Siliciclastic Rocks Research Articles

Recognizing microbial manganese reduction in lacustrine carbonate and its linkage to terrestrial biogeochemical processes

Carbonate authigenesis, the in situ precipitation of carbonate minerals within the sediment porewaters, is a key pathway for carbonate deposition and plays a crucial role in global biogeochemical cycles. Heterotrophic microorganisms are essential in regulating authigenic carbonate formation, primarily through the consumption of organic matter. Although bacterial manganese reduction is known to influence the formation of rhodochrosite and dolomite, its role in limestone deposition is unclear. Here, we present a systematic investigation of mixed calcareous siliciclastic rocks from a Paleogene freshwater lake to identify the formation of authigenic carbonate, decode the role of microbial Mn reduction, and understand the microbial response to ancient lacustrine environmental changes. The positive correlation between carbonate fraction in bulk samples (Carb%) and Mn content in carbonate minerals (Mncarb) suggests that carbonate precipitation is stimulated by Mn2+ enrichment. The dissimilarity between Mncarb and Fecarb, along with the synergic variations of Mncarb and diagenetic indicators, support an authigenic rather than a hydrogenetic origin for the carbonates. Using a one-dimensional diffusion–advection-reaction model, we quantify the impact of Mn reduction on promoting carbonate precipitation. Furthermore, correlations between Pcarb and other values–positive with the chemical index alteration (CIA), negative with Mncarb, and none with TOC–suggest that nitrogen availability, regulated by continental weathering, is likely the primary factor limiting both the primary productivity and the bacterial reduction intensity at the study site. Overall, this study uncovers the role of microbial Mn reduction in stimulating authigenic carbonate precipitation, and reveals the modulation mechanism of Mn-reducing microorganisms in an ancient lake. These findings shed new light on the authigenic limestone formation mechanisms and provide a new perspective on interpreting the authigenic impacts on carbonate chemistry.

Geology of the Eastern Barberton Greenstone Belt, South Africa: Early Deformation and the Role of Large Meteor Impacts

The eastern Barberton Greenstone Belt (BGB) includes four stratigraphic and structural divisions: from northwest to southeast, the Mlumati, Manzimnyama, and Paulus Synclines and the Emlembe Belt. All are made up largely of sedimentary rocks of the Fig Tree Group separated by antiformal belts of sheared Onverwacht Group komatiitic rocks. Fig Tree rocks in the Mlumati and Manzimnyama Synclines are mostly chemically precipitated banded iron formation (BIF) and banded ferruginous chert (BFC) with a major siliciclastic unit, the Gelegela Grit, composed of quartz-poor (<5% monocrystalline quartz, Qm) volcaniclastic sandstone showing abundant ~3.445–3.455 Ga detrital zircons. The Paulus Syncline is dominated by shale containing in the upper half chert-clast conglomerate and sparse lithic sandstone (Qm<10%) but includes near the middle lenticular units up to unit 30 m thick of quartz-rich (Qm >50%) sandstone. The Emlembe Belt consists largely of chert-clast conglomerate and quartz-bearing (Qm = 10–50%) sandstone. The Paulus and Emlembe belts show detrital zircon age peaks at ~3.295–3.275 Ga and ~3.445–3.455 Ga. While exhibiting overall similar stratigraphic development and detrital zircon ages, Fig Tree rocks in these belts show contrasting compositions and sediment sources. They do not represent parts a single basin or fairway of sediment transport and deposition. Fig Tree siliciclastic rocks mark the first deformation, uplift, and erosion in the BGB. However, the thinness of Fig Tree strata, mostly less than 1000 m, and rapid facies changes argue that deformation involved local uplifts and small basins that accumulated thin sedimentary sequences. We suggest that early Fig Tree deformation is consistent with crustal disruption triggered by large meteor impacts, starting perhaps as early as ~3.277 Ga but certainly by ~3.260 Ga. The Fig Tree Group may record a cluster of impacts that fragmented and destabilized a long-lived crust followed during later or post-Fig Tree time by tectonic uplift and orogeny.

Diagenetic features recorded in sedimentary rocks within a gas chimney: A case study from the Makassar Strait, offshore Indonesia

Methane seeps, prevalent in ocean basins globally, indicate upward methane migration from the subsurface, often evident as gas chimneys in seismic reflection data. The footprint of this methane migration is often indicated by methane-derived authigenic carbonate (MDAC), a product of anaerobic oxidation of methane (AOM). Despite extensive research on MDAC from present-day seafloors and outcrops, understanding methane migration footprints from subsurface rock samples remains limited. Therefore, this study aims to investigate methane migration footprints from subsurface rock samples taken from a proven area of gas migration. This study utilized cutting samples from well XS-01 located in the Makassar Strait, offshore Indonesia. The well was drilled through a gas chimney into Oligocene carbonate reservoirs hosting a substantial methane column (102 m). Analysis of 44 cutting samples involved petrographic examination, Scanning Electron Microscope (SEM) imaging, and X-ray Diffraction (XRD) analysis to discern mineralogical content and diagenetic features signaling the presence of gas. A diagenetic texture called clotted peloidal micrite (CPM) was discovered within foraminifera fossils and around fractures based on petrographic analysis. CPM is a type of MDAC and predominantly occurs in fine-grained, siliciclastic rocks, indicating gas migration. This migration is interpreted to occur: (i) during the early burial stages originating from microbial activity since the Oligocene (biogenic gas); (ii) following matured source rock that reached its peak maturity from the Middle Eocene to the Pliocene (thermogenic gas); or (iii) interference of these two processes. The migration route persists until present day as evidenced by gas chimney and seabed pockmarks identified in seismic reflection data. This study emphasizes the importance of subsurface rock samples, such as cuttings, in uncovering gas migration footprints. Especially, where seismic data is unavailable or could not image fluid flow features. In addition, this study also provides a new perspective on diagenesis along methane migration route, complementing most of the research that is primarily focused on reservoir diagenesis.

Distribution of Thanetian-Ilerdian biozones in Lorestan Zone, West of Iran

The Taleh Zang Formation is a carbonate sequence of the late Paleocene–early Eocene age in the Lorestan zone, west of Iran. This Formation overlays siliciclastic rocks of the Amiran Formation and is overlain by red sandstone of the Kashkan Formation. A biostratigraphic scheme, based on the larger benthic foraminifera, is proposed for the Thanetian–Ilerdian deposits in Lorestan Zone. We compare our results with the available data from other parts of Tethys and the zonation of shallow-marine Paleocene–Eocene of Mediterranean Tethys is made. In total, 367 samples were collected from the six sections. From a biochronostratigraphic point of view, three biozones and one indeterminate zone are identified. The zones are shallow benthic zone 3 (early Thanetian), shallow benthic zone 4 (late Thanetian), and shallow benthic zone 6 (early Ilerdian). In the northern part of the Lorestan Zone (Kabutar Bula and Psht-e Jangal sections), the Taleh Zang Formation contains poor fauna. Due to the stratigraphic position, an early Thanetian age can be considered. Our data showed that the late Paleocene and Eocene biozones in Lorestan Zone developed parallel to the axis of the folding, in a northwest-southeast trend. They get younger from the northeast to the southwest. Keywords: biostratigraphy, Eocene, Foraminifera, Lorestan Zone, Paleocene.

Sea level controls on Ediacaran-Cambrian animal radiations.

The drivers of Ediacaran-Cambrian metazoan radiations remain unclear, as does the fidelity of the record. We use a global age framework [580-510 million years (Ma) ago] to estimate changes in marine sedimentary rock volume and area, reconstructed biodiversity (mean genus richness), and sampling intensity, integrated with carbonate carbon isotopes (δ13Ccarb) and global redox data [carbonate Uranium isotopes (δ238Ucarb)]. Sampling intensity correlates with overall mean reconstructed biodiversity >535 Ma ago, while second-order (~10-80 Ma) global transgressive-regressive cycles controlled the distribution of different marine sedimentary rocks. The temporal distribution of the Avalon assemblage is partly controlled by the temporally and spatially limited record of deep-marine siliciclastic rocks. Each successive rise of metazoan morphogroups that define the Avalon, White Sea, and Cambrian assemblages appears to coincide with global shallow marine oxygenation events at δ13Ccarb maxima, which precede major sea level transgressions. While the record of biodiversity is biased, early metazoan radiations and oxygenation events are linked to major sea level cycles.

Geochronology (zircon U-Pb, Hf, O isotopes), provenance analysis, and tectonic setting of the Paleoproterozoic Karrat Group and supracrustal rocks of the Rinkian fold belt, West Greenland

We use zircon U-Pb, Hf and O isotopes to constrain the depositional ages and provenance of metasedimentary rocks of the Paleoproterozoic Karrat Group of West Greenland and to understand the tectonic processes leading to basin development on the eastern Rae craton. An older supracrustal assemblage (Qeqertarssuaq complex) deposited after ca. 2.6 Ga is separated by an unconformity with a younger supracrustal assemblage (the Karrat Group). The Qaarsukassak Formation at the base of the Karrat Group was deposited after ca. 2.0 Ga, with dominantly Archean age modes. The youngest siliciclastic rocks (Nûkavsak and Mârmorilik formations) in the Karrat Group have maximum depositional ages ranging from ca. 1980 to 1950 to 1900 Ma and contain dominant detrital zircon age modes between ca. 2.50 and 1.93 Ga. A ca. 1.92 Ga supracrustal assemblage referred to as the northern domain (Karrat Group, sensu lato) is geographically separated from the Karrat Group (sensu stricto) by the Prøven igneous complex. The stratigraphy and detrital zircon profiles are compared to broadly coeval sedimentary units on the Rae craton and a unifying model of their deposition is presented. The Rae craton is the dominant detritus source; initially these sources were mostly local, changing to a mix of local and distal sources including the western Rae craton. The tectonic setting of the Karrat basin transitioned from extensional to convergent to collisional during its basin evolution, reflecting Wilson cycle phases within an epeiric sea. Accordingly, zircon Hf isotopes in our dataset track the evolution of the opening and closing of the Manikewan Ocean. Detrital zircon Hf isotopes in our dataset reveal a greater proportion of juvenile detritus (especially ca. 2.15–1.95 Ga) than is known from the currently exposed crustal record, pointing to the importance of the detrital zircon record for understanding Paleoproterozoic crustal and tectonic evolution.

Constraining provenance and age of the siliciclastic rocks from the south-western Bundelkhand Craton, Central India

The lithology of the Bundelkhand craton, central India, includes highly deformed tonalite, trondhjemite and granodiorite (TTG) gneisses (3.55–2.7 Ga), followed by volcano-sedimentary greenstone belts and a suite of undeformed granitoids ranging in age from 2.52 to 2.49 Ga. The granitoids, which are by far the most dominant lithology of the craton, have intruded into the TTG gneiss-greenstone assemblage. In addition to huge granitic bodies, rhyolitic rocks of 2.54 Ga have also been observed in the Bundelkhand craton. In this study, we report the first occurrence of a small isolated outcrop of siliciclastic sedimentary rocks within the Bundelkhand granitoid suites in and around the Panchwara village, in the southwestern part of the craton. These siliciclastic sedimentary rocks are intruded by the youngest granitic phase of the Bundelkhand granitoid suite, dated as 2.49 Ga old. Thus, their age is determined to be older than 2.49 Ga. Petrographic studies suggest that these rocks are arkose in nature and geochemical composition indicates that they were derived from the older gneiss-greenstone successions and the older granitic phase (2.52 Ga) of the Bundelkhand granitoid suite. The REE modelling suggests that the sediment contribution from different sources is: 50% greenstone belt (15% basalt + 35% sedimentary rocks), 35% gneisses and 15% older granitoids. Detrital zircons from these sedimentary rocks reveal two age populations: one group of zircons is clustering around 2.52 Ga and the other group is ranging from 3.0 to 3.3 Ga indicating at least two protoliths for these sediments. Our field, petrographical and geochemical data, coupled with previously studied zircon geochronological data, is best explained by a model involving deposition of sediments derived from TTG gneiss, greenstone belt and also from the older phase of the granitoid suite. It is interesting to note that the basin received sediments from the older granitic phase of 2.52 Ga age and was closed before the emplacement of the youngest granitic phase at 2.49 Ga. This study, thus, provides for the first time, conclusive evidence for the presence of a late Archean sedimentary basin within the Bundelkhand craton. It is proposed that the sediments were deposited penecontemporaneously with the pulses of the granitoid magmatism in the Bundelkhand Craton that took place ~2.5 Ga.

Extraction of the three-dimensional architecture of deformation bands from ground-penetrating radar cubes using multiattribute analysis

Fault zones in porous siliciclastic rocks can be dominated by deformation bands (DBs), which are small-scale tabular structures that usually occur as cluster features. DBs can reduce permeability, contributing to the compartmentalization of oil reservoirs and aquifers. DBs cannot be imaged by seismic methods, but can be imaged by Ground-penetrating radar (GPR). Although DBs and host rocks share the same lithology, GPR imaging is possible because DBs can cause small vertical offsets and reduce the amplitude of the GPR signals. We present an automatic approach for extracting the three-dimensional (3D) architecture of DBs from GPR cubes using multiattribute analysis. We used a 200 MHz GPR cube surveyed on an outcrop of a sandstone formation highly impacted by DBs in the Rio do Peixe Basin, northeastern Brazil. The multiattribute analysis is based on edge evidence and sequential ant-tracking, a combination that can identify narrow zones of attenuated GPR signals. Furthermore, the 3D architecture of DBs was extracted as a geobody using an opacity balancing operator. The geological reliability and limitations of the geobody were demonstrated by comparing slices of the geobody with images of exposed DBs in similar positions, in addition to structural measurements obtained in field and in the geobody.

Mississippian (Lower Carboniferous) Facies Heterogeneity and Distribution within the Mixed Carbonate-Siliciclastic Reservoirs of the Midcontinent STACK Play, Oklahoma, USA

Summary The objective of this study is to evaluate facies heterogeneity, including both lateral and vertical distributions within the mixed carbonate and siliciclastic reservoirs of the Mississippian System (Lower Carboniferous). This research and statistical approach will aid in future investigations related to determining optimal landing zones, enhancing completion designs, and providing geologic insight into fracture driven well interference studies to increase production efficiency. This study integrates well log, petrographic, sedimentologic, and conventional core analyses along a set of transects across the Anadarko Basin and includes the development of core-based facies logs. Statistical analysis indicates that the Mississippian System in the STACK play of the Anadarko Basin is fundamentally a highly layered rhythmic succession in which a variety of carbonate rock types, siliciclastic rock types, and chert tend to form couplets with siltstone. Thickness-frequency distributions and Markov chain analysis indicate that sediment thickness and lithologic transitions were stochastically regulated and that lithologic cyclicity is not apparent. Overall lithologic trends indicate a transition from carbonate to sandstone in the midramp and from carbonate to mudstone and siltstone in the outer ramp. Stratal geometry defines a series of south-prograding clinoforms, and detailed analysis of vertical trends in the distribution of mudstone, siltstone, sandstone, chert, and carbonate facilitates identification of shoaling-upward parasequences that can be correlated regionally.

Provenance and tectonic setting of greywacke and siltstone of the Nampala gold deposit, Southern Mali

The petrographical and geochemical analyses of greywacke and siltstone samples from the Nampala gold deposit of the Paleoproterozoic Birimian supergroup, Southern Mali, have been carried out to make inferences on the provenance, tectonic settings, and weathering history of the sediments. Petrographical investigations revealed that greywackes can be classified as feldspathic wackes, with immature to moderately mature sediments, with the siltstones being immature. Geochemically, greywackes show features that resemble typical wacke sedimentary rocks, whereas the siltstones are arkose to litharenite. Overall, Nampala sedimentary rocks experienced low intensity of paleoweathering with <70 CIA and <90 CIW values and have not undergone significant sediment recycling having >1 CIV values. Their quartz and feldspar contents, together with the ratio of Al2O3/TiO2 and La/Sc, suggest the derivation of sediments from felsic igneous rocks, with a possible minor contribution from mafic proto-source rock. The petrographic and geochemical features of the greywackes and siltstones are consistent with siliciclastic rocks formed in an active continental margin, similar to other sedimentary rocks of the Paleoproterozoic Birimian terrane. These findings put positive constraints on the subduction-accretion geodynamic model proposed for the evolution of the Birimian terrane of the West African Craton.

Kerosene or hydrogen peroxide? Comparison between recovery methods of mineralized microfossils in siliciclastic rocks

One of the most important steps in the recovery of mineralized wall microfossils is chemical preparation. However, this process can often be destructive to microfossils if they are not applied extremely carefully. In this way, this research tested two different methods of micropaleontological preparation to compare the rock disaggregation and the amount of recovered microfossils between the two methods. To achieve the objective, the samples were attacked with 20% hydrogen peroxide concentration and pure kerosene in fractions of 200g of each collected sample. Thirteen samples were collected, with different compositions, such as sandstones, shales, heteroliths and siltstones. After preparation, the samples were washed over sieves with a mesh between 420 and 75 μm. The disaggregation rate was calculated based on the initial mass and the mass retained on the 420 μm sieve. These values were plotted in a scatter diagram and the dispersion coefficient r was calculated, which indicated a strong positive linear correlation between the two methods. The strong linear correlation between the disaggregation rate of the samples indicates that probably the parameters that influence the rock disaggregation are intrinsic to its characteristics. Regarding the recovery of microfossils, in the kerosene method the hyaline foraminifera and phytoclasts presented a better preservation, while in the hydrogen peroxide method the agglutinating foraminifera had a better recovery. As a secondary result this research presents new data about the microfauna of the Rio Bonito Formation. The taxa retrieved were the genus Paralingulina, Thuramminoides?, Saccammina and fusiform morphotypes, three phytoclast, an ostracod and unidentified bioclasts.

Frontier of the Paleo-Tethys Ocean in the western Mediterranean: Isotopic (Sm-Nd) constraints on sources of Devonian units from Menorca Island

The c. 1000-m-thick pre-orogenic Devonian mainly metapelitic sequence of North Menorca Island shows a fairly complete stratigraphic succession. The rocks of this sequence indicate gradually increasing deeper marine conditions of sedimentation towards its uppermost levels. Furthermore, the obtained sedimentary characteristics resemble those related to a deep and narrow basin-associated deposit. Thin sills of Ti-augite-bearing alkaline gabbros occur within the Devonian sequence. The intensity of Variscan deformation increases downwards through the structure. According to the characteristics of the Devonian sequence and its location within the Variscan Orogen, a correlation with similar units located in the southern sectors of the Central Iberian Zone (Iberian Massif) is suggested. The Devonian metapelitic rocks have geochemical characteristics suggesting that they represent moderately recycled mature siliciclastic sediments, generated from erosion of distant source areas belonging to an upper continental crust. The relatively narrow range of variation observed in initial 143Nd/144Nd ratios supports a similar source for the Menorcan slates (0.51165–0.51182). However, a marked trend is observed in these isotope ratios, from lower values at the base of the stratigraphic column (minimum value of 0.511941) to higher values at the top (maximum value of 0.512131). The 147Sm/144Nd ratios vary between 0.1074 and 0.1238, within the range defined for siliciclastic rocks with felsic crustal provenance. The Nd model ages define a narrow range between 1496 Ma and 1754 Ma (Late Paleoproterozoic–Early Mesoproterozoic), and they are consistently younger up-section. These data rule out a provenance from the erosion of the West Africa Craton, as they are more compatible with a provenance from regions located in the Trans-Saharan Belt or Sahara Metacraton. The characteristics of the Menorcan Devonian sequence are compatible with its deposition in a narrow and deep peri-Gondwanan transtensional basin, generated to the south of an advancing Variscan orogenic wedge. Systematic variations in the Nd isotopic composition indicate the progressive and continuous denudation of increasingly more easterly North African sectors in a collisional context between Laurussia and Gondwana with a marked dextral component. These data must be interpreted in the sense that there was not a large oceanic domain during Devonian times to the south of Iberia, able to block the arrival of detrital material from North Africa. A large tract of the Paleo-Tethys Ocean would therefore not have existed during the Devonian south of Iberia. This ocean must therefore have had limited extent in this period towards the westernmost sectors. The Devonian peri-Gondwanan shelf was apparently continuous around Iberia. This platform was progressively affected by Variscan deformation advancing from north to south and incorporated into the Variscan orogenic wedge with the same vergence.

Impact of sediment provenance and depositional setting on chlorite content in Cretaceous turbiditic sandstones, Norway

AbstractChlorite minerals, mainly in the form of clay coats, play a critical role in determining the reservoir quality of siliciclastic rocks. They can positively influence reservoir quality by preserving porosity during deep burial, but they can also play a negative role by reducing permeability through pore filling. The main aim of this research is to determine the optimal conditions for chlorite growth in sedimentary basins. This study investigates the Lower Cretaceous turbidite sandstone of the Agat Formation in the North Sea. We used a source‐to‐sink approach to investigate the impact of sediment source composition, chemical weathering and depositional environment on chlorite formation. Understanding the interplay between these processes can help refine exploration and exploitation strategies, optimise hydrocarbon recovery, and reduce exploration risks. Representative samples from two hydrocarbon fields (the Duva and Agat fields) were investigated using petrography, geochemistry, heavy mineral identification and quantification, and U–Pb geochronology of detrital zircons. Our results show a strong heterogeneity in the sediment provenance between the two turbidite systems. In the Duva field, the sandstone is derived from a mixture of mafic and felsic sources, producing Fe‐rich sediments. Intense chemical weathering generates fine fraction materials rich in kaolinite, vermiculite, and hydroxy‐interlayered clays, which are transported into shallow marine settings. Subsequent interaction with seawater results in the formation of glauconitic materials, Fe‐illite, and phosphatic concretions. These Fe‐rich materials are remobilised into deep marine settings, providing precursors for the development of authigenic Fe‐clays such as berthierine and chlorite. Conversely, in the Agat field, the sandstone is predominantly sourced from felsic rocks that underwent low chemical weathering, producing sediment rich in quartz and feldspar with a low amount of clays. With few Fe‐rich materials transported into the basin, the development of chlorite in the Agat field was less pervasive. Basin configuration and depositional environment exerted additional control on chlorite distribution. In the confined turbidite system (e.g. Duva field), chlorite is typically found as coating, whereas in less confined turbidite systems (e.g. Agat field) chlorite shows complex distribution related to depositional environment and dewatering processes. Our findings demonstrate the importance of considering the entire sediment routing system, from source to sink, when predicting chlorite occurrence and its impact on reservoir quality in deep marine settings. This integrated approach can guide exploration and development efforts in deepwater clastic reservoirs.

Genesis mechanism of laumontite cement and its impact on the reservoir of siliciclastic rock: A case study of Jurassic Shaximiao Formation in central Sichuan Basin, China

Laumontite cement's genesis and impacts on reservoir quality in sedimentary basins have long been studied in sedimentology and petroleum geology. This study aims to analyze the petrological and geochemical properties of laumontite in the Shaximiao Formation, Sichuan Basin, China, and to determine the evolutionary process behind the formation of laumontite. Approximately 175 million years ago, huge volume of volcanic materials filled the Sichuan Basin. During the burial diagenesis phase, the hydrolysis of volcanic particles and alteration of plagioclase provided the necessary ions—Ca2+, Al3+, Si4+, Fe3+—facilitating the formation of laumontite. Simultaneously, the hydrolysis of volcanic substances released ions like Ca2+, Mg2+, and Na+, elevating the PH of pore fluids, and fostering the requisite alkaline conditions for laumontite. Additionally, the dehydration of smectite to illite in nearby mudstones generated Ca2+-rich fluids, migrating into sandstones. The hydrolysis of volcanic particles combined with the Ca2+-rich fluids migrating into sandstones led to the abundant formation of laumontite within temperatures ranging from 60 to 100 °C. During this phase, the formation of laumontite accelerates the densification of the reservoir, leading to a reduction in porosity. In the meso-diagenetic period, organic acids from the underlying formations penetrate the sandstones through fractures, creating secondary pores and dissolution-related grain-edge fractures, significantly enhancing reservoir permeability.

Silicate weathering linked with global climate change along the Mid-Pleistocene transition: A record from the Himalayan foreland Basin, India

Tectonic uplift and climate change play a pivotal role in controlling silicate weathering in the source region. Being adjacent to the hinterland, the sediments of the Himalayan foreland basin (HFB) hold an excellent archive to elucidate weathering link with climate and uplift. In this study, we present geochemical records of major, trace and rare earth elements, clay mineral compositions as well as the environmental magnetic and stable carbon isotope composition (δ13C) of siliciclastic sediments of the HFB over the past 2.0 Ma. These records have been used to link silicate weathering with global climate change along the Mid-Pleistocene Transition (MPT) period. The source rock compositions are characterized by selected elemental ratios, i.e., Cr/Th, Th/Sc, Th/Co and La/Sc as well as other geochemical proxies such as Al2O3/TiO2 and TiO2/Zr, suggesting a felsic source rock composition. The enriched LREE pattern of Chondrite-normalised REE with a negative Europium anomaly also attributes to felsic source rock composition. All these inferences suggest that most of the studied sediments were derived from mixed sources of the Higher Himalayan rocks and the Lesser Himalayan crystalline regions. A declining trend in kaolinite/(illite + chlorite) ratios, decreasing values of geochemical weathering indices (such as Rb/Sr and CIA), a decrease in magnetic susceptibility and gradual depleted value of δ13C indicate a decrease in chemical weathering of the siliciclastic rocks in the source region, which is most probably associated with the global climate change from warm-humid to cold-dry condition along the MPT. This suggests that variation in silicate weathering in the Himalayan region are mainly controlled by global climate and monsoon conditions.

Trends in estuarine pyrite formation point to an alternative model for Paleozoic pyrite burial

The early Paleozoic Era (∼540–420 Ma) was an interval of profound biogeochemical changes including increasing oxygen (O2) and the onset of bioturbation (sediment mixing by animals). It is hypothesized that incipient bioturbation caused a monotonic decrease in sedimentary burial of pyrite (FeS2), which would have slowed atmospheric O2 accumulation. However, pyrite accumulation can exhibit complex responses to dynamic, low-O2 environmental conditions. To assess pyrite burial in a potential modern analogue to early Paleozoic environments, we collected sediment cores from the Chesapeake Bay, an estuary with multiple gradients in sulfate concentration, hypoxia intensity, organic carbon flux and lability, and bioturbation. Results indicate that pyrite accumulation is maximized not under strong sulfate depletion in highly reducing sediments, but rather in sediments that occupy the mid-range of sulfate–chloride ratios. This probably occurs through efficient replenishment of pore water sulfate and/or through the generation of sulfur redox intermediates, which promote pyrite formation via the polysulfide reaction pathway. In light of these results and in contrast to earlier models, we hypothesize that mild early Paleozoic bioturbation temporarily increased pyrite burial efficiency by stimulating higher sulfate reduction rates and increasing sedimentary sulfide retention. Compiled sulfur and carbon data from a geochemical database indicate that median sulfur-carbon ratios of fine-grained marine siliciclastic rocks increased from the Ediacaran through the Ordovician, then decreased and became much less variable from the Silurian onward. Thus, the Cambrian and Ordovician Periods may constitute a distinct interval of the Proterozoic-Phanerozoic transition in which bioturbation temporarily accelerated O2 buildup. This transition probably ended in the Silurian, when pO2 rose to sufficient levels to homogenize sedimentary carbon–sulfur cycling.

Rock characteristics and reservoir properties of Upper Carboniferous (Stephanian A–B) tight siliciclastic rocks from the Saar–Nahe basin (SW Germany)

Rock characteristics and reservoir properties of Upper Carboniferous (Stephanian A–B) tight siliciclastic rocks from the Saar–Nahe basin (SW Germany)

Validation of the intrinsic vulnerability to pollution of fractured siliciclastic aquifers using natural background levels

Aquifers are important water reserves in water-scarce areas. However, uncontrolled human activities and lack of knowledge of aquifer characteristics increase their vulnerability to pollution. Assessing intrinsic vulnerability is essential for improving groundwater management. However, traditional tools, such as DRASTIC, ignore relevant parameters that, in particular contexts, lead to underestimating vulnerability. This work assesses the intrinsic vulnerability to pollution of a siliciclastic aquifer system (Shallow and Upper) by comparing the DRASTIC and modified DRASTIC methods. Modified DRASTIC included parameters such as Land Use and fracturing patterns relevant in populated areas where hydrogeological configurations involve highly cemented and fractured siliciclastic rocks with secondary porosity that define the main pathways for transporting contaminants from the surface. The intrinsic vulnerability was validated using Natural Background Levels (NBLs) of contaminant indicator ions (NO3−, PO43− and SO₄2-) to identify areas where the concentration of these indicators surpassed the NBLs. These areas were compared with the vulnerability classes from DRASTIC methods. NBLs were: 2.12 mg/l, 0.05 mg/L and 26.77 mg/L (Shallow aquifer), and 3.17 mg/L, 0.17 mg/L and 5.06 ml/L (Upper aquifer) for the ions of NO3−, PO43− and SO₄2-, respectively. The ion concentrations surpassing NBLs were spatially distributed, being more notable in the dry season and showing a greater coincidence with the high vulnerability class of the Modified DRASTIC. Thus, the modified DRASTIC better represented the high vulnerability of the aquifer system to pollution and the negative effect of anthropic activities. Additionally, Pearson's coefficients were calculated between the concentrations of contaminant indicator ions and intrinsic vulnerability indices of DRASTIC methods. However, the coefficients lack statistical significance. These results support the relevance of adding land use and fracturing patterns to assess the intrinsic vulnerability of fractured, siliciclastic aquifers in populated regions and show NBLs as a better validation method than Pearson's coefficients in data-scarce contexts.

Diverse Structural Styles of the Northeastern Tethyan Himalaya in Southern Tibet Reveal the Early Collisional Tectonics of India and Asia

AbstractThe poor understanding of the structural history of the Late Triassic flysch in the northeastern Tethyan Himalaya has caused many disputes regarding India‐Asia collisional tectonics. Here, we conducted an integrated study including tectonostratigraphic analysis, structural analysis, and zircon U‒Pb and muscovite 40Ar/39Ar dating to unravel the structural evolution of the Late Triassic flysch. Field geological mapping revealed that the flysch can be subdivided into three structural units, including the Gyaca mélange, Qiongjie‐Dengmu shear zone and Langjiexue fold‐thrust belt. The three units all contain voluminous siliciclastic rocks deposited in an abyssal submarine fan environment at the Indian passive continental margin. The Gyaca mélange shows a two‐stage deformation process that generated a collisional mélange resulting from the subduction of the Indian passive continental margin. 40Ar/39Ar dating of top‐to‐the‐south shear bands and block‐in‐matrix structure indicate that the India‐Asia collision happened no later than the Selandian (ca. 60 Ma). The divergent imbricated thrusting and folding of the Gyaca mélange and Langjiexue fold‐thrust belt formed a positive flower structure. The zircon U‒Pb and 40Ar/39Ar dating of syntectonic dikes and sericite flakes within the Gyaca mélange yield ages of ca. 56–55 Ma for the genesis of the divergent structures. Moreover, the Qiongjie‐Dengmu dextral shear zone yields a sericite 40Ar/39Ar age of ca. 35 Ma and thus indicates a transient strike‐slip stress regime. Generally, the early India‐Asia collision tectonics in the northeastern Tethyan Himalaya showed episodic evolution with changing structural styles from mélange formation to imbricate fold‐thrust belt development and finally strike‐slip shear generation.

Evolution of Upper Carboniferous tight sandstone reservoirs in the Ruhr and Lower Saxony basins (NW Germany) of the Central European Variscan foreland

Foreland basins have been extensively explored for hydrocarbon resources, geothermal, and gas storage applications, and multidisciplinarily studied to reconstruct orogenic processes. In fact, in the case of the Late Carboniferous Central European Variscan foreland basin, numerous drill cores have been recovered by the hard coal industry and comprehensive geological data sets have been made available by research. These cores and data sets provide a continuous record of the tectono-sedimentary and reservoir evolution over time. For this purpose, we have compiled petrophysical and petrographic literature data of >450 mostly tight (porosity <10%, permeability <1 mD) siliciclastic rock samples from Variscan foreland (Ruhr and Lower Saxony basin, NW Germany) and intramontane basins (Saar-Nahe basin, SW Germany) covering the complete Late Carboniferous stratigraphy. As a result, increases in mean grain size, sorting, detrital quartz, and proportion of metamorphic to sedimentary rock fragment contents, and decreases in detrital feldspar contents along the Westphalian B–C boundary are interpreted as a response to sedimentary recycling and unroofing of the Variscan hinterland due to tectonic uplift in the course of the northwestward propagating Variscan front. Thus, tectonics have a greater influence on sandstone petrography and porosity than the depositional environment. Porosity is mainly controlled by grain size and dissolution porosity. Basin-specific paleogeothermal gradients affect authigenic quartz (up to 25.0%) and chlorite (up to 7.7%) formation. Moreover, quartz cement contents <5% may stabilize the granular framework against mechanical compaction preserving porosity. With increasing quartz cement contents >5%, however, pore space is progressively clogged and the porosity preserving effect diminishes.