High-entropy alloys (HEAs), due to their exceptional mechanical properties, thermal stability, and corrosion resistance, have garnered significant attention in the field of materials science. This paper reviews the primary preparation methods of HEAs, such as carbothermal shock, electrochemical synthesis, and spark plasma sintering, and analyzes the characteristics of these methods in terms of compositional control and synthesis efficiency. Through various characterization techniques, researchers can gain an in-depth understanding of the microstructure and elemental distribution of HEAs, thereby enhancing their performance in applications such as catalysis. Although substantial progress has been made in HEA research, challenges such as phase separation and equipment costs continue to hinder large-scale industrial applications. Future studies should focus on improving the controllability and environmental sustainability of preparation processes to advance the widespread application of HEAs in energy, catalysis, and electronics.
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