AbstractThis paper presents a theoretical investigation on the solidification of a low Peclet number fluid flow in the thermal entrance region of a round pipe. The velocity is assumed laminar and fully developed throughout the pipe and the fluid temperature is taken to be uniform at X = −∞. The pipe wall is adiabatic at X ≤ 0 and is cooled convectively at X ≥ 0. The exact solution in the liquid and solid phase are obtained by using the method of separation of variables and constructing two sets of orthonormal functions from the nonorthogonal eigenfunctious at X = ± 0.The solutions including temperature distributions, liquid‐solid interfaces and Nusselt numbers for the parameters, Bi = 20, 4, 0.4, 0.04, Pe = 1, 3, 5, 10, 20, 30, ∞ and the superheat ratios, ξ = (1 − θf)/θf, θf= 0.1, 0.2, …, 0.9 are presented in this paper. The length of ice‐free zone xf corresponding to Pe = ∞ are in excellent agreement with the existing solution.