An analysis of clay minerals in core samples around the megasplay fault of the Nankai Trough, Japan, recovered during the Integrated Ocean Drilling Program Nankai Trough Seismogenic Zone Experiment reveals a local progression of the smectite-to-illite conversion (S–I) reaction in the slip zone, possibly associated with local thermogenesis caused by seismic slip on the fault. Our semiquantitative X-ray diffraction analysis demonstrates that the illite content in mixed-layer illite/smectite is ∼15% higher in the gouge than in the host sediments. The thermal history of the fault, constrained in a previous study, requires a reduction of the apparent activation energy by 20–30% compared with the literature value to explain the observed illitization. The Shirako Fault in the Miura–Boso accretionary complex, which is thought to have been activated in a tectonic setting similar to that of the megasplay fault of the Nankai Trough, also shows a 20–30% reduction in the apparent activation energy. These results suggest that the kinetic barrier of the smectite–illite reaction is lowered as a result of mechanochemical processes in seismogenic fault zones.
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