This study examines the fate of high-velocity, high- z ionic projectiles that impact metal targets, with the resulting secondary-electron yields being of particular interest. Three models are constructed for the evolution of the electron clouds of the projectiles as they pass through the first few tens of Å of target material, and the secondary-electron yields predicted from these models are then compared with yields measured at a Van de Graaff facility for 7Li and 12C ions of selected charge states and energies striking thick targets of gold and oxidized aluminum. These measurements provide a first look at the secondaries produced by impacts of z > 1 projectiles travelling with velocities above the Bohr speed (2.18 × 10 8 cm/s), thus allowing tests of the kinetic theory for secondary-electron emission to be made in a new regime. When the secondary-electron yields are high, it is found that measured yields are less than those predicted by theory, most probably because (1) the number of scatterable electrons along the pojectiles's path through the target material is limited (electron-depletion effects) and (2) the probability that scattered target electrons can reach the target's surface is lessened owing to large electrostatic potentials that are set up in the charge trail behind the projectile. It is found that secondary-electron yields for high- z ions are influenced by the attachment and stripping of electrons in the very shallow secondary-electron-escape layers (tens of Å).