Using values of viscosity and its temperature dependence, density, heat capacity and thermal conductivity appropriate to rhyolitic liquids an analysis of the macroscopic heat balances of these liquids flowing under constant stress has been carried out. The analysis shows that for shear couples and shear stresses expected in the flow of silicic lava on the earth's surface thermal feedback may occur after time periods ranging from a few seconds to several days and may cause rapid increases in temperature. For silicic magmas flowing in a dike or circular conduit under a constant pressure gradient these thermal instabilities may occur after a few days to several weeks for dike half thicknesses or conduit radii ranging from a few centimeters to a few meters. For silicic lava flows this phenomenon may be important in producing commonly observed flow structures such as pumiceous banding and color banding. Local temperature increases would have the effect of reducing local water solubility, increasing diffusion rates, and increasing nucleation and growth rates of vapor bubbles, thus causing highly vesicular bands that parallel the shear planes. Temperature increases could also cause increases in f O 2 within a fluid layer resulting in oxidation and red color banding. For silicic lavas flowing in dikes or conduits, the possible thermal instabilities are accompanied by instabilities in volume rate of flow which may contribute to rapid vesiculation of upward-moving magma and result in explosive volcanism.