Shallow Reservoir Research Articles

An Amphibole Perspective on the Recent Magmatic Evolution of Mount St. Helens

Abstract Compositional variations of amphibole stratigraphically recovered from multiple eruptions at a given volcano have a great potential to archive long-term magmatic processes in its crustal plumbing system. Calcic amphibole is a ubiquitous yet chemically and texturally diverse mineral at Mount St. Helens (MSH), where it occurs in dacites and in co-magmatic enclaves throughout the Spirit Lake stage (last ~4000 years of eruptive history). It forms three populations with distinct geochemical trends in key major and trace elements, which are subdivided into a high-Al (11–14.5 wt% Al2O3), a medium-Al (10–12.5 wt% Al2O3), and a low-Al (7.5–10 wt% Al2O3) amphibole population. The oldest investigated tephra record (Smith Creek period, 3900–3300 years BP) yields a bimodal amphibole distribution in which lower-crustal, high-Al amphibole cores (crystallized dominantly from basaltic andesite to andesite melts) and upper-crustal, low-Al amphibole rims (crystallized from rhyolitic melt) document occasional recharge of a shallow silicic mush by a more mafic melt from a lower-crustal reservoir. The sudden appearance of medium-Al amphiboles enriched in incompatible trace elements in eruptive periods younger than 2900 years BP is associated with a change in reservoir conditions toward hotter and drier magmas, which indicates recharge of the shallow silicic reservoir by basaltic melt enriched in incompatible elements. Deep-crystallizing, high-Al amphibole, however, appears mostly unaffected by such incompatible-element-enriched basaltic recharge, suggesting that these basalts bypass the lower crustal reservoir. This could be the result of the eastward offset position of the lower crustal reservoir relative to the upper crustal storage zone underneath the MSH edifice. Amphibole has proven to be a sensitive geochemical archive for uncovering storage conditions of magmas at MSH. In agreement with geophysical observations, storage and differentiation have occurred in two main zones: an upper crustal and lower crustal reservoir (the lower one being chemically less evolved). The upper crustal silicic reservoir, offset to the west of the lower crustal reservoir, has captured compositionally unusual mafic recharge (drier, hotter, and enriched in incompatible trace elements in comparison to the typical parental magmas in the region), resulting in an increased chemical diversity of amphiboles and their carrier intermediate magmas, in the last ~3000 years of MSH’s volcanic record.

New data on the Pleistocene history of the Aral Sea-Lake

A 23.5 m deep borehole was drilled on the dried bed of the Aral Sea 9 km south of the former Barsakelmes Island. At a depth of 21.3 m, the borehole penetrated Paleogene bedrock. In the interval 21.3 - 15.2 m the conditions of a shallow freshwater reservoir at a considerable distance from the flowing rivers (deltaic channels of the Syr Darya River) - the first phase of filling of the Aral Basin with river water - were reconstructed. It has been preliminary attributed by three 14C AMS dates to the time about 23-25 thousand years BP. Above 15.2 m of the section the conditions become even more shallow, starting from 12.0 m of the section - brackish-water. The upper 10.5 m of the section correlates with the sediments of the modern geological phase of the Aral Sea development studied in detail in the same area by Burr et al. (2019), the beginning of which was estimated at 17.6 thousand BP. The new data obtained indicate an earlier appearance of the modern Aral Sea, which originated as a shallow freshwater body.

Shallow and deep geothermal water sources identification in Unai geothermal field, Gujarat, India with applications of Magnetotelluric (MT)

The aim of this study is to conduct and examine the results of a Magnetotelluric (MT) survey in Unai, Gujarat, India for geothermal prospect identification. At Unai, the data was acquired, processed, and interpreted in the form of 2D and 3D MT surveys. Data were acquired at 56 stations in uniformly spaced profiles along the ENE-WSE direction (geological strike direction) with a station spacing of 2 km. Qualitative and quantitative data understanding has been done for geothermal prospect identification. Deep and shallow 1D and 2D models of electrical resistivity were made, which suggests the presence of a geothermal aquifer. This is corroborated by polar and skew tipper diagrams. The one-dimensional Occam models and two-dimensional conjugate gradient models confirm the presence of a low resistivity anomaly near the surface ranging from the depth of 100–700 m. This suggests the presence of a shallow geothermal zone. Apart from the shallow geothermal prospect, this study also delineates a deep conductive body which may be attributed to a matured geothermal reservoir. For a better understanding of the prospect geoelectrical cross sections are analysed from a depth of 10 m to 15 km. The MT cross-sections show the presence of geological features such as a series of faults. These faults form horst and graben in nature and may act as a good trap for the shallow reservoirs.

Perfoliate Leaf-Mimicking Plant Clips: A One Health Strategy to Address the Effects of Urbanization on Insects

The declining abundance of safe water sources for insects in urban areas is a wicked problem requiring urgent attention. Urbanization has transformed natural settings into environments marked by concrete and asphalt, leading to increased heat production, ecosystem degradation, and a reduction of natural water sources including perfoliate plant species whose leaves act as reservoirs. While the proposed initiative's primary aim is to address the challenge of water access for urban insects, a critical component of its scope includes an analysis of biophobia as a systemic contributing factor. Urbanization has been shown to disconnect humans from natural environments and non-human animals, creating feelings of disgust which is a common symptom of biophobia. In turn, humans often distance themselves further from natural stimuli, reducing their awareness of insects' needs. The proposed initiative involves the installation of perfoliate leaf-mimicking plant clips in the gardens of various households in Parkdale, Toronto. These novel clips would contain a shallow reservoir able to collect rain or garden water for consumption by insects. Insects present within these gardens would engage with the clip, bringing them closer to pollination targets. Providing safe and accessible water sources for insects in this manner would contribute to the well-being of humans, non-human animals, and the environment. This would be made possible by facilitating efficient pollen transfer and subsequent plant reproduction while simultaneously attempting to reduce biophobia, exposing humans to the beneficial roles of insects in their gardens.

Oilfield Reservoir Parameter Inversion Based on 2D Ground Deformation Measurements Acquired by a Time-Series MSBAS-InSAR Method

Time-series ground deformation monitoring and reservoir parameter inversion are crucial for the dynamic assessment of oilfield resources and sustainable exploitation in oilfields. As some of the regions with the richest oil reserves in China, the oilfield areas in the western Qaidam Basin were selected as a typical study area. Firstly, we used SAR images collected by the Sentinel-1A satellite from January 2021 to December 2022 and applied the multidimensional small baseline subset (MSBAS) method to obtain vertical and east–west deformation measurements. On this basis, a nonlinear Bayesian inversion method was applied to model the shallow reservoir in a series of complex deformation areas, based on a single-source model and a multi-source model, respectively. As a result, the ground deformation monitoring results obtained by long time-series InSAR clearly reflect the uneven ground deformation caused by the oil extraction and water injection operation processes. There was slight subsidence in the Huatugou oilfield, while significant uplift deformation occurred in the Ganchaigou oilfield and the Youshashan oilfield, with a maximum uplift rate of 48 mm/year. Further analysis indicated that the introduction of the 2D deformation field helps to improve the robustness of oilfield reservoir parameter inversion. Moreover, the dual-source model is more suitable than the single-source model for inverting reservoir parameters of complex deformation. This study not only fills the gap of InSAR deformation monitoring for the oilfields in the western Qaidam Basin but also provides a theoretical reference for the model and method selection of reservoir parameter inversion in other oilfields.

Geophysical imaging of the active magmatic intrusion and geothermal reservoir formation beneath the Corbetti prospect, Main Ethiopian Rift

SUMMARY Silicic volcanic complexes in the Main Ethiopian Rift (MER) system host long-lived shallow magma reservoirs that provide heat needed to drive geothermal systems. Some of these geothermal systems in Ethiopia appear to be suitable for green and sustainable electricity generation. One such prospect is located at the Corbetti volcanic complex near the city of Awassa. High-resolution imaging of the subsurface below Corbetti is of imminent importance, not only because of its geothermal potential, but also due to reported evidence for an ongoing magmatic intrusion. In this study, we present a new subsurface 3-D electrical conductivity model of Corbetti obtained through the inversion of 120 magnetotelluric stations. The model elucidates a magmatic system under Corbetti and reveals that it is linked to a magma ponding zone in the lower crust. Magma is transported through the crust and accumulates in a shallow reservoir in form of a magmatic mush at a depth of $\gtrapprox 4\, {\rm km b.s.l.}$ below the caldera. The imaged extent and depth of the shallow magma reservoir is in agreement with previous geodetic and gravimetric studies that proposed an ongoing magmatic intrusion. Interpreting our model with laboratory-based conductivity models for basaltic and rhyolitic melt compositions suggests that Corbetti is seemingly in a non-eruptible state with ∼6–16 vol. per cent basaltic melt in the lower crust and ∼20–35 vol. per cent rhyolitic melt in the upper crust. With these observations, Corbetti’s magmatic system shares common characteristics with volcanic complexes found in the central MER. Specifically, these volcanic complexes are transcrustal two-stage magmatic systems with magma storage in the lower and upper crust that supply heat for volcano-hosted high-temperature geothermal systems above them. According to the presented subsurface model, a cross-rift volcano-tectonic lineament exerts first-order controls on the magma emplacement and hydrothermal convection at Corbetti. Our study depicts hydrothermal convection pathways in unprecedented detail for this system and helps identify prospective regions for future geothermal exploration. 3-D imaging of both the Corbetti’s magmatic and associated geothermal systems provides key information for the quantitative evaluation of Corbetti’s geothermal energy potential and for the assessment of potential volcanic risks.

Long-lived shallow crustal magma reservoirs beneath Ulleung Island volcano (South Korea) and their rejuvenation recorded in zircon

The microanalytical data obtained from zircons collected on Ulleung Island, an emergent peak of a Quaternary alkaline magma system in the southwestern East Sea (Sea of Japan) back-arc basin, provide new insights into the origin of magma, magmatic processes, and the trigger of explosive eruptions. The U-Th ages of zircons extracted from a pumice layer formed during the intense Plinian eruption at ∼11 ka, known as the Ulleung-Oki tephra, show a wide range spanning the pre-eruption equilibrium state (>350 ka) up to the eruption event itself. Zircon grains derived from syenite and gabbro fragments entrained within the tephra yield weighted mean U-Th and U-Pb ages of 34.7 ± 2.3 ka and 1378 ± 22 ka, respectively. Under cathodoluminescence, zircons from the syenite reveal dark, featureless, or oscillatory-zoned cores, containing numerous inclusions of britholite-like Y-rich phases and pyrochlore. These cores are partially or entirely replaced by inclusion-free, brighter domains, suggesting that in situ dissolution and precipitation processes significantly influenced the transformation of zircon. The consistently low δ18O values (5.4–2.6‰) of zircons from Middle Pleistocene trachyte lavas, the Ulleung-Oki tephra, and lithic fragments indicate the persistent presence of shallow crustal magma reservoirs beneath Ulleung Island. These reservoirs have undergone substantial assimilation of hydrothermally altered rocks, with assimilation rates typically around 10–30% and reaching a maximum of approximately 50%. Zircon core-to-rim variations in oxygen isotopic composition, along with textural observations, suggest the rejuvenation of magma reservoirs through the injection of new melt, which likely served as a trigger for the explosive eruptions at Ulleung Island. The similarity in the range of εHf values between the core and rim (+7.4 to −4.3) implies the Hf isotopic consistency of the recharge melt.

Gas-in-place content and occurrence state of deep shale gas in the Luzhou area, Sichuan Basin, China

The exploration and development of deep shale gas has made significant breakthroughs, but due to the characteristics of deep shale gas, there is no recognized and effective method of evaluating gas-bearing. To effectively determine the gas-in-place (GIP) content and occurrence state of deep shale gas, a total of 909 shales were collected for the study utilizing pressure-holding and conventional coring technologies from Wufeng-Longmaxi Formations in the Luzhou area, Sichuan Basin, China. The GIP content of the above shales was evaluated using various methods, including the USBM, polynomial fitting, ACF, MCF, process analysis and carbon isotope fractionation (CIF) methods. The accuracy of the above methods was verified through comparison with the gas content measured by pressure-holding coring. The results demonstrate that (1) the degassing content obtained from conventional coring ranges 0.06–2.13 cm3/g, averaging 0.64 cm3/g; the measured gas content obtained from pressure-holding coring ranges 2.19–11.91 cm3/g, averaging 7.16 cm3/g. The gas content obtained is significantly higher because pressure-holding coring samples have excellent sealing and minimal lost time. (2) The GIP content is underestimated by the USBM method, while the polynomial fitting, ACF, and MCF methods overestimate it. The process analysis and CIF methods can evaluate the GIP content of deep shales more accurately. Based on the comparative results of the adsorbed gas ratio calculated using the process analysis and the CIF methods (33.49% and 24.53%, respectively), it is recommended that the CIF method be given priority when evaluating deep shale gas-bearing. (3) The GIP content of deep shales in the Luzhou area calculated by the CIF method ranges 2.52–11.99 cm3/g, averaging 7.19 cm3/g; the adsorbed gas ratio accounts for 3.41%–53.32%, averaging 24.53%; and the lost gas ratio accounts for 54.01%–97.45%, averaging 86.38%. Compared with medium and shallow shale gas reservoirs in other areas, deep shale gas reservoirs in the Luzhou area have gas-bearing characteristics of high GIP content, low adsorbed gas ratio and high lost gas ratio, which restricts the applicability of traditional evaluation methods.

Secchi Disk Depth or Turbidity, Which Is Better for Assessing Environmental Quality in Eutrophic Waters? A Case Study in a Shallow Hypereutrophic Reservoir

Water transparency is widely used in environmental monitoring programs and in assessing water quality in aquatic environments. The purpose of this study was to determine which of two water transparency-measuring tools, a Secchi disk or a water turbidity meter, is better to assess environments in shallow eutrophic waters. Measurements of the Secchi disk depth (Dsd) and water turbidity (Turb) were carried out simultaneously at eight stations of the hypereutrophic Sestroretsky Razliv reservoir in 2015–2018. In May, October, and December, Dsd varied around 0.6 m but was significantly lower in August during algal blooms. Turbidity ranged from 10 to 20 nephelometric turbidity units (NTU) in different seasons but increased to almost 70 NTU in August. Principal component analysis revealed that Dsd was inversely proportional to Turb, total suspended solids, and chlorophyll concentrations. The data showed that at turbidities below 20 NTU, the Secchi disk clearly distinguishes differences in water transparency, but when Turb exceeds 40 NTU, measuring transparency using the Secchi disk no longer allows for water differentiation. In this case, it is preferable to use water turbidity measurements, which remain an effective indicator even in highly turbid waters. This should be taken into account when assessing the environment in eutrophic waters.

The role of pre-eruptive gas segregation on co-eruptive deformation and SO2 emissions

The presence of exsolved gas bubbles influences measurements of both volcanic surface deformation and SO2 emissions. In a closed-system, exsolved volatiles remain within the melt but in an open-system, the decoupled gas phase can either outgas or accumulate, leading to large variations magmatic gas fraction. Here we investigate the role of gas volume fraction and gas segregation processes on magma properties and co-eruptive monitoring data. First we use thermodynamic models of gas exsolution to model gas volume fraction and magma compressibility, and use these to calculate SO2 emissions and co-eruptive volume change. We find that volume change is equally sensitive to magma compressibility and chamber compressibility over realistic parameters ranges, and both must be considered when interpreting surface deformation data. Reservoir depth and magma composition are the dominant controls on gas volume fraction, but the initial content of H2O and S have strong influences on volume change and SO2 emissions, respectively. Pre-eruptive gas accumulation produces increased SO2 emissions and muted co-eruptive deformation, while degassing has the opposite effect. We then compare our models to a compilation of data from 20 recent eruptions where measurements of volume change, SO2 emissions and erupted volume are available. To the first order, shallow reservoirs produce smaller volume changes per volume erupted and silica-poor magmas yield greater co-eruptive volume changes than silica-rich systems, consistent with closed system degassing. Co-eruptive degassing causes high SO2 emissions during effusive eruptions. Comparison between model predictions and observations suggests that all magmatic systems experience a certain degree of outgassing prior to an eruption. Our findings are consistent with current conceptual models of transcrustal magmatic systems consisting of heterogeneous mixtures of gas and melt and have important implications for the interpretation of surface deformation and SO2 emission signals at all stages of the eruption cycle.

Miocene Volcanism in the Slovenský Raj Mountains: Magmatic, Space, and Time Relationships in the Western Carpathians

The Miocene volcanic-intrusive complex in the Slovenský Raj Mountains, middle Slovakia, comprises a swarm of subalkaline basalts and basaltic andesites with alkaline basalts, trachybasalts and basaltic trachyandesites. Basaltic to doleritic feeder dykes and sporadic hyaloclastite lavas are exposed in contact with the Triassic Bódvaszilas Formation of the Silica Nappe. The primary clinopyroxene, plagioclase, and Fe-Ti oxide assemblage also contains calcite spheroids inferred to represent carbonatitic melt. These spheroids are associated with subsolidus chlorite, actinolite, magnetite, titanite, calcite, and epidote. Micropoikilitic clinopyroxene, albite, and Ti-magnetite formed due to rapid quenching. There was an incorporation of host rock carbonate during the eruption. The erupted products are the result of magmatic differentiation of the parental basaltic tholeiitic magma with a redox of ∆QFM = +1 to +3, affected by varying degrees of 0%–50% fractionation and the assimilation of carbonate material in a shallow magmatic reservoir. REE geochemistry shows N-MORB-like type patterns with both LaN/YbN and LaN/SmN < 1 at near constant Eu/Eu* (~0.9). This is supported by εNd(t=13 Ma) values of +8.0 to +7.4 determined from the basaltic rocks. The REE values can be modeled by 1% fractional melting of garnet peridotite mixed with 7% melting of spinel peridotite of PM composition (1:9 proportions). SIMS and LA-ICP-MS U/Pb analysis of zircons yields a concordant age of 12.69 ± 0.24 Ma and a 13.3 ± 0.16 Ma intercept (Serravallian) age. The Middle Miocene volcanic activity was related to subduction-collision processes along the boundary of the Cenozoic ALCAPA (Alps–Carpathians–Pannonia) microplate and the southern margin of the European plate.

Seismicity near Mayotte explained by interacting magma bodies: Insights from numerical modeling

Mayotte island experienced a large volcanic eruption 50 km offshore in 2018–2021, creating the submarine volcano “Fani Maoré”. The eruption was accompanied by intense seismicity at mantle depths (20–45 km), divided into a “proximal” and a “distal” cluster centered 10 and 30 km east from the island, respectively. Previous studies suggest that two separate magma reservoirs may lie at the top and bottom of the proximal cluster. Here, we assess whether two reservoirs are a mechanically viable explanation for the proximal cluster's truncated conical shape. We developed finite-element models of pressurized magma reservoirs in a 2D axisymmetric domain, modeling the reservoirs as compliant elastic ellipsoids embedded in an elastoplastic host rock. We find that, at these depths, extremely low friction is required to generate failure at realistically low reservoir pressures. This implies in turn that mechanical weakening must occur at these depths. The weakening could be induced by fractures or pore fluid overpressure in the volcanic system. We find that two superimposed reservoirs can generate a plastic domain between them, if they are spatially close enough. Several reservoir geometries (from spherical to sill-like) are plausible. A conical fracture domain is more likely to appear for reservoirs with opposite pressure loads (i.e. one inflating, one deflating). Given the geometrical match with the proximal seismicity cluster at Mayotte, we suggest that the shallower (Moho-depth) reservoir is inflating, creating a potential hazard for Mayotte island.

Detailed wetland-type classification using Landsat-8 time-series images: a pixel- and object-based algorithm with knowledge (POK)

ABSTRACT Mapping detailed wetland types can offer useful information for wetland management and protection, which can strongly support the Global Biodiversity Framework. Many studies have conducted wetland classification at regional, national, and global scale, whereas fine-resolution wetland mapping with detailed wetland types is still challenging. To address this issue, we developed an integration of pixel- and object-based algorithms with knowledge (POK) by combining pixel-based random forest and an object-based hierarchical decision tree. Taking the Guangxi Beibu Gulf Economic Zone (GBGEZ) and Guangdong-Hong Kong-Macao Greater Bay Area (GBA) as our study areas, we produced wetland maps with 10 wetland types and 6 non-wetland types using Landsat-8 time series. In addition, to comprehensively evaluate the accuracy of our wetland classification, we implemented accuracy validation based on test samples and data inter-comparison based on existing datasets, respectively. The results indicate that the overall accuracy of our wetland map was 91.6% ±1.2%. For wetland types, agricultural pond, coastal shallow water, floodplain, mangrove, reservoir, river, and tidal flat achieved good accuracies, with both user accuracy and producer accuracy exceeding 88.0%. For non-wetland types, most accuracies were greater than 72.0%. By comparison with existing datasets, it was found that our wetland map had good consistencies with the China Ecosystem-type Classification Dataset (CECD) land use dataset, MC_LASAC mangrove dataset, and Tidal Wetlands in East Asia (TWEA) tidal flat dataset. In 2020, the wetland area was 4,198.8 km2 in the GBGEZ and 10,932.2 km2 in the GBA. The main wetland types in the two coastal urban agglomerations were agricultural ponds, coastal shallow waters, mangroves, reservoirs, rivers, and tidal flats. Our study successfully mapped detailed wetland types in the GBGEZ and GBA, serving the Global Biodiversity Framework of Convention on Biological Diversity.

Melt extraction and mineralization: A case study from the Shuangjianzishan supergiant Ag-Pb-Zn deposit (208 Mt), Inner Mongolia, NE China

The supergiant Shuangjianzishan (SJZ) Ag-Pb-Zn deposit is in the southern segment of the Great Hinggan Range (SGHR), northeast China. Previous studies suggest the ore-forming material and fluid originated from the magmatic system, and the mineralization age was consistent with the diagenetic age. However, the relationship between granitic magmatism and mineralization is still unclear in the SJZ. In this study, C-H-O-He-Ar and in-situ S-Pb isotope analyses were conducted to determine the sources of ore-forming fluids and metals, which were combined with geochemistry data of SJZ granitoids from previous studies to constrain the relationship between the magmatism and the mineralization. The C-H-O-He-Ar-S-Pb isotopic compositions suggested the SJZ ore-forming material and fluids were derived from a magmatic source, which has mixed a small amount of mantle-derived materials. In addition, the disseminated sulfide from the syenogranite has comparable S-Pb isotopic composition with the sulfide minerals from ore veins, suggesting that the generation of the SJZ ore-forming fluids has a close relationship with the syenogranite magmatism. Combining with the geochemical characters of the syenogranite, the authors proposed that the mantle-derived fingerprint of the SJZ ore-forming fluid might be caused by the parent magma of the syenogranite, which was derived from partial melting of the juvenile lower crust, and underwent the residual melts segregated from a crystal mush in the shallow magma reservoir. The extraction of the syenogranite parent magma further concentrated the fertilized fluids, which was crucial to mineralization of the SJZ Ag-Pb-Zn deposit.©2023 China Geology Editorial Office.

Crustal root shapes the plumbing system of a monogenetic volcanic field as revealed by magnetotelluric data

The plumbing systems of subduction-zone volcanoes consist of magma reservoirs with different degrees of evolution at multiple depths. The geometries of plumbing system of intraplate monogenetic volcanic fields are generally characterized by basaltic magma ascending from the mantle and/or a shallower reservoir along dikes. However, the shape and vertical extent of these plumbing systems are largely unknown due to the rareness of robust geophysical data. The possible role of faults and mountain chains in controlling the geometry of magma reservoirs is also poorly understood. To address these limitations, we present a three-dimensional resistivity structure beneath the Holocene Jingpohu Monogenetic Volcanic Field (JMVF) in the Zhangguangcai Range (ZGC), northeastern China. The resistivity model was derived from the magnetotelluric data in a dense net-like array. We identified an inverted cone-shaped high-resistivity (∼10,000 Ω m) anomaly below the ZGC. This anomaly traverses almost the entire crust. We interpret this high-resistivity anomaly to be the stiff basement of the ZGC. At the base of the resistive volume, we resolved a sill-like, low-resistivity anomaly that occurs at the top of the lithospheric mantle. Sheet-like low-resistivity anomalies surrounding the high-resistivity body depart from the lithospheric mantle. We interpret these sill- and sheet-like anomalies as a trans-crustal saucer-shaped magma plumbing system beneath the JMVF. This system involves multi-level magma reservoirs, including basaltic magma at its base, basaltic dikes/sills swarms in the middle and sill intrusions in the upper crust. We propose that the stiff crustal root and the topographic loading of the ZGC work together to deflect the upward magma propagation towards the edges of the ZGC. The magma ascent to the surface is probably controlled by pre-existing, lithospheric faults. Our data show how mountain chains, together with the crustal structure, play a key role in controlling the geometry of multi-level plumbing systems of intraplate monogenetic volcanic fields.

The impact of rainfall events on dissolved oxygen concentrations in a subtropical urban reservoir

Understanding controls of dissolved oxygen (DO) concentrations in reservoirs is important as they are important for fisheries and a significant driver of greenhouse gas emissions. The latter is of global significance as IPCC inventories now require greenhouse gas emissions from artificial reservoirs to be included. Declines in dissolved oxygen (DO) concentrations in lakes and reservoirs have been linked to climate change and human activity. However, these effects can vary widely in any given region under various meteorological conditions. There is a clear need to know how changes in weather patterns affect DO in reservoirs by changing internal processes. Based on a six-year (2016–2021) high-frequency (twice a week) dataset from a shallow urban reservoir (Xinglinwan Reservoir) in subtropical China, the long-term (six years) and short-term (8–72-h) drivers of DO concentrations in surface waters were evaluated. Over the past six years, the concentration of DO has gradually decreased in the reservoir from 2016 to 2021. Multivariate adaptive regression spline (MARS) models were developed to identify the key factors explaining variability in DO and partial least squares path models (PLS-PM) were used to explore the short-term relationships between DO and environmental variables in rainy and dry (non-rain) periods, separately. We identified three key drivers operating on different time scales. First, the long-term decline of DO in Xinglinwan Reservoir from 2016 to 2021 was best explained by anthropogenic nutrient inputs. Second, rainy periods prior to sampling reduced DO concentrations indirectly by affecting the algal biomass and nutrient concentrations. This effect varied in complexity with the duration of the rainfall period. Third, water temperature best explained DO concentrations during dry periods, while wind reduced DO by reducing algal biomass. We conclude that anthropogenic nutrient and organic matter inputs drive long-term oxygen declines in urban subtropical reservoirs, while meteorological factors determine short-term variability in DO concentrations.

Accumulation and exploration enlightenment of shallow normal-pressure shale gas in southeastern Sichuan Basin, SW China

Based on the drilling, logging, experimental and testing data of Well PD1, a shallow normal-pressure shale gas well in the Laochangping anticline in southeastern Sichuan Basin, the shallow shale gas reservoirs of the Ordovician Wufeng Formation to Silurian Longmaxi Formation (Wufeng–Longmaxi) were investigated in terms of geological characteristics, occurrence mechanism, and adsorption-desorption characteristics, to reveal the enrichment laws and high-yield mechanism of shallow normal-pressure shale gas in complex structure areas. First, the shallow shale gas reservoirs are similar to the medium–deep shale gas reservoirs in static indicators such as high-quality shale thickness, geochemistry, physical properties and mineral composition, but the former is geologically characterized by low formation pressure coefficient, low gas content, high proportion of adsorbed gas, low in-situ stress, and big difference between principal stresses. Second, shallow shales in the complex structure areas have the gas occurrence characteristics including low total gas content (1.1–4.8 m3/t), high adsorbed gas content (2.5–2.8 m3/t), low sensitive desorption pressure (1.7–2.5 MPa), and good self-sealing. Third, the adsorbed gas enrichment of shales is mainly controlled by organic matter abundance, formation temperature and formation pressure: the higher the organic matter abundance and formation pressure, the lower the formation temperature and the higher the adsorption capacity, which is more beneficial for the adsorbed gas occurrence. Fourth, the shallow normal-pressure shale gas corresponds to low sensitive desorption pressure. The adsorbed gas can be rapidly desorbed and recovered when the flowing pressure is reduced below the sensitive desorption pressure. Fifth, the exploration breakthrough of Well PD1 demonstrates that the shallow complex structure areas with adsorbed gas in dominance can form large-scale shale reservoirs, and confirms the good exploration potential of shallow normal-pressure shale gas in the margin of the Sichuan Basin.

The effect of water on alkali trace element diffusion (Li, Rb, Cs) in silicic melts

Trace element diffusion is a powerful tracer of kinetic magmatic processes such as recharge and fluid exsolution. However, the dependence of diffusivities (D) on melt water contents is poorly quantified, and most trace element diffusivities were determined in water-free melts unrealistic for most natural magmatic systems. Here, we investigate the diffusion of the alkali trace elements Li, Rb, and Cs as a function of water content in rhyodacite, high-silica rhyolite, and peralkaline rhyolite. For the diffusion experiments, homogenous hydrous glass cylinders were produced from trace element-doped and undoped powdered glass with 1–8 wt% H2O. Glass cylinders with the same water content but different trace element concentrations were paired along polished contact surfaces. Diffusion experiments were conducted between 720 and 1100 °C at 100–700 MPa for 5–25 min using gas pressure vessels or a piston cylinder apparatus. Resulting diffusion profiles were analyzed by LA-ICPMS and evaluated by a Monte Carlo iterative fitting procedure for full error propagation. At a given experimental temperature, measured log10D values increase linearly with melt water content, with one order of magnitude increase for Li, two orders for Rb, and three orders for Cs from least hydrous (1 wt%) to wettest (8 wt%) experiment, due to a linear decrease in activation energies. Variations in major element composition only have a minor effect. We illustrate the impact of differential diffusion in hydrous silicic magmas on their trace element budget by coupling our data to a two-phase mechanical model of channelized fluid transport in magmatic systems. Quantifying water-dependent diffusivities provides an important tool to track the exsolution, mass and rate of fluid transport within long-lived shallow mushy magma reservoirs in the Earth’s crust.

PARASITIC DISEASES OF FISH IN THE CONDITIONS OF FARMING PONDS OF "AQVAREST" AND "AQUACITY" LLC IN THE ODESSA REGION

The article provides data on the spread of parasitic diseases in carp and grass carp in the farming ponds of Aqvarest LLC and Aquacity LLC of the Odesa region. Fish diseases are registered both in natural reservoirs and in fish farms, as a result of which the growth rates, reproductive capacity, marketability of fish decrease, quality indicators and biological value deteriorate; in addition, mass kills of fish may occur. The causes of diseases can be both non-contagious (adverse environmental conditions) and contagious (viruses, bacteria, parasitic diseases). Thus, constant monitoring of fish parasitofauna in pond farms of Ukraine is necessary, since the study of patterns of occurrence and spread of fish diseases, forecasting of these diseases affects the effectiveness of aquaculture breeding and preservation of fish products.
 The purpose of the work was to monitor parasitic diseases in carp and white amur in the farming ponds of Aqvarest LLC and Aquacity LLC of the Odesa region.
 During the parasitological examination of this year's and two-year-old carp and white amur in the ponds of LLC "Aqvarest" and LLC "Aquasti" of Odesa region, five diseases were diagnosed, the causative agents of which were: Gyrodastylus birmani, Dactylogyrus vastator, Khavia sinensis, Caryophyllaeus fimbriceps and Philometroides lusiana.
 Gyrodastylus birmani and Caryophyllaeus fimbriceps were recorded the most in the deep pond of "Aqvarest" LLC with the extent of invasion of 25.7%, in two-year-old carp and two-year-old white amur - 21.4%. In the shallow reservoir of "Aquacity" LLC, Gyrodastylus birmani (31.4%) and Caryophyllaeus fimbriceps (25.7%) were most recorded in two-year-old carp, and in two-year-old white amur Khavia sinensis (28.5%) and Caryophyllaeus fimbriceps (32.1 %).
 The intensity of infestation with cestodoses (caviasis and caryophyllosis), as well as nematodes (phyllometroidosis) was low, 1-2 or 3-4 specimen for fish, and clinical manifestations of the disease were not always recorded. However, the presence of these pathogens in the fauna represents a significant danger for the development of commercial fish species, namely carp and white carp.

Impact of the heated water discharge on the water quality in a shallow lowland dam reservoir

Impact of the heated water discharge on the water quality in a shallow lowland dam reservoir