Sediment Mass Accumulation Rates Research Articles

Elevated uranium concentrations in Lake Baikal sediments: Burial and early diagenesis

The water column of Lake Baikal (Siberia) is pervasively oxic and O2 penetrates several cm into the sediment, followed by distinct layers of Fe/Mn oxide that undergo reductive-dissolution/oxidative-precipitation cycles. Uranium (U) contents of the oxic surface sediment layers were ~15μgg−1, which is unparalleled in oxygenated lakes. To understand the processes leading to this enrichment we investigated the geochemical composition of the particulate matter and pore water of four sediment cores from different locations in the lake and performed mass balance calculations based on sediment mass accumulation rates and published loads from major tributaries. The comparison of loads and export of U in Lake Baikal suggested that current estimates of loads are too low by a factor of about 3 compared to sediment mass accumulation rates. Peak loads during spring ice melt in tributaries that are difficult to monitor and quantify might be the main cause for the deviation. The high U concentrations in the lake sediments originated from the scavenging of U in the water column through association with settling organic particles and particulate Fe(III)- and, to a lesser extent, Mn(IV)-oxides. We outline the hypothesis that two distinct U phases, lithogenic and non-lithogenic U reach the lake sediment and that authigenic U is subsequently formed under reducing conditions within the sediment. In some cores we found that most U was remobilized during the degradation of organic matter, in particular within the top oxygenated layer of the sediment. Significant enrichments prevailed due to U adsorption to and/or co-precipitation with Fe-oxides. When Fe-oxides and, to a lesser extent, Mn-oxides were reductively dissolved, they released U to the pore water, leading to peak dissolved U concentrations in the anoxic sediment, which in turn, precipitated as authigenic U under predominantly sulphate-reducing conditions. The onset of the accumulation of authigenic U coincided with the formation of distinct Fe/Mn oxide layers above. We argue that the resilience of Fe-oxides (especially crystalline goethite and hematite), in association with phosphate, even within reducing (but non-sulfidic) sediments support the burial of substantial amounts of U.

Main drivers affecting the Holocene sedimentary record – implications from small lake in Latvia

A multi-indicator paleolimnological study of sediments from Lake Ķūži (central Latvia) was used to obtain a comprehensive record of environmental changes in the Holocene. Periodicity in the changes and the main drivers (lake basin development, catchment properties, climate, human activities) of the sedimentary record was studied. In order to comprehend the whole-lake sedimentation during the Holocene, a detailed multiindicator record from the central part of the lake was integrated with records of sediment mass accumulation rates from four cores from different parts of the lake and a GPR (ground-penetrating radar) survey of the lake basin. The observed changes in the sedimentation regime that took place during the early Holocene are strongly linked with variations in climatic conditions, but the catchment and lake basin also played an important role. In the middle Holocene the water level was stable and the lake was influenced by climate mediated through changes in the catchment vegetation. Around 5 000 cal. BP sedimentation pattern changed, and three of the four main drivers made a comparably strong impact on the sedimentary signal. Since 2 000 cal. BP multiple indicators point to a major disturbance clearly related to human activity, which conceals the impact of the natural drivers.

Contemporary Deposition and Long-Term Accumulation of Sediment and Nutrients by Tidal Freshwater Forested Wetlands Impacted by Sea Level Rise

Contemporary deposition (artificial marker horizon, 3.5 years) and long-term accumulation rates (210Pb profiles, ~150 years) of sediment and associated carbon (C), nitrogen (N), and phosphorus (P) were measured in wetlands along the tidal Savannah and Waccamaw rivers in the southeastern USA. Four sites along each river spanned an upstream-to-downstream salinification gradient, from upriver tidal freshwater forested wetland (TFFW), through moderately and highly salt-impacted forested wetlands, to oligohaline marsh downriver. Contemporary deposition rates (sediment, C, N, and P) were greatest in oligohaline marsh and lowest in TFFW along both rivers. Greater rates of deposition in oligohaline and salt-stressed forested wetlands were associated with a shift to greater clay and metal content that is likely associated with a change from low availability of watershed-derived sediment to TFFW and to greater availability of a coastal sediment source to oligohaline wetlands. Long-term accumulation rates along the Waccamaw River had the opposite spatial pattern compared to contemporary deposition, with greater rates in TFFW that declined to oligohaline marsh. Long-term sediment and elemental mass accumulation rates also were 3–9× lower than contemporary deposition rates. In comparison to other studies, sediment and associated nutrient accumulation in TFFW are lower than downriver/estuarine freshwater, oligohaline, and salt marshes, suggesting a reduced capacity for surface sedimentation (short-term) as well as shallow soil processes (long-term sedimentation) to offset sea level rise in TFFW. Nonetheless, their potentially large spatial extent suggests that TFFW have a large impact on the transport and fate of sediment and nutrients in tidal rivers and estuaries.

Recent organic carbon sequestration in the shelf sediments of the Bohai Sea and Yellow Sea, China

This study provides an extensive depiction of regional scale sedimentary total organic carbon (TOC) sequestration in the Bohai Sea (BS) and Yellow Sea (YS), marginal system of the western Pacific Ocean. The spatial pattern of the sediment mass accumulation rate (MAR) in the BS and YS was summarized based on a 100-year timescale. The relatively higher MAR (3−7g/cm2/y) in the Yellow River estuary, compared to the adjacent areas, indicate a predominant impact of river discharge on the modern sedimentation process in the BS. Relatively stable sedimentary environment in the offshore mud deposits of the BS and YS was also identified based on the along-core sediment composition and radionuclides profiles. The corresponding spatial pattern of grain size and TOC content suggest a hydrodynamic constraint on the sedimentary TOC accumulation. Moreover, in spite of the various TOC sources revealed by the bulk organic matter (OM) proxies (C/N ratio and δ13C), the restriction of these bulk parameters with potential masking of the signature of terrigenous OM was also identified. The average burial flux of TOC (15.3g C/m2/y) was finally obtained with a total sequestration of 5.6×106t C/y, suggesting that the BS and YS serve as a significant repository of sedimentary TOC. The overall organic carbon storage capacity of the BS and YS is mainly sustained by the fluvial/land-based OM input, high phytoplankton primary productivity, convergent hydrodynamic and stable depositional settings.

Using sedimentary phosphorus/nitrogen as indicators of shallow lake eutrophication: concentrations or accumulation fluxes

Inland lakes have been suffering from eutrophication and nutrient sedimentation plays an important role in the eutrophication history of shallow lakes. Sedimentation processes and accumulation fluxes of nutrients were studied in the Central Lake zone (CL) of Taihu Lake (Taihu), a large shallow lake in China, with multi-sampling by the Pb-210 dating method and determination of sediment mass accumulation rates (MARs) and sedimentary phosphorus, nitrogen, carbon and iron concentrations, in order to track the anthropogenic eutrophication history of Taihu and to explore the available sedimentary indicators of trophic states of shallow lakes. It was found that MARs in CL varied from 0.016-0.048 to 0.078-0.339 g cm(-2) a(-1) with a turning point in 1980, corresponding to the rapid developing trend of society and economy in Taihu Basin after 1980. Rather than sedimentary nutrient concentrations, nutrient accumulation fluxes increased by 0.6-7.1-fold (P) and 2.3-12.2-fold (N) acting as paleolimnological indicators for the eutrophication explosion of Taihu since 1980. Yearly elevated TN in sediment cores and more greatly increased N accumulation fluxes than P with 350-1906 t a(-1) in recent years (2009-2012), suggest that nitrogen should get more attention to control for eutrophication risk of Taihu in future. There were spatial differences in nutrient accumulation fluxes and in weights of MARs and sedimentary nutrient concentrations contributing to the nutrient accumulation fluxes in CL. TOC in modern sediment (< 1 m), responsible for increments in sedimentary P/Fe and TN and nutrient accumulation fluxes, acts as a key factor for controlling nutrient sedimentation and needs studies further for nutrient mass balance theory in Taihu.

Anthropogenic impact on river basins: temporal evolution of sediment classes and accumulation rates in the northern Tyrrhenian Sea, Italy

Abstract In this study, sedimentological and geochronological data from sections of a core (GRT50) collected in the Northern Latium coastal area were compared to data on pluviometric (rainfall) trends, river flows and the temporal evolution of human interventions in the three most important hydrographic basins (Mignone, Marta and Fiora) of this coastal area. The statistical analysis of pluviometric trends identified variations due to a decreasing trend in the Fiora river basin, whereas in the two other locations the decrease was not so significant. Data from the sedimentological analysis of the core confirmed a progressive decrease in the sandy component, which declined from about 30% to the current level of 7% over the last 36 years. There was no significant variation in the sediment mass accumulation rates (MAR), which were characterized by an almost cyclic trend that was probably determined by the most intense floods in the study area. The results revealed that the variations caused by the fluvial processes have affected the water runoff of the Fiora River, and that the consequent decrease in the sand production has been responsible for the recession of beaches in the coastal area between Tarquinia and Montalto di Castro.

Vegetation controls on weathering intensity during the last deglacial transition in southeast Africa.

Tropical climate is rapidly changing, but the effects of these changes on the geosphere are unknown, despite a likelihood of climatically-induced changes on weathering and erosion. The lack of long, continuous paleo-records prevents an examination of terrestrial responses to climate change with sufficient detail to answer questions about how systems behaved in the past and may alter in the future. We use high-resolution records of pollen, clay mineralogy, and particle size from a drill core from Lake Malawi, southeast Africa, to examine atmosphere-biosphere-geosphere interactions during the last deglaciation (∼18–9 ka), a period of dramatic temperature and hydrologic changes. The results demonstrate that climatic controls on Lake Malawi vegetation are critically important to weathering processes and erosion patterns during the deglaciation. At 18 ka, afromontane forests dominated but were progressively replaced by tropical seasonal forest, as summer rainfall increased. Despite indication of decreased rainfall, drought-intolerant forest persisted through the Younger Dryas (YD) resulting from a shorter dry season. Following the YD, an intensified summer monsoon and increased rainfall seasonality were coeval with forest decline and expansion of drought-tolerant miombo woodland. Clay minerals closely track the vegetation record, with high ratios of kaolinite to smectite (K/S) indicating heavy leaching when forest predominates, despite variable rainfall. In the early Holocene, when rainfall and temperature increased (effective moisture remained low), open woodlands expansion resulted in decreased K/S, suggesting a reduction in chemical weathering intensity. Terrigenous sediment mass accumulation rates also increased, suggesting critical linkages among open vegetation and erosion during intervals of enhanced summer rainfall. This study shows a strong, direct influence of vegetation composition on weathering intensity in the tropics. As climate change will likely impact this interplay between the biosphere and geosphere, tropical landscape change could lead to deleterious effects on soil and water quality in regions with little infrastructure for mitigation.

Sedimentary geochemical record of human-induced environmental changes in Huanggaihu Lake in the middle reach of the Yangtze River, China

Total organic carbon (TOC), total nitrogen (TN), total phosphorus (TP) and heavy metals were determined along with stable isotope ratios of carbon and nitrogen (δ13Corg and δ15N) in an 86 cm sediment core from Huanggaihu Lake, located in the middle reach of the Yangtze River, China. These geochemical and isotopic records provide a continuous history of lake productivity and the trophic state of Huanggaihu Lake over the past 150 years. Before the 1960s, organic matter, nutrients and heavy metal contents were low, revealing the low trophic state and pollution inputs at Huanggaihu Lake. High sediment mass accumulation rates and low clay content suggested increased catchment erosion related to human activities such as railway construction and forest clearing during the 1910s-1940s in the catchment area. Since the 1960s, TOC, TN and δ15N have increased along with decreased δ13Corg, indicating an increase in the primary productivity of Huanggaihu Lake. After the year 2000, the TOC, TN and TP decreased or remained stable, and the δ13Corg and δ15N dropped slightly, indicating minor improvement in the lake’s water quality.

Unexpected Sink for Deepwater Horizon Oil May Influence Future Spill Response

A town hall meeting was organized by the Marine Oil Snow Sedimentation and Flocculent Accumulation (MOSSFA) inter‐consortia Gulf of Mexico Research Initiative (GoMRI) working group and the Center for Spills in the Environment in conjunction with the Gulf of Mexico Oil Spill and Ecosystem Science Conference. The meeting had the goal of evaluating sedimentation to the seafloor as a significant pathway and fate of oil after the Deepwater Horizon (DwH) well blowout in 2010. About 78,000 cubic meters of crude oil were released into the Gulf of Mexico from a depth of 1500 meters for 86 days, spreading over a large area. Natural and chemically enhanced dispersion, evaporation, dissolution, burning, surface skimming, and direct capture at the wellhead accounted for a significant proportion of the released oil, but the fate of at least 30% of the oil remains unknown. Scientists from different research consortia studying sediments and marine snow in the Gulf began to observe signs of increased sedimentation and hydrocarbon deposition. Sediment mass accumulation rates for the northern Gulf of Mexico increased sixfold to eightfold in 2010, directly following the DwH blowout.

Historical reconstruction of organic carbon decay and preservation in sediments on the East China Sea shelf

AbstractSediment cores were collected from the East China Sea inner shelf in 2010 to study the decay and preservation of organic carbon (OC). The highest sediment mass accumulation rate (0.61 ± 0.20 g cm−2 yr−1), derived from 210Pb, was found near the river mouth and decreased alongshore to the south (0.17 ± 0.004 g cm−2 yr−1), and in an offshore direction (0.31 ± 0.08 g cm−2 yr−1). Average total OC content was higher at inner shelf stations (0.52%) than those offshore (0.38%). The δ13C was more depleted at nearshore (−23.49‰ to −21.97‰) than offshore (−22.49‰ to −21.60‰) stations. Principal component analysis indicated that terrestrial OC, as indicated by lignin‐phenols (Λ8) values, was preserved in sediment closer to the coast (0.22–0.44), while offshore sediment was more composed of lignin‐poor (0.12–0.24) degraded OC that was likely hydrodynamically sorted. Marine‐derived OC, as indicated by plant pigments, was significantly more abundant in the sediment mixed layer than the underlying accumulation layer. Historical flooding events were detected in Λ8 profiles in two of the six cores located at midshelf stations. Despite the magnitude of the 2010 flood in East China, we did not see any signature of this event with the chemical biomarker in these two cores. This may suggest that reduced sediment loading due to recent dam construction may have greatly decoupled river inputs with sediment loading to shelf sediment. The total OC standing stock since 1900 was approximately 1.62 ± 1.15 kg C m−2, about one tenth of all the middle and lower lakes in the Changjiang catchment basin. This work further supports the need for more research to better understand how the reduced inputs of fluvial input of sediments from Chinese rivers (due to river diversions and dams) affect carbon cycling in the East China Sea.

The history and impacts of farming activities in south Greenland: an insight from lake deposits

Agriculture in southern Greenland has a two-phase history: with the Norse, who first settled and farmed the region between 985ad and circa 1450ad, and with the recent reintroduction of sheep farming (1920ad to the present). The agricultural sector in Greenland is expected to grow over the next century as anticipated climate warming extends the length of the growing season and increases productivity. This article presents a synthesis of results from a well-dated 1500-year lake sediment record from Lake Igaliku, south Greenland (61°00′N, 45°26′W, 15m asl) that demonstrates the relative impacts of modern and Norse agricultural activities. Pollen, non-pollen palynomorphs (NPPs), sediment mass accumulation rates, diatoms and stable isotopes of nitrogen provide a comprehensive history of both phases of agriculture and their associated impacts on the landscape and adjacent lake. The initial colonisation of southern Greenland is marked by a loss of tree birch pollen, a rise in weed taxa, and an increase in coprophilous fungi and sediment accumulation rate consistent with land-use changes. The biological and chemical proxies within the lake, however, show only slight changes in diatom taxa, and a rise in δ15N. After the Norse demise and during the Little Ice Age, most of the markers return to pre-settlement conditions. However, the continuation of non-indigenous plant taxa suggests that the landscape did not completely return to a pre-disturbance state. After 1988, the character of the lake changed markedly: mesotrophic diatoms and N isotopes all reveal major shifts consistent with a trophic shift, together with a sharp rise in sediment accumulation rate. The post-1988 lake environment, affected by modern farming development, is unprecedented within the context of the last 1500 years. These results demonstrate the potential of lake sediment studies paired with archaeological investigations to reveal the relationship between climate, environment and human societies.

A high resolution study of spatial and temporal variability of natural and anthropogenic compounds in offshore Lake Superior sediments

An 8km2 area representative of deep offshore basins in Lake Superior was surveyed with multi-beam sonar and a high-frequency seismic-reflection system to create a high-resolution bathymetric map of the lake floor morphology, which is dominated by ring-shaped depressions attributed to the dewatering of glacial-lacustrine clays. Ten multi-cores were recovered from the survey area. The cores were scanned for magnetic susceptibility (MS), dated by 210Pb and analyzed for water content, total organic carbon (TOC) and nitrogen (TON), biogenic silica (BSi), and total (THg) and methyl (MeHg) mercury. MS profiles varied considerably, inferring substantial centennial-scale differences in sedimentation history among the core sites. Concentration profiles of the analyzed constituents displayed differences of about ±15% TOC, ±40% BSi, ±50% THg and ±50% MeHg. Total mercury and methylmercury concentrations were typical of past measurements, and the mean THg accumulation rate (12μg/m2year) was similar in magnitude to that of atmospheric Hg deposition. Sediment mass accumulation rates (MAR) ranged among the cores between average values of about 50g/m2year in the ring centers to as high as 180g/m2year between rings. Temporal variation in MAR within cores varied considerably on a decadal scale as well. Sediment redistribution by bottom currents over the complex morphology of the Lake Superior basin is not uniform in space and time, and indicates that a single core from any given area in the lake may not reflect the true history of environmental conditions that extend even a few hundred meters beyond the core site.

210Pb sediment radiochronology: An integrated formulation and classification of dating models

Environmental archives, such as sediments, banded corals and tree rings, are widely used to reconstruct past environmental conditions of ecosystems. In particular, 210Pb has been used during more than 4 decades, through dating of undisturbed sediment cores, to study ecosystem changes during the last 100yr. Since its inception, diverse dating models have been proposed, developed, used and validated in numerous environments, but their nomenclature and formulation is not homogenous. In this work we emphasize that conceptual models used to date undisturbed sediment cores can be deduced from a single fundamental equation, which relates excess 210Pb concentration in sediment, its flux to the sediment surface and mass accumulation rate. From this equation, models were consistently named based on the main hypothesis used and, using a unified and logical nomenclature, dating equations were derived in detail. We applied in detail most of the described models to a sediment core from Mexico and uncertainty expressions were also included. Finally, some recommendations to use the models are proposed. We believe that this work can facilitate the use of 210Pb as a tool to date sediment cores in a more homogeneous way.

Playa‐lake sedimentation and organic matter accumulation in an Andean piggyback basin: the recent record from the Cuenca de Pozuelos, North‐west Argentina

AbstractExpansive playa‐lake systems situated in high‐altitude piggyback basins are important and conspicuous components of both modern and ancient cordilleran orogenic systems. Extant playa lakes provide vital habitat for numerous endemic species, whereas sediments from these deposystems may record signals of climate change or develop natural resources over geological time. Laguna de los Pozuelos (North‐west Argentina) provides the opportunity for an actualistic sedimentological and geochemical assessment of a piggyback basin playa lake in an area of critical interest for understanding Quaternary palaeoclimate dynamics. Silty clays and diatom ooze are the dominant playa‐lake centre microfacies, with concentrations of total organic carbon and biogenic silica commonly exceeding 1·5 wt% in this sub‐environment. Elemental and stable isotopic analyses point to a mixed organic matter composition in the playa‐lake centre, with substantial contributions from algae and transported aquatic macrophytes. Bulk sediment and organic mass accumulation rates in the southern playa‐lake centre approach 0·22 g cm−2 year−1 and 2·89 mg cm−2 year−1, respectively, indicating moderately rapid deposition with negligible deflation over historic time. Playa margin facies contain higher percentages of fragmented biogenic carbonate (ostracods and charophytes) and inorganically precipitated aragonite crusts due to seasonal pumping and evaporation of ground water. Organic matter accumulation is limited along these heavily bioturbated wet and dry mud flats. Fluvial–lacustrine transitional environments, which are key waterbird habitats, are either silty terminal splay (northern axis) or sandy deltas (southern axis) containing highly oxidized and partially allochthonous organic matter. Modern analogue data from Laguna de los Pozuelos provide key insights for: (i) environmental reconstructions of ancient lake sequences; and (ii) improving facies models for piggyback basins.

Sediment focusing in the Panama Basin, Eastern Equatorial Pacific Ocean

Age-model derived sediment mass accumulation rates (MARs) are consistently higher than 230Th-normalized MARs in the Equatorial Pacific Ocean during the past 25 ka. The offset, being highest in the Panama Basin, suggests a significant role for deep-sea sediment redistribution (i.e., sediment focusing) in this region. Here, we test the hypothesis that downslope transport of sediments from topographically high regions that surround the Panama Basin is the cause of higher-than-expected xs 230Th inventories over the past 25 ka in the deeper parts of the basin. We find little difference in xs 230Th inventories between the highest and lowest reaches of the basin. Furthermore, there is no correlation between xs 230Th-derived sediment focusing factors and water depth which suggests that the topographic highs do not serve as a source of xs 230Th. A spatial analysis suggests that there may be an enhanced scavenging effect on xs 230Th concentrations in sediment closest to the equator where productivity is the highest, although further data is necessary to corroborate this. At the equator xs 230Th-derived focusing factors are high and range from about 1 to 5 during the Holocene and about 1 to 11 during the last glacial. In contrast, non-equatorial cores show a smaller range in variability from about 0.7 to 2.8 during the Holocene and from 0.7 to 3.6 during the last glacial. Based on 232Th flux measurements, we hypothesize that the location at which eolian detrital fluxes surpass the riverine detrital fluxes is approximately 300 km from the margin. While riverine fluxes from coastal margins were higher during the Holocene, eolian fluxes were higher during the last glacial.

Interconnected riverine–lacustrine systems as sedimentary repositories: Case study in southeast Michigan using 210Pb and 137Cs-based sediment accumulation and mixing models

Particle-reactive nuclides, such as 210Pb and 137Cs, serve as powerful chronometric tools in the investigations and reconstruction of historical contamination in coastal marine and lacustrine systems. Towards the first systematic establishment of sediment chronologies of river channel sediments, a set of seven sediment cores from Clinton River and Lake St. Clair riverine–lacustrine system were collected and analyzed for 210Pb, 226Ra, and 137Cs activities. Measured inventories of 210Pb xs and 137Cs were ~ 2 and ~ 9 times higher than that expected from atmospheric fallout. From the measured 210Pb xs/ 137Cs inventory ratios, erosional input of 137Cs was found to be significantly higher than that of 210Pb indicating that anthropogenic watershed disturbances have resulted in accelerated sediment erosion. Good agreement between accumulation rates using 210Pb xs and 137Cs using four different age models were obtained for four of the seven cores in the riverine–lacustrine environment. Average sediment mass accumulation rates, based on the 210Pb xs CFCS model, in the lower Clinton River (mean: 0.91 g cm −2 yr −1) were generally higher than those in Lake St. Clair (mean: 0.55 g cm −2 yr −1) due to a higher sediment flux and the unique riverine system characteristics. Sediment mixing coefficients, based on a 210Pb xs mixing model, were much higher in the river (mean: 64.9 cm 2 yr −1) compared to the lake (mean: 4.7 cm 2 yr −1), as was expected due to the frequency of perturbation and resuspension. Net accumulation of datable sediments in the Clinton River indicates that similar river channel deposits may act as repositories for the reconstruction of historical contamination and environmental changes.

210Pb and composition data of near-surface sediments and interstitial waters evidencing anthropogenic inputs in Amazon River mouth, Macapá, Brazil

Activity profiles of excess 210Pb determined in three sediment cores from Amazon River mouth, Macapá city, Brazil, provided the evaluation of sedimentation rates, contributing to a better knowledge of the hydrological conditions in the site that is the capital of Amapá State and is drained by the waters of the huge Amazon River. Chemical data were also determined in the sediments, allowing identify signatures coupled to anthropogenic inputs held in the past in Amapá State. Significant direct relationships between LOI (loss on ignition) and organic matter were found for all sediments profiles. Silica was found to be inversely related to organic matter in the three profiles; its decrease accompanied an increase on the specific surface of the sediments. This relationship was confirmed by a great number of inverse significant correlations among silica and oxides Na 2O, K 2O, CaO, MgO, Al 2O 3, P 2O 5, Fe 2O 3 and MnO. It was possible to identify the role of organic matter on adsorption of several oxides in the core sediments profiles. Apparent sediment mass accumulation rates corresponding to values between 450 and 2510 mg cm −2 yr −1 were obtained, and are compatible with the results of others studies. The 210Pb activities in one sampling point suggested the occurrence of anthropogenic inputs related to the initial period of the mining activities conducted in Serra do Navio, Amapá State, for the commercialization of Mn ores. This was reinforced by the abrupt fluctuations in chemical data obtained for the sediments and composition of the interstitial waters occurring there. The Atlantic hurricane activity also appeared to affect the sedimentation rates in the area, as two different values were recorded in each profile.

Changing hillslope and fluvial Holocene sediment dynamics in a Belgian loess catchment

AbstractFloodplain deposition is an essential part of the Holocene sediment dynamics of many catchments and a thorough dating control of these floodplain deposits is therefore essential to understand the driving forces of these sediment dynamics. In this paper we date floodplain and colluvial deposition in the Belgian Dijle catchment using accelerator mass spectrometric radiocarbon and optical stimulated luminescence dating. Relative mass accumulation curves for the Holocene were constructed for three colluvial sites and 12 alluvial sites. A database was constructed of all available radiocarbon ages of the catchment and this database was analysed using relative sediment mass accumulation rates and cumulative probability functions of ages and site‐specific sedimentation curves. Cumulative probability functions of ages were split into different depositional environments representing stable phases and phases of accelerated clastic deposition. The results indicate that there is an important variation between the different dated sites. After an initial stable early and middle Holocene phase with mainly peat growth in the floodplains, clastic sedimentation rates increased from 4000 BC on. This first phase was more pronounced and started somewhat earlier for colluvial deposits then for alluvial deposits. The main part of the Holocene deposits, both in colluvial and alluvial valleys, was deposited during the last 1 ka. The sedimentation pattern of the individual dated sites and the catchment‐wide pattern indicate that land use changes are responsible for the main variations in the Holocene sediment dynamics of this catchment, while the field data do not provide indications for a climatological influence on the sediment dynamics. Copyright © 2011 John Wiley &amp; Sons, Ltd.

Particulate organic carbon (POC) in surface sediments of the Baltic Sea

In this study, particulate organic carbon (POC) contents and their distribution pattern in surficial sediments of the Baltic Sea are presented for 1,471 sampling stations. POC contents range from approx. 0.1% in shallow sandy areas up to 16% in deep muddy basins (e.g. Gotland Basin). Some novel relationships were identified between sediment mass physical properties (dry bulk density (DBD), grain size) and POC levels. Notably, the highest POC concentrations (about 10–17 mg cm–3) occur in sandy mud to mud (60–100% mud content) with intermediate POC contents of about 3–7% and DBDs of 0.1–0.4 g cm–3. Areas with this range in values seem to represent the optimum conditions for POC accumulation in the Baltic Sea. The maximum POC contents (8–16%) are found in fluid mud of the central Baltic Sea characterized by extremely low DBDs (<0.1 g cm–3) and moderate POC concentrations (4–7 mg cm–3). Furthermore, sediment mass accumulation rates (MAR), based on 210Pb and 137Cs measurements and available for 303 sites of the Baltic Sea, were used for assessing the spatial distribution of POC burial rates. Overall, these vary between 14 and 35 g m–2 year–1 in the mud depositional areas and, in total, at least 3.5 (±2.9) Mt POC are buried annually. Distribution patterns of POC contents and burial rates are not identical for the central Baltic Sea because of the low MAR in this area. The presented data characterize Baltic Sea sediments as an important sink for organic carbon. Regional differences in organic carbon deposition can be explained by the origin and transport pathways of POC, as well as the environmental conditions prevailing at the seafloor (morphology, currents, redox conditions). These findings can serve to improve budget calculations and modelling of the carbon cycle in this large brackish-water marginal sea.

Sedimentation rates in Atibaia River basin, São Paulo State, Brazil, using 210Pb as geochronometer

The constant initial concentration (CIC) of unsupported/excess (210)Pb model was successfully used to assess (210)Pb data of nine sediment cores from Atibaia River basin, São Paulo State, Brazil. The (210)Pb-based apparent sediment mass accumulation rates ranged from 47.7 to 782.4 mg/cm(2)yr, whereas the average linear sedimentation rates between 0.16 and 1.32 cm/yr, which are compatible with the calculated sediment mass fluxes, i.e. a higher sediment mass accumulation rate yielded a higher linear sedimentation rate. The higher long-term based accumulation rate tended to be found in topographically softer regions. This occurs because the sediments are preferentially transported in topographically steeper regions instead of being deposited. Anthropic activities like deforestation possibly interfered with the natural/normal sedimentation processes, which increased in accordance with modifications on the channel drainage. The radionuclide geochronology as described in this paper allows determination of sedimentation rates that are compatible with values estimated elsewhere. The adoption of an appropriate factor generated from previous laboratory experiments resulted in a successful correction for the (222)Rn-loss from the sediments, bringing the estimate of the parent-supported (in-situ produced) (210)Pb to reliable values required by the CIC model.