Semiclassical Picture Research Articles

Quantum-optical radiative recombination between electrons and ions analyzed with a semiclassical picture

Quantum-optical radiative recombination between electrons and ions analyzed with a semiclassical picture

Shannon entropy in quasiparticle states of quantum chains

Abstract We investigate the Shannon entropy of the total system and its subsystems, as well as the subsystem Shannon mutual information, in quasiparticle excited states of free bosonic and fermionic chains and the ferromagnetic phase of the spin-1/2 XXX chain. For single-particle and double-particle states, we derive various analytical formulas for free bosonic and fermionic chains in the scaling limit. These formulas are also applicable to certain magnon excited states in the XXX chain in the scaling limit. We also calculate numerically the Shannon entropy and mutual information for triple-particle and quadruple-particle states in bosonic, fermionic, and XXX chains. We discover that Shannon entropy, unlike entanglement entropy, typically does not separate for quasiparticles with large momentum differences. Moreover, in the limit of large momentum difference, we obtain universal quantum bosonic and fermionic results that are generally distinct and cannot be explained by a semiclassical picture.

Quantum theory of orbital angular momentum in spatiotemporal optical vortices

Spatiotemporal Optical Vortices (STOVs) are structured electromagnetic fields propagating in free space with phase singularities in the space-time domain. Depending on the tilt of the helical phase front, STOVs can carry both longitudinal and transverse orbital angular momentum (OAM). Although STOVs have gained significant interest in the recent years, the current understanding is limited to the semi-classical picture. Here, we develop a quantum theory for STOVs with an arbitrary tilt, extending beyond the paraxial limit. We demonstrate that quantum STOV states, such as Fock and coherent twisted photon pulses, display non-vanishing longitudinal OAM fluctuations that are absent in conventional monochromatic twisted pulses. We show that these quantum fluctuations exhibit a unique texture, i.e. a spatial distribution which can be used to experimentally isolate these quantum effects. Our findings represent a step towards the exploitation of quantum effects of structured light for various applications such as OAM-based encoding protocols and platforms to explore novel light–matter interaction in 2D material systems.

Nonadiabatic effects lead to the breakdown of the semiclassical phonon picture

Nonadiabatic effects lead to the breakdown of the semiclassical phonon picture

On the limitations of the semi-classical picture in high harmonic generation

On the limitations of the semi-classical picture in high harmonic generation

Entanglement islands read perfect-tensor entanglement

In this paper, we make use of holographic Boundary Conformal Field Theory (BCFT) to simulate the black hole information problem in the semi-classical picture. We investigate the correlation between a portion of Hawking radiation and entanglement islands by the area of an entanglement wedge cross-section. Building on the understanding of the relationship between entanglement wedge cross-sections and perfect tensor entanglement as discussed in reference [18], we make an intriguing observation: in the semi-classical picture, the positioning of an entanglement island automatically yields a pattern of perfect tensor entanglement. Furthermore, the contribution of this perfect tensor entanglement, combined with the bipartite entanglement contribution, precisely determines the area of the entanglement wedge cross-section.

Divergent Nonlinear Response from Quasiparticle Interactions.

We demonstrate that nonlinear response functions in many-body systems carry a sharp signature of interactions between gapped low-energy quasiparticles. Such interactions are challenging to deduce from linear response measurements. The signature takes the form of a divergent-in-time contribution to the response-linear in time in the case when quasiparticles propagate ballistically-that is absent for free bosonic excitations. We give a physically transparent semiclassical picture of this singular behavior. While the semiclassical picture applies to a broad class of systems we benchmark it in two simple models: in the Ising chain using a form-factor expansion, and in a nonintegrable model-the spin-1 Affleck-Kennedy-Lieb-Tasaki chain-using time-dependent density matrix renormalization group simulations. We comment on extensions of these results to finite temperatures.

Smooth extensions of black holes in loop quantum gravity

Vacuum spherically symmetric loop quantum gravity in the midi-superspace approximation using inhomogeneous horizon-penetrating slices has been studied for a decade, and it has been noted that the singularity is eliminated. It is replaced by a region of high curvature and potentially large quantum fluctuations. It was recently pointed out that the effective semiclassical metric implies the existence of a shell of matter which violates energy conditions in regions where the curvature is largest. Here, we propose an alternative way of treating the problem that is free from the shells. The ambiguity in the treatment is related with the existence of new observables in the quantum theory that characterize the area excitations, and how the counterpart of diffeomorphisms in the discrete quantum theory is mapped to the continuum semiclassical picture. The resulting spacetime in the high curvature region inside the horizon is approximated by a metric of the type of the Simpson–Visser wormhole and it connects the black hole interior to a white hole in a smooth manner.

The three kingdoms-Photoinduced electron transfer cascades controlled by electronic couplings.

Excited states are the key species in photocatalysis, while the critical parameters that govern their applications are (i) excitation energy, (ii) accessibility, and (iii) lifetime. However, in molecular transition metal-based photosensitizers, there is a design tension between the creation of long-lived excited (triplet), e.g., metal-to-ligand charge transfer (3MLCT) states and the population of such states. Long-lived triplet states have low spin-orbit coupling (SOC) and hence their population is low. Thus, a long-lived triplet state can be populated but inefficiently. If the SOC is increased, the triplet state population efficiency is improved-coming at the cost of decreasing the lifetime. A promising strategy to isolate the triplet excited state away from the metal after intersystem crossing (ISC) involves the combination of transition metal complex and an organic donor/acceptor group. Here, we elucidate the excited state branching processes in a series of Ru(II)-terpyridyl push-pull triads by quantum chemical simulations. Scalar-relativistic time-dependent density theory simulations reveal that efficient ISC takes place along 1/3MLCT gateway states. Subsequently, competitive electron transfer (ET) pathways involving the organic chromophore, i.e., 10-methylphenothiazinyl and the terpyridyl ligands are available. The kinetics of the underlying ET processes were investigated within the semiclassical Marcus picture and along efficient internal reaction coordinates that connect the respective photoredox intermediates. The key parameter that governs the population transfer away from the metal toward the organic chromophore either by means of ligand-to-ligand (3LLCT; weakly coupled) or intra-ligand charge transfer (3ILCT; strongly coupled) states was determined to be the magnitude of the involved electronic coupling.

Coherent-Phonon-Driven Hot-Carrier Effect in a Superlattice Solar Cell

Carrier thermalization in a superlattice solar cell made of polar semiconductors is studied theoretically by considering a minimal model where electron-phonon scattering is the principal channel of carrier energy loss. Importantly, the effect of an intrinsic quantum mechanical property; the phonon coherence, on carrier thermalization is investigated, within semiclassical picture in terms of phonon wave packet. It turns out that coherent longitudinal optical (LO) phonons weaken the effective electron-phonon coupling, thus supposedly lowering the carrier energy loss rate in solar cell. The resulting thermalization power is indeed significantly reduced by the coherent phonons, resulting in enhanced hot carrier effect, particularly for thin enough well layer where carrier confinement is also strong. A recent experiment on superlattice solar cell prototype is shown to manifest the coherent phonons-driven phenomenon. Our results demonstrate the practical implications of the fundamental quantum coherence property of phonons in semiconductors for improving superlattice solar cell performance, via hot carrier effect.

Field-linear anomalous Hall effect and Berry curvature induced by spin chirality in the kagome antiferromagnet Mn3Sn

During the past two decades, it has been established that a non-trivial electron wave-function topology generates an anomalous Hall effect (AHE), which shows itself as a Hall conductivity non-linear in magnetic field. Here, we report on an unprecedented case of field-linear AHE. In Mn3Sn, a kagome magnet, the out-of-plane Hall response, which shows an abrupt jump, was discovered to be a case of AHE. We find now that the in-plane Hall response, which is perfectly linear in magnetic field, is set by the Berry curvature of the wavefunction. The amplitude of the Hall response and its concomitant Nernst signal exceed by far what is expected in the semiclassical picture. We argue that magnetic field induces out-of-plane spin canting and thereafter gives rise to nontrivial spin chirality on the kagome lattice. In band structure, we find that the spin chirality modifies the topology by gapping out Weyl nodal lines unknown before, accounting for the AHE observed. Our work reveals intriguing unification of real-space Berry phase from spin chirality and momentum-space Berry curvature in a kagome material.

Overcoming the entanglement barrier in quantum many-body dynamics via space-time duality

Describing nonequilibrium properties of quantum many-body systems is challenging due to high entanglement in the wave function. We describe the evolution of local observables via the influence matrix (IM), which encodes the effects of a many-body system as an environment for local subsystems. Recent works found that in many dynamical regimes the IM of an infinite system has low temporal entanglement and can be efficiently represented as a matrix-product state (MPS). Yet, direct iterative constructions of the IM encounter highly entangled intermediate states---a temporal entanglement barrier (TEB). We argue that TEB is ubiquitous, and elucidate its physical origin via a semiclassical quasiparticle picture that exactly captures the behavior of integrable spin chains. Further, we show that a TEB also arises in chaotic spin chains, which lack well-defined quasiparticles. Based on these insights, we formulate an alternative light-cone growth algorithm, which provably avoids TEB, thus providing an efficient construction of the thermodynamic-limit IM as a MPS. This work uncovers the origin of the efficiency of the IM approach for studying thermalization and transport.

The PEE aspects of entanglement islands from bit threads

We study the partial entanglement entropy (PEE) aspects of the holographic BCFT setup with an entanglement island, inspired by the holographic triality of the AdS/BCFT setup developed in the recent study on the black hole information problem, and the “PEE=CFF (component flow flux)” prescription, which is proposed recently to investigate the holographic PEE in the framework of bit thread formulation. Our study provides a bit thread description of the AdS/BCFT setup, which characterizes the specific entanglement details between the different parts of the system with an entanglement island, and may provide further insight into the black hole information problem. Furthermore, we show that in the context of island, one should distinguish between the fine-grained PEE and the semi-classical PEE. Interestingly, similar to the island rule of the fine-grained entropy in the semi-classical picture, we also propose the island rules of the fine-grained PEE.

Temporal Entanglement, Quasiparticles, and the Role of Interactions

In quantum many-body dynamics admitting a description in terms of noninteracting quasiparticles, the Feynman-Vernon influence matrix (IM), encoding the effect of the system on the evolution of its local subsystems, can be analyzed exactly. For discrete dynamics, the temporal entanglement (TE) of the corresponding IM satisfies an area law, suggesting the possibility of an efficient representation of the IM in terms of matrix-product states. A natural question is whether integrable interactions, preserving stable quasiparticles, affect the behavior of the TE. While a simple semiclassical picture suggests a sublinear growth in time, one can wonder whether interactions may lead to violations of the area law. We address this problem by analyzing quantum quenches in a family of discrete integrable dynamics corresponding to the real-time Trotterization of the interacting XXZ Heisenberg model. By means of an analytical solution at the dual-unitary point and numerical calculations for generic values of the system parameters, we provide evidence that, away from the noninteracting limit, the TE displays a logarithmic growth in time, thus violating the area law. Our findings highlight the nontrivial role of interactions, and raise interesting questions on the possibility to efficiently simulate the local dynamics of interacting integrable systems.

Entanglement dynamics of thermofield double states in integrable models

We study the entanglement dynamics of thermofield double (TFD) states in integrable spin chains and quantum field theories. We show that, for a natural choice of the Hamiltonian eigenbasis, the TFD evolution may be interpreted as a quantum quench from an initial state which is low-entangled in the real-space representation and displays a simple quasiparticle structure. Based on a semiclassical picture analogous to the one developed for standard quantum quenches, we conjecture a formula for the entanglement dynamics, which is valid for both discrete and continuous integrable field theories, and expected to be exact in the scaling limit of large space and time scales. We test our conjecture in two prototypical examples of integrable spin chains, where numerical tests are possible. First, in the XY-model, we compare our predictions with exact results obtained by mapping the system to free fermions, finding excellent agreement. Second, we test our conjecture in the interacting XXZ Heisenberg model, against numerical iTEBD calculations. For the latter, we generally find good agreement, although, for some range of the system parameters and within the accessible simulation times, some small discrepancies are visible, which we attribute to finite-time effects.

Entanglement dynamics in confining spin chains

The confinement of elementary excitations induces distinctive features in the non-equilibrium quench dynamics. One of the most remarkable is the suppression of entanglement entropy, which in several instances turns out to oscillate rather than grow indefinitely. While the qualitative physical origin of this behavior is clear, till now no quantitative understanding away from the field theory limit was available. Here we investigate this problem in the weak quench limit, when mesons are excited at rest, hindering entropy growth and exhibiting persistent oscillations. We provide analytical predictions of the entire entanglement dynamics based on a Gaussian approximation of the many-body state, which captures numerical data with great accuracy and is further simplified to a semiclassical quasiparticle picture in the regime of weak confinement. Our methods are valid in general and we apply explicitly to two prototypical models: the Ising chain in a tilted field and the experimentally relevant long-range Ising model.

Three-dimensional topological plasmons in Weyl semimetals

We systematically investigate the properties of bulk, surface and edge plasmons in Weyl semimetals in presence of a magnetic field. It is found that unidirectional plasmons with different properties exist on different surfaces, which is in consistent with the nontrivial topology of the three-dimensional (3D) bulk plasmons. These novel plasmons possess momentum-location lock and may travel between surfaces. The anomalous Hall conductivity brings about abundant anisotropic plasmon dispersions, from linear to parabolic or even hyperbolic bands. With the help of a semiclassical picture for the formation of the Weyl orbits, we point out the Fermi-arc plasmons at opposite surfaces can make up another unique 3D topological plasmon. Furthermore, there is a gapless unidirectional edge plasmon protected by the topology whose direction and position can be controlled by external field. Our work thus uncovers topological features of Weyl plasmons, which may have important applications in photoelectric devices based on chiral/topological plasmonics.

Resistivity saturation in Kondo insulators

Resistivities of heavy-fermion insulators typically saturate below a characteristic temperature T*. For some, metallic surface states, potentially from a non-trivial bulk topology, are a likely source of residual conduction. Here, we establish an alternative mechanism: at low temperature, in addition to the charge gap, the scattering rate turns into a relevant energy scale, invalidating the semi-classical Boltzmann picture. Then, finite lifetimes of intrinsic carriers drive residual conduction, impose the existence of a crossover T*, and control—now on par with the gap—the quantum regime emerging below it. Assisted by realistic many-body simulations, we showcase the mechanism for the Kondo insulator Ce3Bi4Pt3, for which residual conduction is a bulk property, and elucidate how its saturation regime evolves under external pressure and varying disorder. Deriving a phenomenological formula for the quantum regime, we also unriddle the ill-understood bulk conductivity of SmB6—demonstrating a wide applicability of our mechanism in correlated narrow-gap semiconductors.

Three-dimensional network model for strong topological insulator transitions

We construct a three-dimensional (3D), time-reversal symmetric generalization of the Chalker-Coddington network model for the integer quantum Hall transition. The novel feature of our network model is that in addition to a weak topological insulator phase already accommodated by the network model framework in the pre-existing literature, it hosts strong topological insulator phases as well. We unambiguously demonstrate that strong topological insulator phases emerge as intermediate phases between a trivial insulator phase and a weak topological phase. Additionally, we found a non-local transformation that relates a trivial insulator phase and a weak topological phase in our network model. Remarkably, strong topological phases are mapped to themselves under this transformation. We show that upon adding sufficiently strong disorder the strong topological insulator phases undergo phase transitions into a metallic phase. We numerically determine the critical exponent of the insulator-metal transition. Our network model explicitly shows how a semi-classical percolation picture of topological phase transitions in 2D can be generalized to 3D and opens up a new venue for studying 3D topological phase transitions.

Symmetry-breaking patterns, tricriticalities, and quadruple points in the quantum Rabi model with bias and nonlinear interaction

Quantum Rabi model (QRM) is fascinating not only because of its broad relevance and but also due to its few-body quantum phase transition. In practice both the bias and the nonlinear coupling in QRM are important controlling parameters in experimental setups. We study the interplay of the bias and the nonlinear interaction with the linear coupling in the ground state which exhibits various patterns of symmetry breaking and different orders of transitions. Several situations of tricriticality are unveiled in the low frequency limit and at finite frequencies. We find that the full quantum-mechanical effect leads to novel transitions, tricriticalities and quadruple points, which are much beyond the semiclassical picture. We clarify the underlying mechanisms by analyzing the energy competitions and the essential changeovers of the quantum states, which enables us to extract most analytic phase boundaries.