In the past decades, due to an always more electrification and the research of a greener environment, Li-ion Batteries (LIB) have taken an important place in worldwide research. Solid-state batteries (SSBs) have the potential to revolutionize the energy storage industry, offering superior safety and energy density in comparison to traditional LIBs[1, 2]. Our research aims to enhance the performance and safety of solid-state batteries at ambient temperature by incorporating electrodes with high specific capacity with a lithium lanthanum zirconate (LLZO) solid electrolyte.The integration of SiNW electrodes into the solid-state battery architecture offers several advantages. SiNWs are known for their large surface area and superior electrical conductivity and offer a strong platform for efficient lithium-ion transport and cell energy density optimization, theoretically almost 10 times the capacity of graphite[3, 4]. Furthermore, LLZO solid electrolytes are a stable and non-flammable alternative to conventional liquid electrolytes[2, 5], significantly improving battery safety.The main objectives of this study are to investigate the combined effects of silicon nanowires (SiNWs) electrodes and LLZO solid electrolyte and to determine the optimal amount of liquid electrolytes to improve cell safety.In this work, an LLZO thin solid electrolyte tape has been manufactured by casting technique. Precise volumes of liquid electrolyte have been added to the LLZO tape to improve surface contact and ion conductivity. Furthermore, the study will provide a view of the relationship between the quantity of liquid electrolytes introduced and their impact on cell stability and safety.Preliminary results show the preparation of a mechanically stable LLZO tape with high ionic conductivity (>10-4 S cm-1) through an easy and up-scalable procedure. Improvements have been reported in the electrochemical performance of SiNW-LLZO solid-state batteries compared to the relative Li-ion liquid cell.In conclusion, here we developed a new thin solid electrolyte tape with high ionic conductivity, used in solid-state LIBs with silicon nanowires as anode material. Moreover, we standardized a procedure to optimize the use of organic liquid electrolytes as an additive, without omitting the volume or using any excess that could lead to safety issues. This optimization process can contribute to the development of solid-state batteries that are not only high-performance but also safe and reliable for various applications, including electric vehicles and portable electronics. References Wu, F., J. Maier, and Y. Yu, Guidelines and trends for next-generation rechargeable lithium and lithium-ion batteries. Chem Soc Rev, 2020. 49(5): p. 1569-1614.Wang, C., et al., Garnet-Type Solid-State Electrolytes: Materials, Interfaces, and Batteries. Chem Rev, 2020. 120(10): p. 4257-4300.Chan, C.K., et al., High-performance lithium battery anodes using silicon nanowires. Nat Nanotechnol, 2008. 3(1): p. 31-5.Kennedy, T., M. Brandon, and K.M. Ryan, Advances in the Application of Silicon and Germanium Nanowires for High-Performance Lithium-Ion Batteries. Adv Mater, 2016. 28(27): p. 5696-704.Xu, L., et al., Garnet Solid Electrolyte for Advanced All ‐Solid ‐State Li Batteries. Advanced Energy Materials, 2020. 11(2).