packaging to prolong the food shelf-life.

Synthesis, morphology and Raman spectroscopy of ZnS/Ag2S heteronanostructures

Sulfide (ZnS)(Ag2S)x heteronanostructures of various composition were obtained by co-deposition from water colloidal solutions of silver and zinc nitrates using sodium sulfide as a sulfidizer and sodium citrate as a stabilizer. The formation of (ZnS)(Ag2S)x heteronanostructures was confirmed using the XRD, HAADF-STEM, SEM, EDX and Raman spectroscopy. The size of ZnS and Ag2S nanoparticles in heteronanostructures (ZnS)(Ag2S)x with x ≤ 0.01 is 2–4 and no more than 3 nm, respectively. Raman spectroscopy showed that addition of silver sulfide nanoparticles into (ZnS)(Ag2S)x heteronanostructures leads to Ag2S deposition onto the surface of ZnS nanoparticles. Doping ZnS with only 1 mol.% of colloidal Ag2S nanoparticles is sufficient to produce a silver sulfide shell on the surface of ZnS nanoparticles.

Optimization of heat transfer rate of trihybrid nanofluid Embedded between two horizontal coaxial cylinders by RSM

Heat pipes are heat transfer devices that carry heat from one point to another efficiently. The thermal conductivity and heat transfer performance of the heat pipe can be increased by integrating nanofluids, making them appropriate for applications such as electronics cooling, spacecraft thermal management, and heat recovery systems. The suggested work is being carried out for the approximate solution of tri-hybrid nanofluid (copper (Cu), silver (Ag) and graphene oxide (GO)) flow between two horizontal coaxial cylinders. The inner cylinder is rotating with constant velocity and the outer cylinder is fixed. Moreover, the flow is under the influence of magnetic field. The system of governing partial differential equations is converted into a set of non-linear ordinary differential equations by incorporating the suitable similarity transformation and then solved numerically by employing Runga-Kutta 4th order technique. Response surface methodology (RSM) is also incorporated in order to optimize the heat transfer rate by the various combinations of the physical parameters involved in the study. The study revealed that the temperature of the nanofluid increased by raising the strength of the Reynolds number and melting parameter. From optimization technique RSM it came to know that the heat transfer rate reached its peak value when the strength of the Reynolds number and concentration of the nanoparticle of the fluid is higher than normal.

The Self-Organization and Gelation Processes in a Cysteine–Silver Solution Containing Chitosan and an Electrolyte

The Self-Organization and Gelation Processes in a Cysteine–Silver Solution Containing Chitosan and an Electrolyte

The Effects of Colloidal Silver Solution and Hypochlorous Acid on Wound Healing in the New Zealand Rabbit

The aim of this study was to investigate and evaluate the effects of colloidal silver and hypochlorous acid solutions on wound healing. To evaluate the wound healing activity of colloidal silver solution and hypochlorous acid solutions, an in vivo excisional wound model was applied in New Zealand rabbits (n = 21). The rabbits were randomly divided into 3 groups with seven individuals in each group. Group 1 was used as a negative control and no treatment was applied. Groups 2 and 3 were treated with crystalline (hypochlorous acid) and colloidal silver, respectively. The treatments were applied topically (in the form of spray) to the wound area of each rabbit daily. Wound diameters were measured on days 4, 8 and 12 using calipers and histopathological examinations were performed on days 4, 8 and 12 of the treatment. In terms of wound closure, both hypochlorous acid and colloidal silver solutions showed comparable wound healing activity with the control group. In conclusion, hypochlorous acid and colloidal silver have a positive effect on dermal wound healing in rabbits.

Effect of Storage Conditions on the Stability of Colloidal Silver Solutions Prepared by Biological and Chemical Methods

The research aimed to observe the influence of the storage conditions of silver colloidal solutions prepared by biological (green) and chemical methods on their long-term stability. Green methods for reducing and stabilizing silver nanoparticles (AgNPs) use natural substances. The rosemary leaf extract was used for AgNPs synthesis, and prepared nanoparticles were spherical (average size of 12 nm). In the chemical method, commercial chemicals (NaBH4, TSC, PVP, and H2O2) were used, and two colloids were prepared; the first contained spherical nanoparticles with an average size of 8 nm, and the second triangular prisms with an average size of 35 nm. The prepared colloids were stored under four conditions: at room temperature in the light and the dark, and at a temperature of 5 °C (refrigerator) in the light and the dark. The results confirmed the influence of storage conditions on the stability of nanoparticles. Colloids stored at 5 °C in the dark show the best stability. However, differences in stability dependent on the shape of nanoparticles prepared by chemical method were also observed; triangular nanoparticles showed the least stability. Methods such as UV–vis spectrophotometry, TEM, and EDX were used to analyze the nanoparticles before and after storage.

Innovative Synthesis of Adhesive-Assisted and Recyclable Fe3O4@PD-Ag Photomagnetic Nanocomposites as SERS probes for Ultrasensitive Thiram Detection on Fruit Peels

Surface-enhanced Raman spectroscopy (SERS) with enormous advantages has emerged as a powerful tool for both highly sensitive structural detection of analytes and various imaging applications. A notable advancement in the realm of multifunctional SERS substrates is the integration of magnetic nanoparticles endowed with magnetic manipulation capabilities and noble metal nanoparticles exhibiting plasmonic resonance properties. This synergistic combination offers substantial practical benefits for trace analysis across diverse fields. In this paper, a new paradigm of Fe3O4@PEI-DTC-Ag (Fe3O4@PD-Ag) photomagnetic nanocomposites based on magnetic Fe3O4 nanoparticles (NPs), the noble metal silver quantum dots (Ag QDs) and the adhesive layer polyethyleneimine dithiocarbamate (PEI-DTC) for convenient recycling and ultrasensitive SERS detection was developed by engineering hydrothermal and seed-growth methods. The SERS performance of the Fe3O4@PD-Ag substrates with varying amounts of Ag was evaluated by detecting 4-aminothiophenol (4-ATP). Among the tested samples, Fe3O4@PD-Ag-4 with a silver solution volume of 200 ml exhibited the optimal performance, showcasing an enhancement factor (EF) of 4.418 × 105. Moreover, the relative standard deviations (RSDs) were calculated to be less than 11.5 %, demonstrating the SERS substrates exhibit good uniformity and spectral reproducibility. Of note, the SERS substrate has demonstrated successful trace detection of thiram molecules, achieving a limit of detection (LOD) of up to 10-9 M. The intensity of SERS signals shows a linear correlation with the logarithm of thiram concentration, ranging from 10-4 to 10-9 M, thus providing compelling evidence for quantitative detection. Importantly, the Fe3O4@PD-Ag-4 SERS substrate also showcases outstanding performance for detecting thiram in real food, underscoring its significant potential for application in food safety monitoring.

Facile Synthesis of Silver Nanoparticles From Sustainable Sargassum sp. Seaweed Material and Its Anti-inflammatory Application.

Background Sustainable and environmentally friendly methods of producing nanoparticles are now being investigated by scientists. Because there are so many marine renewable resources, scientists are focusing their attention on studying seagrass, seaweed, mangroves, marine macroalgae, and microalgae. An exciting new frontier in research involves the synthesis ofnanoparticles using extracts from seaweed. Seaweed extracts are utilized to synthesize silver nanoparticles (Ag NPs), which serve as both reducing and stabilizing agents. Seaweed extracts possess bioactive substances like proteins, polysaccharides, and polyphenols that enable them to effectively convert silver (Ag+) ions intoAg NPs.Ag NPs derived fromSargassum seaweed have played an essential role in improving the anti-inflammatory properties of seaweed extracts. This study aimed to investigate thebiosynthesis of Ag NPs fromSargassumseaweed and evaluate their anti-inflammatory properties. Materials and methods About 50 g of seaweed samples were mixed with 100 mL of distilled water and stirred for 24 hours. Additionally, 1.2g of silver nitrate (0.120 M) was dissolvedin 60 mL of distilled water to make a silver (Ag) solution. A 60 mL solution of silver nitrate (AgNO3) was mixed with a 40 mL solution of seaweed extract in water, and the mixture was stirred with a stirrer for 24 hours.A UV spectrophotometer was used to regularly monitor the reduction ofAg+ ions in the solution. Ag NPs were purified using a sequence of centrifugation steps with a duration of 10 minutes at a speed of 2500 revolutions per minute (rpm). To remove moisture from the water-suspended nanoparticles, they were vacuum-dried for 24 hours. Results The synthesis of Ag NPsfrom seaweed extract resulted in a noticeable change in the color of the mixture, which went from pale to brown. The alteration in color signifies the reduction of AgNO3 to Ag+ ions, facilitating the creation of Ag NPs. X-ray diffraction (XRD) measurement verified the remarkable crystallinity of the synthesized Ag NPs. Field emission scanning electron microscopy (FESEM) images indicated a spherical, homogeneous structure. The Ag NPs derived from seaweed exhibited significant anti-inflammatory characteristics. Conclusion Utilizing Sargassum sp. seaweed in the biological synthesis of Ag NPs shows promiseto develop nanomaterials that canexhibit anti-inflammatory effects. This technique has benefits, such as being environmentally friendly and cost-efficient. Additional research in this area is essential for effectively exploiting the potential of Ag NPs in anti-inflammatory activity.

Investigating the Effects of Environmentally Friendly Additives on the Exhaust Gas Composition and Fuel Consumption of an Internal Combustion Engine

This article shows the effect of the addition of effective microorganisms and silver on the exhaust gas composition and fuel consumption. Exhaust emission standards are becoming increasingly stringent, which makes it difficult for engine manufacturers to meet them. For this reason, intensive work is underway to use alternative propulsion systems on ships, and for diesel engines, alternative fuels. Among other things, this applies to mixtures of petroleum-based fuels with vegetable oils and their esters. Unfortunately, their use, due to their physicochemical properties, can negatively affect the performance of the engine and the wear of its components. Therefore, the aim of this study was to see how additives of effective microorganisms in the form of ceramic liquid and tubes, and a silver solution and colloidal silver would affect some engine parameters, including the exhaust gas composition and fuel consumption. The authors are not aware of the results of previous research on this issue. The tests were carried out on a diesel engine for four types of green additives at concentrations of 2% and 5%, at different ranges of its load. The additives added to the diesel fuel were characterised, and the test stand was presented, along with the parameters of the tested fuel. The effect of additives on selected engine parameters, including fuel consumption, was presented. The characteristics of hourly fuel consumption and selected components of the exhaust gas, including nitrogen oxides, carbon monoxide and carbon dioxide as a function of the concentration of ecological additives are shown and analysed. It was found that the most beneficial additive that had a positive effect on the exhaust gas composition and fuel consumption was a silver solution in a 2% concentration. There was a decrease of up to 4% in the NOx content of the exhaust gas, a decrease in carbon monoxide of more than 28%, a decrease in carbon dioxide of 4.6% and a decrease in fuel consumption of around 3% was achieved under the tested conditions. The use of these additives is an innovative solution that has a positive impact on reducing the emissions of harmful compounds into the atmosphere. In further research, it will be necessary to study the effect of this additive on the combustion process in the engine and the wear of its components, as well as to confirm the results obtained in real operating conditions.

Применение комплекса биологически активных веществ из Аronia melanocarpa в парафармацевтических фитоплёнках

The article presents the results of using non-pharmacopoeial plant raw material – dried leaves of the perennial cultivated chokeberry shrub Aronia melanocarpa (Michx.) Elliott. as a source of substances with anti-inflammatory and wound-healing effect. The development of a parapharmaceutical phytofilm based on a complex of biologically active substances from A. melanocarpa is described. The results of preclinical evaluation of the developed phytofilm in an experimental model of skin wound on outbred white rats are presented. The developed phytofilm is environmentally safe compared to synthetic analogues which production is accompanied by a negative environmental impact. Substances with antioxidant properties which can play the role of a medicinal base were found in the composition of aqueous extracts from chokeberry leaves: polyphenols – 7.4±0.7, tannins – 4.6±0.5 mg/cm3. The safety of using A. melanocarpa leaves as raw material for phytofilm has been confirmed in heavy metal tests. The composition and film-forming ability of chokeberry leaves aqueous extract, including polyvinyl alcohol (098-15(G)) (6%), food grade gelatin P-11 (0.5%), glycerin (GOST 6259-75) (0.4%), colloidal silver solution 200 mg/dm3 (1%) has been established. A. melanocarpa leaves extract application to the film-forming solution increases the final vapor permeability by 48% and solubility by 14%. The model experiment shows the effect of using the created phytofilm in the reparation of linear wounds, manifested as significant decrease in their length by 30% by the fifth day, by 25% by the seventh day compared with the control, as well as normalization of the skin histological structure by the tenth day.

Braided silk sutures coated with photoreduced silver nanoparticles for eradicating Staphylococcus aureus and Streptococcus mutans infections

BackgroundInfections resulting from surgical procedures and wound closures continue to pose significant challenges in healthcare settings. To address this issue, the investigators have developed antibacterial non-resorbable braided silk sutures using in situ deposited silver nanoparticles (AgNPs) and investigated their efficacy in eradicating Staphylococcus aureus and Streptococcus mutans infections. MethodsThe braided silk sutures were modified through a simple and efficient in situ photoreduction method, resulting in the uniform distribution of AgNPs along the suture surface. The synthesized AgNPs were characterized using scanning electron microscopy (SEM), dynamic light scattering analysis (DLS) and Fourier Transform Infrared Spectroscopy analysis (FTIR) confirming their successful integration onto the silk sutures. The antibacterial activity of the nanoparticle coated sutures were compared and evaluated with non-coated braided silk sutures through in vitro assays against both S. aureus and S. mutans. ResultsThe surface and cross-sectional analysis of the treated sutures revealed a uniform and homogeneous distribution of silver particles achieved through the photoreduction of silver solution. This observation confirms the successful coating of silver nanoparticles (AgNPs) on the sutures. The antimicrobial studies conducted, demonstrated significant reductions in bacterial colonies when exposed to the silver nanoparticle-coated sutures. Notably, the width of the inhibition zone surrounding the coated sutures remained consistently wide and stable for duration up to 7 days. This sustained and robust inhibitory effect against gram-positive bacteria, specifically S. aureus and S. mutans, serves as strong evidence of the antibacterial efficacy of the coated sutures. ConclusionThe coating of silk sutures with AgNPs provided a significant and effective antibacterial capacity to the surgical sutures, with this activity being sustained for a period of 7 days. This suggests that AgNPs-in situ photoreduction deposited sutures have the potential to effectively manage S. aureus and S. mutans infections.

Ultrasound-assisted facile and green preparation of Ag nanoparticle conductive ink for printing electronics

The development of low-cost, high-efficiency, and environment-friendly methods for the preparation of Ag nanoparticle (NP) conductive inks is key to promoting the application of such inks for printing flexible electronic components. This article presents an effective method for preparing a AgNP ink by reducing silver compounds in a polyol solution with ultrasonication. When the silver solution was ultrasonicated at 640 W, 21-nm AgNPs were readily produced within 5 min, and the particles grew considerably to 53 nm as the reaction was continued for 15 min. Thereafter, the NP size increased marginally with further increase in reaction time. When the reaction was conducted for a fixed duration of 15 min and the ultrasonic power was increased from 480 to 760 W, the AgNP size decreased from 63 to 48 nm. During ultrasonication, the bubble eruption in the solution generates large temperature and pressure gradients, inducing the rapid reduction of the Ag(I) to Ag(0). Printing experiments revealed that the synthesized AgNP ink has good inkjet printability. During the sintering of the printed film, the bridge connections between large particles increased and the interparticle voids decreased gradually, resulting in a decrease in film resistivity. A relatively low resistivity of 40×10−5 Ωcm was obtained when the flexible AgNP pattern was heated at 250 °C for 80 min. The facile synthesis process and the favorable conductive properties of the obtained ink render this preparation method promising for the low-cost production of flexible electronics.

Stability study in selected conditions and biofilm-reducing activity of phages active against drug-resistant Acinetobacter baumannii.

Acinetobacter baumannii is currently a serious threat to human health, especially to people with immunodeficiency as well as patients with prolonged hospital stays and those undergoing invasive medical procedures. The ever-increasing percentage of strains characterized by multidrug resistance to widely used antibiotics and their ability to form biofilms make it difficult to fight infections with traditional antibiotic therapy. In view of the above, phage therapy seems to be extremely attractive. Therefore, phages with good storage stability are recommended for therapeutic purposes. In this work, we present the results of studies on the stability of 12 phages specific for A. baumannii under different conditions (including temperature, different pH values, commercially available disinfectants, essential oils, and surfactants) and in the urine of patients with urinary tract infections (UTIs). Based on our long-term stability studies, the most optimal storage method for the A. baumannii phage turned out to be - 70°C. In contrast, 60°C caused a significant decrease in phage activity after 1 h of incubation. The tested phages were the most stable at a pH from 7.0 to 9.0, with the most inactivating pH being strongly acidic. Interestingly, ethanol-based disinfectants caused a significant decrease in phage titers even after 30s of incubation. Moreover, copper and silver nanoparticle solutions also caused a decrease in phage titers (which was statistically significant, except for the Acba_3 phage incubated in silver solution), but to a much lesser extent than disinfectants. However, bacteriophages incubated for 24h in essential oils (cinnamon and eucalyptus) can be considered stable.

Effects of composition and pH on the degradation of hyaluronate and carboxymethyl cellulose gels and release of nanocrystalline silver.

Adhesions are fibrous tissue connections which are a common complication of surgical procedures and may be prevented by protecting tissue surfaces and reducing inflammation. The combination of biodegradable polymers and nanocrystalline silver can be used to create an anti-inflammatory gel to be applied during surgery. In this study, sodium hyaluronate and sodium carboxymethyl cellulose were added in concentrations from 0.25% to 1% w/v to aqueous nanocrystalline silver solutions to create viscous gels. Gels were loaded into dialysis cassettes and placed in PBS for 3 days. pH was adjusted using potassium phosphate monobasic and sodium hydroxide. Release of silver into the PBS was measured at several time points. Polymer degradation was compared by measuring the viscosity of the gels before and after the experiment. Gels lost up to 84% of initial viscosity over 3 days and released between 24% and 41% of the added silver. Gels with higher initial viscosity did not have a greater degree of degradation, as measured by percent viscosity reduction, but still resulted in a higher final viscosity. Silver release was not significantly impacted by pH or composition, but still varied between experimental groups.

Simultaneous ionic cobalt sensing and toxic Congo red dye removal: a circular economic approach involving silver-enhanced fluorescence.

A highly fluorescent quinone-capped silver hydrosol (AgOSA) was obtained using salicylaldehyde and an ionic silver solution. Such metal-enhanced fluorescence was efficiently quenched with Congo red dye (CR), producing CRAgOSA, due to the strong silver-sulfur interaction, replacing the capping of quinone (oxidized salicylaldehyde). The introduction of cobalt ions restored the fluorescence by engaging CR (CoCRAgOSA). Cobalt-induced fluorescence enhancement was 8.3 times higher than that of AgOSA due to the freeing of CR and the release of self-quenching of excess quinone molecules in CoCRAgOSA. The mammoth and selective fluorescence enhancement with ionic cobalt assisted in designing a turn-on ionic cobalt sensor with a limit of detection (LOD) of 9.4 × 10-11 M and a linear detection range (5 × 10-5 to 10-9 M). Moreover, toxic CR dye was eliminated by quinone-capped silver nanoparticles and Co2+ due to chemisorption. Not only the fluorimetric sensing of ionic cobalt but also the colorimetric sensing of Hg2+ was designed due to the simultaneous aggregation of AgNPs and complexation with CR induced by Hg2+ (LOD 1.36 × 10-5 M and linear detection range from 1.00 × 10-4 to 5 × 10-7 M). We applied our sensing method to estimate ionic cobalt and mercury in natural samples. The experiment was a unique case of circular economy, where a toxic dye was used for making a nanosensor.

Comparative Evaluation of the Antibacterial Efficacy of Aloe Vera, 3% Nano Silver Solution, and 2% Chlorhexidine Gluconate on Enterococcus faecalis: An In Vitro Study

Comparative Evaluation of the Antibacterial Efficacy of Aloe Vera, 3% Nano Silver Solution, and 2% Chlorhexidine Gluconate on Enterococcus faecalis: An In Vitro Study

A dual functional turn off florescence sensor using metal–organic framework for sensitive detection of aluminum(III) in aqueous solution

AbstractAluminum, classified as one of the toxic heavy metals, has a recommended daily consumption limit of 3–10 mg, as specified by the World Health Organization (WHO). Herein, the selective and sensitive aluminum(III) fluorescence sensor based on TMU‐16 metal–organic frameworks (MOFs) in aqueous medium, is reported. A sensing pathway was found via the cation exchange between aluminum(III) and zinc(II) ions, and caused selectivity and sensitivity detection of aluminum(III) with a 5–100 ppm linear range and 1.99 ppm limit of detection (LOD).This sensor offers the advantage of accurately determining the concentration range of aluminum(III) ions. At low concentrations, only fluorescence quenching was observed, while at higher concentrations, fluorescence emission not only undergoes quenching but also exhibits a blue shift in wavelength. Notably, the sensor demonstrates no interference from cation solutions of mercury(II), zinc(II), nickel(II), lead(II), cobalt(II), cadmium(II), silver(I), chromium(III), and iron(III).Another significant feature of this sensor is its selectivity toward copper(II) and aluminum(III) ions, due to quenching fluorescence in the presence of copper(II) ion. The results presented the sensor's selectivity toward copper(II) at low concentrations and aluminum(III) at high concentrations.

Effect of processing methods on the electrical conductivity properties of silver-polyurethane composite films (Experimental and numerical studies)

This research investigates the electrical properties of micro silver polyurethane (Ag-PU) composite films with different degrees of agglomeration. Ag-PU composite films were prepared by adding micro silver particles (<3.5 μm) into the thermoplastic PU matrix using a solution mixing method, followed by spin-coating or casting techniques. For some composite preparation, the silver solution was shear-mixed in an ultrasonic bath before being added to the PU solution to obtain higher filler dispersion within the polymer matrix. This method produced several composite films with variable degrees of silver aggregation with concentrations from 0 to 14 vol%. All composites showed only electrical conductivity through thickness when compressed under pressure in a range from 0.5 to 20 kPa. Generally, the percolation threshold and conductivity values of the composite film prepared by spin-coating were lower than those of the casting composite. The maximum conductivity value found in these composites was about 2.45 S/m. All composites’ electrical performance was numerically simulated using the finite element analysis method based on the representative volume element model (FE-RVE) with Digimat software. A correlation was observed between the experiments and those simulations. A semi-analytical model was used to estimate the composite electrical parameters.

Synthesis of Metal Nanoparticles via Pulicaria undulata and an Evaluation of Their Antimicrobial, Antioxidant, and Cytotoxic Activities

Nanoparticle engineering via plants (green synthesis) is a promising eco-friendly technique. In this work, a green protocol was applied to the preparation of silver, zinc, and selenium nanoparticle solutions supported by the extracted aerial parts of Pulicaria undulata. The formation of nanoparticles in the solution was characterized using phytochemical analysis, and UV-visible, TEM, and zeta-potential spectroscopy. In addition, various biological activities were investigated for the extract of P. undulata and the produced nanoparticles (selenium, silver, and zinc), including antioxidant, antimicrobial, and cytotoxic activities. The volatile components of the extracted constitute verified the fact that twenty-five volatile components were characterized for the majority of abundant categories for the fatty acids, esters of fatty acids (59.47%), and hydrocarbons (38.19%) of the total area. The antioxidant activity of P. undulata extract and metal nanoparticles was assessed using DPPH assay. The results indicated reduced potency for the metal nanoparticles’ solutions relative to the results for the plant extract. The cytotoxicity of the investigated samples was assessed using an MTT assay against various tumor and normal cell lines with improved cytotoxic potency of the solutions of metal nanoparticles, compared to the plant extract. The antimicrobial activity was also estimated against various bacterial and fungal species. The results confirmed amended potency for inhibiting the growth of microbial species for the solutions of metal nanoparticles when compared to the extracted aerial parts of the plant. The present study showed that green synthetized nanoparticles using P. undulata have various potential bioactivities.

STUDY OF THE ANTISTATIC PROPERTIES OF MATERIALS TREATED WITH COLLOIDAL COMPOSITIONS BASED ON METAL NANOPARTICLES

The article provides a short overview of the application of metal nanoparticles in the textile indus- try, describes their properties and application`s fields. The definitions of electrification, electrostatic field, electric charge density are given. The application of processing of fabrics by polyurethane dispersion and metal nanoparticles in technological processes of textile materials finishing is justified. The objects of the study are cotton fabric`s samples with addition of synthetic fibres, colloidal solutions of silver and copper nanoparticles, aqueous polyurethane dispersion. The antistatic properties of the fabrics have been studied. The electrostatic field intensity of the samples was measured on the device ST-01, with the density of the electric charge calculating according to the intensity values. It has been experimentally established, that the processing of fabrics by solutions of nanoparticles of metals contributes to reduction of intensity of their electrostatic field to 65 %, compared with the initial samples. It is noted that treatment of fabrics by polyure- thane dispersion in combination with copper nanoparticles gives no clear antistatic properties to the blended fabrics.