Siberian Traps Large Igneous Province Research Articles

Constraints on the source of Siberian Trap magmas from Mo isotope evidence

The relative contributions of asthenospheric mantle, lithospheric mantle, and continental crust in the genesis of the Siberian Traps Large Igneous Province (ST-LIP) remain poorly constrained. Most models invoke partial melting of asthenospheric mantle within a mantle plume with an inventory of recycled crustal material, with or without melting of subcontinental lithospheric mantle, and crustal contamination during ascend through the continental lithosphere. A greater understanding of this topic is of fundamental importance because the ST-LIP basalts are associated with the large Permian-Triassic extinction and the world’s largest magmatic Ni-Cu-platinum group element sulfide resources (Ni-Cu-PGE), the Norilsk-Talnakh mining camp. The ∼250 ± 2 Ma Siberian Traps at Norilsk contain a classic sequence of basaltic rocks that provide a spatial and stratigraphic context for changing chemistry of the eruptive products. We present a detailed geochemical and Sr-Nd-Hf-Mo isotopic investigation of ST-LIP volcanic rocks and associated sedimentary rocks, including coal and anhydrite, from the Norilsk area. The 98Mo/95Mo isotope ratios (reported as δ98Mo ratio relative to NIST SRM 3134) vary significantly from −0.62 to 0.07 ‰ for the older basalt formations and −0.41 to 0.03 ‰ for the younger basalt formations. The range of δ98Mo and its correlation with the other geochemical tracers cannot be explained by post-magmatic alteration, magmatic differentiation, or sulfide fractionation as Mo behaves as a lithophile element under these magmatic conditions. We suggest that the δ98Mo range can be explained by interaction of the plume with subcontinental lithospheric mantle modified by subduction processes. This is particularly prominent in the earlier Ivakinsky to Gudchikhinsky formations where light δ98Mo values coupled with low Mo/Ce can be explained by contributions from a dehydrated eclogitic component, whereas more rare heavy δ98Mo values and high Mo/Ce likely require contributions from a fluid metasomatized mantle source. Later magmas of the Nadezhdinsky formation show clear evidence of crustal contamination in their combined Mo-Sr-Nd-Hf isotope and trace element systematics, while the later more voluminous Morongovsky type magmas are shallower, large degree melts with limited crustal interaction. Our data shows the usefulness of Mo isotopes in deciphering magma sources of large igneous provinces eruptions.

Polycyclic aromatic hydrocarbons (PAHs) evidence for frequent combustion events on land during the Permian–Triassic transition in Northwest China

The Siberian Traps large igneous province and intensive continental arc volcanism are regarded as the primary drivers of the severe environmental changes that triggered the end-Permian mass extinction. However, detailed correlations between volcanism and the collapse of terrestrial ecosystems remain ambiguous. This study used polycyclic aromatic hydrocarbons (PAHs) records and mercury spikes from the terrestrial Dalongkou section as refined proxies for volcanic combustion events. The mercury anomalies, PAH concentrations, and PAH ratios provide insight into the terrestrial ecosystem collapse during the Permian–Triassic (P–T) transition. Based on the multiple PAH ratios, the source and composition of PAHs exhibit obvious pyrolytic-derived origins during the late Permian. Combined with the biostratigraphic records and our PAH proxies in the Dalongkou section, terrestrial ecosystems experienced stepwise crisis and change owing to volcanic effects and frequent high-temperature combustion events during the P–T transition. During the main terrestrial P–T crisis interval, the increased PAH concentrations indicate that the combustion events were gradually enhanced under worse climatic conditions. Based on the PAH records, enhanced soil erosion accompanied by frequent wildfires was found to occur under extremely high-temperature climatic conditions caused by intensive volcanic activity during the P–T transition.

PLUME-GENERATED 90° STRESS CHANGE LINKED TO TRANSITION FROM RADIATING TO CIRCUMFERENTIAL DOLERITE DIKE SWARMS OF THE SIBERIAN TRAPS LARGE IGNEOUS PROVINCE AND TO EMPLACEMENT OF THE NORILSK-TALNAKH ORE DEPOSITS

Abstract A 90° change in stress orientation has been previously proposed as the trigger for the final emplacement of the world-class Norilsk-Talnakh magmatic sulfide mineralization via the migration of accumulated sulfide melts from elsewhere within the plumbing system of the Siberian Traps large igneous province (LIP). We propose that this stress change does not require and was not triggered by a distal change in plate boundary stresses, but instead can be explained both temporally and spatially by stress changes recorded in the dike swarm patterns of the Siberian Traps LIP, namely the transition from a giant radiating dike swarm (associated with mantle plume uplift) to a giant circumferential swarm (linked to flattening of the plume head). The mantle plume stress-related changes recorded by these dike swarms, rather than distal plate boundary stress changes, were therefore most likely the trigger for the emplacement of the Norilsk-Talnakh mineralization. Other LIPs that have both giant radiating and circumferential dike swarms most likely reflect similar major and rapid changes in stress orientation, indicating that mantle plume-induced stress changes revealed by dike swarms should be considered an additional tool in magmatic sulfide exploration.

The terrestrial end-Permian mass extinction in the paleotropics postdates the marine extinction.

The end-Permian mass extinction was the most severe ecological event during the Phanerozoic and has long been presumed contemporaneous across terrestrial and marine realms with global environmental deterioration triggered by the Siberian Traps Large Igneous Province. We present high-precision zircon U-Pb geochronology by the chemical abrasion-isotope dilution-thermal ionization mass spectrometry technique on tuffs from terrestrial to transitional coastal settings in Southwest China, which reveals a protracted collapse of the Cathaysian rainforest beginning after the onset of the end-Permian marine extinction. Integrated with high-resolution geochronology from coeval successions, our results suggest that the terrestrial extinction occurred diachronously with latitude, beginning at high latitudes during the late Changhsingian and progressing to the tropics by the early Induan, spanning a duration of nearly 1 million years. This latitudinal age gradient may have been related to variations in surface warming with more degraded environmental conditions at higher latitudes contributing to higher extinction rates.

Turbulent paleoenvironment linked to astronomical forcing during the Permian–Triassic transition

The Milankovitch cycles are essential for establishing high-resolution chronological frameworks, which can provide a reliable timescale for biological and environmental events. However, astronomical solutions for the Paleozoic are still imperfect. Moreover, global paleoenvironmental turbulence during the Permian-Triassic (PT) transition caused interference with most proxies reflecting astronomical cycles. This study discovered that the Sb/Cd series can reflect astronomical cycle signals through a time-series analysis of geochemical elemental data from cores around the Lopingian–Lower Triassic in the Lower Yangtze region. Combined with zircon SHRIMP dating of volcanic ashes, a reliable absolute astronomical timescale with a duration of 2.5 Myr was established from 100-kyr eccentricity-tuned results. Based on the coupling analysis of palaeoenvironmental proxies, this study evaluated the effect of astronomical forcing and volcanism on the paleoenvironment. The sea level change was influenced by obliquity during the Lopingian–Early Triassic. During the Wuchiapingian–Changhsingian (WC) and PT transitions, regional volcanic activities at South China and the Siberian Traps Large Igneous Province (STLIP) intervened the normal trend of a low-temperature arid climate dominated by the obliquity forcing, respectively. Thus, South China exhibited a hot humid climate during the WC and PT transitions. Conversely, the low-temperature climate in South China was significantly modulated by obliquity forcing during the middle Changhsingian. Besides the influences of intense igneous activities and related environmental effects, disruption the long-term stable low-temperature environment by the abnormal high-temperature around the PT transition was a tremendous challenge to the biological ecological adaptation, and thereby may have contributed to the end-Permian mass extinction.

Evidence for variable provenance of Mercury anomalies during the Smithian–Spathian (Olenekian)

Mercury (Hg) enrichment recorded in Smithian to Spathian (Olenekian) marine sedimentary successions has been used to link putative renewed Siberian Traps Large Igneous Province (STLIP) magmatism to climatic and environmental perturbations during this interval. To assess the potential for massive volcanism as a trigger for marine environmental disturbances across the Smithian – Spathian boundary (SSB), the patterns and provenance of Hg sequestration in four Tethyan marine sedimentary successions are investigated in the current study. We present a diverse array of new, temporally calibrated geochemical data including Hg concentrations and isotopic compositions, strontium, and neodymium isotope records, as well as major and trace element concentrations from carbonate-poor and -rich strata alike, including volcanic ashes. Results indicate that Hg anomalies in middle to late Smithian strata vary in magnitude and age. Based on several lines of evidence, the Hg anomalies recorded for the investigated PaleoTethyan successions are interpreted to have been sourced from subduction-related arc volcanism, with potential contributions from terrestrial Hg reservoirs. In contrast, a low-magnitude mercury enrichment interval recorded for NeoTethyan late Smithian strata is attributed to hydrothermal fluid or submarine volcanic activity. These results, together with previously published Smithian to Spathian Hg records, provide evidence that Smithian Hg anomalies cannot be attributed to a singular source such as renewed STLIP activity. Instead, the stratigraphically variable mercury anomalies reflect local patterns of enhanced mercury sequestration from various sources during the middle Smithian to SSB. Consequently, evidence for STLIP magmatism during the Smithian – Spathian transition is still lacking, and regional volcanic activity may have been influential in causing marine environmental upheavals in the Tethys region across the SSB.

Marine snowstorm during the Permian−Triassic mass extinction

The Permian−Triassic mass extinction (PTME) interval is marked by major excursions in both inorganic and organic carbon (C) isotopes. Carbon cycle models predict that these trends were driven by large increases in productivity, yet organic C−rich rocks are not recorded in most PTME shelf sedimentary successions. Anomalous C-rich facies have been reported from rare abyssal plains records now exposed in Japan and New Zealand, where black shales at the PTME are extraordinarily organic-rich units. We examined organic matter at the Waiheke, New Zealand, section, and results show that these deposits are dominated by lamalginites composed of unicellar solitary or colonial phytoplankton produced during algal blooms that falls as “marine snow.” We modeled the impact of ash fall from eruptions in the Siberian Traps large igneous province and argue that they fertilized the Panthalassa Ocean with P and Fe, leading to a marine “snowstorm” and significant C drawdown marking this major biobloom during the PTME.

Cadmium isotopic evidence for reduced deep-water marine primary productivity during the end-Permian mass extinction

Marine primary productivity is a key control on the stability of marine ecosystems. Decreasing marine primary productivity might have led to the end-Permian mass extinction, although this is debated. However, the changes in primary productivity at different seawater depths during the end-Permian mass extinction remain poorly constrained. We investigated the Cd isotopic systematics of shallow-water (Dajiang) and deep-water (Shangsi) sedimentary sections in South China. Combined with previously published data from an intermediate–deep-water section (Meishan), we were able to reconstruct the depth changes in marine primary productivity. In the Dajiang section, prior to the mass extinction, the Cd isotopic compositions of seawater (δ114/110CdSW) varied from +0.73‰ to +0.92‰, with an average of +0.83‰±0.13‰ (2SD; n=11). During and after the mass extinction, δ114/110CdSW varied from +0.73‰ to +0.91‰, with an average of +0.81‰±0.12‰ (2SD; n=12). In the Shangsi and Meishan sections, prior to the mass extinction, δ114/110CdSW varied from +0.47‰ to +0.85‰, with an average of +0.66‰±0.16‰ (2SD; n=35). During and after the mass extinction, δ114/110CdSW varied from −0.19‰ to +0.36‰, with an average of −0.02‰±0.27‰ (2SD; n=27). During the end-Permian mass extinction, the marine primary productivity recorded by Cd isotopes in the relatively deep-water sections was considerably reduced, which may have caused the destruction of relatively deep-water marine ecosystems. We suggest that upward expansion of sulfidic and anoxic deep water, possibly due to the volcanic eruption of the Siberian Traps large igneous province, was one of the causes of the decrease in marine primary productivity. However, the marine primary productivity did not change in the shallow-water section during the end-Permian mass extinction, although changes in the types of marine primary producers are evident from the fossil record. This change in the types of primary producers may have contributed to the mass extinction in shallow-water platform environments. Vertical variations in the changes in primary productivity indicate that the environmental factors leading to the extinction event mainly began in deep waters during the end-Permian mass extinction.

Zirconium and neodymium isotopes record intensive felsic volcanism in South China region during the Permian-Triassic boundary crisis

The Permian-Triassic mass extinction (PTME), the largest biocrisis in Earth's history, is regarded as having been triggered by volcanism, although the source and nature of this volcanic activity in the South China region remains in debate. In this regard, determining the geochemical composition of the volcanic and terrestrial source fluxes to marine depositional systems is crucial for differentiating material derived from the Siberian Traps Large Igneous Province versus regional volcanic arcs. Here, we report zirconium (Zr) isotopic compositions (δ94/90Zr) of Permian-Triassic boundary strata from a deep carbonate-ramp setting at Xiakou, South China, providing new insights regarding the provenance of volcanic ash layers and their host silicic mudstones. The δ94/90Zr composition of magmatically sourced materials is generally controlled by degree of melt crystallization and has the potential to discriminate between primitive and evolved igneous sources. At Xiakou, the pre-PTME Lower Unit contains volcanic ash layers with δ94/90Zr (+0.05 ± 0.03‰, 2SD) similar to that of upper continental crustal (UCC), recording dominantly detrital zircon sources. About 10 kyr before the mass extinction, a single ash layer (Bed 249) records a transient excursion to mantle-like values (∼0‰), followed by a protracted shift across the Permian-Triassic boundary (PTB) toward signatures characteristic of more evolved felsic sources (+0.19 ± 0.12‰) accompanied by a positive shift in Nd isotopes (εNd(t)). The high δ94/90Zr of volcanic ash layers from the Middle Unit (corresponding approximately to the interval between the PTME and PTB) indicates dominance of regional felsic volcanic sources. In this interval, volcanic ash δ94/90Zr values at Xiakou are distinctly higher than those at Meishan, suggesting that primary volcanic signatures are better preserved in deep-water facies (Xiakou) than in shallow-water facies (Meishan). In the Middle (excluding the Bed 249) and Upper (post-PTME) units, positive covariation of δ94/90Zr with Al2O3/TiO2, Zr/TiO2 and Zr/Sc ratios was the product of mixing of detrital and volcanic materials, with the latter having a dominantly felsic source. This study provides new insight into the sources of zircons in PTB sections of South China, and it demonstrates the general utility of sedimentary Zr isotopic compositions in determining magmatic provenance.

Timing and Provenance of Volcanic Fluxes Around the Permian‐Triassic Boundary Mass Extinction in South China: U‐Pb Zircon Geochronology, Volcanic Ash Geochemistry and Mercury Isotopes

AbstractAnomalous mercury (Hg) contents recorded near the Permian‐Triassic boundary (PTB) are often linked to Siberian Traps Large Igneous Province (STLIP) volcanism and the Permian‐Triassic boundary mass extinction (PTBME). However, mounting evidence indicates that the relation between STLIP volcanism and Hg “anomalies” is not straightforward. This study focuses on the timing and provenance of volcanic fluxes around the PTBME in South China. We constrain carbon isotope (δ13C) and Hg concentration and isotope records by utilizing high‐precision U‐Pb zircon ages from two expanded deep‐water marine sections spanning the Late Permian to Early Triassic in the Nanpanjiang Basin. Results reveal two episodes of Hg enrichment. The oldest episode predates the onset of a large negative δ13C excursion, which is documented to be older than 252.07 ± 0.130 Ma. The second episode occurred between 251.822 ± 0.060 and 251.589 ± 0.062 Ma, coinciding with the nadir of the δ13C excursion. Volcanic ash geochemistry and Hg isotope compositions suggest that mercury was mainly sourced from subduction‐related volcanic arc magmatism in the Tethys region, which peaked between 251.668 ± 0.079 and 251.589 ± 0.052 Ma. These results are compatible with suggestions that regional arc volcanism contributed to the causes of the PTBME in South China and provide evidence that Hg anomalies close to the PTB are not a reliable stratigraphic marker for the PTB extinction event. This study demonstrates that relations between volcanism, environmental perturbations and mass extinction during the Permian‐Triassic transition are better resolved with the aid of high‐precision U‐Pb zircon ages.

End-Permian terrestrial ecosystem collapse in North China: Evidence from palynology and geochemistry

The Permian-Triassic Mass Extinction (ca. 252 Ma; PTME) is the most severe biocrisis of the Phanerozoic in both the oceans and on land. The crisis saw the collapse of terrestrial ecosystems in low, mid and high latitudes. Although terrestrial plant losses have been implicated as a driver of concurrent changes in terrestrial sedimentary environments and facies (e.g., fluvial style and/or grain size), the relationship between extinction and environmental change in the North China Plate (NCP) remains uncertain due to a paucity of plant macrofossils. We explore the relationship between terrestrial environments and changes in plant communities using a combination of sedimentology, palynology, geochemistry, mineralogy and charcoal data from a terrestrial succession in the Yiyang Coalfield located in the southern NCP. Our multiproxy approach places the end-Permian Terrestrial Collapse (EPTC) at the base of bed 20, below the level of the main (marine) PTME at the top of bed 21. The EPTC manifested as a rapid loss of vegetation accompanied by climatic warming and frequent wildfires. The main PTME was accompanied by warming, spikes in the Chemical Index of Alteration (corrected CIA, CIA*) and sedimentary Ni (Ni/Al) concentrations, and a transition from arid floodplain to fluvial facies in the sedimentary record. Our results reveal a rapid increase in charcoal content, rapid decline of spore-pollen content, disappearance of plant macro-fossils, rapid decline in TOC content, the onset of a negative δ13Corg excursion, and a shift in lithology from grayish-green sandstone and mudstone to purplish-red mudstone, suggesting that wildfires induced by global warming during the early eruption phase of the Siberian Traps Large Igneous Province triggered terrestrial ecosystem collapse in the NCP prior to the PTME. Plant extinctions during the EPTC were accompanied by changes in sedimentology and environment, but there was no abrupt change in fluvial styles. Temporal coincidence suggests that shifts in end-Permian terrestrial ecosystems toward those tolerant of warmer and more environmentally stressed environments were driven by concurrent Siberian Traps volcanism.

Mercury evidence from southern Pangea terrestrial sections for end-Permian global volcanic effects

The latest Permian mass extinction (LPME) was triggered by magmatism of the Siberian Traps Large Igneous Province (STLIP), which left an extensive record of sedimentary Hg anomalies at Northern Hemisphere and tropical sites. Here, we present Hg records from terrestrial sites in southern Pangea, nearly antipodal to contemporaneous STLIP activity, providing insights into the global distribution of volcanogenic Hg during this event and its environmental processing. These profiles (two from Karoo Basin, South Africa; two from Sydney Basin, Australia) exhibit significant Hg enrichments within the uppermost Permian extinction interval as well as positive Δ199Hg excursions (to ~0.3‰), providing evidence of long-distance atmospheric transfer of volcanogenic Hg. These results demonstrate the far-reaching effects of the Siberian Traps as well as refine stratigraphic placement of the LPME interval in the Karoo Basin at a temporal resolution of ~105 years based on global isochronism of volcanogenic Hg anomalies.

High temperature methane emissions from Large Igneous Provinces as contributors to late Permian mass extinctions

Methane (CH4) emissions induced by Large Igneous Provinces have the potential to contribute to global environmental changes that triggered mass extinctions in Earth’s history. Here, we explore the source of methane in gas samples from central Sichuan Basin, which is within the Emeishan Large Igneous Province (ELIP). We report evidence of high methane formation temperatures (between 249−17/+19 and 256−20/+22 °C) from clumped methane measurements and mantle-derived signatures of noble gases, which verify that oil-cracked CH4 and pyrobitumen are by-products within the reservoirs, associated with hydrothermal activity and enhanced heating by the ELIP. We estimate the volume of oil-cracked CH4 induced by the ELIP and argue that CH4 emissions would have been sufficient to initiate global warming prior to the end of the Permian. We also suggest that similar emissions from oil-cracked CH4 associated with the Siberian Traps Large Igneous Province may also have contributed to the end-Permian mass extinction significantly.

Zirconium isotopes track volcanic inputs during the Permian-Triassic transition in South China

The Permian-Triassic mass extinction (PTME), the most severe biocrisis of the Phanerozoic, has been widely attributed to intense volcanism. Although the Siberian Traps Large Igneous Province is regarded as the main trigger of this bioevent, volcanic-arc activity around the margins of the Tethys Ocean may have played a significant role also. Here, we report results of a high-resolution study of zirconium (Zr) isotopes in bulk limestone and volcanic ash beds of the Permian-Triassic transition at Meishan, South China. Mass-dependent fractionation of Zr isotopes, which is controlled by magmatic crystallization, has the potential to differentiate between primitive and evolved igneous sources. The Zr isotopic composition (δ94/90Zr) of volcanic ash in Permian-Triassic transition beds at Meishan is more positive than mantle values, indicating that inputs were probably dominated by regional arc volcanism. The sedimentary beds having the heaviest Zr isotopes during the pre-PTME interval may also record inputs from a felsic volcanic source. A mixing model indicates that the observed negative shift of δ94/90Zr at the PTME horizon was likely due to detrital Zr inputs linked to intensified continental weathering. This study demonstrates that volcanism in South China during the Permian-Triassic transition was linked to regional arc magmatism.

Catastrophic event sequences across the Permian-Triassic boundary in the ocean and on land

This review forms the preface of a special issue dealing with Environmental stresses and biotic responses during the Palaeozoic-Mesozoic transition, and develops an improved understanding of the sequence of catastrophe events associated with the Permian-Triassic (P–Tr) transition in particular. The 16 papers that comprise this special issue mostly focus on the Paleo-Tethys and Panthalassia regions, and enable us to recognize seven distinct phases of biotic and environmental evolution that may be precisely correlated between marine and terrestrial environments. Phase 1 represents the normal marine environments and biota that existed at 252.104 Ma, prior to the onset of major environmental perturbation. Phase 2 is marked by the onset of a negative carbon (δ13Ccarb) isotopic excursion, and coincides with a significant decline in radiolarian diversity, the collapse of communities in shallow metazoan reefs and deep-water settings, and the loss of rainforests on land (including the disappearance of Gigantopteris flora). Phase 3 is characterized by a pulse of biodiversification on the eve of the end-Permian extinction (EPE). Phase 4 comprises the EPE event itself, dated to 251.941 Ma, and coincides with an extreme episode of widespread anoxia, biodiversity loss, community structural collapse, and volatile volcanic eruptions. Phase 5 is marked by the renewed onset of oxic conditions in all oceanic environments except those in microbialite-rich shallow platform settings where abundant pyrite framboids signal dysoxia. Phase 6 includes the earliest Triassic extinction (ETE) event, dated to 251.880 Ma, and associated with euxinic to anoxic conditions and ocean acidification. An extended phase of deoxygenation and acidification returned to the marine settings during Phase 7, possibly driving a calcium crisis. The terrestrial extinction event (Phase 2) probably commenced c. 60 kyrs (in South China) or 370 kyrs (in Sydney basin) before the marine P–Tr extinction, the latter consisting of two distinct events (Phases 4 and 6), spaced c. 60 kyr apart, each being marked by both a carbon isotope excursion and ecologic collapse. The environmental changes associated with these three extinction phases in the ocean and on land can be attributed to the effects of volcanic emissions (e.g., CO2, SO2, halogens and metals) during the eruption of the Siberian Traps Large Igneous Province and convergent margin volcanism related to Tethyan tectonics.

Sulfur isotopes link atmospheric sulfate aerosols from the Siberian Traps outgassing to the end-Permian extinction on land

Throughout Earth history, large volcanic eruptions that inject sulfur-bearing gases are believed to have imparted strong forcings on global climates and ecosystems. Sulfur outgassing by the Siberian Traps Large Igneous Province (STLIP) is hypothesized to have catalyzed environmental catastrophe associated with the end-Permian extinction (EPE). However, there is as yet only sparse evidence for dispersal of atmospheric sulfate aerosols that precisely coincided with the EPE on land. Here we report S-isotopic compositions of pyrite (δ34S) from the Sydney Basin in SE Australia, where we find a sharp δ34S decrease from 0.04‰ to −21.52‰ coinciding with the stratigraphic level of the terrestrial extinction. The negative δ34S values in the extinction interval provide new evidence for a significant increase in atmospheric sulfate concentrations linked to fallout of sulfate aerosols originating from the Siberian Traps eruptions. We suggest that climatic perturbations of short-term cooling caused by the sulfate aerosols, along with longer-term global warming, and their interactions, may have contributed to the EPE on land. Our data suggest that sulfuric acid rain and ozone depletion may have greatly deteriorated global environments, leading to the terrestrial EPE.

Thermal history of the Siberian Traps Large Igneous Province revealed by new thermochronology data from intrusions

We present results of apatite fission-track analysis of seven intrusions located within the Permian-Triassic Siberian Traps Large Igneous Province (LIP): (1) alkaline-ultramafic central type plutons of Odikhincha, Yessey and Magan, (2) intrusions of Norilsk-1 and Kontay, (3) Padunsky sill, and (4) Kotuy dike. Additionally, we also present a set of new geochronological data for some of studied intrusions: (a) LA-ICPMS UPb apatite ages of the Odikhincha pluton (266 ± 29 Ma) and the Padunsky sill (241 ± 12); (b) RbSr ages from the Odikhincha (258.0 ± 0.6 Ma), Magan (242.8 ± 6.8 Ma) and Yessey (243.1 ± 2.7 Ma) plutons; and (c) 40Ar/39Ar mica ages from the Odikhincha (264.3 ± 3.0 Ma) and Magan (254.7 ± 3.1 Ma) plutons. Most of these intrusions, probably with the exception of the Odikhincha, were emplaced during the most voluminous phase of the Siberian Traps magmatism ca. 252–251 Ma, but their AFT ages are distributed from 207 ± 17 to 173 ± 13 Ma and much younger than Late Permian to Early Triassic isotopic ages from these and other Siberian Traps LIP intrusions. Available AFT, UPb, RbSr and 40Ar/39Ar data and time-temperature modeling has allowed us to create the first model of the post-Paleozoic tectono-thermal history of the Siberian Traps. After their emplacement ca. 251 Ma the studied rocks underwent a later phase of rapid cooling to below 120–60 °C during the time interval ~207–173 Ma and have remained near the surface until present. We propose this later cooling event is linked to exhumation associated with coeval Late Triassic-Early Jurassic large-scale uplift of the Siberian platform caused by collisional processes at its periphery. Our new results also indicate that at least a 1–2 km thickness of Siberian Traps lavas have been removed by erosion in the north of the Siberian platform since eruption, implying the total volume of the Permian-Triassic lavas was much greater than that currently preserved today.

Environmental crises at the Permian–Triassic mass extinction

The link between the Permian–Triassic mass extinction (252 million years ago) and the emplacement of the Siberian Traps Large Igneous Province (STLIP) was first proposed in the 1990s. However, the complex cascade of volcanically driven environmental and biological events that led to the largest known extinction remains challenging to reconstruct. In this Review, we critically evaluate the geological evidence and discuss the current hypotheses surrounding the kill mechanisms of the Permian–Triassic mass extinction. The initial extrusive and pyroclastic phase of STLIP volcanism was coeval with a widespread crisis of terrestrial biota and increased stress on marine animal species at high northern latitudes. The terrestrial ecological disturbance probably started 60–370 thousand years before that in the ocean, indicating different response times of terrestrial and marine ecosystems to the Siberian Traps eruptions, and was related to increased seasonality, ozone depletion and acid rain, the effects of which could have lasted more than 1 million years. The mainly intrusive STLIP phase that followed is linked with the final collapse of terrestrial ecosystems and the rapid (around 60 thousand years) extinction of 81–94% of marine species, potentially related to a combination of global warming, anoxia and ocean acidification. Nevertheless, the ultimate reasons for the exceptional severity of the Permian–Triassic mass extinction remain debated. Improved geochronology (especially of terrestrial records and STLIP products), tighter ecological constraints and higher-resolution Earth system modelling are needed to resolve the causal relations between volcanism, environmental perturbations and the patterns of ecosystem collapse. At the Permian–Triassic boundary (252 million years ago), a series of environmental crises triggered by the Siberian Traps eruptions caused the extinction of 81–94% of marine species and 70% of terrestrial vertebrate families. This Review discusses the relationships between volcanism, environmental perturbations and ecosystem collapse at the Permian–Triassic boundary.

Felsic volcanism as a factor driving the end-Permian mass extinction.

The Siberian Traps large igneous province (STLIP) is commonly invoked as the primary driver of global environmental changes that triggered the end-Permian mass extinction (EPME). Here, we explore the contributions of coeval felsic volcanism to end-Permian environmental changes. We report evidence of extreme Cu enrichment in the EPME interval in South China. The enrichment is associated with an increase in the light Cu isotope, melt inclusions rich in copper and sulfides, and Hg concentration spikes. The Cu and Hg elemental and isotopic signatures can be linked to S-rich vapor produced by felsic volcanism. We use these previously unknown geochemical data to estimate volcanic SO2 injections and argue that this volcanism would have produced several degrees of rapid cooling before or coincident with the more protracted global warming. Large-scale eruptions near the South China block synchronous with the EPME strengthen the case that the STLIP may not have been the sole trigger.

Latest Permian–Triassic magmatism of the Taimyr Peninsula: New evidence for a connection to the Siberian Traps large igneous province

Abstract This study presents new whole rock major and trace element, Sr-Nd isotopic, petrographic, and geochronologic data for seven latest Permian (Changhsingian)–Late Triassic (Carnian) granitoid intrusions of the northwestern and northeastern Taimyr Peninsula in the Russian High Arctic. U-Pb zircon ages, obtained using secondary ion mass spectrometry (SIMS), sensitive high-resolution ion microprobe (SHRIMP), and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), define the crystallization age of the Taimyr intrusions studied as ranging from ca. 253 Ma to 228 Ma, which suggests two magmatic pulses of latest Permian–Early Triassic and Middle–Late Triassic age. Ar-Ar dating of biotite and amphibole indicate rapid cooling of the intrusions studied, but Ar-Ar ages of several samples were reset by secondary heating and hydrothermal activity induced by the Middle–Late Triassic magmatic pulse. Petrographic data distinguish two groups of granites: syenite–monzonites and granites–granodiorites. Sr-Nd isotopic data, obtained from the same intrusions, show a variation of initial (87Sr/86Sr)i ratios between 0.70377 and 0.70607, and εNd(t) values range between –6.9 and 1.2. We propose that the geochemical and isotopic compositions of the Late Permian–Triassic Taimyr granites record the existence of a magma mush zone that was generated by the two pulses of Siberian Traps large igneous province (LIP) magmatism.