Semiclassical Picture Research Articles

Physics beyond PIXE

The paper reveals geometrical effects that govern the accuracy of PIXE measurements: distinction between thin and thick targets, misorientation of the sample, surface roughness and contribution of the invisible matrix. It shows an importance of the mean X-ray production distance and its application in differential measurements. It further reviews the data base needed for thick target calculations and the importance of developing more accurate theoretical models based on the semiclassical picture and coupled channel approach. An example of transitions in a perturbed harmonic oscillator demonstrates that the united atom limit does not exist at adiabatic collisions and that the cross section likely exhibits an oscillatory behaviour.

Strong-coupling limit of the driven dissipative light-matter interaction

We approach the strong-coupling thermodynamic limit in the response of the open driven Jaynes-Cummings (JC) oscillator. We do so by highlighting the role of quantum fluctuations against the semiclassical response in three distinct regimes of operation. We begin by demonstrating the persistence of photon blockade, predicted in [H. J. Carmichael, Phys. Rev. X 5, 031028 (2015)], as a manifestation of the inherently-quantum and nonlinear JC spectrum revealed for vanishing dissipation. We then proceed to discuss the importance of bistability, which, despite being present in photon blockade, is able to provide an alignment between the semiclassical nonlinearity and quantum dynamics only for a driving amplitude having the same order of magnitude as the light-matter coupling strength. This resolution brings us to the critical point of the well-known quantum phase transition of second order on resonance, where the quantum and semiclassical pictures are once more contrasted for a varying participation of the two coherent interactions when going through the collapse of the quasi-energy spectrum.

New Semiclassical Picture of Vacuum Decay.

We introduce a new picture of vacuum decay which, in contrast to existing semiclassical techniques, provides a real-time description and does not rely on classically forbidden tunneling paths. Using lattice simulations, we observe vacuum decay via bubble formation by generating realizations of vacuum fluctuations and evolving with the classical equations of motion. The decay rate obtained from an ensemble of simulations is in excellent agreement with existing techniques. Future applications include bubble correlation functions, fast decay rates, and decay of nonvacuum states.

Interplay between low-lying isoscalar and isovector dipole modes: A comparative analysis between semiclassical and quantum approaches

We perform Time Dependent Hartree-Fock (TDHF) calculations to investigate the small amplitude dipole response of selected neutron-rich nuclei and Sn isotopes. A detailed comparison with the dipole strength predicted by Random-Phase Approximation (RPA) calculations is presented for the first time. TDHF results are also confronted to Vlasov calculations, to explore up to which extent a semi-classical picture can explain the properties of the nuclear response. The focus is on the low-energy response, below the Giant Dipole Resonance region, where different modes of non negligible strength are identified. We show that the relative weight of these excitations evolves with nuclear global features, such as density profile and neutron skin, which in turn reflect impor tant properties of the nuclear effective interaction. A thorough analysis of the associated transition densities turns out to be quite useful to better characterize the mixed isoscalar(IS)/isovector(IV) nature of the different modes and their surface/volume components. In particular, we show that the dipole response in the so-called Pygmy Dipole Resonance region corresponds to isoscalar-like surface oscillations, of larger strength in nuclei with a more diffuse surface. The ratio between the IV and IS Energy Weighted Sum Rule fractions exhausted in this region is shown to almost linearly increase with the neutron skin thickness in Sn isotopes.

Semiclassical Conservation of Spin and Large Transverse Spin Current in Dirac Systems.

In Dirac materials, the low-energy excitations obey the relativistic Dirac equation. This dependence implies that electrons are exposed to strong spin-orbit coupling. Hence, real spin conservation is believed to be violated in Dirac materials. We show that this point of view needs to be refined in the semiclassical picture which applies to the case of doped Dirac materials (away from the nodal point in the spectrum). We derive a novel type of Boltzmann equation for these systems if they are brought slightly out of equilibrium. Remarkably, spin-momentum locking is softened and a generalized spin conservation law can be formulated. The most striking observable consequence of our theory is a large transverse spin current in a nearly ballistic transport regime.

Dynamical quantum correlations after sudden quenches

We employ the mean-field approach in the fermionic picture of the spin-1/2 XXZ chain to investigate the dynamics of bipartite quantum discord and concurrence under sudden quenching. In the case, when quenching is performed in the anisotropy from an initial value to the critical point, the quantum correlations show periodic cusps in time. Moreover, the first suppression (cusp) in quantum correlations can be explained in terms of the semi-classical picture of quasiparticle propagation. On the other hand, quenching to, as well as away from the criticality point shows that the longtime pairwise quantum discord gets enhanced from its initial state. Finally, we show that in the gapped region a quench in the transverse field displays survival of the next-nearest-neighbor quantum discord. Our results provide a further insight into the dynamical behavior of quantum correlations and their connections to quantum criticality.

Spreading of entanglement and correlations after a quench with intertwined quasiparticles

We extend the semiclassical picture for the spreading of entanglement and correlations to quantum quenches with several species of quasiparticles that have non-trivial pair correlations in momentum space. These pair correlations are, for example, relevant in inhomogeneous lattice models with a periodically-modulated Hamiltonian parameter. We provide explicit predictions for the spreading of the entanglement entropy in the space-time scaling limit. We also predict the time evolution of one- and two-point functions of the order parameter for quenches within the ordered phase. We test all our predictions against exact numerical results for quenches in the Ising chain with a modulated transverse field and we find perfect agreement.

Entanglement evolution and generalised hydrodynamics: noninteracting systems

The large-scale properties of homogeneous states after quantum quenches in integrable systems have been successfully described by a semiclassical picture of moving quasiparticles. Here we consider the generalisation for the entanglement evolution after an inhomogeneous quench in noninteracting systems in the framework of generalised hydrodynamics. We focus on the protocol where two semi-infinite halves are initially prepared in different states and then joined together, showing that a proper generalisation of the quasiparticle picture leads to exact quantitative predictions. If the system is initially prepared in a quasistationary state, we find that the entanglement entropy is additive and it can be computed by means of generalised hydrodynamics. Conversely, additivity is lost when the initial state is not quasistationary; yet the entanglement entropy in the large-scale limit can be exactly predicted in the quasiparticle picture, provided that the initial state is low entangled.

Thickness Dependence of Space-Charge-Limited Current in Spatially Disordered Organic Semiconductors

Charge transport properties in organic semiconductors are determined by two kinds of microscopic disorders, namely, energetic disorder related to the distribution of localized states and the spatial disorder related to the morphological features of the material. From a semiclassical picture, the charge transport properties are crucially determined by both the carrier mobility and the electrostatic field distribution in the material. Although the effect of disorders on carrier mobility has been widely studied, how electrostatic field distribution is distorted by the presence of disorders and its effect on charge transport remain unanswered. In this paper, we present a modified space-charge-limited current (SCLC) model for spatially disordered organic semiconductors based on the fractional-dimensional electrostatic framework. We show that the thickness dependence of the SCLC is related to the spatial disorder in organic semiconductors. For trap-free transport, the SCLC exhibits a modified thickness scaling of J α L <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">-3α</sup> , where the fractional-dimensional parameter α accounts for the spatial disorder in organic semiconductors. The trap-limited and field-dependent mobility are also shown to obey an α-dependent thickness scaling. The modified SCLC model shows good agreement with several experiments on spatially disordered organic semiconductors. By applying this model to the experimental data, the standard charge transport parameters can be deduced with better accuracy than by using existing models.

On the impossibility of localised states for molecular rotors with cyclic potentials

We discover a surprising property of an important class of molecular rotors. These rotors have one (e.g. a methyl group) or two (e.g. the planar boron rotor ) moieties that consist of identical nuclei rotating in cyclic model potential energy surfaces with equivalent potential wells (e.g. for CH, for ). The familiar semiclassical picture of this contorsion assumes that the potential wells support equivalent global minimum structures with corresponding localised wave functions being embedded in the individual potential wells. In contrast, we show that the wave functions of these rotors can never be squeezed into a single potential well, and hence, global minimum structures do not exist. Our quantum mechanical derivation describes the rotors in the frame of the proper cyclic molecular symmetry group and makes use of the spin-statistics theorem and the hypothesis of nuclear spin isomers. We show that if the identical nuclei have zero spins, then a hypothetical localised state would violate the spin-statistic theorem. Otherwise, the hypothetical localised state is ruled out as unphysical superposition of different nuclear spin isomers of the molecular rotors.

Temporal Order in Periodically Driven Spins in Star-Shaped Clusters.

We experimentally study the response of star-shaped clusters of initially unentangled N=4, 10, and 37 nuclear spin-1/2 moments to an inexact π-pulse sequence and show that an Ising coupling between the center and the satellite spins results in robust period-2 magnetization oscillations. The period is stable against bath effects, but the amplitude decays with a timescale that depends on the inexactness of the pulse. Simulations reveal a semiclassical picture in which the rigidity of the period is due to a randomizing effect of the Larmor precession under the magnetization of surrounding spins. The timescales with stable periodicity increase with net initial magnetization, even in the presence of perturbations, indicating a robust temporal ordered phase for large systems with finite magnetization per spin.

Chirality-Dependent Electron Spin Filtering by Molecular Monolayers of Helicenes.

The interaction of low-energy photoelectrons with well-ordered monolayers of enantiopure helical heptahelicene molecules adsorbed on metal surfaces leads to a preferential transmission of one longitudinally polarized spin component, which is strongly coupled to the helical sense of the molecules. Heptahelicene, composed of only carbon and hydrogen atoms, exhibits only a single helical turn but shows excess in longitudinal spin polarization of about P Z = 6 to 8% after transmission of initially balanced left- and right-handed spin polarized electrons. Insight into the electronic structure, that is, the projected density of states, and the spin-dependent electron scattering in the helicene molecule is gained by using spin-resolved density functional theory calculations and a model Hamiltonian approach, respectively. Our results support the semiclassical picture of electronic transport along a helical pathway under the influence of spin-orbit coupling induced by the electrostatic molecular potential.

On the hadron mass decomposition

We argue that the standard decompositions of the hadron mass overlook pressure effects, and hence should be interpreted with great care. Based on the semiclassical picture, we propose a new decomposition that properly accounts for these pressure effects. Because of Lorentz covariance, we stress that the hadron mass decomposition automatically comes along with a stability constraint, which we discuss for the first time. We show also that if a hadron is seen as made of quarks and gluons, one cannot decompose its mass into more than two contributions without running into trouble with the consistency of the physical interpretation. In particular, the so-called quark mass and trace anomaly contributions appear to be purely conventional. Based on the current phenomenological values, we find that in average quarks exert a repulsive force inside nucleons, balanced exactly by the gluon attractive force.

Multidimensional Quantum Mechanical Modeling of Electron Transfer and Electronic Coherence in Plant Cryptochromes: The Role of Initial Bath Conditions.

A multidimensional quantum mechanical protocol is used to describe the photoinduced electron transfer and electronic coherence in plant cryptochromes without any semiempirical, e.g., experimentally obtained, parameters. Starting from a two-level spin-boson Hamiltonian we look at the effect that the initial photoinduced nuclear bath distribution has on an intermediate step of this biological electron transfer cascade for two idealized cases. The first assumes a slow equilibration of the nuclear bath with respect to the previous electron transfer step that leads to an ultrafast decay with little temperature dependence; while the second assumes a prior fast bath equilibration on the donor potential energy surface leading to a much slower decay, which contrarily displays a high temperature dependence and a better agreement with previous theoretical and experimental results. Beyond Marcus and semiclassical pictures these results unravel the strong impact that the presence or not of equilibrium initial conditions has on the electronic population and coherence dynamics at the quantum dynamics level in this and conceivably in other biological electron transfer cascades.

Novel vacuum conditions in inflationary collapse models

Within the framework of inflationary models that incorporate a spontaneous reduction of the wave function for the emergence of the seeds of cosmic structure, we study the effects on the primordial scalar power spectrum by choosing a novel initial quantum state that characterizes the perturbations of the inflaton. Specifically, we investigate under which conditions one can recover an essentially scale free spectrum of primordial inhomogeneities when the standard Bunch–Davies vacuum is replaced by another one that minimizes the renormalized stress–energy tensor via a Hadamard procedure. We think that this new prescription for selecting the vacuum state is better suited for the self-induced collapse proposal than the traditional one in the semiclassical gravity picture. We show that the parametrization for the time of collapse, considered in previous works, is maintained. Also, we obtain an angular spectrum for the CMB temperature anisotropies consistent with the one that best fits the observational data. Therefore, we conclude that the collapse mechanism might be of a more fundamental character than previously suspected.

Quantum interference in laser-induced nonsequential double ionization

Quantum interference plays an important role in various intense-laser-driven atomic phenomena, e.g., above-threshold ionization and high-order-harmonic generation, and provides a useful tool in ultrafast imaging of atomic and molecular structure and dynamics. However, it has eluded observation in nonsequential double ionization (NSDI), which serves as an ideal prototype to study electron-electron correlation. Thus far, NSDI usually could be well understood from a semiclassical perspective, where all quantum aspects have been ignored after the first electron has tunneled. Here we perform coincidence measurements for NSDI of xenon subject to laser pulses at 2400 nm. It is found that the intensity dependence of the asymmetry parameter between the yields in the second and fourth quadrants and those in the first and third quadrants of the electron-momentum-correlation distributions exhibits a peculiar fast oscillatory structure, which is beyond the scope of the semiclassical picture. Our theoretical analysis indicates that this oscillation can be attributed to interference between the contributions of different excited states in the recollision-excitation-with-subsequent-ionization channel. Our work demonstrates the significant role of quantum interference in NSDI and may create an additional pathway towards manipulation and imaging of the ultrafast atomic and molecular dynamics in intense laser fields.

Tunneling method for Hawking radiation in the Nariai case

We revisit the tunneling picture for the Hawking effect in light of the charged Nariai manifold, because this general relativistic solution, which displays two horizons, provides the bonus to allow the knowledge of exact solutions of the field equations. We first perform a revisitation of the tunneling ansatz in the framework of particle creation in external fields a la Nikishov, which corroborates the interpretation of the semiclassical emission rate Gamma as the conditional probability rate for the creation of a couple of particles from the vacuum. Then, particle creation associated with the Hawking effect on the Nariai manifold is calculated in two ways. On the one hand, we apply the Hamilton Jacobi formalism for tunneling, in the case of a charged scalar field on the given background. On the other hand, the knowledge of the exact solutions for the Klein Gordon equations on Nariai manifold, and their analytic properties on the extended manifold, allow us a direct computation of the flux of particles leaving the horizon, and, as a consequence, we obtain a further corroboration of the semiclassical tunneling picture from the side of S-matrix formalism.

Influence of nonmagnetic impurity scattering on spin dynamics in diluted magnetic semiconductors

The doping of semiconductors with magnetic impurities gives rise not only to a spin-spin interaction between quasi-free carriers and magnetic impurities, but also to a local spin-independent disorder potential for the carriers. Based on a quantum kinetic theory for the carrier and impurity density matrices as well as the magnetic and non-magnetic carrier-impurity correlations, the influence of the non-magnetic scattering potential on the spin dynamics in DMS after optical excitation with circularly polarized light is investigated using the example of Mn-doped CdTe. It is shown that non-Markovian effects, which are predicted in calculations where only the magnetic carrier-impurity interaction is accounted for, can be strongly suppressed in the presence of non-magnetic impurity scattering. This effect can be traced back to a significant redistribution of carriers in $\mathbf{k}$-space which is enabled by the build-up of large carrier-impurity correlation energies. A comparison with the Markov limit of the quantum kinetic theory shows that, in the presence of an external magnetic field parallel to the initial carrier polarization, the asymptotic value of the spin polarization at long times is significantly different in the quantum kinetic and the Markovian calculations. This effect can also be attributed to the formation of strong correlations which invalidates the semiclassical Markovian picture and it is stronger when the non-magnetic carrier-impurity interaction is accounted for. In an external magnetic field perpendicular to the initial carrier spin, the correlations are also responsible for a renormalization of the carrier spin precession frequency.

Multilevel perspective on high-order harmonic generation in solids

We investigate high-order harmonic generation in a solid, modeled as a multi-level system dressed by a strong infrared laser field. We show that the cutoff energies and the relative strengths of the multiple plateaus that emerge in the harmonic spectrum can be understood both qualitatively and quantitatively by considering a combination of adiabatic and diabatic processes driven by the strong field. Such a model was recently used to interpret the multiple plateaus exhibited in harmonic spectra generated by solid argon and krypton [Ndabashimiye {\it et al.}, Nature 534, 520 (2016)]. We also show that when the multi-level system originates from the Bloch state at the $\Gamma$ point of the band structure, the laser-dressed states are equivalent to the Houston states [Krieger {\it el al.} Phys. Rev. B 33, 5494 (1986)] and will therefore map out the band structure away from the $\Gamma$ point as the laser field increases. This leads to a semi-classical three-step picture in momentum space that describes the high-order harmonic generation process in a solid.

Enhanced nonlinear susceptibility via double-double electromagnetically induced transparency

We investigate the nonlinear optical susceptibility of an alkali-metal atom with tripod electronic configuration responsible for generating cross-phase modulation and self-phase modulation under the condition of double-double electromagnetically induced transparency. Our investigation demonstrates an enhancement in the nonlinear optical susceptibility of an alkali-metal atom by a factor of 1000 in the region of the second transparency window. This enhancement is in comparison with the atom's susceptibility in the first transparency window for the same parameters under the same conditions. Nonlinear-absorption enhancement arises by canceling Raman-gain generation, which arises when the probe and signal fields have equal intensities. At the center of the second transparency window, we obtain the condition required to attain a nonvanishing nonlinear optical susceptibility. In the bare-state picture, the coupling field must be off resonant from a bare-to-bare-state transition, while working in the semiclassical dressed picture required the signal field to be tuned off resonantly with a bare-to-dressed-state transition. The relation that governs the values of coupling- and signal-field detuning are also obtained. Our scheme exhibits the fact that the second transparency window has advantages over the first transparency window with respect to obtaining an enhanced Kerr effect, and our calculation includes simulation of both low-temperature and Doppler-broadened regimes.