The Qinling Mountains in Central China mark a gigantic composite orogenic belt with a complex tectonic evolution involving multiple phases of rifting and convergence. This belt separates the North China and South China Blocks and consists of the South and North Qinling terranes separated by the Shangdan suture. The suture is marked by the Grenvillian Songshugou ophiolite along the southern margin of the North Qinling terrane, which is key to understanding the Proterozoic tectonic evolution of the belt. The ophiolite consists of highly metamorphosed ultramafic and mafic rocks. Three groups of meta-basalts are present: group 1 rocks are LREE depleted and have a MORB compositional affinity. Their low Ta/Yb ratios (<0.1) are consistent with high degrees of partial melting of a depleted asthenospheric mantle. Rocks of group 2 have higher TiO 2 (1.63–2.08 wt%) and Ta/Yb ratios (>0.12), and display slight enrichment of LREE, suggesting that the original magmas were derived from a depleted mantle source mixed with some enriched material. Samples from group 3 are enriched in LREE and other incompatible elements (Ti, Zr, Ta, Nb), suggesting derivation from an enriched mantle source, possibly a plume. All the basalts have high εNd( t) (+4.2 to +6.9), variable εSr( t) and high 207Pb/ 204Pb and 208Pb/ 204Pb ratios for given 206Pb/ 204Pb ratios. These characteristics are compatible with formation at a mid-ocean ridge system above an anomalous Dupal mantle region. The mafic rocks have a Sm–Nd whole-rock isochron age of 1030 ± 46 Ma. The Songshugou ophiolite was emplaced onto the southern margin of the North Qinling terrane, an active continental margin from the Meso-Proterozoic to Neo-Proterozoic.