Decrease In Shrinkage Research Articles

Applying chia seeds to improve the structural characteristics and nutrient composition of whipped candies

The object of this study is the technology of whipped candies with the introduction of whole and crushed chia seeds. Whole seeds were added at the stage of whipping the protein (% of the mass of dry egg albumin), and crushed seeds were added during the preparation of the milk-fat mixture (% of the mass of fat). The introduction of the additive solves the task of improving the structural characteristics of whipped candy masses and candies made on their basis. The issue of improving the nutritional composition of products has also been resolved. It was established that the introduction of whole chia seeds (up to 50 % of the mass of dry egg albumin included) contributes to the improvement of the foaming of brewed protein masses during whipping and to the reduction of their density. Increasing the dosage of chia causes the deterioration of these indicators. In view of this, it is recommended to limit its dosage to 50 % of the weight of dry albumin when adding whole seeds to the brewed whipped protein mass. It was noted that when adding whole/crushed chia seeds in the amount of (50/40) %, (50/50) %, and (50/60) % of the mass of dry albumin/fat, the viscosity of unstructured candy masses increases slightly. Due to this, the duration of their structure formation is reduced, and the rate of shrinkage decreases. Whipped candies from such masses, compared to the control ones, are characterized by higher values of adhesion, strength, and density indicators. However, the visual deterioration of the porosity and compaction of the structure is characteristic only of the samples with the content of whole/crushed seeds (50/60) %. That is, the rational dosage of whole/crushed chia seeds is (50/50) % of the weight of dry albumin/fat. Such products are characterized by improved nutrient composition. In particular, the content of proteins and non-starch polysaccharides increases, the balance of fats improves, and the content of micronutrients such as polyphenols, minerals, and vitamins increases significantly

The Effects of CaO and MgO on Thermal, Mechanical and Optical Properties of Porcelain Tiles by Utilizing Blast Furnace Slag

In this study, the Blast Furnace Slag (BFS) of Zonguldak Eregli Iron and Steel Factories was used as a recycling raw material for the porcelain tile samples. A kind of clay with high MgO content was also used in the porcelain tile recipes. Maximum 10% of BFS was used instead of Na-feldspar. Sintering temperature for all samples was 1205°C for 50 minutes in the industrial roller kiln. Technological properties such as shrinkage, water absorption, colour measurement, and flexural strength were investigated as well as sintering properties and microstructures of the green and the sintered samples. As a result of the study, the addition of BFS did not adversely affect the technical properties of porcelain tile bodies. Particularly, the addition of BFS up to 3% contributed to an increase in flexural strength, and whiteness values of all samples increased because of the formation of anorthite and diopside compared to the reference body. The phase transformations and crystal formations such as anorthite and diopside resulted in a decrease in the firing shrinkage. Although the anorthite formation and diopside formation in the investigated samples had an adverse effect on condensation, it was found that they showed similar sintering behaviours compared to the reference body. This study showed that an industrial waste material can be converted into an environmentally friendly raw material that can create added value and provide energy efficiency.

Properties and hydration mechanism of slow-setting and expansive cement based on CFB ash and slag

Aiming at the problems of long construction time and easy shrinkage cracking of pavement base, the slow-setting and expansive cement (SEC) was prepared using circulating fluidized bed ash and slag (CFBA and CFBS), S95 ground granulated blast furnace slag (GGBFS), and silica fume (SF) as supplementary cementitious material in this paper. By adjusting the content of supplementary cementitious material, the ratio of ash and slag, the performance of SEC was evaluated by the indexes of water consumption of standard consistency, setting time, flexural and compressive strength. The hydration products of mortar samples and the influence mechanism were studied by means of XRD, TG-DTG, FTIR, and SEM-EDS. The results showed that when the SF content was 6 %, the compressive strength of the mortar specimens reached its maximum (35.19 MPa) at 28 days, which increased by 23.04 % compared to the control group. Meanwhile, the free calcium oxide and gypsum in CFBA reacted under alkaline conditions to form ettringite (AFt) and C-S-H gel, which caused the volume expansion of cement and led to a decrease in shrinkage within the cement system. SEC has higher mechanical properties and much smaller shrinkage cracks than ordinary cement. Therefore, replacing part of the cement by solid waste such as CFBS to prepare SEC to compensate for the shrinkage of the pavement base is an effective way to reduce pavement cracking.

A dual-functional α-diketone-based disulfide monomer for visible LED photopolymerization: Mitigating volumetric shrinkage and triggering polymerization

A α-diketone-based disulfide monomer (OHS), which serves the function of both volumetric shrinkage decreases and photopolymerization initiation under the irradiation of 405 light-emitting diode (LED) was designed and synthesized. The photochemical and photoinitiating performances were study by ultraviolet–visible spectrophotometer, electron spin resonance spin trapping (ESR-ST) experiments and real-time infrared spectrometer (FTIR). Despite OHS exhibits weak absorption at approximately 405 nm, OHS can effectively produce aromatic sulfur radicals to induce photopolymerization of itself and the bisphenol A glycerolate dimethacrylate (Bis-GMA)/triethylene glycol dimethacrylate (TEGDMA) photopolymerizable system under 405 nm LED exposure. With increasing OHS addition, the final double bond conversion and maximum polymerization rate of the Bis-GMA/TEGDMA system improved, reaching up to 86.0% and 2.33% s-1, respectively. Importantly, OHS significantly reduces the volumetric shrinkage ratio of the Bis-GMA/TEGDMA photopolymerizable system, with the volumetric shrinkage ratio (5.01%) of the system containing 5% OHS declining by almost 50% compared to that (8.51%) of the control system without OHS. This reduction is attributed to reversible characteristic of the disulphide bonds and intermolecular hydrogen bondings. Furthermore, OHS has little influence on the gelation ratio, thermostability, and frictional resistance of the cured film.

Sea/coral sand in marine engineered geopolymer composites: Engineering, mechanical, and microstructure properties

AbstractUtilizing marine waste and resources for eco‐friendly building materials is pivotal in promoting sustainable development in island and coastal construction industries. Among the potential alternatives, coral sand as well as sea sand stands out as a promising material. This research seeks to explore the potential of coral/sea sand as a fine aggregate in the creation of environmentally sustainable marine engineered geopolymer composites. An assessment was conducted on the influence of varying proportions of coral sand, meant as a substitute for sea sand, on the flowability, drying shrinkage, mechanical properties, and microstructure of the marine engineered geopolymer composites. The findings indicate that as coral sand replaces sea sand, flowability and drying shrinkage decrease, while compressive strength experiences an initial rise followed by a decline. Encouragingly, a combination of coral and sea sands enhances tensile ductility. Overall, a 20 wt.% coral sand mixture yields optimal results, with the compressive strength is 54.4 Mpa and the tensile strain capacity is 2.397% after 28 days. Moreover, microscopic tests reveal changes in hydration products and pore structure. Our research delves into the potential of coral/sea sand as a fine aggregate in the creation of environmentally sustainable marine engineered geopolymer composites.

Effect of Superabsorbent Polymers and Presoaked Coarse Recycled Shale Lightweight Aggregates on Relative Humidity Development in Early-Age Concrete

Self-desiccation-induced shrinkage may result in cracking at an early age, which is averse to the durability of concrete. Internal curing (IC) agents, such as superabsorbent polymers (SAP), are normally used for moisture regulation and shrinkage reduction. In addition, the make-up of recycled shale lightweight aggregate (RSLA) results in a good absorbing capacity, which makes it a potential candidate for IC. In this paper, the synergistic effect of SAP and RSLA on the relative humidity (RH) variation in early-age concrete under sealed conditions is investigated experimentally in terms of the setting time, relative humidity, and autogenous shrinkage. The results indicate that adding SAP and presoaked RSLA can significantly postpone the initial and final setting times. The initial setting time of RSLA30 and SAP06 is delayed by 127 and 171 min, respectively, compared to the benchmark mixture. In addition, increasing the amounts of SAP and presoaked RSLA can effectively extend the duration of the vapour-saturated stage, reducing the decrease in RH and autogenous shrinkage at 28 days. When the RSLA dosage increases from 0 to 10%, 20%, and 30%, the duration of the vapour-saturated stage is extended by 2, 9.4, and 26 days, respectively. Moreover, due to different water desorption behaviours, more IC water released by RSLA during the initial stage can slow the water release of SAP and lead to a higher RH level at 28 days.

3D‐Printed Porous Organic Cages for Gas Filtration: Fabrication and Flow Simulations

AbstractPorous organic cages (POCs) are a class of emerging porous materials with high porosity and selectivity for gas adsorption and separation. As a representative of first‐generation POCs, the cage molecule CC3, has huge potential for separating noble gases and volatile organic compounds (VOCs). 3D printing CC3 using direct ink writing (DIW) offers significant advantages to build complex structures. Through rational design, formulations that are both printable and functional are achieved. Optimised formulations have the elasto‐visco‐plastic behavior required while retaining the functional properties of the cages. The characterization of printed parts evidence that the CC3 structure and adsorption capacity are well preserved. BET surface areas vary with CC3 concentration and can reach up to ≈249 m2 g−1 for 70 wt% CC3. However, high CC3 content leads to a decrease in shrinkage, higher porosity, and low compressive strength ≈0.7 MPa. Computational fluid dynamics (CFD) is used to investigate the gas flow behavior through grid‐type structures with tailored geometric parameters. The results reveal that changing the offset distance and porosity manipulates the flow path, velocity distribution, and pressure drop. This work provides a pathway to design and fabricate structures with multi‐scale porosity that can be widely used for other functional materials and applications.

Sintering Behavior and Thermal Properties of Cu-Graphite Materials by a Spark Plasma Sintering Method

The use of heat dissipation materials in various field such as power semiconductor device, LED and microelectronic system. Therefore, there is a need for heat dissipation materials using copper (Cu) and graphite (Gr). These materials have high thermal conductivity. In particular, graphite has high thermal stability with a low coefficient of thermal expansion. This study was conducted to enhance the thermal properties of Cu for use in heat dissipation materials, using a spark plasma sintering method. Cu-Gr powders were mixed by a shaking mixer and fabricated with volume fractions of 7:3, 6:4, 5:5, 4:6 and 3:7. The spark plasma sintering method is a uniaxial pressurization process, which can control the direction of Gr. The Cu-Gr powders were sintered at a temperature of 850 oC at a heating rate of 30 oC/min and a sintering pressure of 40MPa. Consequently, as the Gr contents were increased, the relative densities of the Cu-Gr composites decreased from 99.25 to 94.85%. Gr has high resistance to high-temperature deformation, which contributed to a decrease in shrinkage and relative density. The highest thermal conductivity was measured at 539.7 W/ m·K for a Cu-Gr volume ratio of 5:5. The thermal conductivity of the directionally controlled Gr was measured to be about 20-30 W/m·K higher than the uncontrolled sample. Furthermore, the TDP (Thermal distortion parameter), for which a lower value indicates better thermal stability, was systematically investigated.

Microstructure and durability of rapid repair mortar with self-emulsifying waterborne epoxy polymer

Due to the low hydration rate of ordinary Portland cement (OPC), it cannot meet the requirements of rapid repair, especially in negative temperature environments. Simultaneously, facing the harsh marine environment, repair materials urgently need high durability. In this paper, a self-emulsifying waterborne epoxy polymer (WEP) suitable for cement systems was combined with sulfoaluminate cement (SAC) to prepare repair materials. The effect of the WEP on the development of microstructure, auto-drying shrinkage and durability was investigated by nuclear magnetic resonance, XRD and SEM methods. Results showed that a continuous interpenetration polymer network (IPN) was intricately woven within the multiphase composites, using the macromolecular network structure formed by —OH groups in WEP and Ca2+ and Al3+ in cement as a bridge. The resistance to chloride migration and water absorption exhibited an increase followed by a decrease. In particular, the resistance to chloride migration was improved by 45 %. Similar trends were observed for the carbonation resistance. Due to the lower porosity and capillary pressure caused by IPN, leading to a decrease in auto-drying shrinkage. Nevertheless, the larger percentage of capillary pores in a mortar with a P/C of 15 % increased the auto-drying shrinkage. The WEP decreased the availability of pores of critical diameter (14 nm) of mortar exposed to water freezing, leading to an increase in the freeze-thaw resistance. The change in P/C hardly affected the resistance to sulfate attack. Under −10°C, at 2 hours, the compressive strength of CSA-based mortar satisfied the load requirements for vehicular operations. This research provides theoretical and practical implications for the repair work of large-scale projects serving in harsh environments.

ZSM-5@ceramic foam composite catalyst derived from spent bleaching clay for continuous pyrolysis of waste oil to produce monocyclic aromatic hydrocarbons

Spent bleaching clay, a solid waste generated during the refining process of vegetable oils, lacks an efficient treatment solution. In this study, spent bleaching clay was innovatively employed to fabricate ceramic foams. The thermal stability analysis, microstructure, and crystal phase composition of the ceramic foams were characterized by TG-DSC, SEM, and XRD. An investigation into the influence of Al2O3 content on the ceramic foams was conducted. Results showed that, as the Al2O3 content increased from 15 wt% to 30 wt%, there was a noticeable decrease in bulk density and linear shrinkage, accompanied by an increase in compressive strength. Additionally, the ceramic foams were used as catalyst supports, to synthesize ZSM-5@ceramic foam composite catalysts for pyrolysis of waste oil. The open pores of the ZSCF catalyst not only reduced diffusion path length but also facilitated the exposure of more acid sites, thereby increasing the utilization efficiency of ZSM-5 zeolite. This, in turn, engendered a significant enhancement in monocyclic aromatic hydrocarbons content from 39.15 % (ZSM-5 powder catalyst) to 78.96 %. Besides, a larger support pore size and a thicker ZSM-5 zeolite coating layer led to an increase in monocyclic aromatic hydrocarbons content. As the time on stream was extended to 56 min, the monocyclic aromatic hydrocarbon content obtained with the composite catalyst remained 12.41 % higher than that of the ZSM-5 powder catalyst. These findings validate the potential of the composite catalyst. In essence, this study advances the utilization of spent bleaching clay and introduces a novel concept for ceramic foam fabrication. Furthermore, it contributes to the scaling up of catalytic pyrolysis technology.

Tunable yellow and orange emission of Ce, Eu doped multilayered YSZ/YAG ceramics

Eu3+ and Ce3+ doped YSZ/YAG multilayered luminescent ceramics were consolidated by the Spark Plasma Sintering (SPS) method. The optimal modes were explored during the SPS process for functionally graded ceramics (FGCs) structure fabrication. The introduction of rare-earth (RE) oxides into FGCs with different concentration leads to a shift in the temperature range of intense shrinkage to lower temperatures from 1280 °C to 1100–1190 °C and a decrease in the relative shrinkage during the SPS process by 3–6%. Morphological, optical and luminescent properties have been investigated in detail for fabricated YSZ/YAG ceramics with different arrangement of the layers. The nature of luminescent centers in FGCs was studied using time-resolved cathodoluminescent and steady-state photoluminescent (PL) spectroscopy. The PL efficiency of YSZ/YAG ceramics were analyzed and optimal compositions of the FGCs layers were determined. The YSZ/YAG novel functional multilayered ceramics could be promising candidate for light-emitting devices application.

Multicomponent cementitious materials optimization, characteristics investigation and reinforcement mechanism analysis of high-performance concrete with full aeolian sand

Aiming at alleviating the shortage issue of high-quality aggregates in deserts, this study developed an eco-friendly concrete using full aeolian sand (hereafter named FA-HPC). Fly ash (FA), silica fume (SF), and slag powder (SP) are introduced into FA-HPC to optimize the performance by single or multicomponent mixing, including fluidity, strength, dry shrinkage, and chloride resistance. Moreover, the reinforcement mechanism is revealed from a microscopic perspective. The results show that FA increases the fluidity of FA-HPC while continuously reducing its drying shrinkage and strength with the dosage increase, presenting a 42.4 % reduction in 3 d compressive strength. On the contrary, SF exhibits a convex parabolic trend in fluidity and strength, achieving a 55.7 % strength improvement at a 10 % dosage, with a gradual increase in dry shrinkage. Additionally, the effect of SP on the performances is relatively small, including the increase in fluidity and strength, and a decrease in shrinkage. In the binary mixing system of FA and SF, an increase in the percentage of SF reduces fluidity and shrinkage resistance. Moreover, a 52.3 % increase in strength can be achieved at an appropriate substitution amount (30 %) and ratio (3:2). Furthermore, triple mixing system of 14.4 % FA, 9.6 % SF and 20 % SP obtains the optimized performance, especially achieving an improvement of 95.5 % in chloride resistance. Additionally, the microstructure and absorption peak indicate that the triple mixing system presents a fierce volcanic ash reaction endowing FA-HPC with improved pore structure and compactness. This research optimized the cementitious material system of FA-HPC and provided technical strategies for engineering construction in desert areas.

In-situ shrinkage measurement of alkali-activated materials using focused ion beam combined with environmental scanning electron microscopy

Drying shrinkage of alkali-activated slag (AAS) has gained significant attention since the volumetric instability of this material can generate premature cracking and degrade the long-term durability of concrete structures. The unique shrinkage behavior of AAS originates mainly from the particular characteristics of its main hydrated products. However, few studies have even at-tempted to investigate the shrinkage behavior of hydrated products in AAS materials. This paper presented a new method of investigating drying shrinkage behavior of AAS using focused ion beam (FIB) combined with environmental scanning electron microscopy (ESEM). This innovative experimental method allowed the in-situ measurement of phase-specific shrinkage. The results showed FIB/ESEM technique can be successfully implemented to cementitious material to prepare phase-specific samples. Furthermore, object-oriented finite element method (OOF2) has been utilized to compute the shrinkage behavior of AAS concrete using a proposed multi-scale scheme. The computations can be made at multi-scales which highlight the effect of hydration products on shrinkage behaviors. OOF2 calculation at the micro-length scale predicted an increase in the shrinkage due to the well-dispersed hydration products inside the matrix. At larger scale, the decrease in the overall shrinkage is related to the extremely low shrinkage value by aggregates. The findings reveal OOF2 offers the capability to accurately measure local stress and strain distribution within heterogeneous materials, a feature notably absent in conventional numerical homogenization approaches. The importance of this benefit is highlighted particularly in the context of free-restrained shrinkage prediction, as conventional homogenization methods fail to account for stress.

Properties of Un-Torrefied and Torrefied Poplar Plywood (PW) and Medium-Density Fiberboard (MDF)

In a context where there is an increasing need for thermal treatments of wooden products, the current research contributes a description of the torrefaction treatment of two of the composite wood materials available on the international market. The present paper presents the importance of the torrefaction process for poplar plywood and medium-density fiberboard. In this paper, the positive aspects of the torrefaction process (decrease in water absorption, thickness swelling and shrinkage, and color) but also the negative aspects of mechanical resistance to static bending are presented. Poplar plywood (PW) and medium-density fiberboard (MDF) panels, with the initial dimensions of 2000 × 1250 mm, were used. From these, 300 × 300 mm samples were cut and torrefied using two different temperatures (170 and 190 °C) and two different periods (for 1 and 2 h). After the treatment, the samples were cut in different sizes (as necessary for each type of evaluation method) from different zones of the panels and used to evaluate the water absorption and thickness swelling, to determine their modulus of rupture, roughness, and color changes. The obtained results emphasize that the mass loses increase at high temperature as the main disadvantageous characteristics of torrefaction. Also, while the calorific power increases with the increase in the parameters of the torrefaction regime, the hygroscopicity and some mechanical properties of the material simultaneously decrease.

Integration of monitoring indicators for self-sensing alkali activated cementitious materials: From electrical signals - resistivity to autogenous shrinkage

The chemical shrinkage and autogenous shrinkage of alkali-activated materials (AAMs) are usually more significant than that of ordinary Portland cement (OPC). Therefore, both searching for efficient methods to reduce shrinkage and exploring the shrinkage mechanism of AAMs are of great significance in promoting the application of AAMs. In this paper, metakaolin is used to reduce the chemical shrinkage and autogenous shrinkage of AAMs, while an innovative resistivity measurement is used to concretize the electrical signal of AAMs and the relationship between autogenous shrinkage and resistivity was explored. The early resistivity and heat of hydration curves of AAMs can be divided into five stages with high similarity, demonstrating the feasibility of indirectly quantifying the autogenous shrinkage and chemical shrinkage by resistivity. The results of TG-IR, MIP, and heat of hydration prove that the early reaction rate of AAMs decreases with the increase of metakaolin content, which further leads to the decrease of early chemical shrinkage and autogenous shrinkage. The reduction of autogenous shrinkage reached the maximum (49%) when the metakaolin content was 50%. A mathematical model between autogenous shrinkage and resistivity was established, which means that the resistivity of self-sensing materials can be used as an index to evaluate the early autogenous shrinkage of AAMs.

Prediction of Restrained Shrinkage of New-to-old Concrete Interface

The focus of this study is on the shrinkage differences between new and old concrete, which can cause cracks at the bonding surface of the interface. The effects of various factors on shrinkage, such as the content of shrinkage reducing admixtures (SRA) the content of basalt fibers (BF) and the roughness at the new-to-old concrete interface (RI) are also examined. In this research, nine groups old-new concrete composite specimens were tested for shrinkage to gather experimental data. The restrained shrinkage mechanical model (RSMM) was deduced, and the restrained shrinkage model based on grey correlation analysis (RMGC) was proposed. The effectiveness and convenience of both prediction methods were evaluated by comparing their results to the experimental data. It was determined that the RMGC was more effective and convenient. Additionally, the research found that as the content of SRA and BF increases, shrinkage decreases. The effect of SRA was found to be more significant. As RI increases, shrinkage undergoes an initial increase and then decreases. The study can be used to inform the design and construction of structures that use both new and old concrete.

ИЗУЧЕНИЕ ВЛИЯНИЯ ПЛОДООВОЩНОЙ СМЕСИ НА КАЧЕСТВО ХЛЕБОБУЛОЧНЫХ ИЗДЕЛИЙ

This article presents the results of a study of the possibility of using cabbage and applesauce in the produc-tion of bakery products. For research, various dosages of cabbage (3, 6, 9, 12%) and apple (5; 7.5; 10; 12.5%) puree were selected. Studies have been carried out on the organoleptic and physico-chemical parame-ters of raw materials, semi-finished products and finished products. In the experimental part, the influence of cabbage and apple puree on the properties of dough and finished products (a bun made from premium wheat flour) was studied. An increase in acidity and dough volume was revealed when both cabbage and apple pu-ree were added. There is an increase in volume yield and porosity of finished products. The mass fraction of fiber in products increases, shrinkage decreases. As a result of the research, the optimal dosage of cabbage (6%) and apple (7.5%) puree was identified, a fruit and vegetable mixture was compiled and introduced into the bun recipe. The calculation of the chemical composition, calorie content and nutritional value of the con-trol and optimal sample of the bun was carried out. According to the results of calculations, it was found that with the introduction of fruit and vegetable mixture into the recipe of the bun, the content of indigestible car-bohydrates increases by 2 times, the amount of minerals increases slightly, the caloric content of the product decreases (by 6%), as well as the amount of fat, starch, dextrins. Keywords: white cabbage puree, apple puree, bakery products.

Evolution of Durability and Mechanical Behaviour of Mud Mortar Stabilized with Oil Shale Ash, Lime, and Cement

The investigation into earthen construction technologies and materials is now acknowledged as a crucial area requiring further research. Earthen mortars are prevalent in both modern and traditional construction due to the abundance of earth material, their favorable thermal properties, and their low embodied energy. The objective of this study is to support the use of natural materials collected from north Jordan to enhance the mechanical properties and durability of mud mortar. The local soil was stabilized using Oil Shale Ash (OSA), Ordinary Portland Cement (OPC), and lime for producing mud mortar. Particle size analysis, plastic limit, liquid limit, XRD, and XRF were applied to assess the geotechnical characterization and mineral composition of the earthen stabilizers and local soil. In order to examine the mechanical properties (specifically compressive strength) and durability characteristics (such as water absorption and shrinkage) of mud mortar, a total of 8 mixtures were prepared. One of these mixtures served as a control, while the others were created by substituting soil with varying proportions of OSA, cement, and lime. The results show that the mud mortar contained 10% OSA and 10% cement, which exhibited the highest compressive strength. Moreover, an increase in the proportion of OSA in the soil led to a decrease in absorption and linear shrinkage, indicating that OSA is an effective stabilizing agent for mud mortar. Doi: 10.28991/CEJ-2023-09-09-06 Full Text: PDF

Early Shrinkage Modeling of Complex Internally Confined Concrete Based on Capillary Tension Theory

This paper evaluates the shrinkage performance of concrete under complex internal constraint environments comprising steel plates, studs, and reinforcement to investigate their respective influence laws on the shrinkage performance of concrete. An early shrinkage model of concrete under complex internal constraints was established based on the theory of capillary tension, and the effects of steel plate, nails, and steel reinforcement on the shrinkage performance of concrete were theoretically analyzed. Six sets of concrete-constrained shrinkage tests and pore structure tests were then performed under different internal constraint conditions with the steel plate thickness, reinforcement diameter, and stud-related parameters (stud diameter, height, and spacing) as research variables. The test results demonstrate that the pore structure of concrete increases with the increase in the constraint coefficient, and that the increase in the pore structure will cause a decrease in the capillary pore stress, which is the driving force of concrete shrinkage. Its decrease will inevitably lead to a decrease in concrete shrinkage. By comparing the calculated values of the shrinkage model with the measured values, it is found that the average value of the prediction error is less than 15%, which reveals that the predicted values of shrinkage are in good agreement with the measured values and proves that the model can effectively predict the shrinkage of concrete that is restrained by steel plates, pins, and reinforcing bars.

Stabilization of expansive soils using nontraditional chemical additives

The aim of this study is to analyze the stabilization effects of an expansive soil using three different nontraditional chemical additives, in this case: white cement and nano-silica as admixture, waste granite dust, and a new liquid polymer soil stabilizer (i.e. liquid granite). The engineering properties such as soil consistency, linear shrinkage and soil swelling behaviour of a bentonite treated with these stabilizing agents were investigated. Furthermore, the bearing capacity of the stabilized bentonite was analyzed through the California Bearing Ratio test (BCR) and a laboratory foundation model. The experimental program consisted of three series of tests. In the first series, the tests were performed on an expansive soil reinforced with 2%, 4%, 8%, and 10% of white cement combined with 2% of nano-silica. Another series of tests consisted of samples mixed with different percentages of granite powder (5%, 10%, 15%, and 20%). In the third series, liquid granite as a soil stabilizer was blended with soil specimens at various concentrations (1%, 2%, 3%, and 4%). For all admixtures, the results showed a marked improvement in soil consistency, an important decrease in linear shrinkage, a considerable reduction on the expansion index, and a significant improvement of CBR and soil bearing capacity. Moreover, two empirical correlations were proposed between the bearing capacity parameters (i.e. CBR and Improvement factor) and the expansion index.