Silica Fume Research Articles

Interaction of aluminum alloys with MKPC and Portland-based cements on the metal-matrix interface

Cementitious matrices are considered for the immobilisation of radioactive aluminium. The processes occurring at the interface between both materials are relevant for the long-term stability of the repository. The present study compares Ordinary Portland cement (OPC), CEM I-type, with alternative Portland blended cement (CEM IV and CEM I + 50% silica fume) and magnesium potassium phosphate cement (MKPC). Al A1050 and Al AA5754, with 3.5% Mg, have been used as reactive metal alloys. Two exposure conditions were employed: (1) water immersion and (2) isolated in sealed plastic films. Long-term corrosion monitoring (Ecorr, icorr and Vcorr) was evaluated to understand the effect of Al reactivity in the matrix. The associated H2 release was quantified to understand the changes at the metal/matrix interface. Furthermore, pore ion concentrations and the pore microstructure were evaluated. The metal/matrix interface alterations were analysed at the end of the tests. The study revealed that after 300 days of water immersion, the CEM I + 50% of silica fume matrix had reduced the pore solution pH down to 10.5 compared to CEM I, which remained high alkaline (pH 12.9), and CEM IV with no significant decreases (pH 12.3). In contrast, MKPC showed the lowest pH (7–9.8). Low Al corrosion rates were found with MKPC, followed by CEM I + 50% SF according to their lower pH. A corrosion product layer of 90-50 μm thickness was observed at the Al/CEM I matrix interface constituted of aluminium and oxygen. Furthermore, enrichment in Al was detected in the matrix (around 1 mm depth), causing the formation of ettringite nodules. Voids were detected at the interface level associated with the high volume of H2 released. The MKPC matrix showed no alteration at the metal/matrix interface due to the lower reactivity of the matrix and lower H2 release. A homogeneous and dense region (30 μm) rich in phosphorous, potassium and magnesium was observed near the metal surface.

Eco-efficient ultra-high-performance concrete formulation utilizing electric arc furnace slag and recycled glass powder–advanced analytics and lifecycle perspectives

Ultra-high-performance concrete (UHPC) is a promising material for sustainable and resource-efficient construction, but its high Portland Cement content poses environmental challenges. This research proposes an optimized UHPC blend that significantly reduces the Portland Cement dosage by incorporating industrial waste materials [i.e., Recycled Glass Powder (RGP) and Electric Arc Furnace Slag (EAFS)]. The integration of these waste materials in UHPC formulation addresses critical waste management issues and aligns with sustainable construction practices. Utilizing a tri-variable Design of Experiments methodology in conjunction with the Andreasen & Andersen theory, the research aims to reduce Portland Cement in UHPC without compromising its compressive strength and rheological behavior. The optimized blend incorporates RGP and EAFS, achieving the threshold compressive strength established by ACI-239 (150 MPa) while maintaining a self-compacting performance in the fresh state. This mixture features low cement (621 kg/m³) and silica fume (100 kg/m³) content. Life cycle assessments (LCA) were conducted to examine the environmental efficiency of the optimized blend. A comparative LCA demonstrates that the optimized UHPC mixture developed in this study surpasses a control mixture with higher cement and silica fume contents while maintaining comparable mechanical and rheological properties. Notably, this improvement is highlighted by a nearly 20% reduction in CO2 equivalent emissions. The scientific significance of this study lies in its demonstration of a viable pathway to producing UHPC with reduced environmental impact, contributing to the advancement of sustainable building practices, and offering a practical solution to waste management issues.

Development of 3D-printed magnesium silicate hydrate cement mixes involving metakaolin as a substitute for silica source

ABSTRACT The printability of MgO-SiO2 cement pastes involving the use of microsilica (MS) and metakaolin (MK) as a SiO2 source was thoroughly investigated. Fresh properties, including rheology and early-age strength, mechanical properties and microstructures of pastes incorporating different contents of MK were presented and analyzed. Amongst samples studied, those containing 5% MK as a substitute for MS exhibited the highest static yield stress, and fastest re-flocculation and structuration rates, resulting in the best buildability. Although the inclusion of 10% MK resulted in enhanced paste strength at 7 and 28 days, increased MK content impeded paste printability due to diminished formation of hydrate phases. Use of 5% MK led to higher M-S-H generation compared to other samples at 28 days, contributing to subsequent strength development. Results demonstrated that optimisation of the MK content in MgO-SiO2 pastes can yield satisfactory mechanical strengths without compromising printability.

Influence of silica fume addition and content on the early hydration of calcium aluminate cement – The role of soluble silicon

Hydration of a commercial white calcium aluminate cement (CAC) at 23 °C was modified by silica fume (SF) addition in varying amounts. The process was followed by heat flow calorimetry, quantitative in-situ XRD analysis and Gillmore needle experiments supplemented by pore solution analysis, thermodynamic modelling, and 1H-TD-NMR measurements. Lower SF/cement ratios accelerate the hydration of CAC. Higher ratios trigger an intermediate heat flow event, which is correlated to increased setting rates. This intermediate event (IE) initiates an induction period of constant duration, which appears later with increasing SF/cement ratios. Results show the IE is caused by an initially hindered CA dissolution, in which dissolved silicon provided by SF plays a crucial role. Increasing the [Si] concentration in the pore solution leads to a further retardation of the IE and eventually prevents the entire hydration reaction if a critical amount is reached. A detailed model explaining the observed behavior is proposed.

High-temperature properties of fly ash and silica fume composite magnesium potassium phosphate cement

Magnesium potassium phosphate cement (MKPC) is extensively employed in patching materials and fireproof coatings owing to its outstanding properties. This study employs a blend of fly ash and silica fume to substitute a portion of the cementitious materials, aiming to enhance the performance of MKPC under high-temperature conditions. The relative proportions of fly ash and silica fume were considered. MKPC was subjected to cubic compression and three-point flexural tests. Additionally, the phase and microstructure of MKPC were also characterized using XRD and SEM. The compressive strength, flexural strength, visual appearance, and mass loss of MKPC specimens were evaluated before and after exposure to various high temperatures. Following exposure to elevated temperatures, MKPC specimens without fly ash and silica fume doping showed a significant decrease in strength. Conversely, specimens doped with 15 % or 10 % silica fume exhibited the most remarkable strength enhancement. The dehydration of K-struvite at elevated temperatures was the primary reason for the mass loss and strength reduction of MKPC. Silica fume and fly ash can facilitate the sintering of phases and amorphous particles derived from K-struvite decomposition, leading to the formation of ceramic-like structures. Notably, the contribution of silica fume to the sintering effect exceeds that of fly ash. Therefore, blending fly ash and silica fume proves to be an effective approach to enhancing the high-temperature resistance of MKPC.

Compressive strength and gel structure improvement in the high-volume calcium carbide residue activated-blast furnace slag system combined with sodium carbonate and silica fume

Calcium carbide residue (CCR) with high alkalinity favorably corresponds to the alkaline activator in the alkali-activated materials (AAMs) production. Its utilization could reduce the carbon footprint and facilitate cast-in-situ applications compared to traditional liquid alkaline activators. A high-volumed CCR from 10 % to 25 % as alkaline activators in an alkali activated-blast furnace slag system was investigated, in which sodium carbonate (Na2CO3) and silica fume were used to improve the mechanical properties of CCR-activated blast furnace slag (CCR activated-BFS) pastes. Isothermal Calorimetry, X-ray diffraction (XRD), 29Si nuclear magnetic resonance (NMR), and scanning electron microscopy (SEM) were used to characterize the reaction process, phase transformation, and gel structure. The results show that the highest compressive strength of CCR activated-BFS pastes was obtained when the CCR proportion was 20 %. Na2CO3 addition significantly improved the compressive strength, especially at the CCR to Na2CO3 mass ratio at 1:1.5. However, the compressive strength deterioration appeared at 28 d because of the gel structure decomposition in CCR activated-BFS pastes. The silica fume addition inhibited the structure decomposition, improved the connectivity of gel structure, favored the formation of gel, and thus suppressed the compressive strength deterioration. The study established a sustainable waste recycling from acetylene gas production by using CCR as feedstock to mitigate carbon emissions from AAMs production.

Strength Prediction in UHPC with XGBoost Model and Shapley Algorithm Interpretation

This study employs the XGBoost regression model to predict the strength of UHPC and utilizes the Shapley algorithm to interpret the model's predictions, revealing the impact of various feature parameters. The results demonstrate that the XGBoost regression model effectively fits the data and possesses strong predictive capabilities. Furthermore, the interaction between silica fume and cement significantly influences the model predictions. Additionally, using tools such as the Shapley heatmap, the study analyzes the model's characteristics and finds that only a subset of samples have Shapley values below the mean, indicating the dataset contains relatively few high-quality samples. Through the Shapley algorithm, the optimal range for silica fume quantity is determined to be between 0 and 320 kg. This research validates the effectiveness of the XGBoost regression model for predicting UHPC strength and enhances model interpretability using the Shapley algorithm.

Elucidating the role of recycled concrete powder in low-carbon ultra-high performance concrete (UHPC): Multi-performance evaluation

Reusing recycled powder as an alternative binder for ultra-high performance concrete (UHPC) offers a highly value-added approach to recycling concrete waste. This study shows the multi-performance evaluation of low-carbon UHPC containing recycled powder as a substitution of cement and silica fume. Recycled powder, which includes recycled concrete powder (RCP) and recycled paste powder (RPP), contains massive SiO2, CaCO3 and hydration products. Substituting recycled powder for cement reduces the cumulative hydration heat per gram binder, while increasing the cumulative hydration heat per gram cement of UHPC. Replacing high-volume cement and silica fume with recycled powder negatively impacts the micro-characteristics, increasing the drying shrinkage and transport properties. When using recycled powder as cement replacement, incorporating a moderate dosage of recycled powder has negligible impact and can even confer some beneficial effects on the mechanical strength. Substituting recycled powder for high-volume cement reduces the mechanical strength, yet the blended UHPC retains good mechanical strength. The compressive strength of UHPC containing RCP as 0 %, 30 %, 50 % and 70 % of cement is 157.6 MPa, 154.6 MPa, 145.0 MPa and 129.9 MPa, respectively. Due to its good dilution and active effects, the replacement of cement with recycled powder causes a significant increase in compressive strength per unit cement, and the mix of 70 % RCP increases the compressive strength per unit cement by 174.7 %. Besides, incorporating recycled powder as silica fume replacement causes a limited reduction in the mechanical strength of blended UHPC. The RCP-UHPC generally has better micro-macro properties than the RPP-UHPC. By optimizing recycled powder type and replacement rate, UHPC with excellent micro-macro performance can be achieved.

AI-driven design for the compressive strength of ultra-high performance geopolymer concrete (UHPGC): From explainable ensemble models to the graphical user interface

Ultra-high performance geopolymer concrete (UHPGC) has become of interest in recent years as a more economical and sustainable alternative while offering similar mechanical performance to ordinary ultra-high performance concrete (UHPC). The lack of an effective mix design methodology has inhibited the widespread use of UHPGC, despite its potential. This paper adopted an artificial intelligence (AI)-based approach to accurately model the compressive strength (CS) of UHPGC, a critical parameter to ensure structural integrity and reliability. Ensemble machine learning (ML) models such as RF, XGBoost, LightGBM and AdaBoost, which have been very popular lately, were selected as AI algorithms. For the establishment of these models, a comprehensive and reliable dataset of 181 test results was used, including 13 input features. Additionally, feature importance and Shapley additive explanations (SHAP) analyses were used to ensure the explainability of the prediction models and tackle the "black box" challenge of ML models. The results obtained revealed that all ensemble models successfully predicted the CS of UHPGC; in particular, the XGBoost model consistently exhibited the best overall performance in terms of higher R2 (0.948) and lower RMSE (6.68), MAE (4.73), MAPE (4 %), and mean error value (1.095), in the test phase. Moreover, feature importance and SHAP analyses revealed that the most influential features on the CS of UHPGC were age, fiber and silica fume, sodium silicate (Na2SiO3), and water content. Lastly, a graphical user interface (GUI) was developed to easily predict the CS of UHPGC in practical applications.

Unleash the potential of mechanically activated Iron ore tailings in cement mortar containing silica fume and fly ash

This paper presents the effects of mechanically activated Iron Ore Tailings (IOT) in cement mortar containing silica fume, fly ash, and Ordinary Portland Cement (OPC). Five different mixes (i.e. M1- M5) were prepared which include control mix (M1), replacement of cement with IOT (M2), replacement of cement with IOT and silica fume (M3), replacement of cement with IOT and fly ash (M4), and replacement of cement with IOT, fly ash and silica fume (M5). Results reveal that utilization of mechanically activated IOT with 30% replacement of cement, 20% replacement of fly ash, and 10% replacement of silica fume performs well in flowability and compressive strength of cement mortar.

Experimental investigations on mechanical performance, synergy assessment, and microstructure of pozzolanic and non‐pozzolanic hybrid steel fiber reinforced concrete

AbstractThis paper investigates the effects of pozzolanic substitutions for ordinary Portland cement (OPC) with silica fume (SF) and metakaolin (MK) on the mechanical and toughness performances of steel fiber reinforced concrete (SFRC). Initially, a reference concrete mix with a water‐to‐binder ratio of 0.4 is blended with different volume fractions of steel fibers with varying geometry: crimped steel (CS) and straight steel (SS), both individually and in combination, to examine their mechanical properties. In the subsequent phase, the study investigates the impact of combining macro‐ and microsteel fibers on flexural toughness, to determine potential synergy for suitable combinations. Also, the possible influence of pozzolans in the variation of flexural toughness of hybrid steel fiber reinforced concrete (Hy‐SFRC) was evaluated. Hybridization of steel fibers was found effective in improving the workability of the concrete mix up to 11%. SFRC mixes containing pozzolans exhibited a significant enhancement in compressive strength, modulus of rupture, and modulus of elasticity compared to non‐pozzolanic SFRC. The hybrid combination of CS 1.5% and SS 0.5% was considered the best in terms of mechanical properties. Additionally, the results of synergy assessment showed that hybridization of steel fibers in the pozzolanic concrete mix was particularly effective in the post‐cracking stages with a positive 14% compared to a negative 8% in the pre‐cracking stage. The pozzolanic addition improved the flexural toughness of Hy‐SFRC to about 10%–20%. Blending of SF and MK in Hy‐SFRC was found effective in enhancing the toughness mechanism of concrete compared to Hy‐SFRC mixes containing binary SF and MK, indicating a stronger bond between the fibers and the matrix resulting from the pore refinement and hydration products developed at the interface. Hy‐SFRC containing a ternary pozzolanic mix of SF 10% and MK 10% gave the best results in flexural toughness, and the corresponding synergy values were found to be the maximum. The results were consistent with the morphology analysis, which revealed an increase in hydration products at the interface between the aggregate and concrete matrix, as well as between the steel fiber and concrete matrix, due to the ternary blending of SF and MK.

Synergizing metakaolin and waste-glass for sustainable and functional UHPCC– a central composite design and ecological footprint assessment

Optimizing ultra-high-performance cementitious composites (UHPCC) with sustainable materials often compromises certain properties due to the chemical nature of alternative binders used to replace standard UHPCC components like Portland cement (OPC) and microsilica (MS). In the context of Waste-Glass-UHPCC, the reduction in early strength, attributed to the varied pozzolanic reactivity of MS and recycled glass powder as cementitious materials, may reduce its application that requires high early strength. This study addresses the early strength deficiency of Waste-Glass-UHPCC by incorporating metakaolin (MK) and also aims to assess the impact of MK on 28-day compressive strength, durability, and carbon footprint. Research investigating the effects of MK on UHPCC with reduced OPC and MS content is currently limited. Specifically, this investigation explores the influence of MK on UHPCC characterized by a cement content of 620 kg/m3. By utilizing advanced statistical methods [i.e., the Central Composite Design (CCD) and Response Surface Methodology (RSM)], this study investigates the substitution of MK for OPC in formulations of Waste-Glass-UHPCC. The experimental design comprises 18 encoded mixtures, allowing for the development of second-order regression models for critical responses [slump flow and compressive strength at different ages]. Besides, visualization through RSM-3D graphs facilitates a comprehensive examination of the effects of various factors. For a deeper analysis, two of the CCD's points, i.e., SP-12 (Waste-Glass-UHPCC without metakaolin), and SP-10 (Waste-Glass-UHPCC with 65.77 kg of metakaolin per cubic meter) were further investigated along with a control dosage that represents a typical UHPCC formulation. The responses studied encompassed 1, 7, and 28 d compressive strength, chloride ion penetration, and carbon footprint measured by a systematic life cycle analysis (following ISO 15804), assessing the environmental impact of the UHPCC's making materials from raw extraction to disposal. Despite encountering challenges in meeting self-compacting concrete criteria due to MK's tendency to accelerate hydration, the enhanced early strength properties (61 % higher than those of the Waste-Glass-UHPCC) make the MK-based mixture appropriate for various applications such as bridge engineering or pavement rehabilitation. Additionally, the addition of MK in UHPCC formulation demonstrated superior resistance to chloride ion permeability even compared to the control mixture, attributed to MK's ability to enhance the concrete's microstructure and capture chloride ions, attributed to Friedel's salt formation. Noteworthy findings include a significant (27 %) reduction in carbon footprint with the incorporation of MK in Waste-Glass-UHPCC compared to the control counterparts. The current study highlights the durability and environmental advantages of MK-based UHPCC blends while emphasizing the critical requirements of workability and strength development of sustainable UHPCC.

Experimenting the effectiveness of waste materials in improving the compressive strength of plastic-based mortar

The reduction in compressive strength (CS) of cementitious composites incorporating waste plastic is the main concern limiting its applicability in the building sector. Using industrial wastes as cement substitutes to enhance the CS of plastic mortar is a sustainable approach. This study used fine powdered waste materials such as silica fume (SF), marble powder (MP), and glass powder (GP) in plastic-based mortar for their effectiveness in enhancing CS. Plastic mortar specimens were cast using plastic waste in 5–25 % contents as sand replacement by mass, and their 28-day CS was recorded as a reference. SF, GP, and MP were utilized in plastic mortar mixtures separately in proportions of 5–25 %, with a 5 % increment, substituting cement by mass. These waste powders were also used in combinations of two (SF+GP, SF+MP, and GP+MP) and three (SF+GP+MP) in plastic mortar mixtures. Moreover, prediction models were built using the experimental database for the CS of plastic mortar. Gradient boosting and bagging ensemble machine learning (ML) techniques were chosen for model development. The decrease in CS was limited by substituting SF, GP, and MP for cement in plastic mortar. It was determined that the most effective substitution levels for SF, GP, and MP in plastic mortar, according to the strength enhancement, were 15, 10, and 15 wt.% of cement, respectively. The ML models closely matched experimental results, and in terms of R2 and error evaluations, bagging model outputs were more accurate than gradient boosting. The gradient boosting and bagging models had R2 of 0.89 and 0.94, respectively, with average absolute errors of 0.87 and 0.65 MPa.

Mineralogical and geochemical composition of a cementitious grout and its evolution during interaction with water

In the present study, the chemical composition, mineralogy, and mechanisms of alteration of a cementitious grout based on a CEM III/C with addition of smectite, hydrotalcite, and silica fume, are studied using a combination of chemical and physical methods. This material was designed in the context of geological repository of radioactive wastes, with a twofold aim: first, to fill the technical voids left by drilling operations at the interface between the geological formation and the disposal galleries. Second, to neutralize a potential acidic transient due to pyrite oxidation, and to create an environment that favors low corrosion rates of carbon steels. The grout is mainly composed of calcium silicate hydrates having a Ca/Si ratio of ~0.8, incorporating Al in the bridging site of the Si chains (C-A-S-H), and accounting for 29–36 wt.% of the sample. It also contains silica fume (38–48 wt.%), smectite with interlayer Na (11–17 wt.%), hydrotalcite with interlayer CO32− (3–4 wt.%), and lower amounts of portlandite, calcite, and possibly gibbsite and gypsum. Upon alteration by water in a flow-through reactor, the main modifications affecting the sample are calcite and gypsum dissolution, hence releasing aqueous Ca2+ that is adsorbed in smectite interlayer by replacing Na+, and stoichiometric C-A-S-H dissolution. The evolution of solution chemistry and of the solid phase composition are reproduced successfully using a thermokinetic model.

Utilization of marble waste as fine aggregate in the composition of high performance concrete containing mineral additions

This study investigates the effect of adding marble waste as fine aggregate on the properties of high-performance concrete. To achieve this objective, 10%, 20%, 30%, and 40% of marble waste fine aggregate were substituted for ordinary fine aggregate in the composition of high-performance concrete mixtures containing silica fume and ground blast furnace slag. The fresh properties were studied using slump, fresh density and air content tests, while the hardened properties were assessed using compressive and flexural strengths, ultrasonic pulse velocity, water absorption, and chemical acid attack tests. The results obtained revealed that the addition of marble waste fine aggregate significantly improved the properties of high-performance concrete and increased its resistance to chemical acid attacks. The composition-based ground blast furnace slag containing 40% marble waste fine aggregate outperformed all other compositions, increasing compressive strength by 30.98%.

Examining the Workability, Mechanical, and Thermal Characteristics of Eco-Friendly, Structural Self-Compacting Lightweight Concrete Enhanced with Fly Ash and Silica Fume.

This study compares the workability, mechanical, and thermal characteristics of structural self-compacting lightweight concrete (SCLWC) formulations using pumice aggregate (PA), expanded perlite aggregate (EPA), fly ash (FA), and silica fume (SF). FA and SF were used as partial substitutes for cement at a 10% ratio in various mixes, impacting different aspects: According to the obtained results, FA enhanced the workability but SF reduced it, while SF improved the compressive and splitting tensile strengths more than FA. EPA, used as a fine aggregate alongside PA, decreased the workability, compressive strength, and splitting tensile strength compared to the control mix (K0). The thermal properties were altered by FA and SF similarly, while EPA notably reduced the thermal conductivity coefficients. The thermal conductivity coefficients (TCCs) of the K0-K4 SCLWC mixtures ranged from 0.275 to 0.364 W/mK. K0 had a TCC of 0.364 W/mK. With 10% FA, K1 achieved 0.305 W/mK; K2 with 10% SF reached 0.325 W/mK. K3 and K4, using EPA instead of PA, showed significantly lower TCC values: 0.275 W/mK and 0.289 W/mK, respectively. FA and SF improved the thermal conductivity compared to K0, while EPA further reduced the TCC values in K3 and K4 compared to K1 and K2. The compressive strength (CS) values of the K0-K4 SCLWC mixtures at 7 and 28 days reveal notable trends. Using 10% FA in K1 decreased the CS at both 7 days (12.16 MPa) and 28 days (22.36 MPa), attributed to FA's gradual pozzolanic activity. Conversely, K2 with SF showed increased CS at 7 days (17.88 MPa) and 28 days (29.89 MPa) due to SF's rapid pozzolanic activity. Incorporating EPA into K3 and K4 reduced the CS values compared to PA, indicating EPA's lower strength contribution due to its porous structure.

Synergistic influences of ground granulated blast-furnace slag and silica fume on the viscosity of extremely low W/B cement pastes

Particularly with a low water/binder ratio, the synergistic effects of supplemental cementitious materials (SCMs) have drawn a lot of interest in improving the characteristics of cement-based products. The effects of SCMs, such as silica fume (SF) and ground granulated blast furnace slag (GGBS) with varying fineness, on the setting time, saturation point, and viscosity of ultra-high performance cement pastes (UHPCP), are examined experimentally in this work. 56 mixes with various SF and BFS substitutions and exceptionally low water/binder ratios (0.16, 0.20) were used in the experiments. This work demonstrates the synergistic effects of SCMs from several angles, including the UHPCP fresh characteristics. It is shown that carefully regulating the water/binder ratio, the BFS fineness, and most significantly the addition of an ideal SF content will have a beneficial synergistic effect on the fresh qualities of UHPCP. However, utilizing high BFS replacement is discouraged as it may have a negative impact on viscosity.

The thermal conductivity of graphite composite insulation boards: A theoretical and experimental study

Graphite composite insulation boards (GCIB) have emerged as a promising solution in the construction industry, offering a combination of fire resistance, high temperature stability, and excellent insulation properties. As their usage continues to increase, it is crucial to develop and validate a more accurate theoretical model for the effective design and optimization of building insulation systems. Traditional models including series and parallel models are employed for estimating the thermal conductivity of GCIB but revealed higher relative errors and lower theoretical calculation accuracy. Therefore, the primary objective is to design and validate a more efficient theoretical model for thermal conductivity prediction in GCIB. This paper investigates the thermal conductivity of GCIB under varying composition ratios by designing a novel Parallel-Series Parallel (PSP) approach. The PSP model is designed based on a single basic cell where the graphite polystyrene particles are employed as the matrix material while cement, vitrified microspheres, and silica fume are used as inclusion materials. Then, the thermal conductivity unit is divided into three parallel heat conduction subunits where the matrix materials and inclusion materials in the three subunits are integrated in a series-parallel manner to provide a more realistic representation of the heat transfer mechanisms within the composite. For a comprehensive assessment, the study encompasses theoretical analysis, empirical assessment, and finite element (FE) simulations to illustrate its thermal properties. The predicted thermal conductivity reveals perfect consensus in comparison with the FE and experimental test outcomes by achieving lower relative errors of 2.7 %∼3.8 % and 1.9 %∼ 3.0 % respectively. The model validated through numerical simulations and sample experiments illustrates a significant improvement in accuracy of about 76.4 %∼94.3 % when compared to traditional series and parallel methods. Prominently, the findings indicate that the thermal conductivity of GCIBs declines considerably as the volumetric ratio of graphite polystyrene particles (Ф1/Ф3) increases and stabilizes when the proportion reaches 10, emphasizing the importance of optimizing material composition to enhance the thermal performance of GCIB. Overall, the validated PSP model by accurately determining the thermal conductivity of GCIB serves as a reliable tool for designing and optimizing high-performance insulation materials, contributing to energy efficiency and sustainability in building and construction industries.

Experimental Study on Properties of Graphene and Hollow Glass Powder-Added Ultra-High Strength Concrete

A new ultra-high strength concrete, in which oxidized graphene nanoplatelet (GO) and hollow glass powder (HGP) are added, has been developed by authors. This paper presents the material properties of the concrete such as workability, compressive and tensile strengths, internal micro structure (SEM and MIP) as well as air-tightness which was tested using an equipment developed in this study. Test results show that workability and tensile strength significantly increase by a small addition of HGP, and that cGO (GO product of company c) and HGP are well dispersed without agglomeration effect, resulting in more than 20% of reduction in porosity. It is also observed that air-tightness increases by 40% compared with conventional ultra-high strength concrete due to reduction in porosity; thus, new ultra-high strength concrete is anticipated to be effectively used for structures that requires air-tightness such as hyperloop tube. Consequently, it was observed that the workability and mechanical properties of UHSC were increased when cGO and HGP were used instead of silica fume (SF), and authors believe that utilization of new material would contribute to the change in manufacturing method and increase in mechanical properties of concrete.

Influence of manufactured sand, recycled aggregate, reinforcement ratio and wire mesh on the response of reinforced concrete slabs under impact loading

Targeting towards the sustainable goal, the emergence of manufacturing sand (M-sand) and recycled coarse aggregate (RCA) as an alternate for natural aggregates has unfolded new prospects for constructional practices in the world. Therefore, the investigation is focused to study the influence of RCA, M-Sand, Combination of RCA and M-sand, wire mesh and steel reinforcement under impact loading. The reinforced concrete slabs (1 layer @ 25 mm c/c) slabs [S1-S4, S9, S11, S13 and S15] was studied using M-sand (100 %) and recycled coarse aggregate (25 %) with a concrete compressive strength of 40–50 MPa. Also, the flexural reinforcement was varied as 0.23, 0.32 and 0.39 % of the cross-section area. The experimental results were presented in terms of failure pattern, impact force-reaction force, midpoint displacement and energy absorption capacity. It was observed that the spalling of concrete to the conventional slab (S1) whereas, the spalling of concrete as well as formation of radial cracks were observed on slab with RCA (S2). It was also observed that the severe spalling with formation of radial cracks in the slab with M-sand and RCA (S4), however the impactor did not perforate. The peak impact force on control slab, S1, S2, S3 and S4 was 145, 187, 122 and 167 kN, respectively. The significant increase in peak impact force in S2 is due to the use of micro silica fume treatment which enhanced the mechanical properties of RCA. The peak impact force in slab S3 by M-sand found reduced by 15 %, whereas the same was found increased by 15 % in case of slab S4 by RCA and M-sand, as compared to S1. The maximum crack width in slab S15 was limited to 1–2 mm whereas same was found to be 9–10 mm in case of slab S13. The use of wire mesh found to enhance the global bending deformations as well as crack width in the slab. It is concluded that the utilization of wire mesh along with steel reinforcement proves to be an effective method to diminish the permanent deformation. Further, finite element software ABAQUS was used to model the slab under impact loading and the results were compared with the experimental results. The predicted peak impact force of slab S1 was found to be good agreement with the experimental results. However, the predicted peak impact force on slab S2-S4 found to have maximum deviation 11 % as compared to experimental results.