Surface charge accumulation on insulators becomes an important bottleneck to restrain the development of a DC energy transmission system. This study investigates the effects of SiC/epoxy coating on surface charge behaviors and flashover performance of alumina/epoxy spacers. A nonlinear conductive coating consisting of different contents of SiC fillers and epoxy matrix was fabricated and sprayed on only half surface of the spacers. The dependence of surface charges on the contents of SiC fillers is characterized by three stages. Surface charge accumulation is aggravated at deterioration stage, then almost unaltered at balance stage and inhibited at suppression stage. These three stages are determined by the competition between the increased surface trap density from interface region and the improved surface conductivity from SiC fillers. The variation trend of flashover in air and SF6/N2 mixtures is distinguished by three stages as well. Flashover voltage decreases at descent stage where deficient contents of SiC fillers are appended and then goes up at improved stage with moderate supply of SiC fillers. Finally, it ends up with drastically collapse at degenerated stage when affluent SiC fillers are brought in. The theoretical analysis is proposed based on surface trap distribution and conductivity measurement results to reveal the regulation mechanism of SiC/epoxy coating on surface charge behavior and flashover performance.