Siderophile Element Abundances Research Articles

Platinum-rhenium-osmium isotope systematics of chromitite and native osmium from the Guli Massif (Maimecha-Kotui Province, Russia)

To gain insight into the source of ore material, this study presents the first Re-Os and Pt-Os isotopic and highly siderophile element (HSE) abundance data for chromitite and osmium minerals from the Guli massif of ultramafic, alkaline rocks and carbonatites located in the Maimecha-Kotui province, Polar Siberia. The study utilized a number of analytical techniques, including electron microprobe analysis, negative thermal ionization mass spectrometry (N-TIMS) and high pressure asher digestion and an isotope dilution-inductively coupled plasma-mass spectrometry. The HSE concentrations in chromitite samples range from 191 to 866 ppb with a predominance of Ir-group platinum-group elements (PGE) (Os, Ir and Ru) over Pt-group PGE (Rh, Pt and Pd) and Re, which is consistent with their platinum-group mineral control (i. e., Os-Ir alloys and laurite, RuS2) within the chromitite. The Re-Os and Pt-Os isotope data indicate that the HSE budget of the chromitite and osmium minerals from the Guli massif was largely controlled by that of the mantle source, which evolved with long-term near-chondritic Re/Os and Pt/Os ratios; this source is within the range of those for the majority of komatiite and abyssal peridotite sources.

A 187Re-187Os and highly siderophile element study of diamondiferous kimberlite melt-mantle interactions and the inferred age of continental lithosphere

The ∼ 1.15-billion-year-old (Ga) Premier kimberlite pipe (Cullinan diamond mine), South Africa, is composed of several distinct kimberlite facies (Grey, Brown, Pale Piebald, Dark Piebald, Black Coherent [Type 3C], Blue/Brown Transitional, and Fawn). We report bulk rock Re-Os isotope data for Premier kimberlite facies, as well as for a suite of entrained peridotite and mafic xenoliths. These data are complemented by bulk rock highly siderophile element (HSE: Re, Pd, Pt, Ru, Ir, Os), major- and trace-element abundances. Measured 187Os/188Os for the kimberlite facies range from 0.1223 to 0.1672 (ΥOsi of −2.5 to + 17.4), peridotite xenoliths range from 0.1096 to 0.1244 (ΥOsi of −13.3 to −1.1), and pyroxenite xenoliths range from 0.1796 to 0.938 (ΥOsi of + 27 to + 419). A single measured amphibolite xenolith has the most radiogenic measured 187Os/188Os of 2.86 (ΥOsi of + 43). Harzburgite xenoliths yield time of rhenium depletion model ages (TRD) of ∼ 1.5 to 2.8 Ga, consistent with average TRD ages for Premier peridotites (2.4 ± 0.4 Ga). With these and published data, we considered the relationships between kimberlite and mantle xenoliths, compare estimates of relative peridotite incorporation to sampled diamond grade, and explore recratonization versus refertilization arguments with regards to TRD model ages. Kimberlite melt infiltration into Premier peridotite xenoliths is evident from melt veins accounting for ∼ 2 and ∼ 14 modal % of samples, and has led to incompatible element enrichment, including elevated Re. In turn, kimberlites show geochemical evidence for addition of peridotite xenolith fragments, with Type 3C having > 30 % more peridotite contribution than the Brown volcaniclastic facies. Kimberlites and peridotites plot on a 187Re/188Os versus 187Os/188Os mixing line (R2 = 0.92), with kimberlites having older apparent ages than the true age of crystallization. This mixing line provides estimates of lithospheric incorporation into the kimberlites, where the units with higher peridotite incorporation do not correlate with diamond grade. This is likely due to lithological and post-emplacement alteration heterogeneity within the kimberlite units, perhaps also reflecting the eclogitic paragenesis of many Premier diamonds. The peridotites provide evidence for the nature of the lithosphere beneath Premier prior to ∼ 1.15 Ga. Metasomatism of the peridotites is possibly linked to the Bushveld Igneous Event at ∼ 2 Ga, as well as to other magmatic events that affected the Kaapvaal craton from the Archean to the Mesoproterozoic. Premier peridotites do not suggest that the cratonic lithosphere beneath the region was completely replaced. Samples with Proterozoic TRD eruption model ages may represent Archean lithosphere that experienced alteration by metasomatism and modification, such as during the Bushveld Igneous Event.

A heterogeneous mantle and crustal structure formed during the early differentiation of Mars.

Highly siderophile element abundances and Os isotopes of nakhlite and chassignite meteorites demonstrate that they represent a comagmatic suite from Mars. Nakhlites experienced variable assimilation of >2-billion-year-old altered high Re/Os basaltic crust. This basaltic crust is distinct from the ancient crust represented by meteorites Allan Hills 84001 or impact-contaminated Northwest Africa 7034/7533. Nakhlites and chassignites that did not experience crustal assimilation reveal that they were extracted from a depleted lithospheric mantle distinct from the deep plume source of depleted shergottites. The comagmatic origin for nakhlites and chassignites demonstrates a layered martian interior comprising ancient enriched basaltic crust derived from trace element-rich shallow magma ocean cumulates, a variably metasomatized mantle lithosphere, and a trace element-depleted deep mantle sampled by plume magmatism.

182W and 187Os constraints on the origin of siderophile isotopic heterogeneity in the mantle

Major and trace element abundances, including highly siderophile elements, and 187Os and 182W isotopic compositions were determined for ca. 89 Ma mafic and ultramafic rocks from the islands of Gorgona (Colombia) and Curaçao (Dutch Caribbean). The volcanic systems of both islands were likely associated with a mantle plume that generated the Caribbean Large Igneous Provence. The major and lithophile trace element characteristics of the rocks examined are consistent with the results of prior studies, and indicate derivation from both a chemically highly-depleted mantle component, and an enriched, or less highly-depleted mantle component. Highly siderophile element abundances for these rocks are generally similar to rocks with comparable MgO globally, indicating that the major source components were not substantially enriched or depleted in these elements. Rhenium-Os isotopic systematics of most rocks of both islands indicate derivation from a mantle source with an initial 187Os/188Os ratio between that of the contemporaneous average depleted mid-ocean ridge mantle and bulk silicate Earth. The composition may reflect either an average lower mantle signature, or global-scale Os isotopic heterogeneity in the upper mantle. Some of the basalts, as well as two of the komatiites, are characterized by calculated initial 187Os/188Os ratios 10–15 % higher than the chondritic reference. These more radiogenic Os isotopic compositions do not correlate with major or trace element systematics, and indicate a mantle source component that was most likely produced by either sulfide metasomatism or ancient Re/Os fractionation. Tungsten-182 isotopic compositions measured for rocks from both islands are characterized by variable μ182W values ranging from modern bulk silicate Earth-like to strongly negative values. The μ182W values do not correlate with major/trace element abundances or initial 187Os/188Os compositions. As with some modern ocean island basalt systems, however, the lowest μ182W value (−53) measured, for a Gorgona olivine gabbro, corresponds with the highest 3He/4He previously measured from the suite (15.8 R/RA). Given the lack of correlation with other chemical/isotopic compositions, the mantle component characterized by negative μ182W and possibly high 3He/4He is most parsimoniously explained to have formed as a result of isotopic equilibration between the mantle and core at the core-mantle boundary.

Previously melt-depleted mantle beneath the Cascades Range arc

Mantle peridotite xenoliths from Lorena Butte, Simcoe Mountains volcanic field, Washington, USA, have been reported with radiogenic 187Os/188Os (≤0.149) and elevated oxidation states, which have been interpreted to reflect Farallon slab contributions to the mantle wedge. To examine subarc processes beneath the Cascades arc, mineral thermobarometry and bulk-rock compositions, including highly siderophile element (HSE) abundances and 187Os/188Os, were obtained for Lorena Butte harzburgite xenoliths. Harzburgites have 187Os/188Os ratios (0.1231 ± 20; 2 SD; n = 10) that only marginally overlap and are, on average, 7% less radiogenic than the previously reported xenoliths, with estimates of oxygen fugacity (ΔFMQ = +1.0 ± 0.5) within the range of both subduction-related and abyssal peridotites. Lorena Butte harzburgites experienced significant shallow-level melt depletion (>15%) prior to incorporation into the mantle wedge. After incorporation into the lithosphere, the peridotites were erupted within trachybasalt of intraplate origin. This heritage suggests that only low-Os harzburgites preserve radiogenic 187Os/188Os from subduction fluids and that previously melt-depleted mantle forms an important component of mantle wedges. Furthermore, the extent of melt depletion experienced by the peridotites is not necessarily coupled with mineral thermobarometry, which can be affected by melt infiltration and metasomatism.

Age, genetics, and crystallization sequence of the group IIIE iron meteorites

Chemical and isotopic data were obtained for ten iron meteorites classified as members of the IIIE group. Nine of the IIIE irons exhibit broadly similar bulk siderophile element characteristics. Modeling of highly siderophile element abundances suggests that they can be related to one another through simple crystal-liquid fractionation of a parent melt. Our preferred model suggests initial S, P, and C concentrations of approximately 12 wt%, 0.8 wt%, and 0.08 wt%, respectively. The modeled IIIE parent melt composition is ∼4 times more enriched in highly siderophile elements than a non-carbonaceous (NC) chondrite-like parent body, suggesting a core comprising ∼22% of the mass of the parent body. Although chemically distinct from the other IIIE irons, formation of the anomalous IIIE iron Aletai can potentially be accounted for under the conditions of this model through the non-equilibrium mixing of an evolved liquid and early formed solid. Cosmic ray exposure-corrected nucleosynthetic Mo, Ru, and W isotopic compositions of four of the bona fide IIIE irons and Aletai indicate that they originated from the non-carbonaceous (NC) isotopic domain. Tungsten-182 isotopic data for the IIIE irons and Aletai yield similar model metal-silicate segregation ages of 1.6 ± 0.8 Myr and 1.2 ± 0.8 Myr, respectively, after calcium aluminum-rich inclusion (CAI) formation. These ages are consistent with those reported for other NC-type iron meteorite parent bodies. The IIIE irons are chemically and isotopically similar to the much larger IIIAB group. Despite some textural, mineralogical, and chemical differences, such as higher C content, the new results suggest they may have originated from a different crystallization sequence on the same or closely-related parent body.

Nickel isotope ratios trace the process of sulfide-silicate liquid immiscibility during magmatic differentiation

Sulfide-silicate liquid immiscibility (i.e., the coexistence of two liquid phases in equilibrium) plays a significant role in the processes of planetary-scale differentiation, the formation of Earth’s crust, and the genesis of magmatic sulfide ore deposits. The stable isotope geochemistry of nickel can potentially take advantage of fractionation signals produced in magmatic systems where immiscible sulfide and silicate liquid have equilibrated. Variations in Ni isotope ratio beyond those found in sulfide-undersaturated basaltic rocks can provide a hallmark of fractionation processes that control chalcophile and siderophile element abundances. We report high-precision Ni isotope ratio data for a stratigraphically-controlled sequence of Siberian Trap basalts in a volcanic edifice centered over the world’s largest concentration of magmatic sulfide ore deposits at Noril’sk-Talnakh, Russia. Nickel isotope ratios (δ60Ni (‰) = [(60Ni/58Ni)sample/(60Ni/58Ni)SRM986-1] × 1000) in the basaltic rocks range from +0.07 ± 0.02‰ to +1.00 ± 0.04‰ and correlate negatively with Ni and precious metal abundance levels, indicating extensive Ni isotope fractionation due to sulfide saturation of the silicate magma. A Rayleigh fractionation model fits the observed results and enables a precise estimate of the fractionation factor (α) between sulfide liquid and silicate melt to be 0.99965 (i.e., 103*lnα = −0.35). Our study illustrates the application of Ni isotope ratio data in understanding sulfide-silicate liquid immiscibility and the broader implications with respect to the formation of the largest known magmatic sulfide ore deposits in association with the Siberian Trap.

Highly siderophile element fractionation during chondrite melting inferred from olivine-rich primitive achondrites

Metal-silicate segregation is one of the most fundamental mechanisms in planetary differentiation, with primitive achondrites offering important constraints on this process. Brachinites and brachinite-like achondrites (BLA) are olivine-dominated primitive achondrites that experienced up to ∼20% partial melt removal under relatively oxidized (ΔIW ∼ −1) conditions within an initially chondritic parent body and represent residues after inefficient metal-loss. We present bulk rock and in situ lithophile and highly siderophile element (HSE) abundance systematics as well as 187Re-187Os data for five olivine-rich primitive achondrites. These new data confirm classification of Reid 013 as a brachinite, three of the samples as BLA (Northwest Africa [NWA] 6874, NWA 7499, and Miller Range 090805), and the final sample as an ungrouped primitive olivine-rich achondrite (NWA 7680). An aliquot of MIL 090805 shows amongst the highest total HSE contents (>35 ppm) and the highest Pt content (∼23 ppm) of any primitive achondrite. Compiled HSE data for brachinites and BLA show correlations between total HSE abundance, Pt enrichment, and average olivine Fo. This correlation can be explained by variable melting (∼10–20%) of an H ordinary chondrite-like protolith, with retention of both Fe-metal and a Pt-rich alloy phase distinct from the observed Fe-metal phases in more depleted residues. Such a Pt-alloy phase is likely stabilized by elevated abundances of the HSE during chondrite melting and the low solubility of HSE in melts. Rhenium-Os isotope data in the studied samples has been modified by recent mobilization of Re during terrestrial weathering, with the limited range of measured 187Os/188Os in brachinites and BLA supporting minor fractionation of Re/Os during melting and an ancient (∼4.5 Ga) partial melting event to explain their compositions. These results indicate that models of planetary differentiation should consider the low solubility of Pt in chondrite melts and the potential for alloy formation to modify HSE abundances of silicate mantles.

Rejuvenation of the lithospheric mantle beneath the orogens: Constraints from elemental geochemistry and Os isotopes in mantle xenoliths

Continental orogens that involve subduction and collision are important target areas for studying the growth, stabilization and transformation of Earth’s continents. In particular, the nature of the lithospheric mantle and its relationship to the overlying crust in these active subduction-collision zones are key factors to be constrained. Mantle xenoliths entrained by Cenozoic basalts from the Indochina Block, the Sukhothai Arc and the Inthanon Zone (IB-SA-IZ) provide direct deep-seated samples of the lithospheric mantle derived from part of the Tethyan orogenic belt, offering a unique opportunity to study mantle processes during orogenesis in response to the closure of the Paleo-Tethys Ocean. The studied mantle xenoliths comprise 32 spinel lherzolites, six harzburgites, and one olivine websterite. We present a comprehensive study of the elemental geochemistry and Os isotopes of this sample suite. Their lithophile element systematics indicate that they represent mantle residues after varying degrees of melt extraction (5–24%), followed by melt refertilization. Although the highly siderophile element abundances have been affected to some extent by melt refertilization through removal of sulfides, the Os isotopic compositions of the studied xenoliths were minimally disturbed. Lherzolites and the sole olivine websterite from the IB-SA-IZ share similar Re-Os isotope systematics (187Os/188Os: 0.121–0.137) to global abyssal peridotites, representing juvenile lithospheric mantle accreted from the upwelling asthenosphere, most likely associated with arc-continent collision in response to the closure of the Paleo-Tethys Ocean and back-arc basin during the Middle-Late Triassic. In contrast, the refractory harzburgites from the Indochina Block and Sukhothai Arc are characterized by substantially lower 187Os/188Os ratios (187Os/188Os: 0.117–0.122) than the lherzolites, yielding Mesoproterozoic Re-depletion Os model ages, which can be interpreted as either ancient lithosphere relics beneath these regions or accreted ancient mantle debris from the upwelling asthenosphere. Although the interpretation for the origin of the older harzburgites is ambiguous, we can conclude that rejuvenation of the lithospheric mantle commonly occurred beneath different tectonic units of the Tethyan orogenic belt: i.e., the pre-existing lithospheric mantle beneath different tectonic units of the Tethyan orogenic belt has been largely replaced by upwelling asthenospheric mantle during the Middle-Late Triassic orogenesis. This mantle was then further refertilized to varying degrees by asthenosphere-derived melts. Both processes play key roles in defining the nature of the lithospheric mantle in orogenic settings. This study also highlights that the geodynamic processes in the lithospheric mantle beneath orogenic belts can be well constrained by integrated evidence from lithophile and highly siderophile elements and their isotopes (e.g., Os isotopes) of mantle xenoliths.

A partially equilibrated initial mantle and core indicated by stress-induced percolative core formation through a bridgmanite matrix.

The Earth's core formation mechanism determines the siderophile and light elements abundance in the Earth's mantle and core. Previous studies suggest that the sink of massive liquid metal through a solid silicate mantle resulted in an unequilibrated core and the lower mantle. Here, we show that percolation can be an effective core formation mechanism in a convective mantle and modify the compositions of the lower mantle and the core through partial equilibration between them. This grain-scale metal flow has a high velocity to meet the time constraint of core formation. The Earth's core could have been enriched with light elements, and the abundance of the moderately siderophile elements in the mantle could have been elevated to the current value during this process. The trapped core-forming melt in the mantle during the stress-induced percolation can also explain the highly siderophile element abundance in the Earth's mantle.

Pristinity and petrogenesis of eucrites

AbstractNew petrography, mineral chemistry, and whole rock major, minor, and trace element abundance data are reported for 29 dominantly unbrecciated basaltic (noncumulate) eucrites and one cumulate eucrite. Among unbrecciated samples, several exhibit shock darkening and impact melt veins, with incomplete preservation of primary textures. There is extensive thermal metamorphism of some eucrites, consistent with prior work. A “pristinity filter” of textural information, siderophile element abundances, and Ni/Co ratios of bulk rocks is used to address whether eucrite samples preserve endogenous refractory geochemical signatures of their asteroid parent body (i.e., Vesta), or could have experienced exogenous impact contamination. Based on these criteria, Cumulus Hills 04049, Elephant Moraine 90020, Grosvenor Range 95533, Pecora Escarpment 91245, and possibly Queen Alexander Range 97053 and Northwest Africa 1923 are pristine eucrites. Eucrite major element compositions and refractory incompatible trace element abundances are minimally affected by metamorphism or impact contamination. Eucrite petrogenesis examined through the lens of these elements is consistent with partial melting of a silicate mantle that experienced prior metal–silicate equilibrium, rather than as melts associated with cumulate diogenites. In the absence of the requirement of a large‐scale magma ocean to explain eucrite petrogenesis, the interior structure of Vesta could be more heterogeneous than for larger planetary bodies.

Large-scale replacement of ancient mantle lithosphere during supercontinent assembly: Evidence from the South China Craton

The modification and destruction of the sub-continental lithospheric mantle (SCLM) has been identified in numerous studies. However, what principally controls the susceptibility and extent of destruction of the SCLM and how this leads to the corresponding variation of the overlying crust remain long-standing issues. Here we provide an integrated study of petrology, mineralogy, and geochemistry, including highly siderophile element (HSE) abundances and whole-rock and/or mineral Os-Hf-Sr-Nd isotopic compositions of mantle peridotite xenoliths from Hainan Island, together with a compiled dataset from the eastern South China Craton (SCC) to investigate the mechanism and timing of replacement and destruction of the SCLM. The mantle xenoliths from the eastern SCC are overall more fertile than cratonic lithospheric mantle, and have generally experienced various extents of metasomatic enrichment, including carbonate and silicate melt metasomatism. In addition, the absence of Archean ages and compositional or temporal stratification of the SCLM beneath the eastern SCC indicates that the Archean lithospheric mantle may have been replaced/reworked and has essentially vanished, hence the present underlying lithospheric mantle is a relatively new and young lithospheric mantle. The formation time of the SCLM underneath Hainan Island constrained by both the ReOs and LuHf isotopic systems is late Mesoproterozoic (∼1.2 Ga), largely consistent with the Meso- to Neoproterozoic peak of whole-rock TRD ages (0.9–1.3 Ga) of the refractory mantle peridotites in the compiled dataset. This age distribution can be reconciled with the assembly time of the Rodinia supercontinent, indicating a close linkage between the replacement of large-scale lithospheric mantle via mantle convection erosion and regional continental amalgamation. Meanwhile, the relative location to the plate margins influences the preservation of the cratonic mantle. The SCLM located at the plate margin (e.g., eastern SCC compared to western SCC), where destructive processes frequently occur, is susceptible to destruction, whereas that within the plate interior is likely to remain relatively intact.

A Combined Re-Os and Pt-Os Isotope and HSE Abundance Study of Ru-Os-Ir Alloys from the Kunar and Unga Placer Deposits, the Taimyr Peninsula, Polar Siberia

In order to provide further insights into the origin of Ru-Os-Ir alloys, this study presents new highly siderophile element (HSE: Re, Os, Ir, Ru, Pt, and Pd) abundance and 187Re-187Os and 190Pt-186Os isotope data for detrital grains of native Ru-Os-Ir alloys in placer deposits of the Kunar and Unga Rivers, which display a close spatial association with the Kunar dunite–harzburgite complex in the northern part of the Taimyr Peninsula in the Polar Siberia. The study utilized electron microprobe analysis, negative thermal ionization mass-spectrometry (N-TIMS) and laser ablation multiple-collector inductively coupled plasma mass-spectrometry (LA MC-ICP-MS). The primary nature of the Ru-Os-Ir alloys is supported by the occurrence of euhedral inclusions of high-Mg olivine (Fo92–93) that fall within the compositional range of mantle olivine. The LA MC-ICP-MS data show similar average initial 187Os/188Os and γ187Os(740 Ma) values for PGM assemblages from the Kunar and Unga deposits of 0.1218 ± 0.0010, −0.18 ± 0.85, and 0.1222 ± 0.0025, +0.10 ± 2.1, respectively. These values are identical, within their respective uncertainties, to the initial 187Os/188Os value of the Ru-Os-Ir alloy grain measured by N-TIMS (0.1218463 ± 0.0000015, γ187Os(740 Ma) = −0.1500 ± 0.0012). The combined 187Re-187Os isotopic data for all studied grains (γ187Os(740 Ma) = −0.02 ± 1.6) indicate evolution of the Kunar and Unga mantle sources with a long-term chondritic 187Re/188Os ratio of 0.401 ± 0.030. In contrast to the 187Os/188Os data, the initial 186Os/188Os value of 0.1198409 ± 0.0000012 (µ186Os(740 Ma) = +34 ± 10) obtained for the same Ru-Os-Ir alloy grain by N-TIMS is suprachondritic and implies evolution of the Kunar and Unga mantle source(s) with a long-term suprachondritic 190Pt/188Os ratio of 0.00247 ± 0.00021. This value is ~40% higher than the average chondritic 190Pt/188Os ratio of 0.00180 and indicates long-term enrichment of the Kunar source in Pt over Os. Establishing the source of this enrichment requires further investigation.

Abundances of siderophile elements in H-chondrite metal grains: Implications for the origin of metal in unequilibrated ordinary chondrites

Understanding the evolution of metal in the protoplanetary disk is necessary to constrain the first steps of metal-silicate segregation and the early stages of the evolution of the protoplanetary disk. We measured the siderophile elemental compositions (PGE, Ni, Co, Fe, Cu, Ga, Ge) of individual metal grains in H ordinary chondrites by laser ablation inductively coupled plasma mass spectrometry to investigate their formation. We analyzed unequilibrated ordinary chondrites (H3) to constrain processes affecting the metal before accretion, and inferred the effects of metamorphism by comparing their elemental compositions to those of equilibrated chondrites (H4–H6). Our results highlight large variations of refractory (Re, Os, W, Ir, Ru, Mo, Pt) and moderately volatile siderophile element (Pd, Au, Ga, Ge) concentrations among metal grains in H3 samples that permit to classify them according to their Ge/Ir ratios and HSE contents. These intergrain variations are progressively homogenized in H4–H6 samples due to their increasing degrees of metamorphism. To constrain the origin of the metal, we modeled its evolution during melting and crystallization. Our melting model of a single metallic precursor containing 1.5 wt% C and up to 12 wt% S reproduces well the observed range of siderophile element compositions in the metal. Metal grains show a range of W, Mo, and Ga compositions that we interpret to reflect various local (grain-scale) oxidation states during the melting event(s) due to the heterogeneous distribution of various oxidizing components within the precursors. The very similar HSE compositions of H and L/LL metal grains suggests that the variations of bulk metal abundance and HSE concentrations observed among the different classes of ordinary chondrites (H, L, LL) result from the heterogeneous physical distribution of a relatively chemically homogeneous metal component among OC parent bodies, and not from a chemical (sensu lato) gradient between H and LL chondrites.

Genetics, age, and crystallization history of group IC iron meteorites

The IC iron meteorite group is characterized utilizing nucleosynthetic mass-independent isotopic compositions and 182W age constraints, coupled with siderophile element concentration measurements and modeling of crystal-liquid fractionation processes. The six IC irons analyzed, Arispe, Bendego, Chihuahua City, Nocoleche, NWA 2743, and Winburg have indistinguishable Mo and W genetic isotopic compositions and are consistent with derivation from the same parent body, which formed in the non-carbonaceous (NC) nebular reservoir. A pre-exposure µ182W value (parts-per-million deviations in isotopic ratios from terrestrial standards) for the six IC irons of −337 ± 5 corresponds to a metal-silicate segregation age of 1.0 ± 0.4 Myr after calcium-aluminum-rich inclusion (CAI) formation. This age is similar to those determined for other NC iron groups. Siderophile element abundances of the IC irons are generally similar and characterized by minor depletions in the more volatile siderophile elements. Highly siderophile element (HSE) distributions among the IC group suggest that the initial parent body core was S-rich, with preferred model results indicating an initial melt composition with ∼ 18 wt% S, 2 wt% P and 0.03 wt% C. Processes in addition to fractional crystallization, such as late-stage parent body modification, possibly as a result of impacts, and subsequent metal-melt mixing, are required within the first 100 Myr of Solar System history to explain the range of HSE abundances.

Generation of Continental Lithospheric Mantle by Tectonic Isolation of Oceanic Plate

AbstractContinental formation models invoke subduction or plume‐related processes to create the buoyant, refractory character of continental lithospheric mantle (CLM). From similarities in melt depletion, major element composition, modal clinopyroxene, and Os isotope systematics it has been proposed that oceanic mantle lithosphere is the likely protolith to non‐cratonic CLM, however, a direct link between the two has been difficult to ascertain. Using dredged mantle peridotite xenoliths from the Ferrel Seamount, off the west coast of Baja California, Mexico, we show that tectonic isolation of an oceanic plate may lead to formation of non‐cratonic CLM. Ferrel xenoliths are coarse‐grained spinel lherzolite, or rare harzburgite. Bulk‐rock and clinopyroxene trace element compositions reveal two‐stages of melt refertilization following melt depletion, with infiltration by mid‐ocean ridge basalt‐type melts, followed by melt addition from host alkali basalt. Melt depletion correlations with 187Os/188Os and highly siderophile element abundances indicate preserved melt depletion and refertilization processes are ancient. From these observations, the Ferrel xenoliths represent lithosphere from the abandoned Pacific‐Farallon ridge. The history of melt depletion, followed by MORB‐melt refertilization is consistent with the peridotites representing oceanic mantle lithosphere that was subsequently incorporated into the Baja‐Guadalupe microplate during “ridge jump.” These peridotites demonstrate that isolation of oceanic lithosphere that is rafted onto a continental margin provides a viable means for producing non‐cratonic CLM. We suggest that continuation of late‐stage, low degree melt refertilization may provide a link between oceanic lithosphere and non‐cratonic CLM and propose a tectonic model to preserve and facilitate this continued evolution.

Cretaceous Meteorite Impact-Induced Initial Subduction: Records of highly Siderophile Element Abundances and Re-Os Isotopes in Ophiolites

Cretaceous Meteorite Impact-Induced Initial Subduction: Records of highly Siderophile Element Abundances and Re-Os Isotopes in Ophiolites

Meteoritic component in impact breccias of the Jeokjung-Chogye structure, South Korea: Evidence from the HSE abundances and Re[sbnd]Os isotopic systematics

Geochemical compositions, including highly siderophile element (HSE) abundances and Re-Os isotope compositions, of nine polymict impact breccias in two drill cores and three target rocks from the Jeokjung-Chogye structure, South Korea, have been investigated to test the impact origin of the structure, and to infer the potential projectile type for the formation of the crater. The impactites have around 5 times higher abundances of platinum-group elements (PGE) compared to target rocks, and two orders of magnitude higher Re abundances. The weighted mean for 187Os/188Os ratios of impactites is 0.806, which is lower than this value for the target rocks (1.049), suggesting the presence of a meteoritic component. The higher PGE abundances and a broad negative correlation between Os contents and 187Os/188Os ratios show that the impactites incorporated ∼0.05 wt% of a chondritic component. The endogenic or chondritic relative abundances of the HSE argue against iron meteorites as a potential impactor for the Jeokjung-Chogye structure. Yet, the present data do not allow to unambiguously identify the projectile type (i.e., chondrite class) present in the impactites because of the high proportion of the indigenous component.

Geochemistry of lunar meteorite Northwest Africa 11962 and its potential source region/crater in the Procellarum KREEP terrane

AbstractLunar meteorite Northwest Africa (NWA) 11962 is a regolith breccia with a diverse range of mineral and lithic clasts. For the present study, major and trace element contents and selected isotopic compositions were determined on a homogenized bulk powder of NWA 11962 by instrumental neutron activation analysis, thermal ionization mass spectrometry, and inductively coupled plasma mass spectrometry. The chemical composition of the sample points toward an origin of the meteorite from within the Procellarum KREEP terrane (PKT). Samarium‐Nd and Rb‐Sr isotopic compositions and concentrations show a similarity to those of Apollo 15 soils and KREEP basalt. Highly siderophile element (HSE) abundances and ratios, as well as the Re/Os isotopic system, are often used as tracers of different impactor types. The 187Os/188Os and 187Re/188Os isotopic ratios are within the range of ordinary chondrites, yet some of the siderophile element and highly siderophile element ratios are comparable to those of iron meteorites. Using Fe, Th, and Ti abundances of lunar surface regolith, measured by the Lunar Prospector gamma‐ray spectrometer, we attempt to constrain potential lunar source regions for NWA 11962. By matching these possible source regions with coordinates of recently (<1 Ma) formed lunar impact craters (so‐called lunar cold spots), we localized a potential source crater of NWA 11962 at the western rim of the PKT close to Sinus Medii.

Trace element volatility and the conditions of liquid-vapor separation in the proto-lunar disk

The Moon is thought to have formed from material ejected by a giant impact that took place at the end of Earth's accretion. The material ejected to space generated a large hot structure where material beyond the Roche limit accreted to form the Moon. It has long been known that the Moon is characterized by abundances in moderately volatile elements (MVE) lower than that of the Earth, while more recent studies have established that the concentrations in refractory elements are similar to the bulk Silicate Earth. The thermodynamic conditions that prevailed after this impact are poorly known and understanding the origin of the Moon-Earth differences in MVE requires a knowledge of the volatility of elements under these conditions. In this study, we reexamine the volatility of a large set of geochemically relevant elements and attempt to determine the P-T conditions under which volatiles were putatively separated from the liquid material. Our model predicts very different condensation temperatures due to higher pressures, compared with the conditions of the Solar Nebula and we extend the values of these temperatures to a wide number of trace elements (Se, Ag, Pt, Mo, W, Zn, Sn, Sb, Rb, Cs, U, Th, Cr, Ni, Co, Ga, Ge, Cu, and P). Our modeling shows that the observed lunar compositions cannot be explained by a single set of P and T conditions. Rather, it is best explained by a mixture between high-temperature condensates (~4000 K) and low temperature condensates (2000-2500 K). An important constraint is that for the low temperature condensates, liquid metal must have been stable and this is crucial for matching the abundance of volatile siderophile elements in the bulk Moon.