Sediment Mobility Research Articles

Selenium and Other Trace Element Mobility in Waste Products and Weathered Sediments at Parys Mountain Copper Mine, Anglesey, UK

The Parys Mountain copper mining district (Anglesey, North Wales) hosts exposed pyritic bedrock, solid mine waste spoil heaps, and acid drainage (ochre sediment) deposits. Both natural and waste deposits show elevated trace element concentrations, including selenium (Se), at abundances of both economic and environmental consideration. Elevated concentrations of semi-metals such as Se in waste smelts highlight the potential for economic reserves in this and similar base metal mining sites. Selenium is sourced from the pyritic bedrock and concentrations are retained in red weathering smelt soils, but lost in bedrock-weathered soils and clays. Selenium correlates with Te, Au, Bi, Cd, Hg, Pb, S, and Sb across bedrock and weathered deposits. Man-made mine waste deposits show enrichment of As, Bi, Cu, Sb, and Te, with Fe oxide-rich smelt materials containing high Pb, up to 1.5 wt %, and Au contents, up to 1.2 ppm. The trace elements As, Co, Cu, and Pb are retained from bedrock to all sediments, including high Cu content in Fe oxide-rich ochre sediments. The high abundance and mobility of trace elements in sediments and waters should be considered as potential pollutants to the area, and also as a source for economic reserves of previously extracted and new strategic commodities.

A heuristic probabilistic approach to estimating size-dependent mobility of nonuniform sediment

This paper presents a heuristic probabilistic approach to estimating the size-dependent mobilities of nonuniform sediment based on the pre- and post-entrainment particle size distributions (PSDs), assuming that the PSDs are lognormally distributed. The approach fits a lognormal probability density function to the pre-entrainment PSD of bed sediment and uses the threshold particle size of incipient motion and the concept of sediment mixture to estimate the PSDs of the entrained sediment and post-entrainment bed sediment. The new approach is simple in physical sense and significantly reduces the complexity and computation time and resource required by detailed sediment mobility models. It is calibrated and validated with laboratory and field data by comparing to the size-dependent mobilities predicted with the existing empirical lognormal cumulative distribution function approach. The novel features of the current approach are: (1) separating the entrained and non-entrained sediments by a threshold particle size, which is a modified critical particle size of incipient motion by accounting for the mixed-size effects, and (2) using the mixture-based pre- and post-entrainment PSDs to provide a continuous estimate of the size-dependent sediment mobility.

Monitoring bedload sediment transport in a pre-Alpine river: an experimental method

Sediment transport in Alpine and pre-Alpine zones is an essential part of the broad field encompassing hydro-geological instabilities, with particular significance during high intensity rainfall events. This study describes an experimental method for the characterization of the dynamics of this phenomenon at a small spatial and temporal resolution. A set of Radio Frequency IDentificator (RFID) equipped pebbles has been tracked for a period of 6 months and their propagation along the stream has been recorded after each rainfall event. A descriptive database has been devised in order to explore the mobility of the single grains with respect to their geometrical characteristics, their mass as well as the influence of the precipitation intensity on the monitored river reach. Preliminary results indicate the strong correlation of sediment mobility to river discharge and suggest the influence of initial position in terms of morphological characteristics on the sediment mobility.

Multiphase layering and mobility of suspended fine sediment in Lake Apopka, Florida

Multiphase layering and mobility of suspended fine sediment in Lake Apopka, Florida

Geochemical control on the reduction of U(VI) to mononuclear U(IV) species in lacustrine sediments

Contaminated systems in which uranium (U) concentrations slightly exceed the geochemical background are of particular interest to identify natural processes governing U trapping and accumulation in Earth’s surface environments. For this purpose, we examined the role of early diagenesis on the evolution of U speciation and mobility in sediments from an artificial lake located downstream from a former mining site. Sediment and pore water chemistry together with U and Fe solid state speciation were analyzed in sediment cores sampled down to 50 cm depth at four locations in the lake. These organic-rich sediments (∼12% organic C) exhibited U concentrations in the 40–80 mg kg−1 range. The sediment columns were anoxic 2–3 mm below the sediment-water interface and pore waters pH was circumneutral. Pore water chemistry profiles showed that organic carbon mineralization was associated with Fe and Mn reduction and was correlated with a decrease in dissolved U concentration with depth. Immobilization of U in the sediment was correlated with the reduction of U(VI) to U(IV) at depth, as shown by U LIII-edge XANES spectroscopic analysis. XANES and EXAFS spectroscopy at the Fe K-edge showed the reduction of structural Fe(III) to Fe(II) in phyllosilicate minerals with depth, coincident with U(VI) to U(IV) reduction. Thermodynamic modeling suggests that Fe(II) could act as a major reducing agent for U(VI) during early diagenesis of these sediments, leading to complete U reduction below ∼30 cm depth. Shell-by-shell and Cauchy-Wavelet analysis of U LIII-EXAFS spectra indicates that U(VI) and U(IV) are mainly present as mononuclear species bound to C, P or Si ligands. Chemical extractions confirmed that ∼60–80% of U was present as non-crystalline species, which emphasizes that such species should be considered when evaluating the fate of U in lacustrine environments and the efficiency of sediment remediation strategies.

Three‐dimensional hydrodynamic and sediment transport modeling to test the sediment focusing hypothesis in upland lakes

AbstractPalaeolimnological studies rely on assumptions regarding the distribution and completeness of lake deposits that are not always fully supported by observations. In particular, the assumption that “focusing” of suspended sediments leads to preferential deposition in the deepest part of a lake is not always justified, especially in upland lakes subject to energetic wind forcing. Few studies have investigated the hydrodynamic controls on lake sediment focusing, especially the importance of wind‐driven currents in deep water. We combine a three‐dimensional numerical hydrodynamic and suspended sediment model (FVCOM) with a semi‐empirical wind wave model to investigate the potential mobility of bottom sediments in a small oligotrophic upland lake (Llyn Conwy, north Wales, UK). Exploratory simulations of wave‐ and current‐generated bottom stress and suspended sediment dynamics confirm the expected importance of wave‐generated bottom stresses in shallower waters (< 3 m depth) around the shore. Field survey shows that lake sediments are largely absent from this zone. This is consistent with peripheral wave action as a sediment focusing mechanism. In deeper water, wind‐driven currents become the dominant contributor to bottom stress. Strong wind forcing events drive an energetic circulation with peak bottom stresses that intermittently exceed any realistic erosion threshold over a large proportion of the lake at depths far below those at which waves can be effective. The spatial distribution of lake sediments, and the completeness of the sediment record, is thus determined by a complex interaction between wind‐driven circulation and bathymetry, rather than by bathymetry alone. Although our sediment dynamics simulations are purely exploratory, the results are consisted with survey results that show a patchy distribution of deep‐water accumulation. Some implications of these results for the selection of sediment coring locations and the interpretation of sediment records are considered.

Effects of Bed Forms and Large Protruding Grains on Near‐Bed Flow Hydraulics in Low Relative Submergence Conditions

AbstractIn mountain rivers, bed forms, large relatively immobile grains, and bed texture and topographic variability can significantly alter local and reach‐averaged flow characteristics. The low relative submergence of large immobile grains causes highly three‐dimensional flow fields that may not be represented by traditional shear stress, flow velocity, and turbulence intensity equations. To explore the influence of large protruding grains and bed forms on flow properties, we conducted a set of experiments in which we varied the relative submergence while holding the sediment transport capacity and upstream sediment supply constant. Flow and bed measurements were conducted at the beginning and end of each experiment to account for the absence or presence of bed forms, respectively. Detailed information on the flow was obtained by combining our measurements with a 3‐D numerical model. Commonly used velocity profile equations only performed well at the reach scale when shallow flow effects and the roughness length of the relatively mobile sediment were considered. However, at the local scale large deviations from these profiles were observed and simple methods to estimate the spatial distribution of near‐bed shear stresses are likely to be inaccurate. Zones of high turbulent kinetic energy occurred near the water surface and were largely controlled by the immobile grains and plunging flow. The reach‐averaged shear stress did not correlate to depth or slope, as commonly assumed, but instead was controlled by the relative boulder submergence and degree of plunging flow. For accurate flow predictions in mountain rivers, the effects of bed forms and large boulders must be considered.

Source-oriented variation in trace metal distribution and fractionation in sediments from developing aquaculture area—A case study in south Hangzhou bay, China

Elevation in toxic trace metal concentration found in coastal sediments in recent years (2013–2016) increased the risk to the aquaculture industry in south Hangzhou bay. This study assessed the main factors controlling the metal distribution and mobility in sediments by sampling from 20 sites along the bank. Spatial distribution and cluster analysis indicated that Cd, As, Hg and Sb attributed to anthropogenic terrestrial sources; while Cr, Co, Cu, Ni, Zn, and Pb, carried by fine-grained sediments and accumulated on tidal flat, were inputted from marine sources. High mobility of Cd was expected because of its considerable proportion (~50%) associated with the acid extractable fraction. Pb, Cu and Co in redox sensitive fraction should also be taken into concern in management of reclaimed area affected by tide. Risk assessments by potential ecological risk index (PERI) emphasised the importance of further monitor and proper treatment of 4 terrestrial generated metals in sediments.

Planimetric and volumetric changes of reef islands in response to wave conditions

AbstractReef islands are morphologically dynamic features located on atolls and platform reefs that are very sensitive to wave‐induced processes on different timescales. The planform morphological evolution of reef islands is widely described; however, the mechanisms of the volumetric variations in response to wave energy are still poorly documented. To assess their multitemporal vertical and horizontal mobility, we performed a series of synchronous measurements of the volumetric changes and incident wave energies at two reef islands and a shingle bank at the Rocas Atoll in the South Atlantic Ocean. The results show the differences in the magnitudes and locations of the sediment mobility between the reef islands. Whereas one island remained stable on all timescales, with only small volumetric changes concentrated at its extremities, the other island (Farol Island) showed high mobility, especially during the energetic northern swell season. The gross volumetric change reached 10.03 × 103 m3 (5% of the total island volume) on a daily timescale; however, on a seasonal scale, the gross erosion was compensated by the gross accretion, indicating a cyclical seasonal pattern. Moreover, the observed volumetric changes induced by the waves on both daily and seasonal timescales did not result in large shoreline displacements. However, long‐term oceanward erosion and substantial lagoonward accretion were observed at Farol Island on a decadal scale, resulting in a pronounced change in its planform morphology. This appears to be promoted by at least three sediment transport pathways induced by waves at the atoll, including sediment adjustment between the reef islands. Our results show that reef islands on the same atoll can have very distinct morphological behaviors on daily, seasonal and decadal scales in response to the same boundary conditions. Copyright © 2017 John Wiley & Sons, Ltd.

A mobile pool of contaminated sediment in the Penobscot Estuary, Maine, USA

The natural recovery of estuaries from contamination is largely determined by the timescale over which contaminated sediment is exported or buried and replaced by cleaner sediment that enters from the watershed or the ocean. That timescale depends on the size of the “pool” of contaminated sediment that resides in the estuary. The larger the pool, the longer the recovery timescale for a given rate of sediment input. A field study was undertaken as part of a study of mercury contamination in the Penobscot estuary to assess the mechanisms affecting the transport and fate of contaminated sediment. Based on measurements of water properties, currents and sediment transport and seabed samples analyzed for sediment properties and contaminant concentrations, a “mobile pool” of contaminated sediment with relatively uniform geochemical characteristics along a 20-km reach of the estuary was identified. This pool of sediment is mobilized seasonally by resuspension and trapping processes associated with salinity fronts that vary in location with discharge conditions. Sediment is transported down-estuary during high discharge and up-estuary during low discharge, with seasonal, bi-directional transport of sediment in the estuary significantly exceeding the annual input of new sediment from the watershed. This continual, bi-directional transport leads to homogenization of the chemical properties of the mobile sediment, including contaminant concentrations. The large mass of mobile sediment relative to the input of sediment from the watershed helps explain the long recovery timescale of contaminants in the Penobscot estuary.

Content of Inorganic and Organic Pollutants and Their Mobility in Bottom Sediment from the Orlík Water Reservoir (Vltava River, Czech Republic)

ABSTRACTThe content of both inorganic and organic pollutants, in sediment from the Orlík reservoir (Vltava river, Czech Republic), and the main tributaries, was determined to assess the total loads of the pollutants in the upper layer of sediment (0–30 cm), and the potential bioaccessibility and bioavailability of these pollutants. Organic pollutants showed non-hazardous levels of polycyclic aromatic hydrocarbons and polychlorinated biphenyls. Elevated phosphorus content indicated the possible eutrophization potential; however, significant correlation of phosphorus with iron and aluminum suggested a high immobilization rate of this element with iron and aluminum cations. Risk elements in the sediment were separated according to their potential environmental risk: (1) cobalt, nickel, copper, lead, vanadium, and chromium showed both low levels and relatively low mobility, i.e. low environmental risk; (2) the arsenic levels were significantly elevated (exceeding the maximum allowable limits for land application of sediment) but its mobility was low; (3) cadmium and zinc exceeded the limits and showed high mobility and bioaccessibility. These two elements also showed high bioavailability for the bivalves Unio tumidus and Anodonta anatina. The results showed differences in pollutant loads in sediment along the lake, and different input of pollutants via the individual tributaries.

Effects of temperature on phosphorus mobilization in sediments in microcosm experiment and in the field

The release of phosphorus (P) from sediments may have significant influences on the concentration of water P and the trophic status of lakes. This study investigated the effects of temperature on the mobilization of P in sediments and its release to the overlying water in an incubation experiment and in the field of a shallow Lake Taihu (China). The ZrO-Chelex diffusive gradients in thin films (ZrO-Chelex DGT) and dialysis sampler (Peeper) were used to simultaneously measure labile P/Fe and soluble P/Fe in sediments at vertical resolutions of 2 mm and 4 mm, respectively. The results showed that the mean DGT-labile P and soluble reactive P (SRP) concentrations at 25 °C increased by 279% and 125% in comparison with those at 7 °C in the microcosm experiment, respectively, while in the field the proportions became 460% and 189% respectively. The microbial activity in sediments also increased with the rising temperature. Moreover, positive correlations (p < 0.001) existed between DGT-labile P and labile Fe and between SRP and soluble Fe under different temperature, implying that the mobilization of P and its release to the overlying water was dominantly controlled by Fe redox cycling. This study provided strong evidence that the rising temperature enhanced the microbial reduction of P-hosted Fe (oxyhydr)oxide, while an on-site accumulation and degradation of algal material in the sediment surface may lead to a greater effect on P mobilization.

Spatial organization of drumlins

AbstractIce‐sheets flowing over soft sediments produce undulations in the bed, typically of metres in relief, of which drumlins are the most abundant and widely investigated. Consensus regarding their mechanism of formation has yet to be achieved. In this paper we examine the spatial organization of drumlins in order to provide an improved description of the phenomenon and to guide hypotheses of their formation. We review the literature highlighting contradictory findings regarding drumlin spatial organization and then use this to motivate our study based on a large sample (42 488) of drumlins from Canada, Britain and Norway. Are there typical arrangements in drumlin positioning and are they organized in a regular spatial manner (patterned) or are they distributed randomly? We recognize that drumlin fields are inherently patchy and therefore apply inhomogeneous spatial statistics in order to study their distribution. This shows that whilst drumlins are occasionally randomly placed, their main state is non‐ random. They exhibit a strong and statistically significant signal of regularity across lengths scales of 100 to 1200 m. We conclude that patterning is a near ubiquitous property of drumlins. This finding of regularity demonstrates spatial self‐organization in the bedforming process with drumlins as an emergent manifestation of sub‐glacial sediment mobility. Kilometre‐scale interactions between drumlins must occur as they evolve, or interactions may arise as a consequence of growth or migration. Hypotheses or models are required that can explain the regular spacing of drumlins. We highlight three suggestions for such self‐organization: instability in the coupling of ice flow–sediment flux–bed shape; local feedback between sediment mobility and relief; and coarsening by growth or migration. © 2017 The Authors. Earth Surface Processes and Landforms published by John Wiley &amp; Sons Ltd.

Microcosms for evaluating microbial indicator persistence and mobilization in fluvial sediments during rainfall events

Mediterranean rivers, which are subject to long, dry periods and heavy rainfall events, could be particularly useful for understanding future climate scenarios. This study generated microcosms that mimicked riverbank sediment resuspension into the water of a typical Mediterranean river as a consequence of heavy rainfall. The mobilization and inactivation of six fecal pollution indicators and microbial source tracking markers were evaluated. The T90 values in the sediments were: 4 days for sorbitol-fermenting Bifidobacterium, 11 days for culturable E. coli, 36 days for bacteriophages infecting Bacteroides thetaiotaomicron strain GA17 and more than 42 days for qPCR-detected E. coli, somatic coliphages and sulfite-reducing clostridia spores. Bacteriophages and bacteria showed different resuspension and sedimentation patterns. The data obtained could be used in predictive models to assess the effects of climate change on surface water quality. Pathogen mobilization into the water column poses a risk for humans, animals and the natural environment, and breaches the One Health approach.

Modelled responses of the Kalahari Desert to 21st century climate and land use change

Drylands are home to over 2 billion people globally, many of whom use the land for agricultural and pastoral activities. These vulnerable livelihoods could be disrupted if desert dunefields become more active in response to climate and land use change. Despite increasing knowledge about the role that wind, moisture availability and vegetation cover play in shaping dryland landscapes, relatively little is known about how drylands might respond to climatic and population pressures over the 21st century. Here we use a newly developed numerical model, which fully couples vegetation and sediment-transport dynamics, to simulate potential landscape evolution at three locations in the Kalahari Desert, under two future emissions scenarios: stabilising (RCP 4.5) and high (RCP 8.5). Our simulations suggest that whilst our study sites will experience some climatically-induced landscape change, the impacts of climate change alone on vegetation cover and sediment mobility may be relatively small. However, human activity could strongly exacerbate certain landscape trajectories. Fire frequency has a primary impact on vegetation cover, and, together with grazing pressure, plays a significant role in modulating shrub encroachment and ensuing land degradation processes. Appropriate land management strategies must be implemented across the Kalahari Desert to avoid severe environmental and socio-economic consequences over the coming decades.

Observations of wave‐induced pore pressure gradients and bed level response on a surf zone sandbar

AbstractHorizontal and vertical pressure gradients may be important physical mechanisms contributing to onshore sediment transport beneath steep, near‐breaking waves in the surf zone. A barred beach was constructed in a large‐scale laboratory wave flume with a fixed profile containing a mobile sediment layer on the crest of the sandbar. Horizontal and vertical pore pressure gradients were obtained by finite differences of measurements from an array of pressure transducers buried within the upper several centimeters of the bed. Colocated observations of erosion depth were made during asymmetric wave trials with wave heights between 0.10 and 0.98 m, consistently resulting in onshore sheet flow sediment transport. The pore pressure gradient vector within the bed exhibited temporal rotations during each wave cycle, directed predominantly upward under the trough and then rapidly rotating onshore and downward as the wavefront passed. The magnitude of the pore pressure gradient during each phase of rotation was correlated with local wave steepness and relative depth. Momentary bed failures as deep as 20 grain diameters were coincident with sharp increases in the onshore‐directed pore pressure gradients, but occurred at horizontal pressure gradients less than theoretical critical values for initiation of the motion for compact beds. An expression combining the effects of both horizontal and vertical pore pressure gradients with bed shear stress and soil stability is used to determine that failure of the bed is initiated at nonnegligible values of both forces.

Bottom morphology in the Song Hau distributary channel, Mekong River Delta, Vietnam

Field studies in the Song Hau distributary of the Mekong Delta in Vietnam conducted at high (Sept.-Oct 2014) and low (March 2015) Mekong River discharge are utilized to examine channel bottom morphology and links with sediment transport in the system. Multibeam bathymetric mapping surveys over the entire channel complex in the lower 80km of the distributary channel, and over 12- to 24-h tidal periods at six transect locations in the reach are used to characterize bottom type and change on seasonal and tidal timescales, supplemented by bottom sampling. The results of this study indicate that the largest proportion of channel floor (up to 80% of the total area) is composed of substratum outcrops of relict sediment units deposited during the progradation of the delta in the last 3.5ka. These take the form of outcrops that are either (1) steep-sided, tabular channel floor, (2) steep-sided sidewall, or (3) relatively flat channel floor. Flatter outcrops of channel floor substratum are identified by the presence of sedimentary furrows (<0.5m deep) incised into the channel bottom that are exposed at high discharge and oriented along channel and laterally continuous for kilometers. These furrows are persistent in location and extent across tidal cycles and appear to be incised into relict units, sometimes with a thin surficial layer of modern sediment observable in bottom grabs. The extent of substratum exposure, greater than that observed previously in low tidal energy systems like the Mississippi River, may relate both to a relatively low sand supply from the catchment, and/or to an efficient transfer of both sand and mud through this tidally energetic channel. Sand bottom areas forming dunes, comprise about 19% of the channel floor over the study area and are generally less than a few meters thick except on bar extensions of mid-channel islands. Both sandy and substratum areas are mantled by soft muds 0.25–1m thick during low discharge in the estuarine section of the study area. This mud mantling appears to be a key control on bottom sourcing of sand to suspension. An understanding of channel bottom morphology, particularly mobility and erodibility of sediments, is valuable for setting up morphodynamic models of channel evolution that can be used to test system response to anthropogenic alterations in the catchment and rising sea levels.

Numerical simulation of the wind influence on bottom shear stress and salinity fields in areas of Zostera noltei replanting in a Mediterranean coastal lagoon

The paper concerns the numerical simulation of the wind influence on bottom shear stress and salinity fields in a semi-enclosed coastal lagoon (Etang de Berre) which is connected to the Mediterranean through a long and narrow channel (called Caronte). Two different scenarios are considered. The first scenario (scen.#1), starting with a homogeneous salinity of S=20 PSU and without wind forcing, studies a stratification process under the influence of a periodic seawater inflow and a strong freshwater inflow from a hydropower plant (250m3/s). Then, in the second scenario (scen.#2), we study how a strong wind of 80km/h can destroy the haline stratification obtained at the end of scen.#1. The MARS3D numerical model is used to analyze the 3D current and salinity distribution induced by these three meteorological, oceanic and anthropogenic forcings in this lagoon and in the Caronte channel.The main goal is to determine the bottom shear stress (BSS) in the nearshore areas of Zostera noltei replanting, and to compare it with the threshold for erosion of the bottom sediments for different bottom roughness parameters.The most interesting results concern the four nearshore replanting areas; two are situated on the eastern side of EB and two on the western side. The results of scen.#2 show that all these areas are subject to a downwind coastal jet. The destratification process is very beneficial; salinity always remains greater than 12 PSU for a N-NW wind of 80km/h and a hydropower runoff of 250m3/s. Concerning BSS, it presents a maximum near the shoreline and decreases along transects perpendicular to the shoreline. There exists a zone, parallel to the shoreline, where BSS presents a minimum (where BSS=0). When comparing the BSS value at the four control points with the critical value, BSScr, at which the sediment mobility would occur, we see that for the smaller bottom roughness values (ranging from z0=3.5×10−4mm, to 3.5×10−2mm) BSS largely surpasses this critical value. For a N-NW wind speed of 40km/h (which is blowing for around 100days per year), BSS still largely surpasses BSScr - at least for the silt sediments (ranging from z0=3.5×10−4mm, to 3.5×10−3mm). This confirms the possibility that the coastal jet could be a stressor for SAV replanting.

Equilibrium Scour-Depth Prediction around Cylindrical Structures

Offshore gravity base foundations (GBFs) are often designed with complex geometries. Such structures interact with local hydrodynamics, creating an adverse pressure gradient that is responsible for flow and scour phenomena, including the bed shear stress amplification. In this study, a method is presented for predicting clear-water scour around cylindrical structures with nonuniform geometries under the force of a unidirectional current. The interaction of the flow field with the sediment around these complex structures is described in terms of nondimensional parameters that characterize the similitude of water-sediment movement. The paper presents insights into the influence the streamwise depth-averaged Euler number has on the equilibrium scour around uniform and nonuniform cylindrical structures. Here, the Euler number is based on the depth-averaged streamwise pressure gradient (calculated using potential flow theory), the mean flow velocity, and the fluid density. Following a dimensional analysis, the controlling parameters were found to be the Euler number, pile Reynolds number, Froude number, sediment mobility number, and nondimensional flow depth. Based on this finding, a new scour-prediction equation was developed. This new method shows good agreement with the database of scour depths acquired in this study (R2=0.91)(R2=0.91). Measurements of the equilibrium scour depth around nonuniform cylindrical structures were used to show the importance of the Euler number in the scour process. Finally, the importance of the remaining nondimensional quantities with respect to scour was also investigated in this study.

Rates and processes affecting As speciation and mobility in lake sediments during aging

Sediments from an arsenic (As) contaminated groundwater vent site were used to investigate As(III) binding, transformation and redistribution in native and iron oxide amended lake sediments using aging spiked batch reactions and a sequential extraction procedure that maintains As(V) and As(III) speciation. In the native sediments, fractionation analysis revealed that 10% of the spiked As(III) remained intact after a 32-day aging experiment and was predominantly adsorbed to the strongly sorbed (NH4H2PO4 extractable) and amorphous Fe oxide bound (H3PO4 extractable) fractions. Kinetic modelling of the experimental results allowed identifying the dominant reaction path for depletion of dissolved As(III) to As(III) absorbed on to the solid phase, followed by oxidation in the solid phase. Arsenite was initially adsorbed primarily to the easily exchangeable fraction ((NH4)2SO4 extractable), then rapidly transformed into As(V) and redistributed to the strongly sorbed and amorphous Fe oxide bound fractions. Oxidation of As(III) in recalcitrant fractions was less efficient. The iron oxide amendments illustrated the controls that iron oxides can have on As(III) binding and transformation rates. In goethite amended samples As(III) oxidation was faster and primarily occurred in the strongly sorbed and amorphous Fe oxide bound fractions. In these samples, 19.3μg Mn was redistributed (compared to the native sediment) from the easily exchangeable and crystalline Fe oxide bound fractions to the strongly sorbed and amorphous Fe oxide bound fractions, indicating that goethite may act as a catalyst for Mn(II) oxidation, thereby producing sorbed Mn(III/IV), which then appears to be involved in rapidly oxidizing As(III).