Geochemical analyses are difficult because all samples have an unknown composition. As most geoscience programs do not teach “techniques” courses, teaching analytical technique and critical data analysis becomes a priority during the undergraduate research experience. The analysis of rivers is an excellent way to teach geochemical techniques because of the relative ease of sample collection and speed of sample analysis. The sample collection and processing steps, however, are subject to a variety of mistakes that affect sample integrity.This paper focuses on the potential sources of sample contamination during the sampling, filtering, and bottle cleaning processes, and reviews methods to reduce and detect contamination. Training at the beginning of a research program is helpful, but during a ten-week or shorter summer research experience, training time is of necessity short and much learning occurs in the actual research environment. An emphasis on contamination sources and the one million times dilution approach to cleaning will help avoid sample contamination. The cleaning process, though a critical analytical technique, is a tedious, dull, and seemingly menial task. As a result, faculty members engaged in undergraduate research experiences face a difficult task when teaching the need for cleanliness in the laboratory and field. The participating students, however, learn an important lesson of the need for “mindfulness” in the research process.