Sedimentary Period Research Articles

Restoration and Evolution of the Paleogene (E1f2) Shale Sedimentary Environment in the Subei Basin, China.

Restoring the sedimentary environment of paleolakes is of great significance to the formation of laminated calcareous shale deposited in paleolakes and the prediction of shale oil reservoir distribution. This article focuses on the second section shale of the Paleogene in the Funing Formation in the Gaoyou Sag, Subei Basin, China, and uses X-ray fluorescence diffraction technology and core lithology analysis methods to obtain the content datum of major and trace elements such as Sr, Cu, Ba, Ga, V, and Ni in shale at different depths. Based on the empirical values of Sr/Cu, Sr/Ba, V/(V + Ni), and total organic carbon, paleoenvironmental evolution of the continental shale was determined and studied, including the changes in paleoclimate temperature, paleosalinity, paleowater depth, and strong or weak redox intensity. The research results indicate that the sedimentary environment of the paleolake in the Paleogene Funing Formation, second section, in the Gaoyou Sag is mainly characterized by a dry and hot climate; the salinity of paleolake water is that of stable brackish water, and the entire sedimentary period of the Funing Formation, second section, is dominated by a reduction environment, which is conducive to the preservation of sedimentary organic matter. The frequent changes in the depth of sedimentary water and the alternating dry and hot climate are the main reasons for the development of laminated calcareous shale in the second section of the Paleogene Funing Formation of the Gaoyou Sag and have also contributed to the abundant commercial resources of laminated calcareous shale oil in the second section of the Funing Formation.

Physical Properties of Hydrocarbon Source Reservoir in the Lucaogou Formation in Junggar Basin (China) and Its Influence on Adsorption Ability and Surface Free Energy

A physical property of a shale gas reservoir affects shale gas content, then restricts the shale gas resource potential. In this paper, lithofacies and spatial distribution of the southern margin of the Junggar Basin in Xinjiang Province are identified and occurrence strata, gas content, and reservoir properties of shale gas are studied. Based on adsorption potential theory, adsorption and surface free energy of all the sample is discussed. The conclusions are as follows. (1) All the shale samples can be divided into five lithological phases. For example, black oil shale/shale (lithology) phase and gray-black-gray/dolomite mudstone (lithology) phase are the most developed; compared with the middle and lower sections, the vertical development continuity of the upper hydrocarbon source rock is better. Lithology of this section is mainly composed of shale mixed with marlstone and dolomite interlayer. From the horizontal view of this section, the overall trend is gradually thickening from west to east and from north to south. (2) Semi-deep lake-phase is the most developed, indicating a decreasing trend of thickness from sedimentary center to surrounding strata. (3) Sedimentary period of Lucaogou Formation is a deep water area of the lake basin; then, the TOC content is affected by the sedimentary environment. As sedimentary water depth increases, TOC content will increase, which results in the highest TOC content in the area. A specific surface area is roughly positively correlated with porosity, clay mineral content, and percentage of illite/montmorillonite interlayer ratio and negatively correlated with TOC content. (4) During the adsorption process, adsorption potential decreases with an increase in equilibrium pressure, and adsorption space increases with an increase in equilibrium pressure. Maximum adsorption space of all the sample were 0.20~0.25 cm3·g−1; then, its value is larger than the maximum adsorption space of other coal samples (0.025~0.20 cm3·g−1). In the same adsorption space, the corresponding adsorption potential of the coal sample is much larger than that of other samples. The reason is that the porosity permeability of this sample is relatively larger, leading to its better physical properties.

Types and Genesis of Siderite in the Coal-Bearing Beds of the Late Permian Xuanwei Formation in Eastern Yunnan, China

The Late Permian strata of the Xuanwei Formation in the eastern Yunnan region exhibit extensive diverse morphological features within siderite deposits. These variations in siderite deposits suggest potential differences in their formation processes. In this study, fieldwork and comprehensive indoor studies revealed four distinct forms of siderite deposits: stratiform-laminated, lens-like nodule, sandstone cementation, and fracture filling. The stratiform-laminated siderite, varying in color from bluish-grey to dark grey, is composed of uniformly sized microcrystalline to fine-grained siderite along with detrital matter, displaying precise layering and banding structures that suggest direct deposition from cyclic iron-rich seawater under reducing conditions. Lens-like-nodule siderite, which appears grey-yellow, is composed of mud microcrystalline siderite, medium to coarse-grained pseudo-ooids, and glauconite. It shows conformable distribution characteristics resulting from the diagenetic differentiation of iron-rich sediments under reducing conditions during the diagenetic and early diagenetic periods. Siderite as sandstone cementation exhibits a yellow-brown color and consists of dispersed colloidal siderite and cemented siderite clumps that fill intergranular pores of detrital particles. It precipitated under reducing conditions within those intergranular pores. Siderite filling fractures typically appear as vein-like or network-like structures intersecting bedding at large angles. They exhibit grain structures with significant variations in size. These siderite deposits exhibit exceptional purity and result from siderite dissolution during sedimentary periods, followed by reprecipitation within regional extensional fractures during the diagenetic phase. The primary occurrence of siderite deposits in the study area is within coal-bearing strata, as revealed by the integration of sedimentary profiles and sedimentary facies analysis. The coal-bearing strata, influenced by the Emeishan large igneous province, underwent iron enrichment during and after volcanic eruptions while developing a reducing environment, which was facilitated by abundant vegetation. Consequently, geological processes led to siderite layers, lens-like siderite nodules, and siderite cementation. The Yanshan orogeny induced extensive high-angle fracture development in epigenetic coal-bearing strata, facilitating fluid circulation and the redistribution of soluble siderite. This geological activity resulted in the formation of vein-like structures composed of siderite.

Controlling factors of the gypsum-salt strata differences within two adjacent Eocene sags in the eastern Jiyang Depression, NE China and its hydrocarbon significance

Gypsum-salt rocks play a significant role in the process of hydrocarbon migration and accumulation. The fourth member of the Shahejie Formation (Es4) in Dongying Sag and the adjacent Bonan Subsag, bordered by the Chenjiazhuang Uplift, contains extensive gypsum-salt layers. However, there are notable differences in terms of the endowed horizons. Therefore, it is crucial to decrypt the factors that control the development of gypsum-salt rocks, such as paleoclimate, tectonic activity, and geomorphological differences. Comprehensive insights demonstrate that an arid-dominated climate is the primary factor for the development of gypsum-salt rocks, while the tectonic transformation and migration of depocenter also control the differential development of gypsum-salt rocks in these two areas mentioned above. Under the geological background of arid evaporation as a whole, in the lower section of the Es4 (Es4L) sedimentary period, the depocenter was situated south of Dongying Sag but far away from Bonan Subsag, resulting in the deposition of lakeshore to the shallow water of Bonan Subsag and the deep lake deposition of Dongying Sag. Therefore, the gypsum-salt deposits are lacking in the Es4L of Bonan Subsag while being well developed in the Es4L of Dongying Sag. However, in the upper section of the Es4 (Es4U) sedimentary period, due to the migration of the regional depocenter and tectonic transformation, a large-scale and relatively stable deep lake was also developed in Bonan Subsag. Consequently, gypsum-salt rocks developed in both Bonan Subsag and Dongying Sag. This study provides valuable insights for further hydrocarbon exploration in the deep strata of Dongying Sag and Bonan Subsag.

Analysing of palaeoenvironment and organic matter enrichment: A case study from the Triassic Yanchang Formation in the southern Ordos Basin, China

The organic‐rich shale of the seventh Oil Member (Chang 7 Member for short) of the Middle‐Late Triassic Yanchang Formation is extensively distributed in the southern margin of the Ordos Basin. Understanding the palaeoenvironmental conditions during the sedimentary period of the Chang 7 Member is crucial to exploring the main factors that control the enrichment of organic matter in high‐quality source rocks. In this study, lithofacies analysis was conducted, and samples were collected from the N36 well located in the southern part of the Ordos Basin. Subsequently, element geochemical analysis was performed to reconstruct the palaeoenvironment, and total organic carbon (TOC) tests were conducted to analyse the characteristics of organic matter enrichment. The findings indicate that the sedimentary period of the Chang 7 Member was characterized by a relatively warm and humid palaeo‐climate and a brackish water environment with oxygen‐poor or sub‐oxygen‐rich conditions, and a gradual decrease in palaeo‐water depth. The parent rock types were mainly felsic igneous rock and intermediate igneous rock, which provide limited nutritional elements for primary producers. The enrichment of organic matter in the Chang 7 Member is influenced by several factors, mainly including palaeo‐salinity, palaeo‐water depth, palaeo‐redox conditions, terrestrial inputs, and palaeo‐climate. The warm and humid palaeo‐climate, higher palaeo‐productivity, relatively higher palaeo‐salinity, lower terrigenous input, deeper palaeo‐water depth, and better preservation conditions are conducive to the development of high‐quality source rock in the Chang 7 Member.

Formation mechanism of fault accommodation zones under combined stress in graben basin: Implications from geomechanical modeling

A fault accommodation zone is a type of structure that is defined as regulating displacement and strain between faults structure. Increasing numbers of fault accommodation zones are being identified in graben basins, indicating the potential exploration target and petroleum accumulation areas. This study aims to analyze the formation mechanism and development of fault accommodation zones under combined stress by a numerical simulation method considering geomechanical modeling. Using three-dimensional (3-D) seismic interpretation and fractal dimension method, exampled with the Dongxin fault zone, the fault activity and fault combination pattern were conducted to quantitatively characterize the activity difference in fault accommodation zones. Combined with mechanical experiment test, a geomehcanical model was established for fault accommodation zones in a graben basin. Integrating the paleostress numerical simulations and structural physical simulation experiment, the developmental characteristics and genetic mechanism of fault accommodation zones were summarized. Influenced by multi movements and combined stresses, three significant tectonic evolution stages of the Dongxing Fault Zone (DXFZ) were distinguished: During the Es3 sedimentary period, the large difference in the stress, strain, and rupture distribution in various faults were significant, and this stage was the key generation period for the prototype of the DXFZ, including the FAZ between large-scale faults. During the Es2 sedimentary period, the EW-trending symmetric with opposite dipping normal faults and the NE-SW trending faults with large scale were furtherly developed. The junction area of two secondary normal faults were prone to be ruptured, performing significant period for inheriting and developing characteristics of fault accommodation zones. During the Es1 sedimentary period, the high-order faults in the DXFZ exhibited the obvious fault depressions and strike-slip activity, and the fault accommodation zones were furtherly inherited and developed. This stage was the molded and formative period of the FAZ, the low-order faults, and the depression in the DXFZ.

Seismic Response Variance of Depositional Sequences: Implications for Reservoir Prediction in Lacustrine Basin

In recent years, lithologic oil and gas reservoirs have become an important target in continental hydrocarbon-bearing basins. Geophysical prospecting technology using seismic data is an indispensable tool for oil and gas exploration. However, while previous work has paid much attention to the seismic responses of reservoirs (sandstones), the seismic responses of depositional sequences composed of sandstone–mudstone cycles are not well understood in reservoir prediction. This problem seriously restricts efficient oil–gas exploration and development. The Cretaceous Baxigai Formation in the Yingmaili area, west of the Tabei Uplift, is an important exploration target for lithologic oil and gas reservoirs in the Tarim Basin. The Baxigai Formation is deeply buried with thin thickness. The Baxigai Formation in the study area is divided into a lower sandstone section and an upper mudstone section. Braided river delta sand bodies are developed in the lower sandstone section, and braided river delta sand bodies and beach bar sand bodies are developed in the upper mudstone section. According to the difference in the depositional sequences in different zones, five types of the vertical combination style of sandstone and mudstone were identified. Through seismic forward modeling, the seismic response variance of the five kinds of sequence models was established. Then, the amplitude attributes were extracted via wavelet decomposition to reflect the distribution of sandstone–mudstone in different zones. This could help predict the vertical and horizontal distributions of different depositional sequences and the sandstones in these sequences. During the sedimentary period of the upper mudstone section of the Baxigai Formation, the beach bar sand bodies were distributed along the northeast coast. The thin sand bodies pinched out along the up-dip direction to form favorable lithologic traps, which has important significance for lithologic reservoir exploration.

Distribution, evolution and structural properties of Wushenqi paleo-uplift in Ordos Basin, NW China

This paper depicts the distribution of the Wushenqi paleo-uplift in the Ordos Basin by using the latest drilling and seismic data, and analyzes the tectonic evolution of the paleo-uplift with the support of Bischke curve and balanced section. The compressional Wushenqi paleo-uplift which developed in the Early Caledonian orogeny (Huaiyuan orogeny) is approximately a ellipse extending in S-N direction. Its long axis is about 194 km and short axis is about 55–94 km in nearly W-E direction. The denudation thickness and area of the Cambrian in the core are 170–196 m and 11 298 kmbrespectively. It was mainly formed during the Huaiyuan orogeny according to the chronostratigraphic framework. It was in the embryonic stage in the Middle–Late Cambrian, denuded after developed obviously at the end of Late Cambrian. The paleo-uplift of the 3rd member of the Ordovician Majiagou Formation was reactivated and reduced in area. In the sedimentary period of the Ma4 Member–pre-Carboniferous, the paleo-uplift experienced non-uniform uplift and denudation. It entered the stable period of burial and preservation in the Carboniferous and later period. The Wushenqi paleo-uplift was formed on the weak area of the basement and tectonic belts, into an compressional structure with irregular morphology, under the control of the non-coaxial compression in the south and north and the stress transmitted by the uplift in the basin. The Wushenqi paleo-uplift has a controlling effect on the sedimentary reservoirs and hydrocarbon accumulation.

Geochemical Characteristics of Elements and Main Controlling Factors of Organic Matter Enrichment in Shale from Wufeng Formation to Submember Long-11 in Southern Sichuan

A total of 70 shale samples from seven core holes, namely, N203, N208, N209, N210, N211, N215 and N217, in Changning area, south Sichuan, were analyzed for major and trace elements. Based on an analysis of longitudinal variation characteristics of major and trace elements, the REDOX conditions, paleoproductivity, relative sea level height and terrigenous detrital injection amount of gas-bearing shale in Wufeng Formation–Submember Long-11 in the Changning area were studied. And, the main controlling factors of organic matter enrichment in Wufeng Formation–Submember Long-11 were discussed. The results show the following: (1) Trace elements Mo, U, Ba and Ni are relatively enriched in the shale of Wufeng Formation–Submember Long-11 in the Changning area, while the Co element is deficient. The flat distribution pattern of rare earth in Wufeng Formation–Submember Long-11 shows that the shale deposits are weakly influenced by terrigenous materials. The amount of terrigenous injection in Wufeng Formation is higher than that in Submember Long-11, and the amount of terrigenous injection increased gradually from the lower part of Bed Long-111 to the lower part of Bed Long-114. (2) The REDOX environment discrimination indexes such as U/Th, Ni/Co, V/Sc and δU show that the water REDOX conditions of Wufeng Formation–Submember Long-11 in the Changning area have changed many times during the shale sedimentary period, and the overall REDOX conditions are dominated by an anaerobic environment. The REDOX indexes at the boundary between Long-111 and Wufeng Formation are relatively small and in the oxidizing environment range. The REDOX index from Bed Long-111 to Bed Long-114 decreases gradually, and the anaerobic environment of Bed Long-111 and Bed Long-112 gradually changes to the oxygen-poor environment of Bed Long-113; and, the REDOX index of Bed Long-114 is the lowest, which is generally oxygen rich. (3) Organic matter enrichment in Wufeng Formation Submember Long11 in the Changning area is mainly controlled by REDOX conditions. Low terrigenous injection and a relatively high sea level have positive effects on organic matter enrichment, but there is no obvious relationship between the paleoproductivity and organic matter enrichment.

Evaluation of the Geological Characteristics and Exploration Potential of Tight Oil in the Neogene Upper Ganchaigou Formation in the Zhahaquan Area, Qaidam Basin.

The study of the geochemical characteristics of source rocks is an important part of tight oil evaluation. The Zhahaquan area of the Qaidam Basin is a new area for tight oil exploration in China. During the sedimentary period of the Neogene Upper Ganchaigou Formation (N1) in the Zhahaquan area, a set of source rocks of semideep lake and deep lacustrine facies as well as a set of thin, interbedded fine sandstone and argillaceous limestone was deposited, providing favorable conditions for the formation of tight oil. However, the study on the geochemical characteristics of source rocks in this area is relatively weak. The geochemical characteristics of the source rocks in the Zhahaquan area were determined via the experimental analysis of parameters such as vitrinite reflectance (Ro), chloroform bitumen "A", total organic carbon (TOC), group components, kerogen types, rock pyrolysis, and aromatic compounds of crude oil. The following results were obtained: the Zhahaquan area had II1-type hydrocarbon source rock organic matter, and the TOC was 0.32%-1.32%. The type index (TI) was 48.70-72.23, the chloroform bitumen "A" content was 0.0034%-0.1133%, Ro was 0.810%-1.265%, and the cracking hydrocarbon peak temperature (Tmax) was distributed in the temperature range of 362-444 °C. The hydrocarbon generation conversion rate was 0.89%-10.0%. The reservoir mainly had intergranular pores, dissolution pores, and microfractures. The average porosity was 8.0%, and the average permeability was 0.861 × 10-3 μm2. The average oil saturation was 30.0%, and the average water saturation was 21.6%. From a comprehensive analysis of the results, the following inferences were derived. The parent material of the source rocks in the Zhahaquan area mainly originated from algae and other phytoplankton in the lake basin, which was a good source rock for oil exploration. The source rocks of this area have entered the threshold of hydrocarbon generation and are in the peak oil-generation stage. They have potential as industrial oil and gas resources. The oil test results of YD103 and seven other wells showed that the daily oil index per meter ranges from 0.38 to 6.5 m3/d·m, indicating that the source rocks have the ability to form industrial oil. Analysis of the geochemical characteristics of source rocks and study of reservoir geological characteristics will provide theoretical support and reference for tight oil exploration and development in Zhahaquan.

Sedimentary Environment and Organic Matter Enrichment Model of Saline Lake Source Rock in the Linhe Depression, Hetao Basin, China

The well-developed mudstone and gypsum mudstone in the Oligocene Linhe Formation (E3l) in the Hetao Basin are the main source rocks for gypsum. However, the sedimentary environment and organic matter (OM) enrichment factors of E3l are not clear, and this inhibits the prediction of hydrocarbon source rock distribution and resource calculation. Major and trace elements, total organic carbon (TOC), pyrolysis using the Rock-Eval II, and saturated hydrocarbon gas chromatography–mass spectrometry (GC–MS) analyses were performed in this study. The results show that E3l was deposited in brackish water and saline–ultrasaline water, with weak oxidation reduction in an arid and hot environment. Terrestrial input inhibits OM enrichment, while the redox, paleosalinity, paleoclimate, and paleoproductivity play a catalytic role. The main controlling factors of the same lithologic source rocks are different: terrestrial input and paleoclimate have a greater impact on mudstone, and the redox and paleosalinity were more favorable to gypsum mudstone. Although the main controlling factors are different for different lithologies, their OM enrichment characteristics are still consistent. The E3l water body was deep, and the contribution of nutrients from terrigenous debris to OM enrichment was less. In addition, the water retention environment changed significantly during the E3l sedimentary period, resulting in fewer nutrients, which limited the improvement of surface water paleoproductivity. The arid climate increased water evaporation and salinity, which to some extent prevented consumption and decomposition. Weak oxidation-reduction fluctuations and the stratification of the water body were obvious, and this was not only conducive to the enrichment of OM but also to its preservation.

In situ characterization of pyrite from multiple microenvironments in middle Jurassic strata, northeastern Ordos Basin, China: Evaluation of synsedimentary/diagenetic fluid evolution

The sulfur isotopic composition and trace element content recorded in sedimentary pyrite have been widely used as a proxy to establish the geochemistry of pyrite-forming fluids. However, a continuous and complete evolution process of these fluids from the sedimentary period to diagenetic period remains not well constrained. The middle Jurassic strata (the Yan'an Formation containing coal seams and its overlying Zhiluo Formation hosting U deposits in the sandstone) in the northeastern Ordos Basin contain four kinds of microenvironments favorable for pyrite formation, namely coal, carbonaceous debris in barren gray sandstone, barren gray sandstone without carbonaceous debris and U mineralized gray sandstone from bottom to top, providing a good opportunity to decode pyrite formation in response to synsedimentary/diagenetic fluid evolution. In these microenvironments, pyrite named as PC, PD, PB and PM respectively, displays a variety of micro morphologies (framboidal, euhedral, infilling, irregular and cement) formed during sedimentary and diagenetic stages. PC has δ34S values ranging from −36.1 to +26.5 ‰ and low contents of total trace elements (from 6.7 to 58 ppm of Co + Ni + As + Se + Mo). PD and PB present δ34S signatures from −33.6 to +14.4 ‰ and from +9.7 to +22.2 ‰, respectively, with moderate trace element contents (from 21 to 111 ppm and from 23 to 80 ppm, respectively). PM resulting from the oxidation of PD and PB shows negative δ34S values (from −16.9 to −11.1 ‰ for framboidal pyrite and from −56.7 to −34.8 ‰ for euhedral pyrite + pyrite cement) and high trace element contents varying from 350 to 931 ppm. Detailed sulfur isotope and trace element microanalyses indicate that S involved in the formation of pyrite is derived from the fractionation process of organic sulfur in the coal, while Fe and trace elements originate from the surface-derived meteoric water. A paragenetic sequence from early PC, to PD and PB, and finally PM implies an evolution trend of δ34S values increasing first and then decreasing (bacterial sulfate reduction for framboids and Ostwald ripening for euhedral pyrite and pyrite cement of PM) and gradual enrichment of trace elements from synsedimentary to diagenetic fluids. The quantitative results can contribute to a better understanding of synsedimentary/diagenetic fluid evolution both locally and regionally for sedimentary strata in the low-temperature system.

Discussion and application of ball mill in preparation of particle size samples of fine grained sedimentary rocks

The grain size of clastic rocks is one of the most important structural characteristics of clastic sediments, which can directly reflect the hydrodynamic conditions of ancient sedimentary period. The preparation of conventional clastic rock particle size samples is usually done by hand wet grinding with a grinding hammer by experienced experimenter. For the fine-grained sedimentary rocks, the conventional method for preparing grain size samples has the disadvantages of long time and low efficiency. This paper introduces a method of preparing grain size samples of fine grained sedimentary rocks by separating rock particles with ball mill. By carrying out the experiments of separating rock particles by ball mill, the influence of different sample quality and ball mill parameters on the particle size and particle size distribution of fine grained sedimentary rock in the process of rock particle fragmentation by ball mill was discussed. The conditions for separating particles of fine grained sedimentary rocks by ball mill are determined as follows: sample mass is 0.14 g ~ 0.20 g, ball mill frequency is 10 Hz, ball milling time is 3 min, the efficiency of particle size sample preparation is greatly improved. The final particle suspension samples were tested by laser particle size analyzer, and the particle size distribution characteristics of fine-grained sedimentary rocks were given, which provides a basis for the study of lithology classification, lithofacies characteristics and hydrocarbon reservoir heterogeneity, and plays an important role in the exploration and development of unconventional oil and gas.

Synergistic Evolution of Palaeoenvironment—Bionts and Hydrocarbon Generation of Permian Saline Lacustrine Source Rocks in Jimusar Sag, Junggar Basin

This study focused on Middle Permian Lucaogou Formation saline lake source rocks, utilizing a combination of biomarkers and hydrocarbon generation thermal simulation to analyze their biological compositions, depositional environments, and hydrocarbon generation potential. The Pr/Ph ratio, Ph/nC18 ratio, and Pr/nC17 ratio indicate that the Lucaogou Formation was in a reducing environment during the deposition period, and the lower part of the Lucaogou Formation (P2l1) is more anoxic than the upper part of the Lucaogou Formation (P2l2). The maturity index 20S (%) and ββ (%) reflect that the maturity of organic matter in the P2l1 is slightly higher than that in the P2l2. The G/H index and the ETR index indicate that the stratification of the water column is better during the sedimentary period of Lucaogou Formation and the salinity of the P2l1 is higher than that of the P2l2. The biomarker parameters of nC21−/nC22+, CPI, S/H, and C22T/C21T reflect that the organic matter of the source rocks have a higher abundance of bacteria and algae than higher plants, and the contents of bacteria are more than that of algae. The (7- + 8-MMAs)/Cmax and (C28 + C29 − St)/St parameters indicate that cyanobacteria accounted for a certain proportion of bacteria, and the algae are mainly green algae. The co-evolution of the sedimentary environment and the biological composition reflects the control of the sedimentary paleoenvironment on biological composition. According to the relative content of cyanobacteria, green algae, and Rhodophyta, the source rocks of the upper and lower Lucaogou Formation correspond to the low-salinity type (LS-type) and the high-salinity type (HS-type), respectively. Compared with LS-type source rocks, HS-type source rocks have greater generation potential of oil and weaker gas generation potential. This study is valuable for the accurate assessment of source rocks and holds significant practical implications for the exploration of oil and gas resources.

Correlation of Neogene Oil and Paleogene Source Rocks in the Middle Huanghekou Sag, Bohai Bay Basin

Several billion-ton Neogene oil fields have been successfully discovered in the middle Huanghekou sag over the past few years. However, the source of the crude oil needs to be clarified, and the relevant oil-source correlation was less carried out. Six source rocks of the third member of the Paleocene Shahejie Formation (Es3) from five wells and sixteen Neogene crude oil samples from nine wells in the middle Huanghekou sag were investigated for the oil-source correlation with the biomarkers and carbon and hydrogen isotopes of saturated hydrocarbon monomers. The distribution characteristics of n-alkanes, C19/C23 ratio of tricyclic terpanes, long-chain tricyclic terpene ratios (ETR), C24 tetracyclic terpane to C26 tricyclic terpene, and distribution characteristics of conventional steranes suggest that the Es3 parent material is of a mixed-source input from terrestrial higher plants and aquatic phytoplankton. The gammacerane to C30 hopane ratio is low, ranging from 0.094 to 0.134, with a mean value of 0.118; the Pr/Ph ratio is less than 1.5. The Neogene oils show the characteristics of a saturated hydrocarbon biomarker similar to Es3. The carbon and hydrogen isotopes of saturated hydrocarbon monomers also corroborate the oil-source correlation from the depositional environment and parent material source, which characterize the low salinity of the water during the Es3 sedimentary period, which was a brackish or a freshwater delta deposition under weak oxidation–weak reduction conditions. The parity dominance of CPI and OEP values (both greater than 1), higher ratios of Ts/Tm (1.174 to 1.383, mean 1.278) and the C29Ts/C29 norhopane, high values of diahopane and diasterane contents (C30diaH/C30H, C27diaS/C27S), and hopane and sterane isomerization parameters (%22S, %20S, %ββ) confirm that the Es3 source rock samples are mature enough to provide crude oil for the middle Huanghekou sag. The biomarker characteristics of regional Neogene crude oil are significantly different from those of Es4 source rocks in the surrounding depressions (sags), indicating the Es4 strata’s absence in the middle Huanghekou sag. Suitable traps need to be discovered around the hydrocarbon-generating center of the Es3 source rock for oil and gas exploration in the future.

Palaeoweathering Conditions, Provenance, and Tectonic Setting of the Early Silurian Longmaxi Formation in the Upper Yangtze Region (Southern China): Evidence from Geochemistry

The Longmaxi-1 black shales in the Upper Yangtze region are a vital source rocks in southern China. This study investigates the palaeoweathering conditions, provenance, and tectonic setting of the Longmaxi-1 black shale from an elemental geochemical perspective, ultimately revealing its tectonic setting. The results showed that the Longmaxi-1 black shales in the sedimentary period have the characteristics of primary deposition. The Longmaxi-1 black shales were deposited as a primary deposition under a mainly humid climate. However, fluctuations in climatic conditions were recorded from the bottom to the upper part of the formation. The parent rock of the Longmaxi-1 black shales in the Upper Yangtze region is a mixture provenance, mainly composed of intermediate-acid volcanic lithologies (granite and granodiorite), followed by mature quartzite and basalt. Black shale deposition is related to the tectonic setting of active continental margin and island arc-continent collision. The Cathayian orogenic belts and the North Qiangling orogenic belt may have played a role in the genesis of the Longmaxi-1 black shales within the Upper Yangtze region. This study provides significant clues regarding the reconstruction of the palaeoclimatic and palaeogeographical conditions of the Upper Yangtze region during the Early Silurian period.

Positive and negative effects of marine transgression on the quality of lacustrine source rocks in the Upper Cretaceous Songliao Basin, China

The linkage between marine transgression and lacustrine source rock development has been highlighted for decades. Here, improved understandings were obtained on this challenging issue based on valuable comprehensive profiles from the Upper Cretaceous Songliao Basin, NE China (Qingshankou Formation, brief as K2qn1). 48 shale samples from the Central Depression in the northern Songliao Basin were analysed to establish three geochemical profiles of K2qn1. Multiple biomarkers suggested that organic matter in the source rocks of K2qn1 was mainly sourced from aquatic organisms. Systematic organic and inorganic geochemical analyses reveal that at least five transgressive events occurred during the sedimentary period of K2qn1, denoted as TI, TII, TIII, TIV, and TV from bottom to top. In the context of multiple transgression events, the quality of K2qn1 source rocks was primarily controlled by lacustrine primary productivity. Importantly, transgression events have both positive and negative effects on the quality of lacustrine source rocks. During earlier transgressive events (e.g., TI and TII), the quality of source rocks was negatively correlated with transgression intensity, which is likely due to the difficulty of freshwater organisms adapting to salinity, resulting in a decline in primary productivity. In the later transgression events (e.g., TIII and Tv), the quality of source rocks was positively correlated with transgression intensity, which is probably due to the gradual dominance of salt-tolerant or halophilic organisms during multiple stages of salinization. This study provides a comprehensive research approach for evaluating the influence of transgression events on lacustrine source rocks.

Study on the relationship between hydrodynamic conditions and arsenic content in Quaternary sediments.

Groundwater is susceptible to arsenic contamination by sediment with high arsenic content, which is the primary culprit of regional arsenic pollution and poisoning. To explore the influence of the change in hydrodynamic conditions caused by changes in the sedimentary environment over time on arsenic content in sediments during the Quaternary, the hydrodynamic characteristics and arsenic content enrichment of borehole sediments were studied in typical high-arsenic groundwater areas of the Jianghan-Dongting Basin, China. The regional hydrodynamic conditions represented by each borehole location were analyzed, the correlation between the variation in groundwater dynamics characteristics and arsenic content in different hydrodynamic periods was analyzed, and the relationship between arsenic content and grain size distribution was quantitatively investigated using grain size parameter calculation, elemental analysis, and statistical estimates of arsenic content in borehole sediments. We observed that the relationship between arsenic content and hydrodynamic conditions differed between sedimentary periods. Furthermore, arsenic content in the sediments from the borehole at Xinfei Village was significantly and positively correlated with a grain size of 127.0-240.0μm. For the borehole at Wuai Village, arsenic content was significantly and positively correlated with a grain size of 1.38-9.82μm size (at 0.05 level of significance). However, arsenic content was inversely correlated with grain sizes of 110.99-716.87 and 133.75-282.07μm at p values of 0.05 and 0.01, respectively. For the borehole at Fuxing Water Works, arsenic content was significantly and positively correlated with a grain size of 409.6-655.0μm size (at 0.05 level of significance). Arsenic tended to be enriched in transitional and turbidity facies sediments with normal corresponding hydrodynamic strength but poor sorting. Furthermore, continuous and stable sedimentary sequences were conducive to arsenic enrichment. Fine-grain sediments provided abundant potential adsorption sites for high-arsenic sediments, but finer particle size was not correlated with higher arsenic levels.

Sedimentary Filling Evolution under Paleoclimate Transition—A Case Study from the Middle Jurassic Zhiluo Formation, Ordos Basin

Under a specific tectonic background, the change in paleoclimate can show different facies associations and depositional architecture. The Jurassic China continent was an important region for transforming the Paleotethys tectonic domain to the circum-Pacific tectonic domain, and its paleoclimate information was entirely preserved in the continental sedimentary successions. The Middle Jurassic Zhiluo Formation, in the Ordos Basin, was at just the critical period of paleostructure and paleoclimate transition, preserving considerable sedimentological evidence; however, little sedimentological research has been conducted under the transition. This study reconstructed the sedimentary filling characteristics of the Zhiluo Formation under paleoclimate transition based on field outcrop survey, thin section observation, geochemical indices, stratigraphic correlation, and depositional environment analysis. The results showed that with the paleoclimate change from warm and humid to hot and arid, the sedimentary facies of the Zhiluo Formation were characterised by the change from the braided river/braided river delta in the J2z1-1 sedimentary period to the meandering river/meandering river delta in the J2z1-2 sedimentary period, and finally the change to the meandering river, meandering river delta, and lacustrine in the J2z2 sedimentary period. The combined action of the southern super monsoon effect, the increasing global CO2 concentrations, the moving southward of the East Asian block, and the terrain elevation difference, changed the basin’s climate from warm and humid to hot and semi-arid/arid. This study provides a crucial basis for reconstructing the interplay between paleoclimate and paleotectonics, and guiding sedimentology and paleoenvironment research on East Asia during the Middle Jurassic period.

Analysis on Black Shale Sedimentary Paleoenvironment and Tectonic Setting of the First Member of Luzhai Formation of Lower Carboniferous, Rongshui Area of Guangxi, China

In order to promote the discovery of new shale gas exploration areas in Guangxi, based on the latest drilling data, through detailed observation and description of logging data and cores, this paper selects high-quality shale samples of the target layer for X-ray diffraction analysis and testing of clay minerals and whole rock, major and trace elements (including rare-earth elements), TOC, and other related analysis and testing. The study shows that the total amount of rare-earth elements in the first member of Lower Carboniferous Luzhai Formation in Rongshui area, Guangxi, is low; δ EU and δ CE show negative abnormality. The average value of w V / V + Ni , Th / U ratio, and Mo-TOC covariant model diagram of the first member of Luzhai Formation show that it was the condition of anoxic reduction at that time. At the same time, Ba-Sr diagram, Sr/Cu ratio, and total rare-earth elements reflect that the area was in an arid, hot, and marine salt water paleoenvironment during the sedimentary period. Most of the sample parent rocks of the first member of Luzhai Formation are in shale area, and some samples are close to felsic igneous rock area, which is of mixed origin. The tectonic background of the source area is mainly continental island arc and active continental margin, indicating that the sedimentary environment was unstable and highly active under the background of extensional rifting at that time.