SEM Images Research Articles

Upconversion-nanoparticle-assisting near-infrared photosensitive effect at 1550 nm in organic photorefractive devices

The near-infrared (NIR) photosensitive photorefractive device is a promising optoelectronic unit in the optical signal/information processing and telecommunication. In this work, the upconversion-assisting NIR photosensitive device is presented by adding the upconversion nanoparticles (UCNPs) to the photorefractive composite with (Vlieg et al., 2022; Vlieg et al., 2022) [6,6]-phenyl-C61-butyric acid methyl ester (PC61BM) as visible photosensitizer. The XRD and TEM results indicated the hexagonal β-phase nanoparticles of UCNPs. The PL measurement under the 1550-nm excitation showed the upconversion emission peaks of NaYF4:Er@NaYF4 nanocrystals at the visible lights of 525 nm, 545 nm and 650 nm. The SEM images revealed that the CRA-DR1 photorefractive composite takes on a good morphology due to the uniform distribution of UCNPs. The two-beam coupling (TBC) experiment without external electric filed indicated the coupling gain coefficient of 77.4 cm−1 at 1550 nm in the CRA-DR1/ECZ/PC61BM/(5 %)UCNPs composite. This upconversion-assisting photosensitive effect will open up the novel approaches for organic NIR photorefractive devices.

Detrital K-feldspar as a novel archive of continental crustal evolution using coupled in situ Rb[sbnd]Sr dating and Pb isotope analysis

Here we present in situ RbSr and Pb isotopic analysis of K-feldspar from the Shap Granite, (Cumbria, UK) and detrital K-feldspar from the associated Shap Wells Conglomerate Formation, to investigate the potential of the detrital K-feldspar record as an archive of crustal composition. We use a unique, collision cell – multi collector inductively coupled plasma tandem mass spectrometer to make the in situ isotope measurements, using ‘chemical resolution’ of 87Rb+ and 204Hg+ isobaric interferences on 87Sr+ and 204Pb+, achieved with SF6 and NH3 reaction gases, respectively. Using this technique, we successfully demonstrate that the majority of detrital K-feldspar RbSr ages, as well as initial Sr and Pb isotope ratios, from the Shap Wells Conglomerate are within uncertainty of those for parental Shap Granite K-feldspar (398 ± 1 Ma, n = 6). Some detrital K-feldspar grains record perturbed RbSr ages, reflecting post depositional alteration events. The majority of samples with disturbed RbSr ages carry distinct petrographic features evident in SEM imaging, prior to in situ dating, which indicates a means to help screen for reliable ages.We further illustrate the potential value of combined RbSr and Pb isotopic information preserved in K-feldspar to estimate the timing and chemical composition of juvenile continental crust formed in the past. Where UPb has been fractionated during juvenile crust formation, the initial Pb isotope ratio provided by the K-feldspar yields model crustal U/Pb (diagnostic of tectonic setting) and extraction age. The contrast in the U/Pb composition of juvenile crust formed in intraplate or subduction settings allows the model U/Pb ratios of the detrital K-feldspars to be used to constrain the style of juvenile crust formation. Additionally, the initial 87Sr/86Sr isotope ratio measured in detrital K-feldspar can be combined with the calculated crustal extraction age and RbSr K-feldspar age to model the Rb/Sr of the juvenile crustal protolith.

Accurate recognition of micromorphology images of epoxy coatings for deep-sea environments based on a deep learning super-resolution method

Crack initiation and extension occur in organic coatings during service in deep-sea environments. However, when extracting detailed crack information from SEM images of epoxy mica coatings at different time periods in a simulated deep-sea fluid-hydraulic environment, uninteresting background regions are treated equally, resulting in unnecessary computational redundancy. To address the relatively blurred edges and unclear textures of SEM images, a crack image super-resolution network based on global mixed attention (GMA-net) is proposed for application to SEM images of organic coatings. The recognition results of the images processed with GMA-net were compared with those of the original images and the images processed with bicubic method, respectively. The results show that this method not only refrains from destroying the clarity of the original images but also greatly outperforms bicubic method in terms of precision, recall, mAP50 and mPA50-95, which are improved by approximately 23.1%, 32.4%, 36.4% and 26.7%, respectively. This method effectively highlights the details and improves the recognition accuracy of the edge texture with the aim of providing a good basis for subsequent recognition and even lifetime prediction studies.

Inclusion Complexation of Flavonoids with Cyclodextrin: Molecular Docking and Experimental Study

AbstractIn our work, the inclusion ability and binding pattern of flavonoids (catechin, iso‐liquiritigenin, luteolin, puerarin, rutin, and curcumin) with β‐cyclodextrin (β‐CD) and curcumin (CUR) with CDs (α‐CD, β‐CD, γ‐CD, dimethyl‐β‐CD, Hydroxypropyl‐β‐CD, and glucosyl‐β‐CD) were studied by molecular docking. The results showed that CUR among the six flavonoids was more likely to form stable inclusion complexes with β‐CD, and the HP‐β‐CD is the most suitable for CUR inclusion among the 6 types of CD. Phase solubility studies showed that CUR with β‐CD or HP‐β‐CD, respectively, could form stable inclusion complexes in a stoichiometric ratio of 1 : 1. The CUR/β‐CD and CUR/HP‐β‐CD inclusion complexes (ICs) were prepared by freeze‐drying method. The successful preparation of IC was confirmed by SEM images, FT‐IR spectra, and TG‐DSC. The results of in vitro release showed that the release of CUR from IC prepared with β‐CD or HP‐β‐CD could be improved significantly, and the release effect of HP‐β‐CD was better than that of β‐CD. The inclusion with CD could be used to improve the solubility and bioavailability of CUR.

Shape-controlled growth of beta-gallium oxide nanowires and experimental investigation on the origination of electrons

Diameter-controlled growth of monoclinic gallium oxide nanowires was performed by chemical vapor deposition technique. Prior to growth, a thin layer of Au films was fabricated, SEM images indicated that Au could converge nanoparticles to govern the growth of β-Ga2O3 nanowires. The SEM images revealed both diameter and length of β-Ga2O3 nanowires strongly depended on the growth temperature. Nanowires grown at 1100 °C temperature have the minimum diameters and uniform lengths, compared with those grown at 900 °C and 1000 °C. The reasons are that a combination and a competition of vapor-liquid-solid (VLS) and vapor-solid (VS) mechanism occur in the growth process. High temperature would provide enough energy to make Ga and O atoms grow along one-dimensional axial orientation following the VLS mechanism. However, low temperature confines atoms at the nanowires interface and enhance sidewalls coalescence following the VS mechanism. X-ray diffraction (XRD) patterns and refinement indicated that the grown samples were of high crystallinity and had intrinsic oxygen vacancies. Photoluminescence spectra were examined and then followed by Gaussian fitting. Through analysis, the emission peaks were considered to originate from intrinsic oxygen vacancies and Ga-O vacancy pairs, consisting with the XRD refinement results. β-Ga2O3 nanowires was coated on the interdigitated electrode, the response to the ultraviolet light and oxygen was studied.

Preparation, characterization and intercalation mechanism of bentonite modified with different organic ammonium

Three organic ammoniums with different molecular configurations were selected to modify Ca-bentonite and Na-bentonite. The FTIR spectra SEM images and XRD diagrams of bentonite before and after modification were compared. The adsorption performance of bentonite samples for Hg(II) ions was contrasted. The results indicate that the more complex the molecular configuration of organic ammonium, the greater the steric hindrance, and the more difficult it is to insert into the interlayer space. The chelation between the functional groups contained in organic ammonium and the interlayer cations in bentonite is unfavorable for organic ammonium molecules to enter the interlayer space. Some organic ammonium molecules that cannot enter the interlayer space can adhere to the surface of bentonite particles through interaction with functional groups on the particle surface or through electrostatic interactions and hydrogen bonding forces, forming nanocomposites. Thereby, the adsorption performance of benonite samples modified with organic ammonium for Hg(II) ions improved.

Facile room temperature synthesis of MIL-100(Fe) from magnetic zircon tailing and its application for methylene blue removal

Abstract Some of the dominant minerals found in the magnetic separation of zircon tailing are minerals containing iron (Fe). These materials have the potential to be processed into adsorbents. One of the materials synthesized using iron compounds as a precursor is MIL-100(Fe). The aim of this research was to obtain MIL-100(Fe) by utilizing magnetic zircon tailing, and applied as an adsorbent for methylene blue. The synthesis of MIL-100(Fe) was initiated by destruction of magnetic zircon tailing with HCl, followed by reacting the destruction filtrate with trimesic acid (H3BTC) for 24 hours at room temperature, in which the H3BTC was dissolved in NaOH with a molar ratio of 1.5 Fe : 1 H3BTC : 3 NaOH, prior to the reaction. A reddish orange precipitate obtained was then washed, dried, and characterized by using FTIR, XRD and SEM. Characteristics of FTIR spectra, XRD pattern and SEM images was similar with MIL-100(Fe) reported. The best-fitting model for the adsorption mechanism was the pseudo-second order. The most suitable adsorption isotherm was the Langmuir model. The maximum adsorption capacity of MIL-100(Fe)-W (222.89 mg/g) was higher than that of MIL-100(Fe)-C (151.59 mg/g). The result indicated that iron content in magnetic zircon tailing can be used as precursor for synthesis of MIL-100(Fe).

Eco-conscious Silver nanoparticles through “flower extract” of Murraya paniculata (L) Jack for reduction of 4-nitro phenol

Green synthesis of metal nanoparticles using plant extracts has gained recognition. We report, the eco-friendly synthesis of Silver nanoparticles using the aqueous flower extract of Murraya paniculata (L) Jack (MP Silver NPs). Characterisation of the NPs was carried out using different spectroscopic and microscopic techniques. The findings confirmed the presence of silver NPs via UV–vis spectroscopy, FTIR and XRD. SEM and TEM images indicated spherical structured MP silver NPs, with an average size of 27.8 nm. Elemental analysis using XPS confirmed the presence of Ag in NPs. Biosynthesised silver NPs were explored for catalytical activity. The current work produces Silver NPs using a new green source. and, Silver NPs have a broad spectrum of applications.

Synthesis, characterization, and catalytic activity of zinc-isonicotinic acid MOF

The synthesis and characterization of Zn (INA) microcrystalline MOF was conducted, revealing its high catalytic activity in the production of substituted benzyl alcohol (BzOH) to substituted benzaldehyde (BzA). The MOF was found to be cost-effective and efficient, with a short synthesis time and moderate reaction conditions. The MOF's structure was confirmed through XRD, SEM, and TEM imaging, and its purity was confirmed through EDS analysis. The TGA investigation revealed significant thermal stability with minimal weight loss and BET studies shows the substantial surface area and pore volume, suggesting potential for various industrial uses. The MOF's efficiency under mild reaction conditions, low cost, and absence of noble metals makes it a promising candidate for sustainable catalytic applications.

Direct Writing of graphene/graphitic foam through picosecond pulsed laser-induced transformation of soluble polyimide suspension

We report the direct writing of graphene/graphitic foam with high electrical conductivity using laser-induced-transformation of polyimide (PI) resin films on glass surfaces. Raman spectroscopy of the treated surfaces indicated that average laser power irradiation between 900-1500 kW/cm2 transformed the PI film into a few layered graphene-dominated film, and the increase in irradiation power above 1500 kW/cm2 led to the formation of graphitic (multilayered graphene) material. The electrical conductivity of the transformed film was between 5800±750 S/m (lower power irradiation) and 1250±300 S/m (higher laser power irradiation). SEM imaging showed that the transformed material has a closed cell foam morphology enclosed between the smooth top and bottom layers. The results indicate that heat treatment of the polyimide suspension films, and subsequent ultra-short, pulsed laser irradiation resulted in a closed-cell graphene/graphitic foam with high electrical conductivity. The pore aspect ratio, density, and film conductivity are used to estimate the conductivity of the solid phases in the laser-treated films at different powers. Laser-induced transformation of the PI suspension into graphene/graphitic foam is conducive to additive manufacturing and may enable the direct printing of graphitic foam-based three-dimensional components.

Mechanical and thermal stability properties improvement of polyethylene wax-coated tungsten carbide/high-density polyethylene γ-rays shielding composites through irradiation-induced crosslinking

It is well known that the properties of polyethylene can be improved by irradiation-induced crosslinking the formation of three-dimensional network structures. This paper investigated the effects of gamma irradiation on the mechanical, thermal stability, and γ-rays shielding properties of TAIC-containing γ-rays shielding composites (HDPE/WC-PEW/TAIC). As a result, SEM images showed that agglomerations are alleviated after polyethylene wax (PEW) coated tungsten carbide (WC). The tensile strength and hardness increased from 25.39 MPa to 94 HA to 29.49 MPa and 98 HA after 50 kGy irradiation in vacuum as compared with all composites, while the thermal stability was also improved. The XPS and gel content results showed that the more crosslinked structures generated after 50 kGy irradiated in vacuum between high-density polyethylene (HDPE) and PEW, but irradiation in air is accompanied by the destruction of polymer skeleton. Moreover, the shielding rates of HDPE/WC-PEW/TAIC with thickness of 2 mm and containing 50 wt% WC can exceed 50% and 25% for 137Cs and 60Co sources respectively. In summary, HDPE/WC-PEW/TAIC could be an alternative to lead as γ-rays shielding material with excellent mechanical, thermal, and γ-rays shielding properties after 50 kGy irradiation in vacuum.

Characterization of Taro (Colocasia esculenta) stolon polysaccharide and evaluation of its potential as a tablet binder in the formulation of matrix tablet

This investigation focuses on the extraction, characterization, and evaluation of taro (Colocasia esculenta) stolon polysaccharide (TSP) as a tablet binding agent, which is obtained from edible taro stolon. TSP was subjected to phytochemical screening and characterized by FTIR, DSC, TGA, DTA, XRD, particle size, polydispersity index, zeta potential, rheological behavior, and SEM. The tablets prepared with varying concentrations of TSP (2.5 %, 5 %, 7.5 %, and 10 % w/w) and diclofenac sodium (DS) were evaluated and compared with the same concentrations of gum acacia and PVP K-30. The presence of carbohydrates was confirmed by Molisch's test. The FTIR spectra established the compatibility of the drug with excipients. The SEM images revealed asymmetric and elongated particles of TSP powder. The hydration kinetics study showed matrix hydration and water penetration velocity within the range of 0.602–0.753 g/g and 0.112–0.189 cm/g.h, respectively. The tablets showed drug release of >75 % at 45 min. The release-exponent value above 0.89 indicated a super case II drug transport combining matrix erosion and diffusion. Optimum tablet hardness and very low friability, even at 2.5 % binder concentration, suggested the potential application of the novel TSP as a tablet binder in the formulation of the tablets.

Microstructure and properties of Cu-doped β-Ga2O3 rod prepared with liquid metallic gallium

One-dimensional β-Ga2O3 is expected for potential applications in electronics, sensors, and optoelectronics. Gallium hydroxide (GaO(OH)) with different Cu doping was prepared via the hydrothermal method using liquid metallic gallium and copper chloride dihydrate (CuCl2·2H2O) as the starting materials. The material was then transformed to β-Ga2O3 after calcination at 800 °C. SEM images reveal that the obtained powders are well dispersed and have a uniform rod morphology with a length of 13–14 μm and a width of approximately 500 nm. The addition of Cu ion significantly improves the surface morphology of the rod and effectively inhibits the generation of intrinsic oxygen vacancies. And the relative Fermi energy level of Cu-doped β-Ga2O3 undergoes a notable shift from 2.81 eV to 1.25 eV, suggesting the formation of p-type conductivity. Meanwhile, the PL spectra of the Cu-doped samples exhibit emission peaks in the red wavelength range, which is expected for new applications.

Capability lignin from Acacia crassicarpa black liquor as an environmentally benign antibacterial agent to produce antibacterial and hydrophobic textiles

Recently, the growing health awareness of society on the utilization of fabrics has led to an increasing demand for natural-based antibacterial textiles. Lignin, a generous polyphenol compound in nature, is capable of preventing bacterial growth; in particular, it dwells bacteria closely together on human skin, such as Staphylococcus epidermidis, Bacillus subtilis, Propionibacterium acnes, and Staphylococcus aureus. However, the antibacterial properties of lignin are limited by factors such as the lignin concentration, source, and type of bacteria. This study aimed to evaluate the potency of lignin as an antibacterial agent for textiles. Moreover, the thermal properties and wettability of the textile after lignin coating were also investigated. This study showed that lignin isolation methods significantly contributed to the inhibition of bacterial growth in the clear zone diameter. In addition, the lignin structure, lignin concentration, and type of bacteria had notably different antibacterial effects. SEM images showed that lignin was successfully coated on the fiber, and the antibacterial textile was successfully fabricated with clear zones in the range of 0.1–0.5 cm against four different bacteria. Lignin did not significantly improve the thermal stability of the textile, as proven by the TGA results. After the HDTMS coating by dispersion method, the wettability of the lignin-textile improved to that of the hydrophobic material, with a contact angle greater than 119.05° with excellent antibacterial properties (clear zone of 0.1–0.43 cm).

Extraction and characterization of novel alternative cellulosic fiber for sustainable textiles from Aloe barbadensis Miller stems (agricultural waste)

Novel research has been conducted on Aloe vera, focusing on stems fiber (agricultural waste), for the extraction of cellulosic fiber, an area lacking prior scientific exploration. This fiber is being reported for the first time in the scientific community. Aloe barbadensis Miller variety was subjected to various cultivation methods, including the application of inorganic and organic fertilizers, along with the removal of lower leaves to promote stem growth. Stem fibers were extracted using the water retting method and subsequently analyzed. The moisture content was 55.35 % and 6.99 % ash content in the fibers. The bacteriostatic analysis of Aloe vera fibers was assessed against four bacterial strains, with both ethanol and water extracts showing varying degrees of inhibition zones. The UV–Visible spectrum exhibited a distinct λmax at 247 nm in ethanol, while FT-IR analysis provided characteristic peaks at 3759, 1590, 1750, 1663, 1250, 564, SEM images displayed the smooth surface morphology of the fibers, and X-ray diffraction analysis indicated a high degree of crystallinity (78.67 %), suggesting a well-structured and crystalline nature. Energy dispersive X-ray (EDX) analysis was conducted to determine the elemental composition of the fibers, revealing the presence of carbon, oxygen, calcium, and copper, with carbon being the predominant element in cellulose. These results showed promising properties suggesting potential applications in textile industry as an alternative sustainable natural cellulosic fiber.

Microfluidics assisted green synthesis of Copper Oxide nano particles from the aqueous leaf extract of Ipomoea quamoclit L.with its antimicrobial and antioxidant activity

IntroductionGreen nanosynthesis of medicinal plants are useful for the development of antibiotic agents. In this work, we have explored the antimicrobial and antioxidant activity of green synthesized CuO NPs from tropical medicinal plant Ipomoea quamoclit. L. MethodsWith the aid of microfluidic technology, a low-cost, PDMS lab-on-chip micromixer for green nanosynthesis of Copper Oxide (CuO) nanoparticle from Ipomoea is presented. The UV- Vis characteristics, FTIR spectrum, antimicrobial and antioxidant response using DPPH and H2O2 were reported. The antimicrobial efficacy of the synthesized CuO-NPs is tested against two-gram positive bacteria Staphylococcus aureus, Micrococcus luteus, two gram negative bacteria, Enterobacter cloacae, Klebsiella pneumoniae and two fungi species Candida albicans, Aspergillus niger. ResultsUV-Vis spectrum for the synthesized CuO-NPs extract showed the absorbance at 670 nm, SEM image analysis and DLS analysis confirmed the presence of spherical sized nanoparticle between 65 and 94.5 nm. The presence of bioactive functional groups of N-H, C-H and C=0 stretching was identified using Fourier Transform Infrared spectroscopy (FTIR).The maximum mean zone of inhibition obtained was 10.45±0.25mm for fungi Aspergillus niger. The antioxidant activity using DPPH scavenging assay and Hydrogen peroxide scavenging assay showed the IC50 value 33.94 μg/ml and42.54μg/ml respectively. ConclusionsThe obtained results reveal the potential of CuO NPs synthesised from Ipomoea quamoclit. L. as a remarkable medicinal entity for wound healing, respiration, fungal infection and urinary tract infection along with the improved antimicrobial and antioxidant activity.

Synergistic adsorption-photocatalytic degradation of methylene blue by Fe3O4/HKUST-1 composite modified with graphene oxide

Abstract Methylene blue (MB) is the most commonly used cationic dye, but the complex structure of MB makes it harder to be removed from the wastewater by conventional techniques. The integration of adsorption and photocatalytic has been proposed to overcome the drawbacks of the sole technology for more efficient and eco-friendly removal. A magnetic MOF composite, Fe3O4/HKUST-1, was successfully synthesized using the solvothermal method. The addition of graphene oxide (GO) uses the in situ method. XRD and FTIR results revealed the presence of GO, which was dispersed into the composite. SEM images for the composite showed GO(20)/Fe3O4/HKUST-1 was octahedral with Fe3O4 and GO distributed on the surface and between HKUST-1. When the initial concentration of MB was 50 mg/L, the composites exhibited high MB removal efficiency (92,75%) under irradiation through the combination of adsorption-photocatalytic. The effective removal of Fe3O4/HKUST-1 combined with the photocatalyst properties of GO, makes the composite highly efficient for applications in water purification. The adsorption kinetics of MB on the GO(20)/Fe3O4/HKUST-1 were well-fitted with the pseudo-second-order kinetic model.

Effect of Particle Size, Water Saturation, Inorganic Salt and Methane on the Phase Equilibrium of CO2 Hydrates in Sediments

Understanding the thermal stability of gas hydrate in complex marine geological environment is of importance to hydrate-based carbon sequestration. In this work, the factors affecting the equilibrium of CO2 hydrate in ocean sediments, including quartz sands, inorganic salts and gas impurities were quantitatively measured in a temperature range from 273 to 283 K and a phase equilibrium model of hydrate was established. To reveal the distribution in pore structure, the micro-morphologies of hydrate-bearing sediments were measured by cryo-SEM. Results showed that reduction of initial water saturation, addition of NaCl and CH4 were found to have inhibitory effect on CO2 hydrate equilibrium. Initial water saturation reduced the equilibrium temperature by the capillary pressure, but only 0.3-0.7 K temperature depression was observed as the water saturation reduced to 5%. About 5.7 K in the average temperature depression was found by the addition of 10 wt% NaCl and 24 mol% CH4. NaCl and CH4 influenced the hydrate equilibrium by changing the water activity and chemical potential of hydrate water lattice. SEM images showed that the hydrate formed in pores of quartz sand had porous surface and coated the sand particles like a layer of cells which are 5-20 μm in diameter, suggesting the hydrate layer exists between the liquid and gas phase. Based on the van der Waals-Platteeuw model, a hydrate equilibrium model was developed. The model provided a good prediction of the hydrate equilibrium in the presence of quartz sand, NaCl and CH4 with an averaged deviation of ±4.2%, which had the potential to be applicated in more complexed ocean sedimentary environment.

A comparative study of the lubricating properties of various types of base oils containing hydrogen emulsions

The aim of this study is to evaluate the lubricating performance of various base oils in a hydrogen-enriched environment. Experiments were conducted wherein base oils were emulsified with meticulously calibrated hydrogen concentrations, followed by a series of friction and wear measurements. Elemental analysis was performed on the worn surfaces, providing further insight into the wear mechanism. The findings of this study highlight the pronounced effect of hydrogen on the lubrication of pure water emulsions of Class IV 4 base oils, with the Class V 5-1 base oils showing optimal lubricating performance in hydrogen-enriched conditions. SEM images at high magnification scanning revealed the presence of a protective friction film on the surfaces of the wear scars in each sample. X-ray photoelectron spectroscopy (XPS) identified traces of metal sulfide within the friction film, which may play a role in reducing friction. The formation of this friction film is likely a contributing factor to the enhanced lubricating performance of the base oil. These findings contribute a substantial foundation for the development of standards for evaluating the performance of hydrogen internal combustion engine oils.

CaAl1.5Fe0.5O4/6%Ni-ZnO nanocomposites: Synthesis, characterization and effective photocatalyst for the photocatalytic degradation of methylene blue dye

This study focuses on synthesizing and analyzing properties of calcium aluminate photocatalytic nanoparticles using the microwave (MW) combustion method by following the rules of green chemistry and investigates their effectiveness in the adsorption of methylene blue (MB) dye which is a crucial contaminant that enters water resources. The synthesized nanoparticles, including CaAl2O4 (CAO), CaAl1.5Fe0.5O4 (CAFO), 6 %Ni-ZnO (NZO), and CaAl1.5Fe0.5O4/6%Ni-ZnO (CAFONZO) composites, were characterized using various techniques. XRD analysis confirmed the formation of spinel structures in all samples. The crystallite size and lattice constants were determined, showing a reduction in Crystallite size of CAO from 45.98 nm to 37.55 nm after Fe3 + doping. Then, with the formation of CAFONZO Crystallite size 13.99 nm was obtained. FT-IR analysis revealed the chemical interactions between atoms in the spinel structures Nitrogen adsorption/desorption isotherms were used to determine the specific surface area of nanoparticles, pore volume, and pore size. Specific surface area of CAO, CAFO, and CAFONZO are 1.637, 1.745, and 9.903 (m2/g), respectively. SEM and TEM images provided insight into the morphology and size of the nanoparticles. According to TEM images, after Fe3 + doping, the size of particles decreased from 85 to 32 nm. UV-DRS was performed to determine the optical band gap energy of the photocatalysts. The calculated band gap values of pure CAO, CAFO, and NZO nanoparticles were 3.2 eV, 2.5 eV, and 2.7 eV, respectively. Mott-Schottky analysis indicated the type of semiconductors and the energy levels of the conduction and valence bands. Valence band (VB) values of CAFO and NZO are 2.86 eV and 2.03 eV, respectively. The photocatalytic activity of the nanoparticles was evaluated by degrading MB under visible light illumination. The adsorption studies were conducted by varying the dosage, pollutant concentration, and pH. The results showed that CAFONZO nanoparticles exhibited the highest photocatalytic efficiency, achieving 96 % degradation of MB within 120 min. The combined photocatalyst demonstrated improved efficiency compared to the individual components.