Thermal Treatment Of Sewage Sludge Research Articles

Properties of products obtained in the process of solidification and stabilization of fly ash resulting from thermal treatment of sewage sludge

The article presents an analysis of the results of research on the composition of fly ash from the thermal processing of sewage sludge [SSA] collected from three incineration plants located in Warsaw, Cracow and Łódź. It determines the leaching values of selected heavy metals from the tested fly ash and ordinary class concrete C20/25 with partial replacement - up to 20% of cement with fly ash. The laboratory tests performed showed that they have a comparable granulometric composition. In contrast, the physico-chemical properties of the tested fly ashes differ from ashes from coal combustion traditionally used in concrete technology. SSA is characterized by an average lower content of silicon, iron, and aluminium oxides with a much higher content of phosphorus oxides. Leaching tests indicate low mobility of heavy metals, meeting Polish regulations regarding the possibility of using SSA in construction for specific applications. At the same time, they do not pose a significant threat to human health or the environment. Construction waste containing SSA may be disposed of in inert waste landfills.

Migration of trace elements and radioisotopes to various fractions of solid wastes generated as a result of the sewage sludge incineration process

The research was aimed at providing new knowledge in the field of chemical characteristics of solid waste generated in the process of combustion of sewage sludge in fluidized bed furnaces. The research material consisted of disposed fluidized beds (DFB), sewage sludge ash (SSA) and air pollution control residues (APC) from three Polish installations for the thermal treatment of sewage sludge. Natural radionuclides as well as anthropogenic isotope 137Cs were determined in the tested materials and the migration of a wide spectrum of trace elements to various waste fractions generated in the process of sewage sludge combustion was examined. It was observed that both radioisotopes and most of the trace elements determined accumulate in SSA and DFB, while the APC fraction contains a much smaller amount of them. The exceptions are mercury and selenium, whose volatile compounds migrate to the exhaust gas dedusting system and accumulate in the APC fraction (up to 40 mg/kg and 13 mg/kg, respectively). A potential threat from the 226Ra isotope in SSA is identified in the context of the management of this waste in the production of building materials because the typical activity of 226Ra in SSA collected from areas with very low Ra content in natural environment exceeds 1.5–6 times the activity of this isotope in conventional cement mixtures. When managing SSA and DFB, special attention should be paid to the content of metalloids such as As, B and Se, due to the high content of mobile forms of these elements in the mentioned materials.

Practical strategies of phosphorus reclamation from sewage sludge after different thermal processing: Insights into phosphorus transformation

In the context of circular economy and global shortage of phosphorus (P) fertilizer production, it is crucial to effectively recover P during the treatment and disposal of sewage sludge (SS). Although thermal treatment of SS has been widely applied, a targeted P reclamation route is not yet well established. This study has comprehensively investigated and compared the physicochemical properties of SS and solid residues (hydrochar (HC), biochar (BC), sewage sludge ash (SSA), hydrochar ash (HCA), and biochar ash (BCA)) after application of three typical thermal treatment techniques (i.e., hydrothermal carbonization (180‒240 °C), pyrolysis (400‒600 °C) and combustion (850 ℃). P speciation and transformation during thermal processes were extensively explored followed by a rational proposal of effective P reclamation routes. Specifically, thermal processing decomposed organic P and converted non-apatite P to apatite P. Orthophosphate-P was found to be the main species in all samples. Physicochemical properties of the resulting thermal-derived products were significantly affected by the thermal techniques applied, thereby determining their feasibility for different P reclamation purposes. In particular, ash is not recommended for agricultural use due to higher harmful metals content, while acid leaching can be an alternative solution to synthesize non-Fe-containing P products because of the lower co-dissolved Fe content in the leachate. HC and BC offer the option for synthesis of Fe containing products. Eventually, HC and BC demonstrate great potential for agriculture application, however, a comprehensive risk assessment should be conducted before their real-world applications.

Phosphorus Removal in VFCWs with Lightweight Aggregates Made of Fly Ash from Sewage-Sludge Thermal Treatment (FASSTT LWA)

This study analyzed the effect of lightweight aggregates made of fly ash from sewage-sludge thermal treatment (FASSTT LWA) on the effectiveness of phosphorus removal from wastewater in vertical constructed wetlands (CWs), depending on FASSTT LWA content in the CW filling and hydraulic loading rate. It was performed over 13 weeks using 15 lysimeters prepared as double-layer systems. An upper layer was made of FASSTT LWA above the gravel layer with different thicknesses of FASSTT LWA (CW 0 cm: only gravel; CW 12 cm, CW 25 cm; CW 50 cm, and CW 100 cm: only FASSTT LWA). Each filling variant was repeated three times. Wastewater with a mean phosphorus concentration of 7.43 mgP/L was fed to the lysimeters once a day. The hydraulic loading rates tested were 3.0, 5.0, and 7.0 mm/d. Both the increased FASSTT LWA content in the CW filling and the decreasing hydraulic loading rate were found to boost the effectiveness of phosphorus removal in the treated wastewater. Constructed wetland filled in 100 % with FASSTT LWA ensured a reduction in phosphorus concentration below 2.0 mg P/L at all hydraulic loading rates tested.

Assessment of Fly Ash from Thermal Treatment of Sewage Sludge According to the Applicable Standards

Assessment of Fly Ash from Thermal Treatment of Sewage Sludge According to the Applicable Standards

Computationally Inexpensive CFD Approach for the Combustion of Sewage Sludge Powder, Including the Consideration of Water Content and Limestone Additive Variations

As a result of growing interest in the thermal treatment of sewage sludge with methods such as combustion, gasification or pyrolysis, and also in processes that aim to recover precious components such as phosphorus from this waste, a growing demand has been observed for Computational Fluid Dynamics (CFD) models that provide solutions rapidly and accurately for efficient application in research and development. This study was carried out to develop a computationally inexpensive modelling approach for the combustion of pulverized sewage sludge in entrained flow furnaces. Sewage sludge is a very volatile-rich fuel. Therefore, the Steady Diffusion Flamelet model (SFM), in combination with a validated skeletal reaction mechanism, was applied to consider the pulverized firing of sewage sludge. It was possible to represent the complex composition of volatiles emitted from the sludge particles by releasing surrogate fuels. In addition, the influence of limestone additive (calcination reaction) and varying water content (water–gas shift reaction) was investigated experimentally and modelled via CFD. The simulation results confirm that the surrogate fuel approach is valid and can be used to describe pulverized sewage sludge effectively. The temperature and species concentration results, including the influence of the additive and different levels of water content, were confirmed by experimental data, which is usually hard to obtain due to the tendency of PSS to form agglomerates in entrained flow combustion furnaces. The model yields plausible and experimentally validated results for the combustion of sewage sludge powder across a wide range of operating conditions.

Predictions of NOx and SOx in MILD regime based on thermal conversion of solid sewage sludge surrogates

Thermal treatment of sewage sludge using a combination of gasification and combustion of the producer gas is an attractive option to produce sterilized high-notorious bio-char and recover energy from the feedstock. Given the high temperature of the producer gas after gasification, employing the MILD (Moderate or Intense Low Oxygen Dilution) combustion regime in the second stage might benefit the heat balance of the process and result in low emissions. The current work employs multi-component surrogates derived from solid fuel samples of various ultimate elemental compositions and moisture content, a stochastic reactor model for gasification, and a 1D counterflow diffusion flame configuration for combustion with a dedicated, detailed chemical mechanism. Using an improved methodology for emission measurement, we analyzed the combustion emissions of the wet producer gas from gasification, which includes fuel-NO precursors, sulfur components, and tar species up to a size of C11. The analysis confirms that thermal and fuel-NO emissions are reduced in the MILD regime. While high moisture content in the feedstock has been shown to enhance the formation of the pollutant via identified chemical pathways, different representations of fuel samples (ultimate composition) are found to have a significantly more considerable impact on the overall SOx and NOx emissions. The more sulfur is contained in the ultimate composition of the solid surrogate fuel, the more SOX is formed in the combustion stage. This direct relation does not hold for NO. The NO emissions in MILD combustion are the lowest in the performed simulations for the highest amount of fuel-bonded nitrogen. This is caused by the key role of the fuel-NO precursor ammonia (NH3) and its radicals that act in NO formation but also are a driving force in NO reduction. Given this key role of specific fuel-NO precursors, it is further highlighted that there is a significant difference in predicting NO, depending on the complexity of the fuel-NO precursors in the boundary condition of the flame calculation.

Thermal Disintegration of Sewage Sludge as a Method of Improving the Biogas Potential

Operating and research experiments indicate that the potential benefits of thermal treatment of sewage sludge before methane fermentation include increasing the biodegradability of substrates, reducing the amount and improving the dewaterability of the fermentate and its hygienization, reducing the emission of odours during stabilization, higher production of biogas, and improving the energy balance of the process. The process of disintegration (liquefaction) can be carried out, for example, through the use of mechanical homogenization, microwaves and ultrasonic waves, chemical agents, thermal methods, and biological processes. The article reviews the literature data on thermal hydrolysis research, from the first source information to the present. The thermal hydrolysis achieved enhanced hydrolysis, biogas potential, and faster sludge degradation during anaerobic digestion without compromising the quality of the end products.

The Impact of Fly Ashes from Thermal Conversion of Sewage Sludge on Properties of Natural Building Materials on the Example of Clay

The reduction of carbon dioxide emissions, introduced by the European Union, opened the possibility of conducting experimental works on a new generation of materials—ecological and environmentally friendly ones. Such materials include those which combine raw natural resources with waste subject to disposal. The objective of the performed investigations was an assessment of the influence of fly ashes on selected parameters of building materials. The paper proposes a method of the enrichment of clay with fly ash, which would lead to the neutralization of heavy metals in the burnt matrix, possible oxidation of organic substances present in the ashes, or the destruction of pathogens, as well as an increase of the resistance of the clay ceramics to low temperatures. Clay samples were prepared with the addition of the fly ash from three sewage treatment plants. The experiments encompassed investigations of physical and chemical properties of the fly ash, as well as bending strength tests of the beam-shaped samples heated at temperatures of 20, 300, 500, and 700 °C. The beam halves, resulting from the destruction of the samples during these tests, served for testing the compressive strength. The collected results allowed a comparison of the properties of the samples. The obtained test results confirm the possibility of manufacturing a product modified with the fly ash from the thermal treatment of sewage sludge. The obtained compressive strength of the samples amounted 0.3–2.6 MPa.

Preparation of activated coke by carbonization, activation, ammonization and thermal treatment of sewage sludge and waste biomass for SO2 absorption applications

Flue gas desulfurization of coal-burning power plants is imperative to mitigate pollution and acid rain. Use of activated coke as a sulfur dioxide adsorbent is a promising technology, particularly since activated coke can also effectively remove other emissions, such as mercury. In this manuscript, a modified method of ammonia water was used to prepare activated coke for flue gas desulfurization. The feedstock is a blend of sewage sludge and waste biomass, at a mass ratio of 2:1. This material was carbonized prior to activation and ammonization; in some cases, additional thermal treatment was applied. The products were successfully tested for sulfur dioxide adsorption. A graphene model incorporating nitrogen-containing functional groups was used to simulate the sulfur dioxide adsorption process. Thereby, the effects of different ammonia modification concentrations on the physical and chemical properties of activated coke were studied, and the sulfur dioxide adsorption process of nitrogen-containing functional groups (such as pyridine and pyrrole) in activated coke, during flue gas desulfurization, was simulated. This study confirmed that the method of ammonization and heating can introduce nitrogen-containing functional groups on the surface of the activated coke. This greatly improves its chemical properties and, as a result, it markedly improves its SO2 adsorption capacity. It was found through simulation that the doping of nitrogen atoms changes the uniform electrostatic potential distribution and changes the surface polarity. H2O, pyridine functional groups and pyrrole functional groups can promote the adsorption of SO2 on the graphene surface. The pyrrole functional group showed selective adsorption for both SO2 and H2O, but it was predicted to be more effective in adsorbing SO2 than in adsorbing H2O. The pyridine functional group showed no selective adsorption for SO2 and H2O, and it was predicted to be more active in adsorbing SO2 when compared with the pyrrole functional group. The O2 had no effect on the physical adsorption of SO2 on the graphene.

Agronomic valorization of sewage sludge: The potential of thermal drying to achieve sanitation and biological stability

This work aims to contribute to the discussion of using a waste (sewage sludge) to obtain a valuable product (organic-rich fertilizer), based on a circular economy perspective. The composition of sewage sludge (SS) was considered, highlighting important characteristics as raw material for fertilizer production (e.g., macronutrients, microbiological contamination, phytotoxicity). Particularly, the biological stability of SS was evaluated measuring the oxygen uptake rate (OUR) using the Oxitop® method, and the phytotoxicity using germination tests. The potential of thermal drying to stabilize the SS was evaluated at two temperatures (100 and 130°C). The results showed that the organic matter (OM), N, and P levels are within the range of interest for agronomic valorization, while the content of some potentially toxic metals (e.g., Zn and Cu) may exceed the legal limits. The phytotoxicity assessment showed that raw SS samples negatively impacted the germination phase. Concerning the biological stability, results showed that raw anaerobic digested samples were characterized by OUR values above 50 mmol O2/kg OM.h (the limit for stable SS). Although thermal treatment of SS at 100 and 130°C eliminated pathogens and significantly stabilized SS to OUR values below 50 mmol O2/kg OM.h, it was not enough to reach the limit established for a stable fertilizer (25 mmol O2/kg OM.h). Globally, SS has potential for soil application, within the scope of circular economy, but it is essential to control its microbiological contamination and stability.

Fly Ash from the Thermal Transformation of Sewage Sludge as an Additive to Concrete Resistant to Environmental Influences in Communication Tunnels

Concrete is an ecological material with a high potential to adapt to specific operating conditions, and the lowest carbon footprint as it is made from local raw materials—aggregate, cement, water, admixtures, and mineral additives. It is the most widely used composite material among those that are man-made and second only to water in the entire range of materials used. The aim of this research was to assess the possibility of using fly ash from the thermal treatment of sewage sludge as an alternative additive to concretes resistant to environmental influences occurring in communication tunnels. A concrete mix based on CEM I 42.5R Portland cement with various ash content of 0–20% of the cement mass was designed for the experimental work. In the course of the experimental work, the compressive strength was measured after three maturing periods, and the influence of both high temperature and the material modification on the course of carbonation were determined. The test results confirm the possibility of producing plain concrete, modified with fly ash obtained from the thermal treatment of sewage sludge. The highest average compressive strength of 43.6 MPa, 45.6 MPa, and 51.2 MPa after 28, 56 and 720 days of maturation, respectively, was for concrete containing 10% ash.

Chemical Model for Thermal Treatment of Sewage Sludge

Sewage sludge is here studied as a valuable source for processing or energy conversation thanks to its high nutrition and energy content. However, various origins of the wastewater, different water cleaning technologies, and seasonal and regional dependencies lead to the high variability of the sewage sludge properties. In thermal treatment units, that is, incineration, gasification and pyrolysis, sewage sludge serves as feedstock or fuel, hence a proper characterization and a mathematical description of the sewage sludge are required to estimate product streams and to formulate numerical simulations and optimization methods. The presented work introduces a surrogate concept that allows replication of sewage sludge’s ultimate composition, moisture, and ash content. The surrogate approach aims to model the decomposition of any sewage sludge sample, opposite to the established determination of kinetic rates for individual samples. Based on chemical solid surrogate species and corresponding reaction mechanisms, the thermal decomposition path is described. Sewage sludge is represented by a combination of lignocellulosic species, proteins, sugars, lipids, and representative inorganic species. The devolatilization and heterogeneous reactions are formulated such that they can be used together with a detailed gas-phase model, including tar oxidation and emission models for nitrogen and sulfur oxides, recently proposed by the authors. The developed chemical model is applied using a zero-dimensional gasification reactor in order to model weight loss within the thermogravimetric analysis, pyrolysis, gasification and combustion conditions. Weight loss, the composition of product gases, and emission release (nitrogen and sulfur oxides) are captured well by the model. The flexible surrogate approach allows us to represent various sewage sludge samples.

Thermal treatment of sewage sludge for phosphorus fertilizer production: a model experiment

Phosphorus (P) resource availability and quality is declining and recycling P-fertilizers from waste materials are becoming increasingly important. One important secondary P resource is sewage sludge (SSL) where P is often bound as aluminum phosphate (Al-P), iron phosphate (Fe-P) and polyphosphate (poly-P), respectively. Thermal treatment in different ways is a promising way in P recycling to produce highly plant-available P-fertilizers. To investigate mechanisms behind transformation of hardly available P-species toward plant-available P forms we treated a model SSL containing different kinds of defined P sources by low-temperature conversion (LTC) at 500 °C and subsequent thermochemical treatment of the LTC product with Na additives (TCT) at 950 °C, respectively. Pot experiments with ryegrass were carried out to determine the plant availability of P of the different treatments. The poly-P (here pyrophosphates) based fertilizers had a very high plant availability after both thermal treatments. During LTC treatment the plant availability of the Fe-P and Al-P variants increased because of the formation of Fe(II)-phosphates and/or pyro-/polyphosphates. Especially the formation of Al-polyphosphate shows a high plant availability. The subsequent TCT further increased strongly the plant availability of the Fe-P variants because of the formation of highly plant-available CaNaPO4. Thus, a direct TCT without prior LTC probably also produce CaNaPO4 and is recommended for Fe-P based SSL. However, a molar Ca/P ratio of ∼1 in the fertilizer is favorable for CaNaPO4 formation. Thus, the knowledge on the source of primary P in SSL is essential for choosing the accurate thermal treatment method to produce highly plant-available P-fertilizers from SSL.

Sustainable transformation of sewage sludge ash and waste industrial additive into green cement blend

AbstractCement is an essential construction material and its production and demand are becoming challenge for environmental (carbon dioxide emission) and sustainability (natural resources consumption) related issues. The sustainable alternative is a key requirement to fulfill the increasing demand for natural resources and reduction in carbon dioxide (CO2) emission. For sustainable development, ash generated from the thermal treatment of sewage sludge (SSA) and carbide lime sludge (CLS) has been used for the production of green cement. For the feasibility study, the influence of using SSA and CLS are compared in terms of the properties of fresh paste and hardened mortar with Portland Pozzolana cement (PPC) containing FA. The outcome of the study shows that up to 45% of ordinary Portland cement can be replaced by using SSA with CLS blends, which enhance the compressive strength, save the natural resources and reduce CO2 emission up to 52% when compared with FA substitution.

Sewage Sludge Thermal Treatment Technologies with a Focus on Phosphorus Recovery: A Review

Phosphorus presents a limited, irreplaceable and essential nutrient necessary for the growth of organisms. There is an increasing effort to recover phosphorus from production waste streams. Sewage sludge presents an important source of phosphorus but also contains organic pollutants and heavy metals. Thermal treatment technologies seem to be a promising option to treat sewage sludge and obtain ash/char from which high recovery rate of phosphorus can be reached. In this review, sewage sludge management options in compliance with EU legal requirements are first reviewed. Follows, an overview of sewage sludge thermal treatment technologies including incineration, hydrothermal carbonisation, pyrolysis and gasification, for the purpose of phosphorus recapture. We summarize recent advances in thermal treatment processes of sewage sludge and phosphorus recovery, identify challenges and knowledge gaps. Thermochemical methods proved to have many advantages over pure wet chemical methods for phosphorus recovery. The review provides the foundation for future research aimed at achieving efficient, economic and environmental sustainable recapture of phosphorus from sludge thermal treatment products.

Assessment of Valuable and Critical Elements Recovery Potential in Ashes from Processes of Solid Municipal Waste and Sewage Sludge Thermal Treatment

Due to the increasing amount of produced and accumulated wastes, a potential source of elements might be the global waste stream coming from the waste incineration process. As a result of this process, bottom ash, fly ash and air pollution control residues are produced. The goal of this study was to evaluate the raw material potential of the anthropogenic materials which are fly ashes from municipal waste incineration and municipal sewage sludge incineration, and the possibility for the recovery of metallic or other economically valuable elements by comparison of their chemical composition with the chemical composition of Earth materials (ultramafic, mafic and felsic igneous rocks, various sedimentary rocks), and with their lowest content in currently exploited ores. Fly ashes contain more valuable and critical elements when compared to Earth materials; however, they are less concentrated in comparison to the content in currently exploited ores. Since natural resources are becoming depleted, the costs of exploitation, mineral processing and related operations are increasing and the fly ashes are easily accessible. Cheap materials do not demand complicated treatment which might be considered as a future source of P, Zn, Sn, Cr, Pb, Au and Ag, and thus fulfilling the assumptions of close-loop economy and to maximize natural resources protection.

Comprehensive Evaluation of the Control Efficiency of Heavy-Metal Emissions during Two-Step Thermal Treatment of Sewage Sludge.

Recycling the phosphorus in sludge by incineration has received great interest at home and abroad. However, heavy metals (HMs) is a restrictive factor for SS thermal treatment. In this study, a comprehensive evaluation method was adopted to evaluate the comprehensive control efficiency of HM emissions during two-step thermal treatment (incineration–calcination). The effects of temperature, calcination time, and additives (CaO and NaCl) on leaching rates, stabilized rates, and comprehensive control efficiency of HM emissions were investigated. Results showed that comprehensive control efficiency increased significantly with an increase of temperature because of the transformation of chemical speciation from a leachable to a more stable combined form. Additives Cao and NaCl promoted the volatilization of HMs and reduced the comprehensive control efficiency. The highest comprehensive control efficiency of HM emissions was 78% when the incineration temperature reached 950 °C. Furthermore, a comparison was made between leaching rates, stabilized rates, and a comprehensive evaluation method. The results were inconsistent when leaching rates and stabilized rates were adopted. In contrast, when the comprehensive evaluation method was used, the results were coordinated and unique. This work can provide a promising approach for the evaluation of control efficiency of HM emissions during the process of thermal treatment of sludge.

Treatment of Wastewater Containing Runway De-Icing Agents in Biofilters as a Part of Airport Environment Management System

Large volumes of pavement de-icing and anti-icing fluids, collectively termed de-icing agents, are used at airports to facilitate wintertime safe air travel. After use, most of the them get typically mixed with storm water runoff and may enter soil and waters near the airports. Wastewater resulting from airports’ winter operations is contaminated mainly with nitrogen and carbon compounds. Previous research results have shown that the use of biofilters filled with lightweight aggregates prepared from fly ash from sewage sludge thermal treatment (FASST LWA) could be an effective method for removing nitrogen and organic compounds at low temperatures, i.e., 0–8 °C. For this to be possible, it is necessary to maintain a proper ratio between the amounts of carbon and nitrogen in the treated wastewater, through the simultaneous application of de-icing agents containing urea and carbon compounds. Biofilter technology is part of the concept of sustainable development. Their filling is made of waste materials and one of the pollutants (organic compounds) present in the wastewater is used to remove other pollutants (nitrogen compounds). In this study, technological systems for the treatment of wastewater containing airport runway de-icing agents with biofilters were proposed, which allow for the treated wastewater to be discharged into natural waters, soil, and sewerage network.

Sewage Sludge Thermal Treatment Technology Selection by Utilizing the Analytical Hierarchy Process

Sewage sludge management has gained significance in the last several years, due to its nutrient and energy content. However, technology selection is one of the greater challenges because it is not possible to implement a technology that covers all the requirements of the considered environments. Consequently, this paper shows an example of the utilization of an analytical hierarchy process, as a decision-making tool in terms of technology selection, for sewage sludge management in Rijeka, Croatia. The criteria structuring and evaluation process with the description of several possible alternatives for thermal treatment technologies are defined within this research. For the case of Rijeka, the best and most suitable technology for sewage sludge treatment is gasification, which coincides with the results obtained from the analysis of the literature review. According to the results in this paper, the possibilities of the use of this scientific method on the national level for the selection of sewage sludge treatment technology should be considered, due to the simplicity of its use and capability of its adaptation to various situations and areas.