Silica Filler Research Articles

Hydrophobic nanosilica-stabilized graphite particles for improving thermal conductivity of paraffin wax-based phase-change materials

Phase change materials based on paraffin wax are characterized with low thermal conductivity, which could be improved by the addition of particles of a heat-conducting material, for example, graphite. However, graphite particles agglomerate in molten paraffin wax matrix and settle. In this study, the use of hydrophobic nano-sized silicon dioxide as a stabilizer was considered to obtain stable dispersions of graphite in paraffin wax. Rheological and thermophysical properties of paraffin-based mixtures containing from 1 to 5 vol. % of hydrophobic silica and from 1 to 15 vol. % of graphite were investigated. At the concentration of 3 vol. %, silica nanoparticles form a percolation structure, which is expressed in the emergence of the yield stress that is capable to prevent the sedimentation of graphite particles introduced into the mixture. It allows obtaining dispersions that are stable both in time and at passage of cooling–heating cycles. The joint influence of silica and graphite fillers on the ability of paraffin wax to accumulate and conduct heat was investigated. Thermal conductivity of dispersions at the introduction of graphite increases according to the Maxwell's model, which allows improving the thermal conductivity on 33 % from initial value at the introduction of 15 vol. % of graphite.

Use of Metal Oxide–Silica Fillers NiО‒SiO2 and СuO‒SiO2 as Active Modifiers of Polyurethane Composites

Use of Metal Oxide–Silica Fillers NiО‒SiO2 and СuO‒SiO2 as Active Modifiers of Polyurethane Composites

N-ethyl carbazole-1-allylidene-based push-pull dyes as efficient light harvesting photoinitiators for sunlight induced polymerization

In this article, the free radical polymerization of acrylates was successfully achieved with a series of twelve push-pull chromophores comprising the N-ethyl carbazole-1-allylidene group as the electron-donating group. Using this strong donor, the resulting dyes, never synthesized before, could efficiently initiate the free radical photopolymerization of acrylates upon mild irradiation conditions e.g. using sunlight. These novel multi-component systems comprising the above mentioned push-pull dyes, a tertiary amine (ethyl dimethylaminobenzoate EDB) and an iodonium salt could act as efficient photoinitiating systems (PISs) in free radical polymerization (FRP), leading to the formation of 3D patterns with precise shapes under the direct laser write (DLW) approach. Among these new PISs, dyes 3, 6, 7 and 8 were selected due to their efficient photoinitiation performances for chemical mechanism studies including steady state photolysis, fluorescence quenching measurements, electron spin resonance (ESR) spin-trapping experiments and cyclic voltammetry. Markedly, their excellent photochemical reactivities prompted us to investigate the performance of these multi-component photoinitiating systems upon sunlight as an ecofriendly approach. As a result, this research proved that sunlight could be used as a potential light source that can advantageously replace LEDs when highly reactive push-pull dyes are used as photosensitizers for the free radical photopolymerization of acrylate resins. Finally, 3D patterns could be prepared with the new photocomposites, and silica fillers could be even incorporated within the photosensitive resins so that a gradient of resolution could be successfully demonstrated.

Photopolymerization shrinkage-stress reduction in polymer-based dental restoratives by surface modification of fillers

ObjectivesThis research explores the use of polymer brushes for surface treatment of fillers used in polymer-based dental restoratives with focus on shrinkage stress reduction. The influence of interfacial reactive groups on shrinkage stress is explored. MethodsOligomers of varying lengths and with varying number of reactive groups along the length were synthesized by modifying commercial oligomers. Surface of silica fillers (OX50) was treated with methylaminopropyltrimethoxysilane and this was further reacted with the synthesized oligomers to obtain a series of polymer brushes on the surface. Fillers modified with γ-methacryloxypropyltrimethoxysilane were used as a control. Filler surface treatment was confirmed using diffuse reflectance spectroscopy and thermogravimetric analysis. Fillers were added at 30 wt % to a resin made of BisGMA/TEGDMA and polymerization kinetics, shrinkage stress, volumetric shrinkage, flexural strength and modulus, viscosity were measured. ResultsComposites with polymer brush functionalized fillers showed up to a 30 % reduction in shrinkage stress as compared to the control, with no reduction in flexural strength and modulus. Shrinkage stress reduced with increasing length of the polymer brush and increased with increase in number of reactive groups along the length of the polymer brush. SignificanceThe interface between inorganic fillers and an organic polymer matrix has been utilized to reduce shrinkage stress in a composite with no compromise in mechanical properties. This study gives insights into the stress development mechanism at the interface.

Composite solid polymer electrolyte with silica filler for structural supercapacitor applications

Structural supercapacitors are energy storage devices that can function as structural materials. We synthesized composite solid polymer electrolytes (CSPEs) from 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIm][OTF]), poly (ethylene glycol) monomethyl ether acrylate (PEGA) and functionalized silica filler. Two types of fumed silica were used: one had an unmodified surface, and the other an organically modified surface. The CSPEs were prepared by adding ionic liquids (IL) to the PEGA and the ratios between PEGA and IL were 7: 3 and 5: 5, respectively. The functionalized silica was synthesized by the sol-gel method under acidic conditions using methacryloxypropyl trimethoxysilane (MAPTMS), whereas the effects of silica filler on the electrochemical and thermal properties of CSPEs were investigated using electrochemical impedance spectroscopy, cyclic voltammetry, and differential scanning calorimetry. The ionic conductivity of CSPEs based on PEGA/[OTF]_SiO2 at various concentrations of [EMIm][OTF] was 5.7×10−4 and 4.8×10−4S/cm, and their specific capacitance was 10.0 and 9.5 F/g, respectively. With the addition of silica filler, the ionic conductivity and specific capacitance of the synthesized CSPEs were lower than those of the neat CSPEs.

MODIFICATION OF MIXTURES BASED ON ETHYLENEPROPYLENE RUBBER AND SILICON ACID FILLER

The aim of the work was to study the effect of bis-(triethoxysilylpropyl)-tetrasulfide (TESPT) mixed with carbon black N330 in a ratio of 1:1, as a technical product OFS 6945 on the structure and properties of rubber mixtures and rubbers based on ethylene propylene rubber of the brand Vistalon 2504N and silica filler (KKN) of the brand Rosil-175, taken at a dosage of 30 wt. h. per 100 wt.h. rubber. The content of TESPT was 0.035, 0.050 and 0.070 mmol / 100 g of rubber. A group of vulcanizing agents included sulphur, thiuram, captax, zinc oxide and technical stearin. Rubber mixtures were prepared on rollers Lb 320 160/160. Organosilane was injected into rubber at the same time as Rosil-175. The homogeneity of the filler distribution in the finished mixtures was evaluated based on the results of testing samples on the RPA-2000 vibrorheometer. Vulcanization characteristics were determined using an MDR-2000 device. The structure of mixtures and rubbers was studied by the method of equal swelling of samples in toluene. It is shown that with the increasing content of TESPT, the proportion of bound rubber in a three-component mixture of the rubber – filler – organosilane increases due to the formation of interfacial connections. The uniformity of distribution of silica fillers in rubber matrix also increases. Workability of the mixtures on roller equipment improves. The rate of cross-linking in the core period and the degree of cross-linking of macromolecules at the same time curing increase as well. As a result, the elastic-strength properties of rubbers determined in the static test mode are improved, the best complex of which is provided with an organosilane content of 0.050 mmol/100 g of rubber.

Effect of Molecular Weight of Methylphenylsiloxy-Containing Vinyl-Functionalized Terpolysiloxanes on Their UV-Activated Crosslinking by Hydrosilylation and Mechanical Properties of Crosslinked Elastomers.

Effects of molecular weight of methylphenyl-containing vinylsiloxy-functionalized terpolysiloxanes on their UV-activated crosslinking by hydrosilylation at room temperature in air, shelf life stability of "all-in-one" pastes prepared from them for additive manufacturing, and mechanical properties of the resulting crosslinked elastomers, are investigated. It is found that while rheology of pastes containing base polymers, trimethylsilylated silica fillers, and thixotropic additives is not significantly affected by the base polymer molecular weight but is dominated by the filler concentration, the pastes based on higher molecular weight polymers exhibit faster crosslinking (corresponding to higher catalyst turnover numbers) and their crosslinked elastomers show transient strain-induced crystallization. The latter appears in networks from terpolymers with degrees of polymerization (DP) of 240 and above (corresponding to about one half of the critical polydimethylsiloxane chain length for entanglement formation of DP=460), within the temperature range of -80 to -30°C, characteristic for polydimethylsiloxane melting transition. It is believed that this is the first time an observation of this chain length effect is reported for polysiloxane elastomers and that the properties reported herein can be expected to have major implications on the application potential of these polymers in both additive manufacturing and performance of their elastomers at sub-ambient temperatures.

Using fillers to tune material properties of an ion-containing semi-crystalline poly(ethylene glycol) for fused filament fabrication additive manufacturing

Abstract The materials library for Fused Filament Fabrication (FFF) additive manufacturing processes has been primarily dominated by amorphous thermoplastic materials. Semi-crystalline polymers form tough plastics due to their strong intermolecular forces, which makes them well suited for applications requiring wear and chemical resistance, thermal stability, and structural loading. However, they are infrequently used in FFF because of large shrinkage that occurs due to recrystallization during cooling, which causes printed layers to warp. The authors have previously evaluated a semi-crystalline polymer series (sulfonated poly(ethylene glycol) (SPEG)) for FFF printability. The influence of divalent counter-ions in the SPEG series altered the material properties and crystallization to enable processing via FFF. The SPEG containing a calcium counterion resulted in the print quality due to the higher viscosity (105 Pa∙s) allowing the material to hold shape in the melt and high-nucleation and small spherulite size mitigating the layer warping. However, the dialysis used for the ion exchange in the polymer synthesis procedure proved challenging for mass manufacturing scale-up. To circumvent this limitation, the authors explore the incorporation of ionically charged filler materials in the SPEG with a sodium counter-ion, poly(PEG8k-co-NaSIP), to achieve the desired properties for FFF processing. Both ionic (calcium chloride and calcium carbonate) and non-ionic (silica and starch) filler particles were added to poly(PEG8k-co-NaSIP) and the resulting material properties and effect on FFF printability were measured. The calcium chloride filler changed the viscosity, crystallinity, spherulite growth, and spherulite size which improved the processing via FFF without requiring an ion exchange. This technique may be applicable to other ionic polymers in order to alter their material properties to enable FFF printing.

Investigations on Mechanical Properties of Carbon and Glass Fiber Composites with Titanium Oxide and Silicon Dioxide Filler

The utilization of carbon and glass fiber composites is very extensive in the fields of aviation and automobiles. The strength to weight fraction of these composites is immense. Even though, the modern applications require a lot of improvement in strength. The addition of Nano fillers had brought about significant changes in mechanical properties of the composites. The present work aims at finding out the effects on mechanical properties of composites due to the addition of titanium oxide 10% + silicon dioxide 10% hybrid filler. Hand layup process is used for the fabrication of tensile and flexural test specimens which are prepared as per the ASTM standards. The tensile test specimen is D-638 type-iv and the flexural specimen is D-790. Epoxy is used as resin and forms the matrix whereas the carbon and glass fibers act as reinforcement. The comparison is made between the specimens with and without hybrid filler. Two specimens of each type are prepared to have repeatability. The tensile and flexural tests are carried on universal testing machine (UTE-10) and results were obtained. The results showed a significant improvement in tensile and flexural strengths of carbon composites and only flexural strength in glass fibers with hybrid filler.

Amphiphilic, thixotropic additives for extrusion-based 3D printing of silica-reinforced silicone.

The ability to utilize extrusion-based, direct ink write (DIW) 3D printing to create silica-reinforced silicones with complex structures could expand their utility in industrial and biomedical applications. Sylgard 184, a common Pt-cure silicone, lacks the thixotropic behavior necessary for effective printing and its hydrophobicity renders cured structures susceptible to biofouling. Herein, we evaluated the efficacy of various PEO-silane amphiphiles (PEO-SAs) as thixotropic and surface modifying additives in Sylgard 184. Eight amphiphilic PEO-SAs of varying architecture (e.g. linear, star, and graft), crosslinkability, and PEO content were evaluated. Modified formulations were also prepared with additional amounts of silica filler, both hexamethyldisilazane (HMDS)-treated and dimethyldichlorosilane (DiMeDi)-treated types. Numerous PEO-SA modified silicone formulations demonstrated effective water-driven surface hydrophilicity that was generally diminished with the addition of HMDS-treated silica filler. While increased yield stress was observed for PEO-SA modified silicones with added HMDS-treated filler, none achieved the initial target for 3D printing (>1000 Pa). Only the formulations containing the DiMeDi-treated filler (17.3 wt%) were able to surpass this value. These formulations were then tested for their thixotropic properties and all surpassed the targets for recovered storage modulus (G') (>1000 Pa) and loss factor (<0.8). In particular, the triblock linear PEO-SA produced exceptionally high recovered G', low loss factor, and substantial water-driven restructuring to form a hydrophilic surface. Combined, these results demonstrate the potential of silicones modified with PEO-SA surface-modifying additives (SMAs) for extrusion-based, DIW 3D printing applications.

Silica-nanoresin crosslinked composite polymer electrolyte for ambient-temperature all-solid-state lithium batteries

A novel poly(vinyl ethylene carbonate) based composite polymer electrolyte using a cellulose membrane as a separator, adding a NR acting as both a silica filler and ETPTA crosslinker, and eventually constructing a crosslinked structure with a high modulus.

Loading Silica for Supporting Carbon Black Filler to Prevent Degradation Natural Rubber Caused DME

DME (Dimethyl Ether) is the future environmental friendly fuel. Some parts of equipment for transporting the DME are using rubber as a hoses or seals. This research is about the using of natural rubber for those applications. The influential part in the manufacture of natural rubber products are fillers. The use of filler depends on what the product will be made. DME nature have high permeability and easy to absorb into a rubber and plastic. In such of that, the rubber or plastic could be damaged and not durable. In order to determine the type of degradation, the number of samples were immersed in liquid DME. The ratio of the loading of carbon black/silica filler in natural rubber was varied. DME causes two types of degradation, namely absorption and extraction. The addition of filler composition can reduce the absorption and extraction, which can cause a reduction in the percentage decrease in the value of the change in mass and a decrease in tensile strength. On the other hand, the addition of filler composition will increase the changes of hardness. The higher filler loading, will increase the crosslink density and lower scorch time. The presence of silica further is to enhance the crosslink density as well as to lower scorch time. Therefore, the presence of silica affect on the decreasing of the swelling level and shrinking. In general, the presence of silica filler in the mixture will be slightly lowering the tensile strength, but not affecting the elongation at break. The presence of silica before and after soaking with DME will increase hardness.

Filler Type and Particle Distribution Effect on Compact Properties of Polymer Composites

This study reports the effects of silica (S), quartz (Q), and basalt (B) fillers on the chemical, thermal, and mechanical properties of unsaturated polyester (PE) composites. In the study, fillers were selected as same class grain distribution and mixed with orthophtalic based PE resin to produce composites. The thermal characterization of the composites was determined with thermogravimetric and thermal conductivity. Chemical characterization was carried out with FT-IR. Compressive strength was investigated with Universal Testing Machine. SEM device was used to investigate the morphological alterations of the composites. Also, statistical analysis was carried out for thermal conductivity and mechanical results. At the end of the present study, some minor chemical alterations were seen in FT-IR after the interaction of the fillers and PE resin. Thermal stability decreased after adding fillers. The thermal conductivity and thermogravimetric analysis were not agreed with each other that higher thermal conductivity was seen in the PE-Q composites. The compressive strength of filler-based composites was higher than that of the neat PE composite whereas the higher compressive strength was obtained in the PE-Q. This study confirms the applicability of various fillers as a reinforcing agent in the polymer.

Optimization of the Electrochemical Performance of a Composite Polymer Electrolyte Based on PVA-K2CO3-SiO2 Composite.

Composite polymer electrolyte (CPE) based on polyvinyl alcohol (PVA) polymer, potassium carbonate (K2CO3) salt, and silica (SiO2) filler was investigated and optimized in this study for improved ionic conductivity and potential window for use in electrochemical devices. Various quantities of SiO2 in wt.% were incorporated into PVA-K2CO3 complex to prepare the CPEs. To study the effect of SiO2 on PVA-K2CO3 composites, the developed electrolytes were characterized for their chemical structure (FTIR), morphology (FESEM), thermal stabilities (TGA), glass transition temperature (differential scanning calorimetry (DSC)), ionic conductivity using electrochemical impedance spectroscopy (EIS), and potential window using linear sweep voltammetry (LSV). Physicochemical characterization results based on thermal and structural analysis indicated that the addition of SiO2 enhanced the amorphous region of the PVA-K2CO3 composites which enhanced the dissociation of the K2CO3 salt into K+ and CO32− and thus resulting in an increase of the ionic conduction of the electrolyte. An optimum ionic conductivity of 3.25 × 10−4 and 7.86 × 10−3 mScm−1 at ambient temperature and at 373.15 K, respectively, at a potential window of 3.35 V was observed at a composition of 15 wt.% SiO2. From FESEM micrographs, the white granules and aggregate seen on the surface of the samples confirm that SiO2 particles have been successfully dispersed into the PVA-K2CO3 matrix. The observed ionic conductivity increased linearly with increase in temperature confirming the electrolyte as temperature-dependent. Based on the observed performance, it can be concluded that the CPEs based on PVA-K2CO3-SiO2 composites could serve as promising candidate for portable and flexible next generation energy storage devices.

Evaluating The Effects of Micro and Nano Size of Silica Filler on Asphalt Cement Properties

This research study examines the practicability of using micro and nano size silica to improve the asphalt characteristics. Asphalt cement penetration grade of (60 /70) was prepared using (0%, 2%, 4% and 6%) of silica filler by weight of asphalt and investigated in terms of the softening point, penetration, and penetration index, viscosity, and ductility values. To modify the asphalt binder, the silica powder was mixed by a mechanical blender set at (2000) rpm at a mixing temperature of 140°C. However, the main challenge is an agglomeration of nano-silica powder which can reduce the ductility of nano silica modified binder. Therefore, this paper studies the efficiency of mixing period to obtain a homogeneous composite binder while alleviating the agglomeration issue. To do so, the effect of periods of mixing ranged between (30 to 60) minutes were examined on characteristics of modified asphalt binders. Overall, the addition of silica filler has an encouraging impact on the asphalt binder rheological properties. Also, the ductility value decreases with the addition of nano-silica content, attributed to the huge surface area and degree of agglomeration. Furthermore, results exhibited that 6% of micro silica powder and 4 % of nano silica powder were reasonable to develop the rheological properties.

The Investigation of the Silica-Reinforced Rubber Polymers with the Methoxy Type Silane Coupling Agents.

The methoxy-type silane coupling agents were synthesized via the modification of the hydrolyzable group and characterized to investigate the change in properties of silica/rubber composites based on the different silane coupling agent structures and the masterbatch fabrication methods. The prepared methoxy-type silane coupling agents exhibited higher reactivity towards hydrolysis compared to the conventional ethoxy-type one which led to the superior silanization to the silica filler surface modified for the reinforcement of styrene-butadiene rubber. The silica/rubber composites based on these methoxy-type silane coupling agents had the characteristics of more developed vulcanization and mechanical properties when fabricated as masterbatch products for tread materials of automobile tire surfaces. In particular, the dimethoxy-type silane coupling agent showed more enhanced rubber composite properties than the trimethoxy-type one, and the environmentally friendly wet masterbatch fabrication process was successfully optimized. The reactivity of the synthesized silane coupling agents toward hydrolysis was investigated by FITR spectroscopic analysis, and the mechanical properties of the prepared silica-reinforced rubber polymers were characterized using a moving die rheometer and a universal testing machine.

Thermal, morphological and mechanical properties of composites based on polyamide 6 with cellulose, silica and their hybrids from rice husk

The use of cellulosic fibers from different natural sources as fillers in polymer matrices to improve their properties has been extensively studied in the last years. It is mainly due to the vast availability of natural fibers as well as their biodegradability. The purpose of this present work was to extract cellulose, silica, and cellulose-silica fillers – these last called “hybrids” – from rice husk through delignification and subsequent oxidation and, then, prepare composites with polyamide 6 and improve mainly its thermal-mechanical properties. The content of 10 wt.% of fillers was inserted in PA 6 matrix. Infrared spectroscopy pointed the main characteristic peaks of cellulose and silica of hybrids, as thermogravimetric analysis showed high thermal stability of fillers, allowing their incorporation in PA-6 matrix by extrusion method. Thermo dynamic-mechanical analysis showed, in a general overview, a significant improvement of mechanical properties of composites, as elastic modulus, compared with neat polyamide-6, mainly the one with 2.5 wt% of silica and 7.5% of cellulose. This last also showed increasing of degree of crystallinity, measured by differential scanning calorimetry, showing the extraction efficiency of fillers from rice husk as well as the potential application of composites as structural components in automotive parts.

Molecular Insights into Adhesion at a Buried Silica-Filled Silicone/Polyethylene Terephthalate Interface.

Silicone adhesives are widely used in many important applications in aviation, automotive, construction, and electronics industries. The mixture of (3-glycidoxypropyl)trimethoxysilane (γ-GPS) and hydroxy-terminated dimethyl methylvinyl co-siloxanol (DMMVS) has been widely used as an adhesion promoter in silicone elastomers to enhance the adhesion between silicone and other materials including polymers. The interfacial molecular structures of silicone elastomers and the adhesion promotion mechanisms of a γ-GPS-DMMVS mixture in silicone without a filler or an adhesion catalyst (AC) have been extensively investigated using sum frequency generation (SFG) vibrational spectroscopy previously. In this research, SFG was applied to study interfacial structures of silicone elastomeric adhesives in the presence of a silica filler and/or a zirconium(IV) acetylacetonate adhesion catalyst at the silicone/polyethylene terephthalate (PET) interface in situ nondestructively to understand their individual and synergy effects. The interfacial structures obtained from the SFG study were correlated to the adhesion behavior to PET. The interfacial reactions of methoxy and epoxy groups of the adhesion promoter were found to play significant roles in enhancing the interfacial adhesion of the buried interface. This research provides an in-depth molecular-level understanding on the effects of a filler and an adhesion catalyst on the interfacial behavior of the adhesion promotion system for silicone elastomers as well as the related impact on adhesion.

The presence of stearamide as a rubber chemical in silica loaded-styrene butadiene rubber: The curing properties

This research-study investigated the influences of stearamide on the curing properties of silica-loaded styrene-butadiene rubber (SBR). The SBR was loaded with silica at a fixed loading (thirty phr) and the stearamide was added into the silica-loaded SBR compounds with varied doses from two to eight phr. The influences of stearamide additions on the scorch time, optimum curing time and cure rate index (CRI) of silica-loaded SBR were investigated. It was observed that the stearamide caused an enhancement in the rate of the curing process on the SBR compounds. The stearamide decreased both the times to scorch and optimum curing times but increased the CRI. The bigger the stearamide doses caused in the lower were the scorch time, curing time and CRI. The decreases in CRI was attributed to the role of a reactant that interacted chemically inside the silica-loaded SBR compounds. The amine content of stearamide presumably triggered the chemical reaction between the SBR, silica filler and amine itself.

MOC Cement-Based Composites with Silica Filler and Wood Chips Ash Admixture

As Portland cement and cement-based materials are the most widespread materials in construction industry, there is a concern to develop and search cement alternative materials with similar or better functional properties and a lower negative environmental impact. Magnesium oxychloride cement (MOC) is considered as low-energy and low-carbon binder possessing some advantageous properties superior to Portland cement. Therefore, lightweight MOC-based composites were designed and tested in the presented study. As filler, silica sand was used in composition of control composite mix. Later, it was partially replaced with wood chips ash coming from bioenergy production from biomass. The chemical composition and morphology of wood chips ash were characterized using X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Energy Dispersive Spectroscopy (EDS) analyses. For the hardened composites, bulk density, specific density, and total open porosity were measured. Among mechanical parameters, flexural and mechanical strengths were tested. The thermal performance of composites was studied using a transient hot disk method and the assessed parameters were thermal conductivity and volumetric heat capacity. The use of fly ash led to the great decrease in porosity compared to the control materials with silica sand as only filler. The mechanical strength of all developed materials was high. Both the compressive strength and flexural strength decreased the dosage of wood chips ash in composite mix. However, the decrease in mechanical resistance was lower than the send replacement ratio. It clearly proved assumption of filler function of fly ash, whereas its assumed reactivity with MOC cement components was not proven. The heat transport was partially mitigated by wood chips use, similarly as heat storage. Based on the obtained data, the developed composites were considered as alternative low-carbon materials possessing interesting functional properties for construction practice. Moreover, the reuse of by-product from biomass bioenergy treatment can be considered as an environmentally friendly solution for production of sustainable advanced building materials.