Liquid Separation Research Articles

Working Condition Sensitivity Analysis and Optimal Structure Parameter Determination of IVT Based on CFD and Orthogonal Experiment

To address liquid accumulation in horizontal gas wells, a specialized internal vortex tool (IVT) was developed for use in the horizontal sections, functioning as a drainage gas recovery device. This tool operates by leveraging centrifugal forces generated during fluid swirl to separate liquid from gas. The study examined the performance of IVT under various operational conditions and sought to identify optimal structural parameters. Through a controlled variable approach, the impact of inlet velocity and the water-gas volume ratio on pressure drop range, MGV (maximum gas velocity), and MVFLP (maximum liquid phase volume fraction) was analyzed. The results indicated that when the inlet velocity is between 2-4m/s and the water to gas volume ratio is between 0.5-2m3/104m3, the smaller the inlet velocity and the smaller the water to gas volume ratio, the better the gas-liquid separation effect of the IVT. An orthogonal test was subsequently employed to fine-tune the tool's structural parameters for different conditions, culminating in the creation of a comprehensive optimization chart for IVT. This study can effectively design drainage gas production tools for gas wells under different working conditions, reduce energy loss during drainage gas production, effectively utilize downhole resources, and achieve the goal of increasing natural gas well production and reducing costs.

MXene: A new revolution in the world of 2-D materials

MXenes have imposed a profound effect on materials science and nanotechnology fields after their discovery in 2011. Theoretical models have predicted more than 100 potential compositions of MXene whereas laboratory-scale synthesis reflects their success of over 40 distinct structures till date. The distinctive properties of MXenes have led to their use for a diverse range of applications, such as energy storage, environmental remediation, electronics, communications, gas and liquid separation and adsorption, biomedical fields, and optoelectronics. The increased interest of researchers in MXenes has led to a wide rise in research publications, showing their growing importance in different scientific domains. In 2024, MXenes had shown wide potential in various areas, including energy storage devices, electromagnetic interference shielding, nanocomposites, and hybrid materials. However, the variations in the choice of precursors, reactor design, cost, synthesis parameters pose several challenges in ensuring the production of high-quality MXenes. The applicability of MXenes continues to broaden as its compositions are continuously accelerating. This review aims is to provide a comprehensive overview of MXene history, its properties, challenges, latest trends, and different applications to highlight its potential and gather new audiences towards this family of two-dimensional materials.

Highly Enantioselective Transportation Across Liquid Membranes Mediated by Porous Covalent Organic Frameworks.

Chiral liquid membrane separation is crucial in pharmaceuticals and chemical synthesis for its simplicity and stability, yet designing membrane carriers that enable efficient enantioseparation remains a challenge. Here, we demonstrated for the first time that chiral porous materials can act as mobile carriers of bulk liquid membranes (BLMs) to enhance enantioselective transport and separation. We design and prepare three 2D chiral covalent organic frameworks (CCOFs) by imine condensations of a chiral dialdehyde with triamines containing ethyl, fluorine and/or isopropyl groups. These isostructural CCOFs feature ABC stacking, excellent water, acid and base tolerance, and chiral amine groups in 1D porous channels, promoting efficient enantioselective transportation of amino acid enantiomers. Among them, the CCOF with both -F and -iPr groups showing superior transport performance. Exfoliating the CCOF into chiral nanosheets creates flexible layers with accessible active sites, enabling nanosheet-mediated liquid membranes to separate chiral drug enantiomers, a feat unattainable with the pristine CCOF. This work establishes CCOFs as a promising platform for chiral BLM separations and will guide the design of high-performance BLMs using porous materials for enantioselective separation.

Highly Enantioselective Transportation Across Liquid Membranes Mediated by Porous Covalent Organic Frameworks

Chiral liquid membrane separation is crucial in pharmaceuticals and chemical synthesis for its simplicity and stability, yet designing membrane carriers that enable efficient enantioseparation remains a challenge. Here, we demonstrated for the first time that chiral porous materials can act as mobile carriers of bulk liquid membranes (BLMs) to enhance enantioselective transport and separation. We design and prepare three 2D chiral covalent organic frameworks (CCOFs) by imine condensations of a chiral dialdehyde with triamines containing ethyl, fluorine and/or isopropyl groups. These isostructural CCOFs feature ABC stacking, excellent water, acid and base tolerance, and chiral amine groups in 1D porous channels, promoting efficient enantioselective transportation of amino acid enantiomers. Among them, the CCOF with both ‐F and ‐iPr groups showing superior transport performance. Exfoliating the CCOF into chiral nanosheets creates flexible layers with accessible active sites, enabling nanosheet‐mediated liquid membranes to separate chiral drug enantiomers, a feat unattainable with the pristine CCOF. This work establishes CCOFs as a promising platform for chiral BLM separations and will guide the design of high‐performance BLMs using porous materials for enantioselective separation.

Numerical and experimental study of dynamic gas–liquid separator with various viscosities

The gas–liquid separation process is important in various industries, such as electric power, aerospace, and petroleum. This study introduces an innovative, dynamic gas–liquid separator (DGLS) in which a cyclonic flow pattern is induced by blade rotation. This cyclonic flow enhances the efficiency of gas and liquid phase separation while also imparting energy to facilitate the transport of the separated fluid. Numerical simulations are used to analyze the internal flow dynamics, power requirements, and separation efficiency of this DGLS. A comparison with experimental results is conducted to validate the reliability of the numerical model. The effects of liquid-phase viscosity on the internal energy consumption and separation performance of the DGLS are explored at various flow rates. The simulation results indicate that for a given viscosity, the degassing rate of the separator decreases while the liquid removal rate increases as the inlet flow rate rises. Furthermore, it is observed that higher viscosity leads to poorer separation performance, with a decrease in turbulent kinetic energy near the rotating axis and an increase in turbulence intensity near the wall. At lower flow rates, the effectiveness of liquid-phase outlet pressurization improves with increasing viscosity. However, at higher flow rates, increasing viscosity leads to a substantial decline in energy performance and a reduction in liquid-phase outlet pressurization. The increment in turbulent kinetic energy is greater than the square of the mean velocity, indicating a positive correlation between turbulence intensity and turbulent kinetic energy. These findings not only provide a theoretical basis for the prediction of flow losses within a DGLS and the efficient design of these separators, but also provide guidance for industrial applications involving high-viscosity fluids.

Old and new wetting liquids separation in grain-based pattern micromodel during wetting cycles

Old and new wetting liquids separation in grain-based pattern micromodel during wetting cycles

К РАСЧЕТУ ЖИДКОСТНЫХ ТАРЕЛЬЧАТЫХ СЕПАРАТОРОВ С ПАРАБОЛИЧЕСКИМИ ВСТАВКАМИ

The object of the study is liquid disk separators with curvilinear inserts, which are described by equations of the type . The study was conducted to study the effect of the insert shape on the intensity of the centrifugal force on the liquid flow, as well as on the length of the sedimentation path (or float) of dispersed medium particles. The efficiency of clarification of dispersed media is predetermined by two design characteristics of the device - the length of the particle sedimentation path and the direction of the centrifugal force relative to the walls of the curved channel. For parabolic inserts, the distance between them and the angle of inclination of the walls are variable quantities. To calculate these quantities, nonlinear equations are constructed and an algorithm for numerical calculations is proposed. The calculation results are presented as graphical dependencies of the above parameters along the channel length. The calculations were performed for paraboloids of revolution with degrees m=2, 3 and 4 at coefficient a=2, 3 and 4. As the coefficient a increases, the distance between the inserts decreases. The influence of the exponent m on the gap between the paraboloids of revolution is more complex. The gap size along the channel length decreased from 3 cm to several millimeters. The angle of inclination of the walls relative to the rotation axis decreased in the range from 70 to 10 degrees. As the parameters a and m increase, this angle decreases, therefore, the component of the centrifugal force directed perpendicular to the channel wall increases. The equations of motion of the liquid system were solved by the method of equal flow surfaces, according to which the flow is represented as several layers with their own velocities. At the inlet section, the velocity diagram develops from a flat profile to a parabolic form. As a result of the action of the centrifugal force, an asymmetry of the velocity profile is observed. The obtained results can be used to justify the geometric characteristics of a plate separator with parabolic inserts and to coordinate them with the flow regime parameters.

Gradient-Elution Nanoflow Liquid Chromatography without a Binary Pump: Smoothed Step Gradients Enable Reproducible, Sensitive, and Low-Cost Separations for Single-Cell Proteomics

Mass spectrometry-based proteome profiling of trace analytes including single cells benefits from liquid chromatography separations operated at low flow rates (e.g., <50 nL/min). However, high-pressure binary pumps needed to achieve such flow rates are not commercially available, and instead require splitting of the gradient flow to achieve low-nanoliter-per-minute flow rates. Gradient flow splitting can waste solvent and lead to flow inconsistencies. To address this, we have developed a method for creating gradients by combining plugs of mobile phase of increasing solvent strength together in a column, and then relying on Taylor dispersion to form the desired smooth gradient profile. Additionally, our method dramatically reduces costs, as only a single isocratic high-pressure pump is required. Following development of gradient profiles for both 10- and 20-min active gradients, we measured 200 pg injections of HeLa digest using a timsTOF mass spectrometer. Finally, we investigated differences in protein expression between single cells originating from two different colonies of ATG-knockout HeLa cells. Thousands of proteins were quantified, and a potential mechanism explaining differential immune responses of these two colonies upon exposure to viral DNA treatment was determined.

Experimental study on the unsteady evolution mechanism of centrifugal pump impeller wake under solid–liquid two-phase conditions: Impact of particle concentration

To study the spatiotemporal evolution process of particle wakes behind the impeller in the centrifugal pump, this paper utilized high-speed photography to capture the particle motion characteristics under different solid-phase particle concentrations (1%, 1.5%, and 2%). First, this paper studies the changes in hydraulic performance of the centrifugal pump under solid–liquid two-phase flow conditions. It then introduces the evolution process of the impeller particle wake, comparing the differences in particle wake evolution under varying solid-phase concentrations. Finally, the impact of the solid-phase concentration on the wear of the volute's partitions is investigated. This study found that as the solid-phase particle concentration increases, the hydraulic performance of the pump gradually declines. Under the design conditions, when the solid-phase concentration increases by 0.5%, the efficiency of the centrifugal pump decreases by 0.56% and 0.35%. There is mutual transport of particles between adjacent wakes, and the movement of particle wakes within the volute passage is not equidistant over time. As the solid-phase particle concentration increases, wake cutting occurs at the volute partitions, and there is a significant solid–liquid separation between the particle wakes. The spatial evolution of the particle wakes is significantly influenced by the solid-phase concentration. Wear at the volute partitions intensifies with increasing solid-phase concentration and is also affected by changes in the particle wakes. The research results provide a basis for further exploration of the solid–liquid two-phase flow dynamics within centrifugal pumps.

Solution Processable Metal-Organic Frameworks: Synthesis Strategy and Applications.

Metal-organic frameworks (MOFs), constructed by inorganic secondary building units with organic linkers via reticular chemistry, inherently suffer from poor solution processability due to their insoluble nature, resulting from their extensive crystalline networks and structural rigidity. The ubiquitous occurrence of precipitation and agglomeration of MOFs upon formation poses a significant obstacle to the scale-up production of MOF-based monolith, aerogels, membranes, and electronic devices, thus restricting their practical applications in various scenarios. To address the previously mentioned challenge, significant strides have been achieved over the past decade in the development of various strategies aimed at preparing solution-processable MOF systems. In this review, the latest advance in the synthetic strategies for the construction of solution-processable MOFs, including direct dispersion in ionic liquids, surface modification, controllable calcination, and bottom-up synthesis, is comprehensively summarized. The respective advantages and disadvantages of each method are discussed. Additionally, the intriguing applications of solution-processable MOF systems in the fields of liquid adsorbent, molecular capture, sensing, and separation are systematically discussed. Finally, the challenges and opportunities about the continued advancement of solution-processable MOFs and their potential applications are outlooked.

Enhanced Phase Change Heat Transfer with Fused Deposition Modeling (FDM) Printed Pit and Pillar (Pi2) Arrays

Phase change heat transfer, crucial in thermal management systems, can be significantly enhanced through optimized surface structures. This study investigates pool boiling heat transfer enhancement using 3D printed structures with carefully designed pillar and pit geometries. We present a novel approach combining the Dual Rise model with separate liquid–vapor pathways to improve Critical Heat Flux (CHF) and Heat Transfer Coefficients (HTC). Using copper-infused Polylactic Acid (PLA) filaments, we created and sintered structured surfaces featuring pit-assisted nucleation sites, interpillar spacing for vapor escape, and pillar roughness for enhanced liquid supply. Experiments with deionized water and ethanol under atmospheric pressure demonstrated substantial improvements over plain surfaces: water showed an 87% increase in CHF and 39% in maximum HTC, while ethanol exhibited even greater enhancements of 122% in CHF and 61% in HTC. These improvements are attributed to the synergistic effects of optimized surface geometry and separated liquid–vapor pathways, reducing counterflow resistance and improving hydrodynamic stability. A theoretical framework based on the Dual Rise model explains these enhancements, providing insights into coupled capillary action and hemiwicking effects in boiling heat transfer. The study introduces predictive models for CHF and HTC enhancement, offering valuable tools for future design optimization in applications ranging from electronics cooling to power plant thermal management and advanced heat exchangers.

Use of the droplet convergence effect of under-medium superlyophilic membranes in designing a system for on-demand separations of oil-in-water and water-in-oil emulsions

Separation using superwetting membranes that have discrepant interactions with water and oil, primarily those that display extreme liquid repellence, is a facile approach for oily wastewater treatment and purification of water-containing oil. However, these kinds of membranes suffer from size-sieving limitation. Owing to greater affinity toward dispersed droplets over liquid media, under-medium superlyophilic membranes have greater flexibility in the design of superwetting interfaces for oil–water separation. Herein, two membranes with completely opposite superwettabilities both in air and under oil/water media were utilized to create an integrated system for effective, on-demand separation of oil-in-water and water-in-oil emulsions. At superwetting interfaces, the under-medium superlyophilic membrane facilitates convergence of emulsion droplets while the other membrane intercepts converged droplets. As a result, the integrated membranes exhibit high purification capabilities of water and oil in surfactant-stabilized emulsions (e.g., > 99.97 % oil purification under gravity). The viscosity-dependent fluxes are > 550 L m−2h−1 when the viscosities of the liquid media are ≤ 1 mPa s. In contrast, an integrated system in which conventional in-air superhydrophilic membranes are utilized in place of the under-medium superlyophilic membranes does not efficiently separate the emulsions. The unique affinity profiles will endow under-medium superlyophilic membranes with a high potential for liquid–liquid separation.

Zwitterionic covalent organic framework membranes for efficient liquid molecular separations

Covalent organic frameworks (COFs) featuring uniform topological structure and devisable functionality have emerged as promising membrane materials. The design and precise manipulation of COF membranes with advanced spatial structure to achieve efficient liquid molecular separations are of great necessity. Herein, zwitterionic COF membranes have been in-situ fabricated on porous polymeric substrates using an interfacial polymerization modification strategy. The continuous defect-free COF membranes with two-dimensional in-plane dominant growth can be achieved by optimizing the fabrication parameters including reaction time, monomer concentration, and catalyst concentration. Subsequent zwitterionic modification thereon not only favors the formation of hydrophilic surface but also improves the sieving capability by sheltering effect. Attributed to the synergistic contribution, the optimized zwitterionic COF membrane possesses a superior separation factor of 2839 with the water content in the permeate up to 99.7 wt%, while maintaining a comparable permeation flux of 3309 g m−2 h−1 during the ethanol dehydration process, outperforming most of other representative membranes. Furthermore, the excellent durability of the zwitterionic COF membrane in the ethanol dehydration process and its efficient separation performance towards other alcohol dehydration systems demonstrate its potential practical applications. The easy scalability of the fabrication and regulation method offers crucial guidance for the engineering of advanced COF membranes in efficient liquid molecular separations.

Improvement of energy efficiency and production performance in a heteroazeotropic batch distillation unit: A study on decanter control and feeding strategy

Dehydration of methyl isobutyl ketone (MIBK) using a batch distillation unit has been investigated through process simulation. Applying a decanter for upgrading the heteroazeotropic distillation is analyzed in different aspects. The unit performance dependency on the feed quantity, decanter design/control policy, decanter holdup volume, and subsequent phase separation quality are evaluated in detail. Feed quantity is recognized as a key factor influencing unit performance. Although increasing the feed quantity leads to a higher production rate (SPF) and lower specific energy cost (SEC), the optimal feed quantity is identified as the point beyond which further improvements in these variables become negligible. Also, reflux initiating time, liquid–liquid separation grade, loss of the desired component along with the effluent stream, and holdup loss at the end of the process are recognized as functions of decanter holdup quantity. Accordingly, a perfect decanter with a large holdup volume is not necessarily the best option. The evaluation indicates that an effective decanter lies on a larger aqueous phase holdup and smaller organic phase holdup, as long as it is capable of efficiently separating the liquid phases (over 75% separation efficiency for each phase). It is found that applying a well-designed and properly controlled decanter for the mixture separation (MIBK-water) can improve the unit recovery by up to 6% and the production rate (and energy cost) by up to 7% compared to a conventional batch distillation unit. Furthermore, an inverted batch distillation configuration with a gradual feeding policy is applied as an alternative and compared to other operation policies. The feeding schedule is found to be the key factor in this mode. The results reveal that an inverted distillation unit equipped with a properly designed and controlled decanter provides up to 17% improvement in energy and production rate as well as 7% in recovery for a 9% shorter process time compared to a conventional batch distillation unit.

An Effective Method for Reproducing the Flow of a Gas-Liquid Mixture Using a Flow Standard

The appearance on the market of measuring equipment of multiphase flowmeters used in the oil and gas industry to measure the amount of extracted hydrocarbons directly at wells without preliminary separation and performing the function of operational accounting raised the question of their metrological support in accordance with the requirements of regulatory documents of the sphere of state regulation in this field of measurements. His decision was to create a reference base, the basis of which was the State primary special standard for units of mass flow of gas-liquid mixtures GET 195-2011 and a verification scheme for measuring multiphase flow rates, regulated by GOST 8.637-2013. When transmitting units of volume and mass flow of a multiphase mixture with the required accuracy, the main problem is the difficulty of reproducing and maintaining stability of several flow parameters at once – mass flow and content of liquid components (water and oil simulator) and volume flow of the gas phase. It should also be borne in mind that test programs for the purpose of approving the type of multiphase flow measuring instruments, as well as verification and calibration methods, provide for changing the modes of reproduction of a gas-liquid mixture, covering the measurement ranges of multiphase flowmeters. Such standards used in practice represent a very complex measuring system consisting of storage tanks for components, supply pumping and compressor units, control equipment, mixers and separators, measuring instruments for the physical parameters of multiphase flow components and an automated control system. Given the high cost of multiphase standards, when creating them, effective methods and methods should be used to reproduce the flow of a multiphase mixture with specified parameters, as well as to make a fairly rapid transition to the next mode provided by the program or methodology, which will reduce the time and production costs for the procedure of transferring units of measurement from the standard to the working measuring instrument. This article describes a method for reproducing the flow rate of a gas-liquid mixture according to the original technological scheme introduced during the development of the 1st category standard. Constructive solutions are presented that increase the efficiency of the liquid component separation apparatus to increase the dosing accuracy, as well as expand the range of reproduction of the flow rate and parameters of the multiphase flow, ensuring the consistency of the composition of the liquid mixture at a given regime. An original rational method of compressing and maintaining the pressure of the gas phase is described, which allows you to quickly switch to the next mode, confirmed by the results of experimental studies of the standard.

Spontaneous Formation of π-Conjugated Polymeric Colloidal Molecules Through Stepwise Coacervation and Symmetric Compartmentalization.

Coacervation, the phase separation of liquid induced by polymeric solutes, sometimes results in the formation of oligomeric clusters of droplets. The morphology of the clusters is non-uniform because the clustering is a consequence of the random collisions of the drifting droplets. Herewereportdistinctively organized coacervation, yielding colloidal molecules with monodisperse size, morphological symmetry, and compositional heterogeneity.Weinvestigate the coacervation of a mixture of two types of synthetic polymers and find that one of the polymers coacervates first and serves as a core droplet, on which the other polymer coacervates subsequently to form satellite droplets. The satellite droplets arrange themselves symmetrically around the core and solidify without losing the morphology. The number of satellites and their symmetry are modulable depending on the chemical affinity and the diameter of the droplets. This finding highlights the capability of coacervation as a non-templated and non-covalent pathway to form aspherical colloidal materials with structural and functional complexity.

Dehydration by Pervaporation of an Organic Solution for the Direct Synthesis of Diethyl Carbonate

Pervaporation has been a central subject in the research community within the scope of the further development of energy- and cost-efficient alternatives to conventional liquid–liquid separation technologies. The potential eligibility of four commercial membranes (ZEBREX ZX0, PERVAPTM 4155-80, PERVAPTM 4100, PERVAPTM 4101) for use in an integrated dehydration application of a diethyl carbonate/water/ethanol mixture by pervaporation was assessed experimentally. The impact of feed concentration, operating temperature, pressure, and sweep gas flow rate on membrane separation performance, including permeation flux, permeate quality, selectivity, and permeance, was thoroughly investigated. Applying the ZX0 membrane delivered the best qualities of all tested membranes of the permeate stream, with a water concentration of mostly &gt;98%. In comparing the water flux, the ZX0 membrane remained reasonably competitive with the polymer membranes. Furthermore, the sweep gas volume flow rate and the operating temperature were identified as influencing the flux significantly but not the product composition. At the same time, the feed concentration of water also influenced the water purity within the permeate. The experiments were monitored with a partial least squares model, allowing a quick assessment of obtained samples while delivering accurate results.

Water-in-water emulsions stabilized by nano-chitin

A water-in-water (W/W) emulsion consists of microdroplets was formed by the spontaneous liquid–liquid separation by mixing polyacrylic acid and chitosan oligosaccharide in water, and these microdropletes were stabilized by nano-chitin, formed water-in-water Pickering emulsions. By taking the advantage of interfacial adsorption of nano-chitin, the W/W emulsion droplets composed of polyacrylic acid/chitosan oligosaccharide (COS/PAA) polyelectrolyte coacervate were successfully stabilized. Research results indicated that composite microspheres were formed by the nano-chitin stabilized COS/PAA emulsion, and the size of these composite microspheres was related to the concentration and morphology of the nano-chitin. As the concentration of nano-chitin increases, the size of the composite microspheres first increases and then decreases, gradually becoming more uniform; whereas a decrease in the length of nano-chitin will lead to an increase in the size of the composite microspheres. The formation of composite microspheres may be due to the electrostatic interactions between nano-chitin and the emulsion droplets. In addition, the composite microspheres exhibit the best release effect for berberine hydrochloride at a pH value of 3.

Solid–liquid separation state control system for shale shaker based on computer vision

Shale shakers are crucial in drilling operations, separating solid–liquid mixtures, protecting equipment, improving efficiency, and supporting environmental protection and resource recovery. Typically, the solid–liquid separation status on shaker screens is assessed through manual inspection and experiential judgment, with the screen tilt angle adjusted manually. This method has inherent delays, failing to promptly detect and address screen surface abnormalities. To overcome this, a computer vision-driven intelligent control system has been proposed, enhancing drilling sieving operations’ efficiency. The system uses computer vision and servo motors to monitor and adjust the sieving state. Twin industrial cameras capture images, which undergo preprocessing like perspective correction, grayscale conversion, noise reduction, and illumination equalization. Local threshold segmentation and morphological analysis distinguish between liquid and solid states. The segmented images’ contours and area analysis precisely determine the separation state. Results are transmitted to motors via an industrial computer to adjust the sieve net angle. Servo motors on both sides manipulate the sliding block lifting mechanism for precise tilt adjustment. Experiments demonstrate that the method achieves an average accuracy of 93.635% in identifying mud edges. The system’s high efficiency and reliability ensure accurate identification and adjustment of the solid–liquid separation state, thereby optimizing drilling sieving workflows.

Cationic Covalent Organic Framework-Modified Polypropylene Separator for High-Performance Lithium Metal Batteries.

As an important component of lithium batteries, the wettability and thermal stability of the separator play a significant role in cell performance. Despite the availability of numerous commercial separators, issues such as low ion selectivity and poor thermal stability continue to limit the efficiency and reliability of the batteries. Herein, two cationic covalent organic frameworks (Br-COF and TFSI-COF) with abundant imidazole cationic groups were designed to modify commercial polypropylene (PP) separators. The strong lithium-ion affinity of the cationic COF enables the effective dissociation of lithium salt ion clusters, simplifying the solvent structure of lithium ions to promote lithium ions transport. Additionally, solvent anions can be anchored to the cationic COF by electrostatic interactions, reducing side reactions on the lithium metal anode surface to form a favorable SEI layer, which can effectively inhibit the growth of lithium dendrites. The rapid dissociation of anions in lithium salts with some organic solvents and cationic COFs was revealed by a molecular dynamics simulation. A LiF-rich SEI layer on the lithium metal anode surface was formed, which can speed up Li+ transport at interfaces, leading to consistent lithium deposition and outstanding battery performance. The ordered porous structure of the cationic COF provides interconnected and continuous channels, improving the wettability between the liquid electrolyte and separators, which is conducive to ion transport. When paired with a LiFePO4 cathode and electrolyte (1.0 M LiTFSI in DEC: EC: DMC = 1:1:1), the LiFePO4/TFSI-COF@PP/Li cell demonstrates a prominent cycling capacity of 148.0 mAh g-1 at 0.5 C with a Coulombic efficiency of 98.0% in the first cycle, and the capacity retention is 82.0% after 100 cycles, showing good cycling stability. Thus, this investigation provides inspiration for the expansion of cationic COF-modified separators for next-generation lithium metal batteries.