In this paper, we investigate the existence and stability of the delta shock wave in ternary chromatography equations by the self-similar viscosity vanishing approach. Considering the appropriate initial values, we prove the existence of the self-similar solution for the corresponding Riemann problem of the ternary chromatography viscous equations. Furthermore, we rigorously demonstrate that the delta shock wave is the weak star limit of the self-similar solution as viscosity tends to disappear. The result implies that the structure of the delta shock wave is stable under the self-similar viscosity perturbation, which guarantees that the delta shock wave is a unique entropy solution. In addition, we present numerical simulations in agreement with the theoretical analysis.