Silicic Volcanism Research Articles

Timing of post-orogenic silicic volcanism in the eastern part of the European Variscides: constraints from SHRIMP U–Pb zircon study of the Permo-Carboniferous Góry Suche Rhyolitic Tuffs (the Intra-Sudetic Basin)

Timing of post-orogenic silicic volcanism in the eastern part of the European Variscides: constraints from SHRIMP U–Pb zircon study of the Permo-Carboniferous Góry Suche Rhyolitic Tuffs (the Intra-Sudetic Basin)

Volcanic tuff as a World Heritage Georesource, a Case Study of Tokaj Wine Region UNESCO Cultural Landscape

Volcanic tephra and pyroclastic rocks are common georesources worldwide. Volcanic eruptions produce these materials, and the freshly deposited volcaniclastic sediments undergo variable diagenesis and possible hydrothermal alteration. The rhyolitic pyroclastic rocks of the Carpathian Basin were formed as a result of major silicic volcanism during the Miocene and are exposed in several volcanic regions. The use of these stones depends on their physical properties, such as hardness, colour, and transportability, especially in masonry and ornamental design. The study site, the Tokaj Wine Region (TWR) Historic Cultural Landscape is a UNESCO site located in NE Hungary, which was inscribed on the World Heritage List in 2002. The silicic pyroclastic rocks, here we also referred to them as rhyolite tuffs, are significant geological resources in the UNESCO cultural heritage designation. The pyroclastic formations cover an area of about 100 km2 and were deposited by three major explosive eruptions (13.1–11.5 Ma). The local varieties are defined by primary volcanological features and secondary (diagenetic, hydrothermal) effects. The stone was extracted from more than 40 open pit quarries dating from the Middle Ages. The wine cellars and dry-built terrace walls are important cultural features of the volcanic tuff use. The geoconservation value of the rhyolite tuff is well illustrated by the exposed special geological features, which represent important sites of volcanic formations. However, only one site has been declared a nature conservation area. Several historic quarries are currently abandoned, and there are many problems due to the lack of their restoration. The most common problems are the instability of quarry walls, illegal dumping, pollution, and dense vegetation covering the geological values. The volcanic tuff has a great potential as a georesource (quarries, cellars, and terrace walls) adding value to World Heritage Site, but special efforts are needed to demonstrate its potential for geoconservation, geotourism, and geo-education.

Spread and frequency of explosive silicic volcanism of the Carpathian-Pannonian Region during Early Miocene: Clues from the SW Pannonian Basin and the Dinarides

Explosive silicic volcanism of the Carpathian-Pannonian Region (CPR) is increasingly recognized as the primary source of tephra across the Alpine-Mediterranean region during the Early and Middle Miocene. However, the tephrostratigraphic framework for this period of volcanic activity is still incomplete. We present new multi-proxy data from Lower Miocene ignimbrites and tephra fallout deposits from the southwestern CPR and the Dinaride Lake System and integrate them into existing datasets to better resolve the regional extent and scale of these eruptions of the CPR. Volcanic glass geochemistry indicates distal fallout tuffs deposited in the Sinj Basin are correlative with the proximal Ostoros ignimbrites from the Bükkalja Volcanic Field, indicative of regionally extensive volcanism at 17.295 ± 0.028 Ma, based on CA-ID-TIMS UPb zircon geochronology. Based on integrated tephrostratigraphic data, newly identified 17.064 ± 0.010 Ma massive rhyolitic ignimbrite deposits from the Kalnik Volcaniclastic Complex located in the southwestern CPR are correlative with the 17.062 ± 0.010 Ma Mangó massive ignimbrite found in the Bükkalja Volcanic Field located in the northern CPR. Based on these new observations of its potential areal distribution and estimated thicknesses, these two widespread ~17.1 Ma ignimbrites represent intermediate to large caldera-forming ignimbrites, larger than previously suggested. Finally, volcanic glass geochemistry of fallout deposits from the Dinaridic Sinj and Livno-Tomislavgrad Basins have similar volcanic glass geochemistry as the rhyolitic pumices from the lowermost part of the Bogács ignimbrite unit of the Bükkalja Volcanic Field. However, high-precision geochronology indicates that these distal ashfalls were deposited at 16.9567 ± 0.0074 Ma, significantly predating the 16.824 ± 0.028 Ma emplacement of the fiamme-bearing part of the Bogács ignimbrite. These distinct ages suggest that the Bogács unit represents multiple eruptive events and indicating that further work is required to deconvolve this portion of the CPR volcanic record. Together, these data suggest that large volume CPR ignimbrite volcanism was more frequent and widespread than previously understood, enhancing the existing volcanic framework and history of the source region for this time period.

Anatomy of a Lunar Silicic Construct—The Wolf Crater Complex, Mare Nubium and Implications for Early Silicic Magmatism on the Moon

AbstractSilicic lithologies on planetary surfaces indicate magmatic evolutionary processes in their interiors. The Wolf crater complex within Mare Nubium on the Moon is one such silicic construct associated with a high thorium anomaly. This study integrates morphological, compositional, chronological and gravity anomaly analyses of high‐resolution data from various lunar missions to establish this construct as a silicic volcanic caldera. Lobate flows with steeply sloping fronts indicate that the crater rims comprise high‐viscosity silicic lavas, while the structurally controlled inner crater walls suggest caldera collapse triggered by magma depletion. In the crater rims, low Christiansen Feature position values reaffirm the presence of silicic lithologies, consistent with the low gravity anomaly signature beneath the complex, while spectroscopic data reveal low mafic mineral abundances and negligible hydration features. Chronological analyses yield silicic volcanism ages coeval with surrounding mare basalts (3.8–3.6 Ga), while intra‐caldera basalts have 2.36–2.02 Ga ages, indicating prolonged magmatism in this region. Melting of suitable crustal protoliths like alkali gabbronorite/monzogabbro/troctolite by basaltic underplating is inferred to have generated silicic magmas that formed the Wolf volcanic complex, instead of basaltic magma fractionation or silicate‐liquid immiscibility processes. Large impacts during the Late Heavy Bombardment may have enhanced partial melting of the mantle and created crustal fractures that facilitated the ascent of viscous silicic melts through the lunar crust. Contemporaneous existence of suitable protoliths and adequate crustal pathways for magma ascent may have controlled silicic volcanism on the Moon, and can explain the sporadic occurrence and overlapping ages of the lunar silicic constructs.

Evidence for the formation of silicic lava by pyroclast sintering

Silicic lavas can be produced by the sintering of pyroclasts in the volcanic sub-surface, and then advected out of the vent. Here, we provide evidence for this mechanism preserved in the exposed post-glacial remnants of a silicic volcanic conduit at Hrafntinnuhryggur, Krafla volcano, Iceland. We show that the conduit margins are a clast-supported pumice lapilli tuff deposit that grades continuously into dense obsidian and that the obsidian contains cuspate relict clast boundaries and country rock lithic fragments throughout. Transects of H2O concentrations across the conduit show that the magma was degassed to different degrees laterally with systematic spatial variation that is consistent with progressive conduit clogging and final gas pressurisation. Textures in the overlying effusive lavas record the variably sheared and brecciated remnant of the same in-conduit sintering. This record of a silicic conduit system connected to upper eruptive deposits provides support for the ‘cryptic fragmentation model’ for effusive silicic volcanism.

Extended Silicic Volcanism in the Gruithuisen Region—Revisiting the Composition and Thermophysical Properties of Gruithuisen Domes on the Moon

The formation mechanisms, extent, and compositions of red spots on the lunar surface have intrigued the lunar community for decades. By identifying a new dome and another silicic crater in the highlands nearby, we find that the silicic volcanism in the Gruithuisen region extends beyond the three major domes. Our observations indicate that the Gruithuisen domes have low iron and titanium contents. They are enveloped by ejecta from surrounding regions and host silica-rich material excavated by the young craters consistent with previous work. Our boulder maps of the Gamma dome display a high boulder count and indicate that the Diviner rock abundance maps are only sensitive to boulders larger than ∼2 m. The H-parameter values are sensitive to presence of rocks and may be a better indicator of rocks at submeter scales. The Delta dome has gentle slopes, lower rock abundance, and one young crater, and it could serve as a safe and scientifically valuable site for landing and exploration of the domes and nearby region. The dome also displays anomalously high H-parameter in the same region as the crater, indicating the potential presence of pyroclastic materials. We observe up to 200 ppm of OH/H2O on the domes and nearby mare despite the presence of a weak magnetic field to the south of Delta dome, further supporting the potential presence of pyroclastics in the region. This study could potentially aid in logistical and scientific decisions of the future NASA missions in the region.

Early Triassic Silicic Volcanics of South China: Petrogenesis and Constraints on the Geodynamic Evolution of the Paleo‐Tethys Ocean Region

AbstractThe only occurrence of Lower Triassic silicic volcanic rocks within the South China Block is in the Qinzhou Bay area of Guangxi Province. LA‐ICP‐MS zircon U‐Pb dating reveals that volcanic rocks of the Beisi and Banba formations formed between 248.8 ± 1.6 and 246.5 ± 1.3 Ma, coeval with peraluminous granites of the Qinzhou Bay Granitic Complex. The studied rhyolites and dacites are characterized by high SiO2, K2O, and Al2O3, and low MgO, CaO, and P2O5 contents and are classified as high‐K calc‐alkaline S‐type rocks, with A/CNK = 0.98–1.19. The volcanic rocks are depleted in high field strength elements, e.g., Nb, Ta, Ti, and P, and enriched in large ion lithophile elements, e.g., Rb, K, Sr, and Ba. Although the analyzed volcanic rocks have extremely enriched zircon Hf isotopic compositions (εHf(t) = –29.1 to –6.9), source discrimination indicators and high calculated Ti‐in‐zircon temperatures (798–835°C) reveal that magma derived from enriched lithospheric mantle not only provided a heat source for anatectic melting of the metasedimentary protoliths but was also an endmember component of the S‐type silicic magma. The studied early Triassic volcanics are inferred to have formed immediately before closure of the Paleo‐Tethys Ocean in this region, as the associated subduction would have generated an extensional setting in which the mantle‐derived upwelling and volcanic activity occurred.

From source to surface: clues from garnet-bearing Carboniferous silicic volcanic rocks, Iberian Pyrite Belt, Portugal

This work investigates the relationships between partial melting, melt extraction, pluton growth and silicic volcanism in garnet-bearing felsic volcanic rocks that were extruded in the Iberian Pyrite Belt, at ca. 345 Ma. The garnets are of peritectic origin, displaying textural and chemical features of disequilibrium crystallization during partial melting reactions involving biotite at high temperatures (up to 870 °C) in the middle-lower crust. Major element composition suggests compositional equilibrium with the entrained and pinitized peritectic cordierite, but reveals some subsequent homogenization by diffusion. Trace element maps and spot analyses of garnet show, nonetheless, significant trace element variations, reflecting biotite and Y-REE-P-rich accessory phase breakdown during partial melting reactions. Peritectic garnet and cordierite growth resulted in the preservation of Th- and Y-rich prograde suprasolidus monazite, which constrains the timing of partial melting of the metapelitic protolith at ca. 356.8 ± 2.4 Ma. The zircon cargo further shows that a significant amount of zircon crystals from previously crystallized felsic melts were also remobilized and erupted. These were likely stored in an upper crustal pluton that grew episodically since ca. 390 Ma during voluminous melt generation periods within the middle to lower crust, which also resulted in voluminous volcanism. The geochemical trends of the felsic volcanic rocks reflect the entrainment of xenoliths of peritectic garnet, cordierite and feldspar, and as such, the garnet-bearing felsic volcanic rocks represent an erupted mixture of a lower-temperature (ca. 770 °C) silicic melt and autocrysts, and peritectic phases and zircon crystals from previously crystallized and stored felsic melts.

Ancient silicic volcanism and incipient rift propagation during Gondwana breakup; geophysical insights from the Bumbeni ridge, South Africa

A detailed understanding of the association between magmatism and rift initiation is key to defining the prevailing tectonic conditions active during the initial break-up of Gondwana. The Bumbeni Complex in northern KwaZulu-Natal, South Africa represents an early Cretaceous silicic volcanic centre exposed at the southwestern termination of a linear zone of magnetic anomalies which are buried beneath sedimentary cover. Newly acquired high resolution aeromagnetic data combined with legacy seismic and borehole data is analysed to define the structural architecture of the basement beneath the Zululand Basin in northern KwaZulu-Natal. Multiple prominent positive and negative anomalies ranging from −200 nT to +300 nT based on International Geomagnetic Reference Field (IGRF) and corrected Reduced to Pole (RTP) data are resolved and form a distinct geophysical lineament. Geophysical and borehole core data indicate that the lineament represents a chain of silicic central volcanoes developed as a ridge feature, the Bumbeni Ridge, along the axial zone of an incipient rift structure. Detailed geological mapping and high resolution geophysical data are analysed and compared with analogous contemporary continental rift environments, as well as published data within the adjacent offshore Northern Natal Valley. Results are presented which propose a continental rift evolutionary model for Gondwana breakup in the Zululand Basin in northern KwaZulu-Natal.

Reassessment of the sulfur and halogen emissions from the Millennium Eruption of Changbaishan (Paektu) volcano

The 946 CE ‘Millennium Eruption’ of Changbaishan (aka Paektu) volcano ranks among the largest volcanic events of the Common Era. Its fallout represents a widespread precisely-dated marker horizon yet little is known of its environmental impacts. Here, we revisit petrologic constraints on the pre-eruptive conditions of the dominant rhyolitic magma in order to estimate the eruption's volatile budget. We show that silicic reservoirs may lose more than half of their volatile complements prior to eruption and estimate that the Millennium Eruption emitted just 2–7 Tg of sulfur and 5–10 Tg of chlorine to the atmosphere, depending on the accepted eruption magnitude. These values are lower than previous petrologic estimates but consistent with ice core glaciochemistry and tree-ring-based climate reconstructions. We further suggest that any reawakening of Changbaishan / Paektu should be heralded by enhanced CO2 emissions if driven by basalt intrusion, or by H2-H2O-rich and halogen-poor gases if resulting from evolution of a silicic reservoir. Our findings emphasise the importance of robust assessments of pre-eruptive conditions, especially in respect of temperature, when applying petrologic arguments to evaluate outgassing from silicic volcanism.

U–Pb zircon age and chronology of the Torfufell central volcano: implications for timing of rift relocation in North Iceland

The Late-Miocene Torfufell central volcano (ToCV), situated between the now extinct Snæfellsnes-Húnaflói rift zone and the presently active rift in North Iceland, provides an excellent opportunity to recreate the construction history of a volcanic edifice. We present new U–Pb zircon ages from six silicic units of the ToCV. The results range from 7.15 ± 0.12 to 6.76 ± 0.02 Ma, taken here to represent a ~ 400 kyr time-span for silicic activity at the volcano. Before that, the central volcano had produced basaltic lavas for 600–800 kyr, implying that it was active for ~ 1–1.2 Myr. A stratigraphically documented ~ 1 Myr hiatus above the volcano is contemporaneous with, but shorter than, a major unconformity in the Flateyjarskagi peninsula, considered to result from a major rift relocation in North Iceland. The new U–Pb ages show that silicic volcanism at the ToCV took place 1–2 Myr earlier than assumed previously and nearly synchronously with the rift relocation. As the age progression of the ToCV and the neighboring 5–6 Ma Tinná central volcano conflicts with the generally established geotectonic framework of central N-Iceland, we propose that these two volcanoes were formed at a leaky transform zone that developed to accommodate the rift relocation, with the ToCV formed at its junction with the embryonic rift zone, thus marking the initiation of the presently active rift in North Iceland. Since then, the two volcanoes have drifted away from the rift system due to plate spreading and migration of the plate boundary relative to the Iceland mantle plume.

Large-volume Permian felsic volcanism in the Tisza Mega-unit (East-Central Europe): Evidence from mineralogy, petrology, geochemistry, and geochronology

Permian felsic volcanic rocks are widespread in the Tisza Mega-unit (Carpathian–Pannonian region), covering a relatively large area from southern Transdanubia (Hungary) to the Apuseni Mountains (Romania). The present occurrence and structural position of these Permian volcanic rocks are the result of a complex tectonic evolution (including Alpine nappe stacking and Neogene extension); meanwhile, multiple hydrothermal effects and deformation modified their microtexture and chemical composition. In this study, the same emphasis was given to Permian felsic volcanism as well as the subsequent fluid- and/or deformation-related processes in the Tisza Mega-unit to extend our knowledge in regional issues (e.g., geochronology, stratigraphy, and lithologic correlations) and to investigate if the variably altered volcanic rocks can be used in petrogenetic studies.The zircon U-Pb dating yields ages of ∼270.4–262.9 Ma for the Apuseni samples and ∼268.4–260.2 Ma for those of the Pannonian Basin. Whole-rock geochemistry, considering immobile trace elements, since most of the major element compositions were severely modified by alteration processes, indicates that the studied rocks are dacite to rhyolite. They belong to a voluminous silicic volcanism during the Middle Permian, most probably related to rifts.Petrography, whole-rock geochemistry, and X-ray powder diffraction mineralogy revealed that the predominant alteration of the studied rocks is hydrothermal sericitization, locally superimposed by mylonitization in greenschist to subgreenschist conditions during Alpine orogeny. The K-Ar dating of the separated illite fractions confirms that the ductile deformation acted during the Turonian nappe stacking, as the main Alpine deformation phase in the study area.On a regional scale, the Permian magmatism in the Tisza Mega-unit looks significantly younger than the similar magmatic activity of the stable Europe (∼300–290 Ma).

Flare Up of Hot-Dry-Reduced Ignimbrites Related to Extension in the Cascades Arc: The Deschutes Formation, Central Oregon

Abstract Ignimbrite flare-ups are rare periods of intense silicic volcanism during which the pyroclastic volume and eruptive frequency is more than an order of magnitude higher than background activity. Investigating the compositional differences between flare-up and steady-state magmas provides critical constraints on the petrogenetic causes for the event and can offer unique opportunities to investigate the role of large-scale tectonic or geodynamic processes in arc magmatism. In this study, we focus on the bimodal Deschutes Formation ignimbrite flare-up of Central Oregon, which erupted unusually high volumes of pyroclastic material 6.25–5.45 Ma from a new axis of volcanism in the Cascades arc. This episode is marked by increased eruption rates and eruption of more silicic compositions relative to the Quaternary Cascade arc, which rarely erupts rhyolites. Ignimbrites are crystal-poor (<10%) dacite to rhyolites (mostly 65–77 wt.% SiO2) with anhydrous mineral assemblages and higher FeO/MgO, Y, Eu/Eu*, MREE and Zr/Sr, indicating drier magmatic evolution compared to the Quaternary arc, and are more similar to those from the rear-arc High Lava Plains (HLP) province that lies to the east. Magnetite-ilmenite oxybarometry indicates that Deschutes Formation felsic magmas tend to be hotter and more reduced (NNO-1 to NNO) than the Quaternary arc (NNO to NNO + 1.5). Rhyolite-MELTS geobarometry suggests complex storage of diverse Deschutes Formation magmas within the shallow crust (50–250 MPa), and the common co-eruption of multiple plagioclase populations, pumice compositions, and compositionally banded pumice suggest variable degrees of mixing and mingling of distinct magmas. Deschutes magmas also have low δ18Oplagioclase values that indicate partial melting and assimilation of hydrothermally altered shallow crust. Trace element systematics and rhyolite-MELTS modeling suggests that felsic pumice cannot be produced by simple fractionation of co-erupted mafic pumice or basaltic lavas, and requires a crustal melting origin, and trace elements and Pb isotopes suggest that young mafic crust may have been the primary protolith. We suggest that partial melting produced low-Si rhyolite melt (~72 wt.%) that acted as both a parent for the most evolved rhyolites, and as a mixing endmember to create the dacite to rhyodacite magmas with heterogenous plagioclase populations. Unlike the predominantly calc-alkaline basalts erupted in the Quaternary Cascade arc, Deschutes Formation primary basalts are mostly low-K tholeiites, indicative of decompression melting. These are similar to the compositions erupted during a contemporaneous pulse of low-K tholeiite volcanism across the whole HLP that reached into the Cascades rear-arc. We suggest that intra-arc extension focused decompression melts from the back-arc into the arc and that tensional stresses allowed this high flux of hot-dry-reduced basalt throughout the crustal column, causing partial melting of mafic protoliths and the production of hot-dry-reduced rhyolite melts. Depletion of incompatible elements in successive rhyolites implies progressive depletion in fertility of the protolith. Extension also allowed for the establishment of a robust hydrothermal system, and assimilation of hydrothermally-altered rocks by magmas residing in a shallow, complex storage network lead to low δ18O melts. Our findings suggest the integral role that extensional tectonics played in producing an unusual ignimbrite flare-up of hot-dry-reduced rhyolite magmas that are atypical of the Cascades arc and may be an important contributor to flare-ups at arcs worldwide.

The physical volcanology of large-scale effusive and explosive silicic eruptions in southeastern Saurashtra, Deccan Traps

AbstractSilicic magmatism, minor overall in the ∼65.5 Ma Deccan Traps continental flood basalt (CFB) province of India, was widespread in the Saurashtra region. We describe the physical volcanology of silicic volcanics and dykes exposed around Rajula–Savarkundla–Gariyadhar–Talaja towns in southeastern Saurashtra. The silicic volcanics conformably overlie basaltic lavas, suggesting rapid subaerial volcanism, and the sequence shows gentle tectonic dips (∼15°) towards the Arabian Sea. Rhyolites and dacites with preserved thicknesses of tens of metres show intense internal rheomorphic deformation, and a dacite shows a well-formed basal autobreccia. The rheomorphic rhyolites, and vitrophyres which often underlie them, lack vitroclasts (glass shards and pumice clasts). They have very similar mineral assemblages (quartz and alkali feldspar phenocrysts, and crystal cargoes dominated by calcic plagioclase and clinopyroxene or orthopyroxene, sometimes with olivine). The rheomorphic units are thus flood rhyolite and dacite lavas, apparently common in the northern-northwestern Deccan, and the vitrophyres their basal chilled parts. Tuffs (including crystal-vitric Plinian fallout ash) and eutaxitic ignimbrites formed from pyroclastic density currents; one tuff contains extraordinary numbers of lithophysae. Ridges of rhyolitic tuff breccias with pervasive secondary silicification and ferruginization represent pyroclastic eruptive fissures. The area thus records large-scale effusive and explosive silicic eruptions. Mafic and silicic dykes intrude the basaltic lavas and rarely the silicic volcanics. Mafic enclaves in several silicic dykes and some volcanics indicate magma mingling as a common phenomenon. The seaward-dipping volcanic units define a regional-scale flexure comparable to coastal flexures in CFB provinces worldwide, suggesting extensive block-faulting of this classical volcanic rifted margin.

Buried Silicic Volcanoes Discovered in the Gruithuisen Region on the Moon

AbstractMons Gruithuisen is a rare example of nonmare silicic volcanoes on the Moon. We have conducted analyses of the topography, chemical compositions, and subsurface structures of the Gruithuisen region based on remote sensing and gravity data. Our findings include presence of newly detected magma chambers in addition to the previously identified silicic domes in Gruithuisen Region. Our analysis suggests that multiple phases of silicic volcanism have occurred in the Gruithuisen region. The subsurface density revealed by the gravity data also suggests the presence of several low‐density masses in the crust. These early‐formed silicic volcanoes at low elevations are overlain by later‐emplaced mare basalts, however, the side slopes of these volcanoes are not covered by mare basalts, and the low‐FeO abundance material is exposed on the lunar surface.

Geochemistry and origin of felsites and associated A-type granites at Wadi Atalla area, Central Eastern Desert, Egypt: Implication for genesis of Neoproterozoic post-collisional highly silicic melts

Alkaline volcanics (felsites) and A-type granites are spatially and temporally associated in the Wadi Atalla area, Central Eastern Desert, Egypt. These rocks represent final Neoproterozoic magmatic activity in the Northern Nubian Shield. Wadi Atalla felsites form NW-trending elongate mass consisting of silicic volcanics, which is intruded by A-type granites of Um Had and Um Effein plutons. Field relations indicate that both felsites and A-type granites were emplaced in a series of magmatic pulses. Felsites include tuffaceous, porphyritic and hypabyssal varieties, while A-type granites comprise syenogranite and alkali feldspar granite. Geochemically, they are highly silicic rocks and display a narrow range of SiO2. They have high-K alkaline nature with metaluminous to peraluminous character and were erupted in a post-collisional tectonic setting. Mineral chemistry of biotite supports the alkaline and A-type characters of the studied rocks. Atalla felsites and associated A-type granites show light REE enrichment relative to heavy REE [(La/Lu)n = 2.67–5.72] with pronounced negative Eu anomalies (Eu/Eu* = 0.15–0.52). Compositional similarities between Atalla felsites and A-type granites in the studied area suggest that the intrusive and extrusive events are broadly related. The systematic variation of major- and trace-element contents of the felsites and A-type granites indicates derivation from similar sources through partial melting of juvenile crustal rocks, followed by extensive fractional crystallization. The main fractionated phases are feldspars, with minor role of fractionation of amphibole, biotite, apatite and FeTi oxides. Multiple saturation calculations indicate water-saturated storage and final equilibration conditions for the felsites ranging from 788 °C at 90 MPa to 740 °C at 255 MPa. The parental magmas of the felsites and A-type granites were linked to lithospheric delamination and upwelling of asthenospheric mantle material. This process led to generation of mantle melts that supplied heat to melt the juvenile crust of the Arabian-Nubian Shield (ANS), along with crustal uplift recorded by intersecting strike-slip faults and shear zones. Atalla felsites represent a distinctive post-collisional alkaline volcanic phase in the Nubian Shield that has been emplaced in an extensional tectonic regime, during a phase of fracturing and crustal uplift, which followed the end of the Pan-African orogeny. This volcanic phase is younger than the Dokhan volcanics in the Eastern Desert and older than the typical Katherina volcanics in southern Sinai.

From the Lebombo Monocline to the Mozambique Deep Basin, using combined wide-angle and reflection seismic data

The North Natal valley (NNV), South Mozambique margin, is a key area for the understanding of the SW Indian Ocean history since the Gondwana break-up as its crustal nature and geometry strongly impacted the reconstruction of the paleogeography before the rifting. It is also of considerable importance for the understanding of the evolution of a margin system as the NNV is situated at the transition between divergent and strike-slip segments and at the conjunction of Oxfordian-Kimmeridgian Indian Ocean and the Valanginian-Aptian Atlantic one. As one part of the PAMELA project (PAssive Margins Exploration Laboratories), the NNV and the East Limpopo margin have been investigated during the MOZ3/5 cruise (2016), through the acquisition of 7 intersecting wide-angle profiles and coincident marine multichannel (720 traces) seismic as well as potential field data. Simultaneously, land seismometers were deployed in the Mozambique coastal plain (MCP), extending six of those profiles on land for about 100 km in order to provide information on the onshore-offshore transition. Wide-angle seismic data are of major importance as they can highlight constraints on the crustal structure of the margin and the position of the continent-ocean boundary in an area where the crustal nature is poorly known and largely controversial. The MOZ3/5 data set therefore reveals new essential constraints for kinematic reconstructions. This work presents results on the crustal structure from P-waves velocity modeling along two E-W wide-angle profiles (MZ1 and MZ2) through the NNV, from the Lebombo Monocline to the Mozambique Basin (MB), and crossing the Mozambique Fracture Zone (MFZ).The new geophysical data reveals an upper sedimentary sequence characterized by low velocities generally not exceeding 3 km/s, and up to 3 km thick where a major contouritic structure was observed. This feature formes together with several other contouritic structures, a N-S alignment just west of the MFZ, which produces high positive gravity anomalies, previously thought to be related to the magmatism that built the Galathea and Dana Plateaus. High velocity lenses are locally identified through the sedimentary layers and interpreted as inter-bedded volcanic sills. Furthermore, from the NNV to the MFZ, the underlying sequence is formed of a 3.0–3.5 km thick volcano-sedimentary sequence presenting important lateral changes in its seismic signature and characterized by a large velocity range (4.4 to 5.8 km/s), which partly reflects variations in the volcanic/sedimentary ratio laterally and with depth. At depth, an initially smoother and reduced eastward thinning of the crust occurs to the West below the continental shelf, from 34 to 31 km thick. The crustal thickness remains relatively constant of about 28–29 km along the Central Domain (CD), whereas a second and major region of thinning (26 to 12 km thick) is imaged West of the MFZ, in the southward prolongation of the Limpopo Corridor (LC). By contrast, as the eastern extremity, the crust is <10 km thick when reaching the MB. Crustal velocities reveal low velocity gradients, with atypical high velocities, increasing to 7.3 to 7.6 km/s at the base of the crust, and globally in the whole crust in the LC, just West of the MFZ. We interpreted the velocity architecture combined with the evidence of volcanism at shallower depths as indicative of an intensively intruded continental crust in the NNV, and discuss the particular segmentation of the longest profile (MZ1) in the kinematic context of both divergent and strike-slipe segments offshore Mozambique.Combining wide-angle and reflection seismic observations along these two profiles and the other MOZ3/5 lines, the data shows a coherent segmentation of the E-W crustal architecture off South Mozambique. These results along MZ1 and MZ2 profiles, combined with the previously published profiles, gives a 3D-view of the NNV, which becomes one of the most passive margins covered in the world by deep wide-angle seismic data.

Magmatic addition rates differentiate periods of steady-state versus flare-up magmatism in the Central Andean arc

Cordilleran arcs are built by long periods of steady-state magmatism punctuated by transient high-flux magmatic episodes or flare-ups. Such flare-ups, manifested as periods of prodigious silicic volcanism and magmatism, result from geodynamic perturbations that cause elevated rates of magma addition to the crust. Questions remain, however, about how magmatic addition rates quantitatively compare between steady-state and flare-up modes of arc magmatism, and how long after the major geodynamic perturbation the flare-up begins. Here, we compute new estimates of erupted volumes over the last 35 Myr for the 22.5–29°S segment of the Central Andes based on a new volcanic geospatial database. These yield magmatic addition rates at least an order of magnitude higher during flare-up compared to steady-state conditions. A lag time of ~8–12 Myr between ocean ridge subduction (the major geodynamic perturbation in the Central Andean arc) and the onset of flare-up conditions is estimated.

Using Apatite to Track Volatile Evolution in the Shallow Magma Chamber below the Yonaguni Knoll IV Hydrothermal Field in the Southwestern Okinawa Trough

The Yonaguni Knoll IV is an active seafloor hydrothermal system associated with submarine silicic volcanism located in the “cross back-arc volcanic trail” (CBVT) in the southwestern Okinawa Trough. However, the behavior of volatiles during magmatic differentiation in the shallow silicic magma chamber is unclear. Here, the volatile contents of apatite inclusions trapped in different phenocrysts (orthopyroxene and amphibole) and microphenocrysts in the rhyolite from the Yonaguni Knoll IV hydrothermal field were analyzed by using electron microprobe analysis, which aims to track the behavior of volatiles in the shallow magma chamber. Notably, the ‘texturally constrained’ apatites showed a decreasing trend of XCl/XOH and XF/XCl ratios. Based on the geochemical analyses in combination with thermodynamic modeling, we found that the studied apatites were consistent with the mode of volatile-undersaturated crystallization. Therefore, volatiles were not saturated in the early stage of magmatic differentiation in the shallow rhyolitic magma chamber, and consequently, the metal elements were retained in the rhyolitic melt and partitioned into crystalline magmatic sulfides. Additionally, previous studies suggested that the shallow rhyolitic magma chamber was long-lived and periodically replenished by mafic magma. The injection of volatile-rich and oxidized subduction-related mafic magmas can supply abundant volatiles and dissolve magmatic sulfide in the shallow magma chamber. These processes are important for the later-stage of volatile exsolution, while the forming metal-rich magmatic fluids contribute to the overlying Yonaguni Knoll IV hydrothermal system.

Origin of silicic rocks of the Deccan Traps continental flood basalt province: Inferences from field observations, petrography, and geochemistry

The origin of silicic rocks (SiO2 > 65 wt%) in Continental Flood Basalt (CFB) provinces could be attributed to complex petrogenetic processes. The 65.5–66 Ma old Deccan Traps CFB contains eight sporadic but significant silicic rock exposures that are studied here in a comprehensive framework using field observations, petrography, major oxides (n = 56), and trace element chemistry. Rhyolite and granophyre, as well as subordinate felsite, ignimbrite, trachyte, pitchstone, and microgranite coexist with volcanic and plutonic mafic rocks such as basalt, basaltic andesite, and gabbro. Multiple isolated and circular/semi-circular hills and linear dykes of silicic rocks are present in the form of lavas with prominent flow folding, rheomorphic ignimbrite, and tuffs. The ‘Rheological Agpaitic Index’ (RAI) indicates that most of the silicic rocks in the Deccan Traps are effusive in nature, except for Rajpipla, Alech, Bombay, and Osham silicic rocks, which are marked by explosive volcanism. Thermodynamic-based Rhyolite-MELTS modelling suggests that the major oxide composition of Pavagadh and Barda basalt is a likely candidate for the parental melt composition of the silicic rocks of the Deccan Traps. Ba, Sr, P, Zr, and Ti anomalies are consistent with the fractionation of K-feldspar, plagioclase, apatite, zircon, and Fe-Ti oxides, respectively. Two broad REE patterns are noticed in the Deccan Traps silicic rocks: a flat pattern for Barda, Alech, and Chogat-Chamardi silicic rocks, and a steep REE pattern for Osham, Rajula, Pavagadh, Rajpipla, and Bombay silicic rocks. Trace element modelling reveals that 5–10 % partial melting of a spinel peridotite source could produce an REE pattern and abundances similar to the associated basalts. Further extensive fractional crystallization (60–90 %) of the parental mafic melt at a deeper depth (where spinel is stable) could produce the REE composition and pattern observed in most silicic rocks except for those of Barda, Alech, and Chogat-Chamardi, which require fractional crystallization of the same parental melt at a shallower depth (where spinel is not stable). The geochemical variability of Deccan Traps silicic rocks reveals an origin from a mantle-derived parental mafic melt that evolved via the assimilation and fractional crystallization (AFC) process to form the silicic exposures, which is typical of silicic volcanism in other global CFBs.