Semi-crystalline Phase Research Articles

Chemical properties of peat micro particles modified asphalt.

This study investigated the chemical properties of peat microparticles modified asphalt (Pt.M.A.). The originality of the study resides in the examination of the chemical characteristics of peat microparticles (Pt.) modified asphalt (Pt. M.A.) utilising FTIR, SEM, SFE, and XRD methodologies. This encompasses Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), surface free energy (SFE), and X-ray diffraction (XRD). Initially, FTIR examined the functional groups of both unaltered and altered asphalt binders. The SEM images reveal improved compatibility, showcasing superior diffusion of the modifier across the asphalt. A further critical factor is that improved adhesion properties, according to the SFE study, indicate that modified binders generally offer more SFE compared to unmodified binders. The XRD measurements revealed a semi-crystalline structure in the Pt. modifier and an amorphous structure in the basal asphalt binder. The integration of Pt. into the asphalt cement resulted in modifications to the phases of both constituents, culminating in the emergence of a new semi-crystalline phase inside the modified asphalt binder. These data suggest that peat microparticles (Pt.) can improve the efficacy of asphalt binders by enhancing compatibility, adhesion, and resistance to ageing.

Advanced photocatalytic membrane GO-NiFe@SiO2/PVDF for efficient decontamination of synthetic dyes in batik wastewater with superior antifouling features

A novel composite membrane, GO-NiFe@SiO2/polyvinylidene fluoride (PVDF), was prepared via the sol-gel method for nanocomposite synthesis and phase inversion method for membrane fabrication. The investigation encompassed the structural features and properties of the nanocomposite membranes, including photocatalytic activity under UV type C, antifouling capability, and self-cleaning behavior. The degradation of dyes in real Batik wastewater followed pseudo-first-order kinetics, with the GO-NiFe@SiO2/PVDF 1 wt% nanocomposite membranes exhibiting a highest dyes removal efficiency up to 90.50 % within 8 h, compared to the pristine PVDF membrane (60.95 %). The XRD pattern analysis indicates that the incorporation of GO-NiFe@SiO2 into the PVDF membrane induced a transformation in the semi-crystalline phase of PVDF, shifting from the alpha-phase to the beta-phase, consequently facilitating the development of electrostatic charge on the membrane surface. The pore-size distribution analysis revealed that all prepared membranes fall within the range of nanofiltration and tight ultrafiltration (NF-TUF). Additionally, the photocatalytic membrane demonstrated enhanced permeation flux of 30.46 L.m−2.h−1 and flux recovery rate up to 92.57 % under simulated UV light irradiation, showcasing improved antifouling capability. Moreover, the membrane exhibited outstanding cycle test with 6 consecutive cleaning every 3 h, self-cleaning efficiency, with 61.32 % cleaning efficiency under UV irradiation. The incorporation of GO-NiFe@SiO2 enhanced the physicochemical properties of the photocatalytic membrane, including hydrophilicity, surface topologies, and mechanical strength, thereby improving photocatalytic anti-fouling performance and expanding the potential applications of membrane filtration technology.

Effect of calcium bromide hydrate on the structural and optical properties of polyethylene glycol/niobium pentoxide polymer layers

The blend polymer layers of polyethylene glycol with various Nb2O5 and CaBr2⋅xH2O concentrations were synthesized using the solution-dropping process. X-ray diffraction spectra revealed polyethylene glycol peaks, which could be attributed to the polymers' inherent semi-crystalline phase. The Raman spectra revealed stretching Nb–O bonds and confirmed the Nb2O5 phase. The stretching modes of the CH, CH2, and CH3 groups are presented for polyethylene glycol. Adding more CaBr2⋅xH2O (0–3 wt%) increases the transmittance values to about 0.64 %, 1.18 %, 2.79 %, and 6.29 %. At the same time, the band gap values of the polymer layers go down from 3.0 eV to 2.06 eV. The refractive index values increased from 6.16 (0 wt% CaBr2⋅xH2O) to 7.46 (3 wt% CaBr2⋅xH2O). The low Urbach energy of 837.26 meV for the 2 g polyethylene glycol/4 wt% Nb2O5/1 wt% CaBr2⋅xH2O sample confirms the appropriate concentration of less disorder in the polymer layer.

Construction of Benzoxazine-linked One-Dimensional Covalent Organic Frameworks Using the Mannich Reaction.

Covalent polymerization of organic molecules into crystalline one-dimensional (1D) polymers is effective for achieving desired thermal, optical, and electrical properties, yet it remains a persistent synthetic challenge for their inherent tendency to adopt amorphous or semicrystalline phases. Here we report a strategy to synthesize crystalline 1D covalent organic frameworks (COFs) composing quasi-conjugated chains with benzoxazine linkages via the one-pot Mannich reaction. Through [4+2] and [2+2] type Mannich condensation reactions, we fabricated stoichiometric and sub-stoichiometric 1D covalent polymeric chains, respectively, using doubly and singly linked benzoxazine rings. The validity of their crystal structures has been directly visualized through state-of-the-art cryogenic low-dose electron microscopy techniques. Post-synthetic functionalizations of them with a chiral MacMillan catalyst produce crystalline organic photocatalysts that demonstrated excellent catalytic and recyclable performance in light-driven asymmetric alkylation of aldehydes, affording up to 94 % enantiomeric excess.

Construction of Benzoxazine‐linked One‐Dimensional Covalent Organic Frameworks Using the Mannich Reaction

AbstractCovalent polymerization of organic molecules into crystalline one‐dimensional (1D) polymers is effective for achieving desired thermal, optical, and electrical properties, yet it remains a persistent synthetic challenge for their inherent tendency to adopt amorphous or semicrystalline phases. Here we report a strategy to synthesize crystalline 1D covalent organic frameworks (COFs) composing quasi‐conjugated chains with benzoxazine linkages via the one‐pot Mannich reaction. Through [4+2] and [2+2] type Mannich condensation reactions, we fabricated stoichiometric and sub‐stoichiometric 1D covalent polymeric chains, respectively, using doubly and singly linked benzoxazine rings. The validity of their crystal structures has been directly visualized through state‐of‐the‐art cryogenic low‐dose electron microscopy techniques. Post‐synthetic functionalizations of them with a chiral MacMillan catalyst produce crystalline organic photocatalysts that demonstrated excellent catalytic and recyclable performance in light‐driven asymmetric alkylation of aldehydes, affording up to 94 % enantiomeric excess

Comprehensive new insights on the potential use of SiC as plasma-facing materials in future fusion reactors

The performance of silicon carbide as an alternative plasma facing material (PFM) was studied at various irradiation conditions relevant to ion energies and fluxes of a fusion reactor. This analysis involves detailed modeling of subsurface plasma/material interactions, sputtered particle transport above the surface and redeposition, and related changes in material composition and microstructure induced by steady-state and Edge Localized Mode ion fluxes. Transition of a crystalline SiC surface to semi-crystalline and amorphous phases was analyzed based on advanced modeling of DIII-D tokamak experiments where SiC was irradiated in single- and multiple- L-mode and H-mode discharges. This analysis shows that displacement damage, particle deposition/redeposition, and D accumulation on the SiC divertor surface can lead to significant microstructural changes that result in enhanced sputtering erosion in comparison with the original crystalline material. However, the resulting total net erosion rate for a full-coverage, advanced tokamak, SiC coated divertor may well be acceptably low. Moreover, the C sputtering yield from the evolved SiC surface can be seven times lower than from a pure graphite surface; this would imply significantly reduced tritium co-deposition rates in a D-T tokamak reactor, compared with a pure carbon surface. It was also determined that chemical sputtering of both C and Si should not result in any noticeable effect on the net erosion, for attached plasma regimes. Our results thus show encouraging results overall for use of SiC as a PFM in tokamaks.

Thermoluminescence properties of Eu2O3-doped and MgSO4–Co-doped Na2O silica borate glasses produced by recycling renewable source of soda-lime-silica (SLS)

This study investigates the thermoluminescence characteristics of Eu/Mg doped sodium silica borate glass for thermoluminescence dosimeter. Two sets of glass samples doping with Eu2O3 and co-doped with MgSO4 with compositions (Eu2O3)x (Na2O)0.1 (B2O3)0.6 (SLS)0.3-x and (Eu2O3)0.01 (Na2O)0.1 (B2O3)0.6 (SLS)0.29-y (MgSO4)y respectively with x and y = 0, 0.005, 0.01, 0.03, and 0.05 mol % were prepared using a melt-quenching technique. XRF analysis revealed a SiO2 content of 70.81 wt% from the SLS powdered sample. The semi-crystalline phases were identified for all glass samples. The glasses were annealed for 2 h at 400 °C and exposed to X-ray with an absorbed dose of 500 mGy, a tube potential of 80 kVp, focus to film distance (FSD) of 100 cm, and a tube load of 64 mAs. The glow curves were analyzed to determine various characterizations of a thermoluminescence dosimeter of the glass. For NaSBEu, only 0.01 mol% Eu2O3 was sensitive to the X-ray. The glass content NaSBEu0.01 was co-doped with varying contents of MgSO4. The sample containing 0.03 mol% MgSO4 demonstrated the most favorable TL response, exhibiting superior TL attributes, including minimal detectable dose, fading behavior, sensitivity, linearity, reproducibility, and effective atomic number. These findings strongly indicate that glass incorporating magnesium in the sodium silica borate composition has promising potential to be regarded as a dosimeter for low radiation doses.

Insight into Poly(l-lactic acid) Coexisting Amorphous and Semicrystalline Phases Using FT-IR Imaging and Four Polarization-Three Dimensional Macromolecular Orientation Calculation

Insight into Poly(<scp>l</scp>-lactic acid) Coexisting Amorphous and Semicrystalline Phases Using FT-IR Imaging and Four Polarization-Three Dimensional Macromolecular Orientation Calculation

Chitosan/PVA Films and Silver Nanoparticle Impregnated Nanofibrous Dressings for Evaluation of their Wound Healing Efficacy in Wistar Albino Rat Model

The exoskeleton of marine shrimp contains a natural, biocompatible polymer chitin, which is dumped as a waste. The study proposes the sustainable single-pot-extraction of chitosan from the waste and its use in the fabrication of wound-dressings, and thus leverage its piezoelectric, antioxidant, hypoglycaemic and medicinal properties in wound-healing. The Fourier transform infrared spectrum revealed that marine chitosan contains functional groups with N-O, O-H, and CO stretching. Scanning electron micrographs demonstrated the spherical and mesoporous structures of the extracted chitosan. X-ray diffraction analysis showed a semi-crystalline phase of chitosan particles with a mean size of 28.9 nm. The film prepared with marine shrimp chitosanpolyvinyl alcohol (PVA) composite, and used as a wound dressing exhibited significant wound healing properties with a regeneration efficiency of 78% in 8 days in Wistar albino rats. The wound healing efficiency was enhanced by the addition of cost effective, non-toxic/environmentally friendly silver nanoparticles (AgNPs) synthesized from Rumex acetosa (sorrel) plant extracts and electrospinning of the nanofibrous composites of chitosan/PVA/AgNPs with high antibacterial, antioxidant and wound healing capacity of 96% in 8 days. Thus, the current study supports the use of a natural piezoelectric chitosan polymer as a wound dressing material, either in film or nanofiber, for normal as well as diabetic wounds.

The Development of Sustainable Polyethylene Terephthalate Glycol-Based (PETG) Blends for Additive Manufacturing Processing-The Use of Multilayered Foil Waste as the Blend Component.

The polymer foil industry is one of the leading producers of plastic waste. The development of new recycling methods for packaging products is one of the biggest demands in today's engineering. The subject of this research was the melt processing of multilayered PET-based foil waste with PETG copolymer. The resulting blends were intended for additive manufacturing processing using the fused deposition modeling (FDM) method. In order to improve the properties of the developed materials, the blends compounding procedure was conducted with the addition of a reactive chain extender (CE) and elastomeric copolymer used as an impact modifier (IM). The samples were manufactured using the 3D printing technique and, for comparison, using the traditional injection molding method. The obtained samples were subjected to a detailed characterization procedure, including mechanical performance evaluation, thermal analysis, and rheological measurements. This research confirms that PET-based film waste can be successfully used for the production of filament, and for most samples, the FDM printing process can be conducted without any difficulties. Unfortunately, the unmodified blends are characterized by brittleness, which makes it necessary to use an elastomer additive (IM). The presence of a semicrystalline PET phase improves the thermal resistance of the prepared blends; however, an annealing procedure is required for this purpose.

Characterizing Biochar Derived from Palm Kernel Shell Biomass via Slow Pyrolysis for Adsorption Applications

This comprehensive study delves into the thorough characterization of biochar derived from palm kernel shells, with a focus on its potential as an environmentally friendly solution to tackle waste management challenges within Malaysia's agro-industry. Employing the (BET) method, the current investigation unveils an impressive specific surface area of 299.7565 m²/g, complemented by a pore size of 2.17783 nm and a substantial pore volume of 0.1632 cm³/g, attesting to its extraordinary adsorption capacity. Assessment of thermal stability through (FESEM) imaging underscores its resilience, FTIR spectroscopy unravels distinct peaks within the stretching region. XRD analysis introduces a characteristic pattern for palm kernel shell-derived biochar (PKSBC), marked by a prominent, broad peak observed at approximately 2? = 20-30º and 2? = 40-50º, indicative of crystalline and semi-crystalline phases, respectively. Elemental analysis assumes a pivotal role in assessing biochar quality, with a particular emphasis on carbon content, instrumental in identifying potential impurities or contaminants that could compromise its effectiveness in critical applications, including water treatment, air purification, and gas adsorption. This study not only underscores the substantial promise of palm kernel shell-derived biochar in addressing environmental challenges but also provides invaluable insights into its exceptional properties. These findings have the potential to redefine sustainable practices and drive environmental stewardship, offering innovative solutions to the pressing issues of our time.

Hydrophobic polymer nano hybrid ternary composite electrode for nanomolar tracing of Cd2+ ions

AbstractIn the present study, we reported the successful synthesis of a ternary nano hybrid polymer composite system obtained by solution casting. Composing carbon nanotubes (CNTs) and molybdenum disulfide (MoS2) in ethylene vinyl acetate (EVA) derived ECM ternary electrode. It demonstrated an excellent electrochemical sensor performance and a more efficient supercapacitor. Chemical structure of hybrid electrode Fourier transform Infrared Spectroscopy (FTIR) illustrated the CS and CN stretching with MoS2 and CNT new bands (at 1368 and 1032 cm−1). FE‐SEM and Atomic force microscopy (AFM) 3D topographic image identified the decreased rough morphology of the hybrid electrode. Whereas contact angle measurements revealed the enhanced wettability of electrode system. Microporous nature of the hybrid electrode was observed through SEM investigation. Transmission electron microscopy (TEM) revealed the nano hybrid entity in a hybrid electrode system. XRD and TEM investigation confirmed semicrystalline phase of the hybrid electrode system due to the presence of MoS2. D band, G bands, E12g and A1g vibrational modes in Raman spectroscopy revealed the occupied hybrid filler CNTs and MoS2. An electroactive site for the Cd2+ ion sensor was confirmed by the ECM/PGE hybrid electrode. It comply the desirable sensor qualities, such as excellent selectivity, reproducibility and repeatability with a high accuracy and lower detection limit of 15 nM. Additionally, the ECM/PGE electrode demonstrated a capacitive nature with an aerial capacitance of 73 μF/cm2 at an applied current density of 3 μA/cm2. Furthermore, it exhibited a power density of 44 mW/cm2 and an energy density of 148 μWh/cm2 over a wide potential range of 1 V.

Effect of v-PP/r-PET composites filament on specific density, structural and mechanical properties

Polypropylene (PP) and its derivatives are widely used to produce molded plastics due to their lightweight and impact resistance. Polyethylene terephthalate (PET) is considered one of the essential engineering polymers for its applications, widely used to manufacture containers for liquids such as water, oil, etc. The compatibility of PP/PET increases the impermeability, thermic and mechanical properties. The present study shows the blend binary of recycling PET as refill into a v-PP matrix extruded in filament analyzing the specific density and XRD. The result XRD pattern exhibited the presence of miscibility of monoclinic α-form phase v-PP/r-PET peaks predominantly attributed to the crystallinity of baseline material. Likewise, crystallinity, and amorphous peaks are attributed to the semi-crystalline phase of r-PET with a triclinic structure. In the impact strength test, all specimens tested showed partial failure on the surface, majorly presenting cracks, and fractures.

Modification of Polyethylene Glycol and Citric Acid on Palm Fiber Waste Nanofibers on the Adsorption of Violet Crystal Dyes

&lt;p&gt;This study developed nanofibers derived from sugar palm fiber waste, incorporating citric acid and polyethylene glycol (PEG) modifications to adsorb crystal violet (CV) dye. The synthesis process involved alkalization-acid hydrolysis and bleaching techniques. Subsequent analyses of nanofiber characteristics were conducted using Fourier-Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), and Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX). The efficacy of these modified nanofibers in adsorbing CV was quantitatively measured using an Ultraviolet-Visible (UV-Vis) spectrophotometer. The study successfully synthesized nanofibers from sugar palm fiber waste with modifications: PEG-modified nanofibers (NP 2 and NP 24) and citric acid-modified nanofibers (NS 2 and NS 24). These modifications resulted in nanofibers with a smooth, white texture. FTIR analysis of the samples (N, NP 2, NP 24, NS 2, and NS 24) revealed the presence of functional groups essential for cellulose, specifically -OH, C-H, and C-O groups. The addition of citric acid introduced a new group, C=O, albeit with very weak intensity. PEG modifications were evident from the stretching observed in the -OH groups. SEM analysis confirmed the presence of a layer on the nanofibers, attributed to citric acid (NS 2 and NS 24) and PEG (NP 2 and NP 24). XRD results indicated that the pre-and post-modification nanofibers exhibited a semi-crystalline phase. The adsorption mechanism was predominantly guided by Van der Waals electrostatic interactions between the absorbent material and the adsorbate. Intriguingly, the citric acid and PEG modifications did not significantly alter the adsorption outcomes. The adsorption capacity remained stable over time, as evidenced by measurements of 0, 15, 30, 45, 60, 90, and 120 minutes.&lt;/p&gt;

Reinforcement of linear/nonlinear optical and dielectric characteristics of PVC/PEG blend based on CeO2/TBAI filler

Blended polymer nanocomposites with novel enhanced properties are gaining in popularity around the world, prompting an increase in their production. In this study, cerium dioxide (CeO2) nanoparticles were prepared via the sol–gel method and PVC/PEG/CeO2/x wt % tetrabutylammonium iodide (TBAI) blends were prepared via the casting procedure. The influence of CeO2/TBAI doping on the structural, optical, and dielectric features of formed blends was analyzed. The structural characteristics were studied using X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS) and scanning electron microscope (SEM) techniques. XRD shows a creation of nano CeO2 with a cubic structure and semicrystalline phase of undoped and doped PVC/PEG/CeO2/TBAI blends. SEM and EDS techniques confirm the presence of the filler in the blend matrix. The optical characteristics appeared in the modification in optical band gap from (4.27, 5.05) to (3.01, 3.84) eV for a direct optical band gap and from (4.06, 4.58) to (2.51, 3.51) eV for an indirect optical band gap. In the same way, the values of linear and nonlinear parameters of PVC/PEG blends are altered with the doping of nano CeO2/TBAI. Doped blends have higher dielectric permittivity and ac conductivity than PVC/PEG blend. The effect of doping on the emitted colors from different blends was examined under different excitation wavelengths. According to the experimental results, these films show promise for good absorbance for different types of UV spectra, and energy storage devices.

Extraction and characterization of marine chitosan from sea shrimp shell and its biomedical applications

Biopolymer "Marine Chitosan" (MC) was extracted from the chitin of sea shrimp shells using standard protocol and was investigated for its morphological, elemental and biomedical applications. The extracted chitosan powder was first characterised by analytical techniques viz. XRD, FTIR, FESEM and UV-Vis/NIR spectroscopy. Then, the material was tested for its in vitro anti-oxidant assay using KMnO4 method with the highest mean inhibition of 96.94% at 1 mg/mL. MC showed a semi-crystalline phase investigated through XRD analysis and the FESEM presented non-spherical morphology with a mean particle size of 293 nm. The FTIR spectrum showed functional groups with O-H, N-H and C-O stretching. The anti-cancer activity determined on MCF-7 cell lines with an IC50 of approximately 71.45 μg and the optical property of MC-TiO2 composite with 19.16% higher absorbance than pure TiO2 at wavelength 808 nm could be applicable for photodynamic and photothermal therapy.

One-pot upcycling strategy achieved in Bi-continuous thermal conductive polymer composites

Though upcycling post-consumer polymers into high-value materials is appealing, it faces challenges including complex, costly processes and difficulties to achieve a circular lifecycle. To address these issues, we have developed a novel approach that involves designing a unique bi-continuous phase morphology with selective distribution of the conductive fillers in the semi-crystalline polymer phase. As a result, these composites exhibited excellent thermal conductivity (7.07 W m−1·K−1) and stable environmental longevity (thermal aging and 500 h UV irradiation) and can be upcycled as effective flame retardant (vertical combustion grade V-0) and smoke suppressed materials (smoke density grade 64.1) after their service life as a thermal conductive material has ended. Rather than being discarded or undergo molecular upcycling, they could be straightforwardly repurposed through melt processing and even displayed better processability, suggesting a one-pot but effective upcycle strategy for polymeric materials.

Acid-base potentiometric titration using a stainless steel electrode without oxidative treatment.

An AISI 304 stainless steel laminar electrode without oxidative treatment was investigated for the potentiometric titration of hydrochloric acid with sodium hydroxide. The proposed electrode was obtained from metalworking cuttings. Scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray fluorescence spectroscopy and X-ray diffraction were used to study the surface morphology and chemical composition of the electrode. The electrode showed a sensitivity of 59.18 ± 0.37 mV/pH, which was reproducible under intermediate conditions. Potentiometric titration showed a curve with deviations from pH 9.5 with respect to the glass electrode. However, this did not affect the quantification as the jumps of the curves coincided. The endpoint was 9.25 mL for both electrodes and the hydrochloric acid concentration was 0.0845 mol/L, with a deviation of 0.0004 mol/L from the standard concentration of 0.0841 mol/L. The nonartificially oxidised electrode did not show any crystalline oxide phases, whereas after oxidation it showed semicrystalline phases of iron and chromium oxides and increased the crystallinity of the steel. Despite the low content of surface oxides, stainless steel electrodes can give a Nernstian response to pH, depending on the surface characteristics of the material. This leads to the need to calibrate any electrode prior to oxidative treatment to rule out a Nernstian response without surface modification.

Quantum effects of hydrogen storage in ϵ and δ semicrystalline phases of syndiotactic polystyrene through adsorption

Syndiotactic polystyrene (sPS) is a stereoregular semicrystalline polymer which presents complex polymorphic behaviour and has been explored as an alternative for hydrogen storage using adsorption. The methodology of gas retention using a light and cheap porous material offers many advantages. To establish the adsorption capacity of a specific material, adsorption isotherms are generally measured. However, to gain a better understanding of the underlying phenomena occurring at a nanoscale level (e.g. confined interactions of in sPS) and, moreover, as a predictive tool, alternative methods such as molecular simulations are required. In this work, we present Grand Canonical Monte Carlo simulation results for hydrogen () adsorption isotherms of δ and ϵ phases of sPS. molecule was described as a 1-site model with Lennard-Jones and Exp-6 potentials, within the Wigner–Kirkwood mean-field approximation to introduce quantum corrections. Both polymer phases were modelled using an atomistic force field and the initial configurations were relaxed using molecular dynamics for temperatures , and . Adsorption isotherms for each system were obtained for both classical and semiclassical potentials. Additionally, adsorption isotherms for both phases were compared with experimental adsorption data at from previous work.

Electrocoagulation treatment of compost leachate using aluminium alloy, carbon steel and zinc anode

Analysis of surface changes and corrosion occurrence at the electrode surface, electro-generated sludge analysis, and electrocoagulation (EC) treatment efficiency using aluminium alloy, low carbon steel, and zinc sacrificial anode as electrodes for the treatment of compost leachate with the medium organic load were compared for the first time. Different operating conditions (initial pH values in the range of 4–8, stirring rates in the range 70–270 rpm, and contact times in the range of 10–30 min) were used to study the EC process. Light microscopy analysis show the significant corrosion of anodes, while minor corrosion damage was also observed on the cathodes. Pitting was found on carbon steel and aluminium electrodes, and general corrosion on the zinc electrodes, which increase with the duration of EC (10 to 30 min). Weight loss analysis of electrodes shows a decrease in anode mass in all experiments and aluminium cathode mass, while steel cathode mass increases. Zinc cathode mass increases in initially acid and decreases in an alkaline environment. The highest anode consumption was obtained in the experiment with the Zn electrode (in the range of 0.3300–0.6469 g). SEM/EDS analysis of the electro-generated sludge confirmed the presence of aluminium, zinc, and iron, with oxygen as the main elements, while carbon indicated collected organic matter from the compost leachate. PXRD analysis of sludge shows a mixture of amorphous phase with the a semicrystalline phase of AlO(OH) and the crystalline phase of AlPO4 obtained with Al electrodes, an amorphous structure of the sludge obtained with Fe electrodes, and structurally well-ordered phases of Zn7Cu(OH)13((SiO(OH)3)0.7(O4H7)0.3(SO4)) and (Zn0.9Cu0.1)O obtained with Zn electrodes. In addition, the treatment efficiency was analysed and Taguchi's L9 orthogonal array design was performed.