The Tarim Block, northwest China, was positioned on the periphery of Rodinia during the Neoproterozoic Era, and preserves a geological archive chronicling the assembly and breakup of the supercontinent. Due to its antiquity and limited exposure, sedimentary records along the margin of the Rodinia supercontinent remain sparsely documented. This study focuses on the Xifangshan and Dongqiaoenbrak formations, the oldest sedimentary units in the northwestern Tarim Block, which comprise a Neoproterozoic sedimentary record at the supercontinent margin during the transition from subduction to breakup. A comprehensive analysis employing sedimentology, petrology, elemental geochemistry, and UPb detrital zircon chronology was undertaken, to elucidate paleoenvironment, parent rocks, and tectonic-sedimentary evolution. Findings show that the Neoproterozoic witnessed the subduction of an oceanic plate beneath the Tarim Block, resulting in the formation of a continental margin magmatic arc. The Xifangshan Formation, deposited during the late phase of this arc (with the earliest sedimentary age recorded at 770 Ma), represents a submarine fan dominated by turbidity currents. Around 760 Ma, rapid crustal uplift occurred, and the tectonic setting gradually shifted from subduction to rift, giving rise to the coastal alluvial fan sedimentary system observed in the Dongqiaoenbrak Formation. Both the Xifangshan and Dongqiaoenbrak Formations record deposition in an oxic to suboxic marine environment with moderate salinity, influenced by a semiarid to semihumid palaeoclimate. The continental margin arc served as the primary source for sedimentation in both formations, and a few magmatic products linked to extension (syenite, monzonite) were also cannibalized into the sedimentary system of Dongqiaoenbrak Formation. This transition from a turbidite system to a coastal alluvial fan represents a sedimentary response to the subduction-to-breakup dynamics along the margin of the Rodinia supercontinent.