Silica Fiber Research Articles

Chalcogenide Ge20Sb5Se75 photonic crystal fiber with seven air-hole rings for ultraflat mid-infrared supercontinuum generation

Supercontinuum (SC) generation in solid-core circular photonic crystal fibers (PCFs) made of Ge20Sb5Se75 is numerically analyzed. A large core is projected to increase light coupling efficiency into selected PCFs as well as raise coupling to standard silica fibers. High nonlinear coefficient and near-zero flat dispersion allow ultraflat SC spanning 1.5–4.6 μm in an all-normal dispersion regime. This requires 3 kW of peak power with 180 fs of pulse duration. The fiber with one zero-dispersion wavelength (ZDW) generates SC bandwidth in the range of 1.54–7.39 μm at 3.5 μm using peak power of 10 kW. For the same input power, the SC spectral covers from 1.39 to 7.36 μm in 10 cm of fiber with two ZDWs. These are wider SC bandwidths than those of previous chalcogenide fibers reached with lower peak powers. Therefore, the proposed Ge20Sb5Se75 PCFs are excellent candidates for the broadband ultraflat mid-infrared SC spectra used in high-speed nonlinear imaging and frequency measurement.

Novel three-dimensional live skin-like in vitro composite for bioluminescence reporter gene assay.

We genetically manipulated HaCaTcells, a spontaneously immortalised normal keratinocyte cell line, to stably express two different coloured luciferase reporter genes, driven by interleukin 8 (IL-8) and ubiquitin-C (UBC) promoters, respectively. Subsequently, we generated a three-dimensional (3D) skin-like in vitro composite (SLIC) utilising these cells, with the objective of monitoring bioluminescence emitted from the SLIC. This SLIC was generated on non-woven silica fibre membranes in differentiation medium. Immunohistochemical analyses of skin differentiation markers in the SLIC revealed the expression of keratins 2 and 10, filaggrin, and involucrin, indicating mature skin characteristics. This engineered SLIC was employed for real-time bioluminescence monitoring, allowing the assessment of time- and dose-dependent responses to UV stress, as well as to hydrophilic and hydrophobic chemical loads. Notably, evaluation of responses to hydrophobic substances has been challenging with conventional 2D cell culture methods, suggesting the need for a new approach, which this technology could address. Our observations suggest that engineered SLIC with constitutively expressing reporters driven by selected promoters which are tailored to specific objectives, significantly facilitates assays exploring the physiological functions of skin cells based on genetic response mechanisms. It also highlights new avenues for evaluating the physiological impacts of various compounds designed for topical application to human skin.

High pressure sensor based on intensity-variation using polymer optical fiber

Silica fiber under high pressure increases the risk of fiber breakage or permanent deformation, which may cause sensor failure due to mechanical strength limitations. High pressure can also induce birefringence in optical fiber. In this study, we present a simple design and low-cost high pressure sensor using polymer optical fiber (POF) based on the intensity-variation technique. A side-coupling mechanism in the sensor structure is adopted, which varies the intensity with applied pressure. Two POFs are twisted together to create a sensing region where the light is launched in the first fiber and measurement is taken from the second fiber. In sensing phenomena, cladding mode frustrated total internal reflection occurs when pressure increases. Silicone gel is used in the pressure chamber for sealing and preventing leakage. The sensor structure is able to detect high pressure in the MPa range, where we tested up to 4 MPa. For higher sensitivity, twisted and bend structure is analyzed, and sensitivity is achieved at about 432.21 nW/MPa. However, twisted helical structure is adopted to enhance sensing range which is about 50 cm. The proposed high-pressure sensor structure is easier to fabricate and has high stability because it doesn’t require any destructive method as compared to other conventional methods.

Nanoparticle doping and molten-core methods towards highly thulium-doped silica fibers for 0.79 μm-pumped 2 μm fiber lasers – A fluorescence lifetime study

We study the fluorescence lifetime of Thulium-doped silica fibers for efficient laser operation in the 2 μm “eye-safe” wavelength range pumped by 0.79 μm radiation. A large set of optical fibers prepared by Modified Chemical Vapor Deposition combined with solution doping or nanoparticle doping, and Molten-core method is investigated in terms of fluorescence lifetimes of the 3F4 and 3H4 excited levels, which contain information about the Tm3+ ion environment, the rate of unwanted processes, such as concentration quenching or multiphonon relaxation, as well as the inter-ionic energy-transfer processes, including the cross-relaxation. Maximum evaluated lifetime values are 778 μs for the 3F4 level and 56 μs for the 3H4 level. From the lifetime study, we conclude that for Tm3+ concentrations above 10,000 ppm and enhanced aluminum concentrations above 5 mol. % Al2O3, the cross-relaxation efficiency is enhanced and multiphonon relaxation is remarkably reduced due to the lower phonon energy of the resulting alumino-silicate glass.

Gamma irradiation-induced enhancement of Pb-related near-infrared luminescence in PbS/Al co-doped silica fiber

The impact of Al co-doping and gamma irradiation (0.3-3 kGy) on the spectral properties of lead-related active centers (PACs) in PbS/Al co-doped silica fiber (PADF) has been studied. Distinct absorption peaks at 700 and 1030 nm, and photoluminescence at 1100 nm, originated from Al-related lead active center (PAC-Al). The luminescence intensity of PACs at 900 and 1150 nm increased with irradiation doses in PADF with 0.01 at% Al co-doping. Notably, after irradiation with a 0.5 kGy dose, over a 16 dB enhancement of luminescence from PAC-Al was observed in PADF doped with 0.1 at% Al under 980 nm pumping. The on-off gain of the PADF at 1100 nm increased ∼12 dB after irradiation with a dose of 0.3 kGy. It was found that PAC-Al was preferentially generated over PAC at 1150 nm in Al co-doped fibers under irradiation. The proposed underlying mechanism for photoluminescence enhancement is the irradiation-induced reduction of Pb ions and Al-related defects. PbS/Al co-doped silica fiber is a promising candidate for active fibers operating at ∼1100 nm.

Application of advances in the development and production of optical fiber in the development and design of fiber optic devices.

The dimensions of devices based on optical fiber are limited by the sensitivity of the optical fiber to macrobending, which leads to an increase in optical losses at small bending radii. New types of fibers with low macrobending losses make it possible to significantly tighten the dimensions. However, there may be a risk of fiber failure at bending points during the life of the product due to mechanical fatigue. In the article, based on the use of a static fatigue model of silica glass, a simple expression is obtained to estimate the probability of fiber failure under long-term bending stress depending on the length of the bent section, bend radius and humidity, taking into account the result of a proof-test carried out by the fiber manufacturer. The possibility of increasing the mechanical reliability of silica fiber by applying a hermetical carbon coating is discussed. The use of the obtained expressions in design makes it possible to reduce the dimensions of fiber optic products without the risk of reducing their reliability.

Optical cooling of a Yb-doped alumino-phosphosilicate fiber in air by -250 mK.

Recent progress in the fabrication of Yb-doped silicate fibers with low concentration quenching and low background absorption loss has led to the demonstration of anti-Stokes-fluorescence cooling in several aluminosilicate compositions. This breakthrough is critical to combat deleterious thermal effects due to the quantum defect in fiber lasers and amplifiers. Since cooling efficiencies remain low (1-2.7%), it is paramount to engineer compositions that improve this metric. We report a silica fiber with a core glass heavily doped with aluminum and phosphorus that sets, to our knowledge, a few new records. This few-mode fiber (16-µm core) was cooled in air by -0.25 K from room temperature with ∼0.5 W of 1040-nm power. The measured cooling efficiency is 3.3% at low pump power and 2.8% at the power that produced maximum cooling. The critical quenching concentration inferred from the measured dependence of cooling on pump power and careful calibration of the pump absorption and saturation is 79 wt.%. The inferred background absorption loss is 15 dB/km. Together with the fiber's average Yb concentration of 4.2 wt.%, these metrics rank among the best reported in a silica glass.

Enhanced hydrophilicity and stability of carbon-based aerogel with assembling of halloysite nanotubes and silica fibers for efficient solar seawater evaporation and desalination

Solar vapor generation has emerged as a sustainable technique for seawater evaporation and desalination. Integrating high hydrophilicity, strong light absorbance, good salt resistance, fast water transfer and good structural stability simultaneously in one evaporator at low cost for achieving cost-effective evaporation and long-term utilization is highly desirable but still challenging. Herein, an eco-friendly and low-cost aerogel (CSH) with natural chitosan, halloysite nanotubes and silica fibers was prepared by freeze-casting, which was then carbonized to construct a robust aerogel (cCSH) as evaporator. The cellular structure of cCSH aerogel with microchannels enables fast water transfer and rapid salt dissolution, the carbonized chitosan favors enhanced light absorption, the halloysite assembled on the walls endows the aerogel with excellent hydrophilicity, and the silica fibers penetrating the multilayer guarantee good structural stability. As expected, the prepared evaporator (cCSH200) exhibits remarkable evaporation rates of 2.49/7.20 kg·m−2·h−1 under one/four sun, respectively, exceeding most biomacromolecule-derived aerogels. Besides, it displays outstanding salt resistance, wastewater purification ability and long-term cycle stability. Outdoor test further substantiates the admirable evaporation performance, long-term durability and enormous application prospect of the cCSH200. This work affords a low-cost tactic for the development of efficient evaporator for solar-driven seawater desalination and wastewater treatment.

Impact of Yb2+ on the anti-Stokes fluorescence cooling performance of Yb-doped silica fibers

To unlock the full potential of laser-cooled silica optical fibers, a better understanding of the internal mechanisms of heat generation is required. This work explores ytterbium-doped aluminosilicate fibers produced via industry-standard modified chemical vapor deposition (MCVD) techniques with varied levels of divalent ytterbium to determine their effect on anti-Stokes fluorescence thermal performance. The inclusion of Yb2+ is shown to have a significant negative impact on cooling potential. Yb2+ ions are shown to correlate with heat generation by two distinct mechanisms, absorption and quenching of active Yb3+ ions. This excess heating represents a reduction in quantum efficiency that is detrimental to Yb-doped fiber lasers and amplifiers beyond the laser-cooling application.

Polyphenylene oxide based lossy mode resonance fiber sensor for the detection of volatile organic and inorganic compounds

This study presents the fabrication and characterization of a fiber optic gas sensor based on Lossy Mode Resonances (LMR). For the first time to our knowledge, a nanosized coating of polyphenylene oxide (PPO) is deposited on a cladding removed multimode silica fiber, serving both as the LMR supporting coating and sensitive overlay. The device exhibits a notable sensitivity of 2500 nm/RIU when immersed in glycerol-water based solutions. For gas detection, the PPO-based LMR device is exposed to varying concentrations of different volatile organic and inorganic compounds, including two alcohols (methanol and ethanol) and ammonia. The sensor demonstrates similar responses to methanol and ethanol gases with a sensitivity of about 0.56 nm/ppm and sensitivity of 0.25 nm/ppm to ammonia in the concentration range of 2.5–37.5 ppm, achieving limits of detection of a few ppm. To comprehensively evaluate the sensor performance, the investigation is also focused on the repeatability, reversibility, response times, as well as cross sensitivity to temperature and relative humidity.

High-efficiency, single-frequency, polarized thulium-doped silica fiber lasers.

We report on single-frequency, linearly polarized, high-concentration thulium-doped silica fiber-distributed Bragg reflector lasers operating at wavelengths between 1908 and 2050 nm with high efficiencies up to 48% and high powers up to 1 W. Low relative power noise and frequency noise are demonstrated using a low-noise pump diode.

Enhanced radiation resistance of Er3+/Yb3+ co-doped high-phosphorus silica glasses and fibers via phase-interface engineering

Enhanced radiation resistance of Er3+/Yb3+ co-doped high-phosphorus silica glasses and fibers via phase-interface engineering

Visible silica fiber laser based on Dy:BaF2 nanoparticle doping

A silica fiber laser based on Dy3+-doped nanoparticles (NPs) and operating at a wavelength of ∼581.5 nm is reported. Specifically, Dy-doped BaF2 nanoparticles were synthesized, and suspension doped into an aluminosilicate preform fabricated using conventional MCVD methods. Though the precursor BaF2 reacts partially with the SiO2 host, a presumed barium rich environment and localized doping persists. Spectroscopic characterization included visible emission spectrum, fluorescence decay, and loss of spectrum measurements and, where applicable, comparisons are made to previously reported Dy3+-doped silica visible fiber lasers. To the best of the author’s knowledge, this is the first report on a dysprosium NP-doped silica fiber and visible fiber laser made using this approach. This work paves the way for the development of visible silica fiber lasers with engineered local environments surrounding the rare earth ions.

Short-length nanosecond pulsed 1.653-μm DBR fiber Raman laser oscillator fabricated by femtosecond laser direct-writing

We demonstrate a nanosecond pulsed 1.653-μm fiber Raman laser (FRL) oscillator in a short-length distributed Bragg reflector (DBR) cavity made by femtosecond laser direct-writing technique. The DBR FRL cavity is composed of commercial ultrahigh NA germanium-doped silica fiber with a short length of 10 m and a pair of fiber Bragg gratings (FBGs). The FBGs were directly inscribed on the ends of the Raman gain fiber, using femtosecond-laser point-by-point (PbP) writing method. A home-made 1.55-μm nanosecond fiber laser source was used as the pump of the FRL. 1.653-μm nanosecond pulsed laser oscillation with maximum average output power of 125 mW (corresponding to peak power of 6.6 W), 3 dB linewidth of ≤ 0.15 nm, and slope efficiency of 48 % was obtained under 1.55-μm pump with optimized repetition rate of 10 MHz. The optical signal-to-noise-ratio (OSNR) of the 1.653-μm narrow-linewidth Raman lasing is above 70 dB. The short-length DBR FRL output exhibits decently high degree of polarization (DOP) and high degree of linear polarization (DOLP) above 80 % in 3-hour period, benefitted from the birefringent FBGs made by femtosecond laser direct-writing method. It is expected that by further reducing the cavity length to < 1 m, the 1.653-μm DBR FRL oscillator made by femtosecond laser direct-writing method is promising as single-frequency narrow-linewidth, highly linearly polarized, high-OSNR laser sources for high-sensitivity CH4 gas detection.

Recent Advancements and Challenges in High‐Power Thulium‐Doped Laser

AbstractHigh‐power all‐fiber thulium lasers have gained considerable interest in recent times due to their distinct characteristics and versatile applications in the medical and industrial sectors. This review article presents a comprehensive examination of the advancements and challenges in this field. It begins with an overview of thulium‐doped silica fiber, which is a critical component for high‐power lasers operating at the 2 µm (micrometer) wavelength band. The research progress of essential high‐power thulium laser sources, including continuous‐wave (CW), quasi‐continuous wave (QCW), and pulsed lasers, is then thoroughly analyzed, highlighting their respective strengths and limitations. Additionally, the diverse applications of high‐power thulium fiber lasers in medical and industrial domains are summarized. Furthermore, the article emphasizes the current challenges in the advancement of high‐power thulium‐doped fiber lasers (TDFLs) and outlines potential avenues for future development. Despite TDFLs being the predominant laser source in lithotripsy and material processing applications, optimizing their performance and expediting further progress in thulium laser technology remain crucial objectives. This review article aims to provide valuable insights for researchers, engineers, and professionals working in the field of high‐power fiber lasers operating at 2 µm.

Graphene-Perovskite Fibre Photodetectors.

The integration of optoelectronic devices, such as transistors and photodetectors (PDs), into wearables and textiles is of great interest for applications such as healthcare and physiological monitoring. These require flexible/wearable systems adaptable to body motions, thus materials conformable to non-planar surfaces, and able to maintain performance under mechanical distortions. Here, fibre PDs are prepared by combining rolled graphene layers and photoactive perovskites. Conductive fibres (~500 Ωcm-1) are made by rolling single-layer graphene (SLG) around silica fibres, followed by deposition of a dielectric layer (Al2O3 and parylene C), another rolled SLG as a channel, and perovskite as photoactive component. The resulting gate-tunable PD has a response time~9ms, with an external responsivity~22kAW-1 at 488nm for a 1V bias. The external responsivity is two orders of magnitude higher, and the response time one order of magnitude faster, than state-of-the-art wearable fibre-based PDs. Under bending at 4mm radius, up to~80% photocurrent is maintained. Washability tests show~72% of initial photocurrent after 30 cycles, promising for wearableapplications.

Distributed strain sensing using Bi-metallic coated fiber optic sensors embedded in stainless steel

Silica fiber optic sensors are resistant to corrosive environments and high temperatures, making them attractive candidates for harsh conditions found in nuclear and aerospace industries. Moreover, fibers can be deployed remotely for continuous measuring of spatially distributed temperatures and strains. This study investigated embedding a Ni/Cu bi-metallic coated fiber in a stainless-steel 316 (SS316) matrix using laser powder bed fusion towards functionalizing metal components for site-specific health monitoring. The embedded fiber was continuously interrogated during controlled heating to 1000°C. The measured fiber strains were similar to the expected differential thermal strains between the fiber and the SS316 matrix, until divergent behavior was observed at temperatures >500°C. No debonding at the matrix–coating–fiber interfaces was observed during microscopy, but significant interactions between the coatings and matrix resulted in diffusion-driven chemistry variations and Kirkendall void formation. Applying the strain-lag theory revealed plastic behavior in the Ni coating at temperatures >500°C, limiting the strain transfer to the fiber at higher temperatures. It was estimated that the elastic modulus in the Ni coating had decreased from ∼200 GPa at room temperature to below 40 GPa, starting at 600°C. The low elastic modulus above 600°C is within the margin of what the tangent modulus would be in the case of bilinear isotropic hardening. Regardless of the divergent strain transfer at higher temperatures, the fiber was exposed to the equivalent of 1.9 % engineering strain at 1000°C, but measured only a 0.7 % engineering strain due to the poor strain transfer. Although compensating for the plastic behavior of Ni proved challenging, the bonding of a brittle silica fiber to a metal matrix surviving to 1000°C invites potential iterations on coating material for future application. For example, the embedded fiber is sufficient for acoustic energy transfer, realizing high temperature distributed acoustic sensing.

Generation of second harmonic at wide conversion band in GRIN multimode fibers

Optical poling of multimode graded-index fibers (GRIN) has emerged as a promising technique for creating periodic inscriptions of the second-order nonlinear optical susceptibility χ(2), enabling the generation of a second harmonic in silica fibers. In this work, we investigate the generation of multiple spectral peaks using a continuous broadband source in the infrared domain, generated in the same fiber by a femtosecond laser with a central wavelength different from the one used for the poling process. Building upon theoretical foundations, this work contributes at explaining how second and third-order nonlinear processes participate to the broad generation of the second harmonic in GRIN fibers.

Crystal field effects of Al doping on the Stark splitting and gain bandwidth of erbium doped silica fibers

In this study, erbium-doped silica fibers (EDFs) with different Al/Er ratios were prepared by high-temperature source combined with the modified chemical vapor deposition (MCVD) method. The effects of different Al/Er ratios on the gain performance of erbium-doped silica fiber amplifiers (EDFA) were investigated. The EDFA demonstrated in this paper achieves a maximum gain of 45 dB at 1560 nm when the signal power is −20 dB, while the bandwidth of 20 dB gain is up to 68 nm (1532∼1600 nm). Additionally, the effect of Al doping on the crystal field around the Er ion was analyzed and the Stark energy level distribution of the Er ions was further derived. Our approach offers a feasible solution for C + L band amplification from the perspective of Stark effect and crystal field analysis.

Generation of sub-150 fs, 10 W-class, pedestal-free 2.07 µm ultrashort pulses using a cascade compression system.

We report high-power pedestal-free ultrashort pulses in a cascade compression system. In the self-compression stage, the 2 µm ultrashort pulses with 123 fs duration and up to 21.7 W output power were obtained in a 0.3 m 50 µm core diameter fiber. It is the highest self-compressing power ever obtained in a silica fiber with an all-fiber 2 µm laser amplifier as the pump source. To obtain purer pedestal-eliminated pulses, we further increase the fiber length to 1 m to trigger the soliton self-frequency shifting (SSFS) effect. By employing an enhanced SSFS technique based on third-order dispersion (TOD) and filtering out the unshifted signal light, we finally achieved sub-150 fs, 10 W-class, 1.2-MW peak-power, pedestal-free 2.07 µm ultrashort pulses. This is also the highest, to the best of our knowledge, power and energy of Raman soliton obtained by SSFS in an ordinary silica fiber.