Silty Sediments Research Articles

Analysis of fine-grained sediment dynamics from field observations with a vector autoregressive model

Empirical models and process-based theoretical or numerical models are valuable tools for analyzing sediment dynamics by reproducing the suspended sediment concentration (SSC) observations, but they are either limited by simplified assumptions or computationally complex. Some data-driven models have been developed to predict SSC but are still weak in explaining the causes of its changes. A field observation of silty sediment dynamics was performed in the Yellow River Delta, China. Then, a vector autoregressive (VAR) model is employed to analyze and predict the SSC variations. Using the impulse response function, the VAR model quantifies the transient and cumulative responses of the SSC to storm and current shocks (i.e., the impulse input), which reveals the key mechanisms of SSC changes from a new perspective. Results show that the storm effect on SSC in the study area lasts for ca. 85 h, and the SSC peaks at around the 36th hour with a cumulative increase of about 1.3 g/L due to the storm’s cumulative effect. Quantitative analysis reveals that waves contribute 73.78% to the SSC, while tidal currents contribute 26.22%. Fine SSC is significantly impacted by horizontal advection. A single reciprocal motion of the tidal current affects the SSC for approximately 6.25 h, while the overall duration exceeds 100 h. The proposed model physically reveals that the storm-induced high concentration gradient has been pushed back and forth by the tidal currents, affecting the SSC at the observation site, and the horizontal advection effect lasts for more than 100 h. Moreover, the VAR model achieves high-accuracy interval predictions of SSC for the next 5 h using only historical hydrodynamic data, with a 100% coverage probability of the 95% prediction interval. This paper provides a simple and efficient method for sediment dynamics analysis, which is of great significance for marine environment protection and disaster warning.

Characterization of sediment organic matter in the outer Yangtze River Estuary using stable isotopes, optical techniques, and FT-ICR-MS: Implications for the carbon burial mechanism

The burial of sediment organic matter (SOM) in the estuary and shelf plays an important role in the global carbon cycle. However, it is challenging to determine the source, composition, and burial of SOM in the coastal sea, especially at the molecular level. This was explored in the coastal area outside the largest Yangtze River of China with multiple techniques including elemental and stable isotopic analysis, absorption spectroscopy, fluorescence excitation-emission matrices coupled with parallel factor analysis (EEMs-PARAFAC), and ultra-high resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS). The end-member mixing analysis based on δ13C and δ15N showed a dominance of marine contribution (up to 70%) at most stations while the terrestrial contribution increased to >55% nearshore in summer at a high fluvial sediment flux. This was consistent with the offshore decreasing humic-like C1 and C2, humification index (HIX), %lignin-like compounds, and %CHO but increasing tryptophan-like C3, biological index (BIX), %protein-like compounds, and %CHOS from EEMs-PARAFAC and FT-ICR-MS analysis. The %clay correlated positively with SOM content, HIX, %lignin-like compounds, O/C, and modified aromaticity index (AImod) but correlated negatively with %C3, H/C, and the relative abundance of labile formulas (MLBL), while %silt showed contrasting correlations. These results indicated the fine clay sediments adsorbed more humified, aromatic, oxygenated, and terrestrial compounds that were probably more resistant to biodegradation and thus had a higher burial efficiency than those on the silty sediments. Principal component analysis based on SOM indices further revealed different characteristics of SOM in the nearshore, northern offshore, and southern offshore regions, which were probably dependent on the delivery by local current systems. Overall, these findings contributed to unraveling the source and molecular composition of SOM associated with different grain size sediments and local current delivery, which are fundamental for understanding the factors underlying carbon burial in the complex coastal environment.

Micro-Nano Dual-Scale Coatings Prepared by Suspension Precursor Plasma Spraying for Resisting Molten Silicate Deposit

Yb-doped Y2O3 stabilized ZrO2 (YbYSZ) coatings, developed through solution precursor plasma spraying (SPPS), are engineered to resist calcium–magnesium–alumino–silicate (CMAS) infiltration by leveraging their unique micro-nano structures. This provides superior anti-wetting properties, crucial for preventing CMAS penetration at high temperatures. The investigation focused on the structural and compositional changes in YbYSZ-SPPS coatings subjected to prolonged thermal exposure at 1300 °C. Results indicate that while the coatings undergo significant sintering, leading to densification and microstructural evolution, the elemental composition and phase stability remain largely intact after up to 8 h of heat treatment. Despite some reduction in CMAS resistance, the coatings maintained their overall protective performance, demonstrating the potential of SPPS coatings for long-term use in high-temperature environments where CMAS infiltration is a concern. These findings contribute to the development of more durable TBCs for advanced thermal protection applications.

Fossil Geyserite and Testate Amoebae in Geothermal Spring Vent Pools: Paleoecology and Variable Preservation Quality in Jurassic Sinter of Patagonia (Deseado Massif, Argentina).

Geyserite is a type of terrestrial siliceous hot spring deposit (sinter) formed subaerially in proximal vent areas, with near-neutral pH, alkali chloride discharge fluids characterized by initial high temperatures (~73°C to up to 100°C) that fluctuate rapidly in relation to dynamic hydrology, seasonality, wind, and other environmental parameters. We analyzed sinters at the Claudia paleogeothermal field from the Late Jurassic (~150 Ma) Deseado Massif geological province, Argentinean Patagonia. The geyserite samples-with spicular to columnar to nodular morphologies-contain abundant microfossils in monotypic assemblages that occur in three diagenetic states of preservation. The best-preserved microfossils consist of vesicle-like structures with radial heteropolar symmetry (~35 μm average diameter), circular apertures, smooth walls lacking ornamentation, and disk- or beret-like shapes. Comparisons with extant, morphologically similar organisms suggest an affinity with the testate amoebae of the Arcella hemisphaerica-Arcella rotundata complex and Centropyxis aculeata strain discoides. These species occur in active geothermal pools between 22°C and 45°C, inconsistent with the temperature of formation of modern geyserites. We propose that the testate amoebae may have colonized the geyserite during cooler phases in between spring-vent eruptive cycles to prey on biofilms. Silica precipitation through intermittent bathing and splashing of fluctuating thermal fluid discharge could have led to their entrapment and fossilization. Petrographic analysis supports cyclicity in paleovent water eruptions and later diagenesis that transformed the opal into quartz. Spatially patchy degradation and modification of the silicified microorganisms resulted in variable preservation quality of the microfossils. This contribution illustrates the importance of microscale analysis to locate early silicification and identify high-quality preservation of fossil remains in siliceous hot spring deposits, which are important in early life studies on Earth and potentially Mars.

Observing changes of fish community in a semi-arid subtropical coastal lagoon subject to ecological conservation

El Soldado is a semi-arid subtropical coastal lagoon subject to ecological conservation in the Gulf of California, where we reviewed the changes in the fish community structure before (1972; 1978–79; 1990–92) and after (cycle 1, 2018–2019; cycle 2, 2019–2020) the decree as a protected area, and we determined spatio-temporal changes between two consecutive annual cycles. We conducted monthly fish sampling cycles 1 and 2 with a small trawl net at three sites, where water and sediment variables were recorded, and drift macroalgae biomass was estimated. Results showed 99 fish species have been recorded in previous studies, and our study added 11 species. The fish assemblage (2018–2020) comprised 34 marine species and nine of them were dominant in both cycles. In general, higher fish abundance, richness, and diversity were observed in the cycle 1. Spatial changes, in both cycles, showed higher fish abundance, richness, and diversity in the innermost area of the lagoon, characterized by silty sediment and higher drift macroalgae biomass. Temporal changes showed higher fish abundance, richness, and diversity in summer-autumn during cycle 1, while during cycle 2, the higher values were in winter-autumn, mainly associated with seasonal variations in water temperature and the biogeographic affinity of fish species, but were also attributed to changes in the density of species classified as dominant. There was notable a drastic decrease of fish richness, diversity, and density during summer in cycle 2, which was attributed to be a warmer year. El Soldado fish community showed changes before and after the decree as a protected area, but also in the contiguous cycles. These changes include the addition of species, the prevalence of common species over 48 years, and the current dominant species that belong to indicator groups, which exhibit effectiveness in the conservation of this ecosystem.

Greensand formation, siliceous earth deposition and coastal metal drawdown in the Danubian Cretaceous Basin (Bavaria, Germany)

The Late Cretaceous epoch was characterized by extreme greenhouse climates and widespread glaucony formation in shallow marine settings. However, in the Danubian Cretaceous Basin (DCB, Bavaria, SE-Germany), contemporaneous shallow marine deposition of glauconitic sandstones of the Regensburg Formation in the eastern and the glaucony-free Neuburg Siliceous Earth deposits of the Wellheim Formation in the western parts of the basin during Cenomanian–early Turonian times is puzzling. An integrated approach of sedimentology, stratigraphy, mineralogy and geochemistry reveals that the striking lithological and mineralogical differences can be attributed to the geological structure of the hinterland and the nature of element input: in the eastern DCB, deeply chemically weathered granites and gneisses of the Bohemian Massif were leached due to the warm climate and high precipitation rates as indicated by high values of the modified Chemical Index of Alteration (CIXrev). Elements crucial for glaucony formation (K, Fe, Si, Al) were amply supplied by rivers, fueling a shallow marine glaucony factory. Slightly reducing conditions and a temporally increased primary productivity further promoted favorable conditions for geologically fast shallow water glaucony authigenesis. In the western DCB, in contrast, a hinterland consisting of karstified Upper Jurassic carbonates devoid of essential elements for glaucony formation and a lack of significant fluvial input inhibited shallow marine glaucony formation. Furthermore, we suggest that the depositional environment of the Neuburg Siliceous Earth was affected by submarine discharge of silica-rich groundwater resulting in intense early diagenetic silicification. Additionally, our geochemical data provide the first evidence of a trace metal drawdown during Oceanic Anoxic Event 2 (approx. 94 Ma) in shallow water/coastal settings in Germany, as shown in very low V/Al, Ni/Al, Cu/Al and As/Al ratios, much lower than the average shale and upper continental crust.

The Conditions for the Formation of Strontium in the Water of Ancient Silicate Deposits Near the Arctic Coast of Russia

The Conditions for the Formation of Strontium in the Water of Ancient Silicate Deposits Near the Arctic Coast of Russia

Siliceous deposition in limestone-marl alternations of the Yangtze Carbonate platform during the Permian Chert Event

During the Permian Chert Event (PCE), limestone-marl alternations (LMAs), contemporaneously developing in the Yangtze region with chert-mudstone alternations, differed from typical LMAs by their enrichment in authigenic siliceous components (quartziferous components and Mg-phyllosilicates). However, the factors driving the transition from distal chert deposits to proximal siliceous-rich carbonate deposits remain unclear, and the genesis of authigenic siliceous components is puzzling. Resolving these issues could provide a deeper understanding of the paleoclimate and paleoenvironment during the PCE. Optical and SEM observations and geochemical analyses revealed that Si4+, derived from seawater, silica-secreting organisms, and terrigenous clasts, precipitated as authigenic quartziferous components under relatively acidic conditions, while it precipitated as Mg-phyllosilicates through reverse weathering by combining with the dissolved high-Mg calcites under relatively alkaline conditions. Through the facies division of LMAs, its variations describe relative and short-term sea-level fluctuations in the Yangtze Carbonate Platform (YCP). By integrating tendency comparisons and time series analyses of sea level fluctuations, continental weathering intensity, authigenic siliceous content, and relative proportions of quartz vs. Mg-phyllosilicates, four proxies exhibit covariation and similar astronomical signals, indicating that the high sea level period of the YCP, corresponding to intensified continental weathering, favored the deposition of authigenic siliceous components and reverse weathering. Because the facies variations encompass short eccentricity, obliquity, and precession cycles, sea level fluctuations are considered to have been influenced by Gondwana glaciation P3. The seawater in the continental shelf cooled and became rich in silica and nutrients under the effect of upwelling. Interglacial periods may trigger high sea levels and intensified continental weathering in the YCP, facilitating the influx of Si-rich eutrophic seawater and stimulating biological silica secretion by radiolarians. However, the direct precipitation of activated silica resulted in weakened reverse weathering. Consequently, the lithological transformation from distal to proximal areas during the PCE was attributed to differences in silica-secreting organism abundance, upwelling intensity, biological pump activity, reverse weathering intensity, OM abundance, pH conditions, and seawater temperature between the continental shelf and carbonate platform.

Critical Raw Materials Supply: Challenges and Potentialities to Exploit Rare Earth Elements from Siliceous Stones and Extractive Waste

Critical raw materials (CRMs) supply is a challenge that EU countries have to face, with many thinking about domestic procurement from natural ore deposits and anthropogenic deposits (landfills and extractive waste facilities). The present research focuses on the possibilities linked to the supply of CRMs and the potential for exploiting rare earth elements (REEs), investigating a large variety of extractive waste and siliceous rocks in the Piedmont region (Northern Italy). Indeed, the recovery of REEs from the extractive waste (EW) of siliceous quarries and other siliceous ore deposits can be a valuable way to reduce supply chain risks. Starting with a review of the literature on mining activities in Piedmont and continuing with the sampling and geochemical, mineralogical, petrographic, and environmental characterization of EW facilities connected to siliceous dimension stones, of kaolinitic gneiss ore deposits, and of soils present near the investigated areas, this study shows that the degree of REEs enrichment differs depending on the sampling area (soil or EW) and lithology. The concentration of REEs in the EW at some sampling sites fulfils the indicators of industrial-grade and industrial recovery; the high cumulative production and potential market values of EW and the positive recovery effects through proven methodologies indicate a viable prospect of REE recovery from EW. However, REE recovery industrialization faces challenges such as the difficulty in achieving efficient large-scale recovery due to large regional differences in REE abundance, the mismatch between potential market value and waste annual production, etc. Nonetheless, in the future, EW from dimension stone quarries could be differentially studied and reused based on the enrichment and distribution characteristics of trace elements. The present paper shows investigation procedures undertaken to determine both CRMs potentialities and environmental issues (on the basis of literature data employed to select the more-promising areas and on sampling and characterization activities in the selected areas), together with procedures to determine the waste quantities and tentative economic values of REEs present in the investigated areas. This approach, tested on a large area (Piedmont region), is replicable and applicable to other similar case studies (at EU and non-EU levels) and offers decision makers the possibility to acquire a general overview of the potential available resources in order to decide whether and where to concentrate efforts (including economic ones) in a more detailed study to evaluate the exploitable anthropogenic deposits.

Recent Trends in Tailoring External Acidity in Zeolites for Catalysis.

Zeolites are crystalline aluminosilicates with well-defined microporous structures that have found several applications in catalysis. In recent years, great effort has been devoted to defining strategies aimed at tuning structural and acidity properties to improve the catalytic performance of zeolites. Depending on the zeolitic structure, the acid sites located inside the crystals catalyze reactions by exploiting the internal channel shape-selectivity. In contrast, strong acid sites located on the external surface do not offer the possibility to control the size of molecules involved in the reactions. This aspect generally leads to a loss of selectivity toward desired products and to the uncontrolled production of coke. Passivating surface acidity is a promising way to overcome deactivation issues and to enhance the catalytic performance of zeolites. This Mini-Review aims to provide, for the first time, a complete overview of the techniques employed in recent years to neutralize strong external acid sites. Both chemical and liquid vapor deposition of silicates have been widely employed to passivate the external surface acidity of zeolites. In recent years, the epitaxial growth of layers of aluminum-free zeolite, e.g., silicalite-1, over the surface of the acidic zeolite has been proposed as a new approach to neutralize strong external acid sites controlling diffusional phenomena. NH3-TPD, FT-IR, SEM-EDX, and other techniques have been used to provide information about the level of control of the external strong acidity of passivated zeolites. In this Mini-Review, both passivation treatments and characterization techniques are compared and advantages and disadvantages deeply discussed to elucidate the effect of passivation procedures on physical features and especially the catalytic behavior.

The geomechanical response of the Gulf of Mexico Green Canyon 955 reservoir to gas hydrate dissociation: A model based on sediment properties with and without gas hydrate

Gas hydrate is commonly found concentrated in sand- and silt-rich reservoirs and these are thought to have great potential as an energy resource. To evaluate this potential, it is critical to understand their in-situ stress state and their behavior during production. We explore the geomechanical behavior of sandy silt sediments from a hydrate reservoir at Green Canyon GC 955, deep-water Gulf of Mexico without hydrate and compare these results to previous work on the same sandy silty sediments with hydrate present. Previous results from hydrate-bearing sediments at GC 955 using intact specimens show that the ratio of lateral to axial effective stress under uniaxial strain (K0) is strongly time-dependent and over long timescales approaches 1 (isostatic stress state). New results from sediments without hydrate using reconstituted specimens reveal that K0 is 0.51 and independent of time and stress. The reservoir without hydrate is approximately three times more compressible than with hydrate. In addition, we find that hydrate-free sediments have a normalized creep rate of Cα/Cc of about 0.028 at all stress levels, whereas hydrate bearing sediments exhibit a decrease in Cα/Cc with stress. We use these observations to present a new geomechanical model that describes how stress and porosity evolve during production of the hydrate reservoir. The key insight in our proposed model is that the sediment skeleton and gas hydrate phases share any applied external load in proportion to their relative stiffnesses. The model results predict that hydrate-bearing sediments are stiffer than gas hydrate-free sediments and that K0 reduces dramatically after gas hydrate dissociation, as is observed. At GC 955, a 5 MPa depressurization is needed to cause gas hydrate dissociation. This change in pore pressure increases the vertical and horizontal effective stresses from 3.8 to 8.8 MPa and 3.8–4.4 MPa, respectively. The dramatic vertical effective stress increase will cause significant compaction (7%) and perturb stresses near the wellbore. These experimental observations and the load-sharing model presented have the potential to underpin a new generation of hydrate reservoir simulation models, which may drive more effective production approaches.

Morphology, Biochemistry and Distribution of Villorita cyprinoides and Meretrix casta (Bivalve) Shells in Vembanad Estuary, Kerala, India

Estuaries are among the most commercially significant ecosystems on the earth, and they provide different habitats for numerous bivalve species. The Clams are one of the most widely distributed and used aquatic bivalves, providing much more protein-rich food than mussels and oysters. The Vembanad Estuary is one of the richest clam fisheries coastal wetland in Kerala. The present study focusing on comparatives ofmorphology and biochemistry of Villorita cyprinoides and Meretrix casta shells in Vembanad Estuary. It also attempts to understand the variations in clam distribution caused by salinity fluctuations and sediment texture. According to the morphological and morphometric analysis, medium size shells were found in greater abundance in both species. Atotal of 306 shells of V. cyprinoides and 169 shells of M. casta were obtained from the ten sample locations of Vembanad Estuary. The density of V. cyprinoides shells (192) was higher in the southern part while the northern portion of Vembanad Estuary represented by M. casta shells (108) with comparatively lower density. V. cyprinoides has a negative linear correlation with salinity, as indicated by R2 of 0.96. M. casta, on the other hand, exhibits a positive correlation with salinity, with 0.94 linear coefficient. V. cyprinoides was more prevalent in clayey and silty sediments, while M. casta was more common in sandy sediments. The X-ray Fluorescence (XRF) analysis showed that the Calcium Oxide percentage of V. cyprinoides and M. casta shells were 39.47% and 38.72%, respectively, while all other metal oxides were present only in trace amount. Keywords: Bivalves, Villorita cyprinoides, Meretrix casta, Major Oxides, Vembanad Estuary

A dilute sodium hydroxide technique for radiolarian extraction from cherts

Radiolarians have been used to determine geological ages and have contributed markedly to our understanding of Earth’s history. Hydrofluoric acid (HF) has traditionally been used to extract radiolarian fossils from siliceous deposits (i.e., radiolarian cherts), but this acid is strictly regulated because of environmental and human health concerns. Here we report on the successful extraction of radiolarians from cherts using a low-concentration NaOH solution (1 mol/L NaOH) as an alternative to HF. The degree of chert dissolution in NaOH is strongly temperature-dependent and is limited at < 80 °C. However, even a 1 mol/L NaOH solution is sufficient to dissolve chert at 100 °C. Our new NaOH method yields better-preserved radiolarian fossils compared with the conventional HF method. The 1 mol/L NaOH solution is less hazardous, easier to handle, and has fewer effects on the environment and human health than HF. Therefore, this method can be widely used for research and teaching purposes in studies of radiolarian fossils, even in institutions where HF cannot be used owing to chemical restrictions.

A distinct manganese deposit on a Middle Permian carbonate platform in South China

During the Middle Permian, Earth experienced a period of profound environmental changes, including the final stages of the Late Paleozoic Ice Age (LPIA), global seawater regression, the Guadalupian mass extinction event, and the eruption of the Emeishan Large Igneous Province (ELIP) in South China. These events collectively induced significant shifts in both the environment and biosphere, yielding several geochemical anomalies, including deposition of manganese (Mn) deposits. The link between Middle Permian Mn deposits and the prevailing environmental conditions, however, remains unclear. Here, four sections spanning the Middle Permian Maokou Formation to the Late Permian Longtan Formation in the Zunyi area of northern Guizhou, South China are investigated. Through sedimentological and geochemical analyses, this work aims to elucidate the evolution of sedimentary environments over the Middle to Late Permian. During this period, a transition from a shallow-water carbonate platform in the 1st Member of the Maokou Formation to a deeper, siliceous deposit in its 2nd Member was recorded. This shift results in a pronounced paleogeographic differentiation in the 3rd Member, juxtaposing the shallow-water carbonate platform against a deeper Mn-enriched basin. A number of geochemical proxies indicate a strong hydrothermal signal in the Mn deposits. Combined with positive Eu anomalies and low Sr isotopes, the data underscore the profound influence of hydrothermal input linked with early subaqueous eruptions from the ELIP on the nearby marine environment. A detailed examination of carbon isotope profiles from the Maokou Formation indicates that volcanic influences, shifts in marine ecosystems, and changes in primary production caused the fluctuations of δ13Ccarb and δ13Corg. Moreover, the formation of Mn carbonate in deeper waters effectively sequestered organic C. Collectively, our new data demonstrate that the essential conditions for the development of the carbonate-hosted Mn deposits include drowning of the carbonate platform through an increase in sea level, the availability of a sufficient Mn source, and the presence of a redox-stratified water column.

A speleogenetic history of Novoafonskaya Cave in the Western Caucasus

Speleogenesis in hypogene karst settings may be closely tied to regional tectonic dynamics and concomitant hydrochemical evolution of karst waters. However, placing temporal constraints on these processes can require a wider array of field observations and techniques than for typical karst systems. Herein, we present a comprehensive study of Novoafonskaya Cave (Western Caucasus, Abkhazia). The updated speleogenetic history of the cave comprises four stages: (1) the most ancient, a low-T hydrothermal (ca. 40–50°C) priming stage; (2) the main stage enabled by mixing of upwelling thermomineral and locally recharged common karst waters; (3) the late sulfuric-acid speleogenesis (SAS) stage, which left significant mineralogical overprint (gypsum and a suite of minerals resulting from the alteration of silicate sediments) but did not alter the morphology of the cave appreciably; and (4) the contemporary stage, occurring predominantly in the phreatic and epiphreatic zones. Ages of speleogenetic stages were constrained by radiometric dating (230Th-U and 40Ar/39Ar) and paleomagnetic data, alongside the Quaternary geological history of the region and paleodynamics of the Black Sea level. Conditions for the low-T hydrothermal karstification occurred from Miocene – Middle Pliocene. The main stage, which created the main volumes of the cave, took place from Late Pliocene – Middle Pleistocene. The cave emerged from the phreatic into the vadose zone after ca. 400 ka ago, due to the combined effect of the Black Sea regression and intensification of tectonic uplift in the Caucasus. The presence of sulfidic waters during dewatering led to the development of transient SAS processes during Middle to Late Pleistocene. Dating of calcite underlying SAS-associated overgrowths constrains the cessation of this SAS activity to within the last 147 ka. In its present state, the cave has no connection with thermomineral waters; however, such waters are found deeper in the southern parts of the karst massif (based on the hydrochemistry of Psyrtskha spring), implying that hypogene karstification, primarily driven by mixing corrosion, may still be active deep in the phreatic zone.

Late Mesoproterozoic iron and manganese deposition on a deep-water carbonate platform (Penganga Group), Adilabad, India: Constraints from C, O and Sr isotopes

Abstract The Penganga Group in the Pranhita-Godavari Rift Valley of central India includes a rather unique example of Late Mesoproterozoic iron and manganese formations deposited in a deep-water below storm wave base distal carbonate platform environment. The carbonate rocks of the Penganga Group are mostly lime-mudstones that have been classified into a number of sedimentary cycles with intervals mostly distinguished by color, ranging from brown/pink and siliceous gray to steel-gray and black. At least two about one-meter-thick Mn-Fe formations occur in siliceous gray limestone of the distally steepened part of the Penganga carbonate platform. A number of northwest-southeast striking thrust faults repeat the succession in down dip sections bringing up distal profiles of the Penganga Group against proximal counterparts at the present exposure level. This contribution provides the first comprehensive record of stable C and O and radiogenic Sr isotopes for proximal and distal profiles, allowing for direct comparison and thus, providing context for the environmental conditions of Fe and Mn deposition in a Mesoproterozoic platform environment. Carbon and oxygen isotope compositions determined from the proximal and distal profiles of the platform yield trends that are attributed to variations in circulation pattern and cycles of warm and cold climatic stages across the platform. Secular trends of Sr-isotope compositions suggest a variation in continental input between cold (0.7065) and warm climatic stages (0.7149), similar to that observed for modern marine sediments. The sedimentation of siliceous deposits and ferromanganese deposits in the distal platform environment was likely favored by the onset of upwelling circulation during cold climatic stages. The moderately negative δ13CPDB values (-5.34‰ to -6.34‰) of the Mn-carbonates and variation in δ13Corg values 31.7‰ to -21.7‰ obtained for early diagenetic Mn-carbonate ovoids indicate oxidation of organic matter in the ferromanganese deposits by Mn-oxides during early diagenesis. We conclude that upwelling and platform-wide deposition of ferromanganese deposits on the Penganga carbonate platform may mark the transition from the stagnant Mid-Proterozoic ‘sulphidic’ ocean to a ‘respiring’ open ocean during the Late Mesoproterozoic Era.

Trace metal and organic biosignatures in digitate stromatolites from terrestrial siliceous hot spring deposits: Implications for the exploration of martian life

Novel biosignatures of laminated, microbial, digitate sedimentary structures – stromatolites – from modern geothermal fields of the Taupō Volcanic Zone, New Zealand, and from El Tatio, Chile, provide an opportunity to investigate evidence of extremophile life preserved in siliceous hot spring deposits, or sinters, interpreted as analogs for early life on Earth and possibly Mars. Synchrotron-μXRF, electron microprobe analysis, Raman spectroscopy, and optical microscopy are used in a coordinated approach to identify corroborating textural and chemical (organic, inorganic) evidence of life in these modern, opaline (amorphous) siliceous materials. Fluid mobile elements, such as As and Sr, track the growth history of the digitate structures. Trace element enrichments of Ca, Al, Ga, +/− Fe, Mn, As, Rb, Cs, and Sr, are identified in silicified sheaths of microbial filaments embedded within the sinter. In contrast, silicified diatoms in some sinter samples show no trace element enrichment. Gallium enrichments have also been observed in other 16 ka and Jurassic (150 Ma) microbial palisade sinter textures, suggesting the potential for preservation through geologic time, even after recrystallization to quartz. Raman analysis reveals spectra of organics, consistent with pigments for UV protection in cyanobacteria, in silicified sheaths around microbial filaments and are co-located with trace metal enrichments in digitate structures. Due to spectral bands, the location of these molecules (i.e., in the sheaths), and the sampling locations, we ascribe the spectra to scytonemin and carotenoid class molecules. The combined analytical approach outlined here provides a robust means to assess the validity of novel biosignatures, with application to the exploration of Mars, where preservation of opaline silica in >3.6 Ga deposits has the potential to preserve a range of microbial biosignatures.

Enrichment mechanism of organic matter and silicon in lower Cambrian shale of the Yangtze Platform

Early Cambrian time witnessed accumulation of high-quality organic-rich siliceous shale deposits that comprise an especially promising shale gas exploration target, especially in China. The present study of the Cambrian Niutitang Formation of the shelf area of the Upper Yangtze Platform utilizes mineralogical and elemental geochemical data to aide in the paleoenvironment reconstruction of these organic-rich deposits. We are especially interested in elucidating organic carbon and silicon enrichment mechanisms of the Niutitang Formation that will benefit shale gas exploration and development of these deposits. The Niutitang Formation can be subdivided into three intervals based on lithology, gamma ray (GR) signature, and TOC abundance. Enriched TOC (average = 6.7%) and nano-size authigenic microcrystalline quartz (Qn) contents of Interval I deposits likely reflect deposition in an environment that experienced persistent euxinic and elevated organic matter delivery associated with enhanced paleoproductivity driven by hydrothermal activity. Interval II shale is interpreted to have accumulated under euxinic-ferruginous conditions that experienced the effects of robust paleoproductivity and diminished terrigenous input related to persistently warm, humid climatic conditions. Enriched TOC (average = 4.9%) and moderate microcrystalline quartz content of these deposits were likely the result of redox conditions and elevated paleoproductivity. Interval III strata appears to have accumulated under oxygenated bottom conditions that experienced moderate paleoproductivity, brackish water and elevated terrigenous detritus input driven by the establishment of cold, dry climatic conditions. The combined results of these conditions are diminished TOC content (average = 0.7%) and enrichment of the sediment in terrestrial quartz. The elevated content of authigenic quartz appears to have diminished the reservoir capacity of Niutitang Formation shale. Interval II organic-rich siliceous shale deposits of Upper Yangtze Platform shelf areas, which have the comparable authigenic microcrystalline quartz content, reservoir performance, and greater organic matter abundance as the rift trough, appear to comprise the stratigraphic horizon with the greatest exploration and development potential. Results of the present study offer theoretical guidance for future shale gas exploration and development efforts in geologically similar regions.

Условия образования рудовмещающих нижнесреднепалеозойских осадочных формаций Чаткало-Кураминских гор Узбекистана

The article describes stratiform lead-zinc and polymetallic deposits in Paleozoic sedimentary rocks of the southwestern Tien Shan of the Chatkal-Qurama Mountains using rhythmostratigraphic analysis developed by professor at Tashkent State University V. I. Popov (Popov et al., 1963; Popov, 1980). Tectonic movements play a major role in the formation of new structural elements of the lithosphere and the earth's surface. Large tectonic movements spread over large areas and become regional tectonic rhythms. Considerable phases of tectonic movements were divided into smaller phases. We observed the change in formational composition: the boundary and beginning of the rhythm series were dominated by clastic facies of mobile shallow water (surf-clastic), closer to the beltv — quiet-water or stagnant (Popov et al., 1963; Popov, 1980). We stadied the northwestern slopes of the Qurama ridge in the upper reaches of the Karakiya River. Lithological-facies sections and maps of actual materials were made in the study areas. Early Silurian sediments of the were formed in the conditions of a quiet-water (central-sedimentary) shallow-water basin, zones under the influence of bottom currents (bottom current) and deltaic (underwater deltaic) facies belt; Devonian-Lower Carboniferous sediments were accumulated in wave surf zone, bay (shallow-flood belt) and underwater delta (underwater delta belt). Three ore-bearing units with high contents of gold, copper, lead, zinc and a number of other metals were identified in the Lower Silurian terrigenous formations. Black dolomites of the stagnant zone of a shallow-water bay (shallow-bay facies) with high contents of lead were identified in the Devonian sedimentary formations. The confinement of increased concentrations of polymetals to certain layers and units of sedimentary dolomite rocks enriched in organic matter indicates that the accumulation of dispersed ore matter is syngenetic to the sedimentation process.

Co‐occurring intertidal ecosystem engineers with opposing growth strategies show opposite responses to environmental gradients during establishment

Coastal vegetated ecosystems including mangroves, seagrasses, and salt marshes are often shaped by positive plant–environment feedbacks. Plants improve their own living conditions with increasing patch size and density by attenuating hydrodynamics and stabilizing sediments. As these habitat modifications are critical for survival and growth, the positive density‐dependent nature of these feedbacks can lead to establishment thresholds for young plants in absence of mature conspecifics. Although feedback strength is known to depend on hydrodynamic exposure and plant traits (e.g. stiff versus flexible stems), it remains unclear how 1) opposing morphological plant traits affect establishment in contrasting environments, and 2) whether trait plasticity influences establishment success. Here, we investigate this by transplanting two tidal species with opposing growing strategies – Spartina anglica forms tussocks of stiff stems while Zostera noltii forms patches of stress‐avoiding flexible shoots – from two different donor sites in eight experimental locations. Results show that the survival and growth of both species was most successful at field locations with diverging environmental characteristics, while overall survival was highest for Z. noltii. Mainly, S. anglica survival was highest at locations with high organic matter and silt content and higher elevation relative to the tidal amplitude. In contrast, Z. noltii survival was highest at locations with larger grainsize and lower relative elevations. Furthermore, despite initial differences in plant traits between the two donor sites of Z. noltii, we found no effects of donor origin. Contrastingly, we found a significant effect of donor origin on S. anglica growth, even though transplants from the two donor sites showed no initial trait differences. Collectively, these results suggest that the stress‐tolerance strategy of S. anglica hampers establishment in exposed conditions, whereas the stress‐avoiding Z. noltii appears to be more susceptible to stress from desiccation and silty sediments.