Sediment Flux Research Articles

Modified stochastic diffusion particle tracking model driven by skew Brownian motion: Analysis of sediment particle motion in turbulent flow under the effects of ejection and sweep.

Turbulent bursting events have been classified into outward interactions (Q1), ejections (Q2), inward interactions (Q3), and sweeps (Q4) in various studies. Ejections (Q2) and sweeps (Q4) have been identified as significant contributors to time consumption, momentum flux, and sediment flux. Additionally, research has shown that the distribution of these events varies nonuniformly at different bed elevations. Despite extensive investigations into the nonuniform distribution of turbulent bursting events, their impact on sediment transport has been rarely explored. In this work, we developed a modified stochastic diffusion particle tracking model (SD-PTM) driven by skew Brownian motion (SBM) using the stochastic Lagrangian approach to scrutinize sediment particle movement in turbulent flows. The model incorporates turbulent characteristics derived from a direct numerical simulation dataset, allowing for a comprehensive analysis of sediment particle dynamics. Moreover, the proposed model accounts for the nonuniform spatial distribution of ejection and sweep events, as well as the particle movement direction during these events. Numerical simulations of the model were conducted to trace sediment particle trajectories in the streamwise and vertical directions. The analysis of sediment transport involved calculating the variance of particle trajectories to examine anomalous diffusion. The model's performance was evaluated by comparing it with flow velocity and sediment concentration profiles obtained from measurements in previous studies. In conclusion, our study suggests that the motion of sediment particles in turbulent flow can be thoroughly investigated under extreme flow conditions using the modified SD-PTM driven by SBM.

Architecture and evolution of shelf‐margin clinoforms developed in a back‐arc tectonic setting: Insights from quantitative analysis on the south‐west shelf margin of the Ulleung Basin

AbstractGeophysical and geological research in the Ulleung Basin has been ongoing since the 1970s, involving continuous seismic acquisition and multiple well‐drilling projects. This study utilized an integrated quantitative approach with conventional seismic interpretation based on recent trends to understand the history of the shelf‐margin development and individual controls that may have influenced each period in the Ulleung Basin. Quantitative analysis was conducted by measuring the progradation (Pse), aggradation (Ase) and sediment influx (Fc) of individual shelf margins in seven dip‐oriented seismic profiles, and calculating the shelf‐edge gradient (αse) and the P/A ratio. Based on these data and the ratio of accommodation to sediment supply (A/S ratio), which was interpreted from the stratal stacking pattern, five shelf‐edge trajectory types were defined and assigned to each shelf margin. By considering individual controls (eustatic fluctuations, sediment supply and tectonic events), we defined the three evolution intervals of the Ulleung Basin during the Middle Miocene to Late Miocene (15 to 6.5 Ma): (1) the upper Middle Miocene (15 to 11.63 Ma) characterized by a moderate sediment supply and high aggradation margin induced by rapid subsidence, (2) the lower Upper Miocene (10.8 to 10 Ma) as a high sediment supply and low aggradation margin associated with reworked sediments from the uplifted Dolgorae Thrust and (3) the uppermost Miocene (9.2 to 6.5 Ma) characterized by a low sediment supply and low aggradation margin experiencing sediment starvation. A comparison with worldwide continental margins indicated that the Ulleung Basin formed under a relatively low rate of progradation (low sediment supply; 4.79 km/Myr) and a high rate of aggradation (high shelf accommodation; 361.04 m/Myr) condition. The SW margin of the Ulleung Basin provides a unique example of understanding stratigraphic architecture variations under changing stress regimes of back‐arc setting (extensional to compressional) and understanding of individual controls that influence margin development.

Geochemical and mineralogical characteristics of shales from the early to middle Permian Dohol Formation in Peninsular Malaysia: Implications for organic matter enrichment, provenance, tectonic setting, palaeoweathering and paleoclimate

The early to middle Permian Dohol Formation is characterized by a significant presence of shale deposits. While these shales exhibit a low potential to generate hydrocarbons, there is a need to ascertain the possible reasons for the low hydrocarbon generation potential. Also, there are several unidentified properties and attributes associated with these shales in terms of their inorganic geochemical characteristics and their mineralogy. This study is focused on using XRF, ICPMS, and SEM with EDX to determine the mineralogical and geochemical characteristics of these shales and use these data to discuss their provenance history and tectonic setting and interpret the paleoclimatic and paleoweathering conditions. The inorganic geochemical analysis shows that the shales from the Dohol Formation are from a felsic igneous source. The shales were also identified to be from a passive margin based on the bivariate plot of SiO2 vs log (K2O/Na2O) and several multidimensional diagram plots. The CIA and CIW data, as well as the A–CN–K plot, all point to a significant degree of chemical weathering, ranging from mild to intense. The Sr/Cu ratio and C-value, combined with various other geochemical proxies, indicate that the shales were formed in warm-humid climatic conditions. The SEM analysis shows that the samples are mainly composed of kaolinite and illite, and this result was supported by the EDX elemental composition. The high terrigenous influx of sediments, the oxic to sub-oxic conditions in which the sediments were deposited, and finally low marine productivity were found to be the reasons for the low TOC in the shales from the Dohol Formation.

Large‐Scale Channel Response to Erosion‐Control Measures

AbstractErosion‐control measures in rivers aim to provide sufficient navigation width, reduce local erosion, or to protect neighboring communities from flooding. These measures are typically devised to solve a local problem. However, local channel modifications trigger a large‐scale channel response in the form of migrating bed level and sediment sorting waves. Our objective is to investigate the large‐scale channel response to such measures. We consider the lower Rhine River from Bonn (Germany) to Gorinchem (the Netherlands), where numerous erosion‐control measures have been implemented since the 1980s. We analyze measured bed level data (1999–2020) around four erosion‐control measures, comprising scour filling, bendway weirs, and two fixed beds. To get further insight on the physics behind the observed behavior, we set up an idealized one‐dimensional numerical model. Finally, we study how the geometry and spacing of the measures affect channel response. We show that erosion‐control measures reduce the sediment flux due to (a) lack of erosion over the measure and (b) sediment trapping upstream of the measure, resulting in downstream‐migrating incision waves that travel tens of kilometers at decadal timescales. When the measures are in close proximity, their downstream effects may be amplified. We conclude that, despite fulfilling erosion‐control goals at the local scale, erosion‐control measures may worsen large‐scale channel‐bed incision.

Transitional circulation patterns from full ice cover to ice-off in a seasonally ice-covered lake

There is consensus that under-ice circulation presents multiple phases through the winter, and that different mechanisms dominate each period. In this work, measurements of temperature, water velocity, conductivity, and dissolved oxygen from Lake Massawippi, Quebec, Canada, obtained during the ice-covered season in 2019, were used to characterize the time scales of different winter regimes and transitions among dominating circulation mechanisms. Lake circulation during this period began with a single-cell convection induced by sediment flux pulses in early winter. The single-cell convection decayed into a brief quiescent period. Radiatively driven convection then formed a convectively mixed layer in late winter. The defined mixed layer and temperature structure provided the necessary conditions for the formation of a potential rotational feature, which briefly formed immediately prior to ice break-up. Ice break-up led to complex hydrodynamics that persisted for nearly 28 days following full ice-off. Dissolved oxygen was directly correlated with the varying circulation features throughout the field campaign. This work provides a quantitative measure to delineate the transitions between under-ice regimes and provides novel insights into the subsequent circulation during and after ice break-up.

Determining sediment deposition dynamics influenced by check dams in a semi‐arid mountainous watershed

AbstractSemi‐arid environments are characterized by infrequent large magnitude rainfalls that produce flash flood events with high sediment concentration. Control structures such as check dams are widely used in this environment for mitigation. However, their impact on the overall sediment balance of watersheds, particularly those severely affected by anthropogenic activity, is sparsely documented. This study used topographic measurements, sediment analysis, and fallout isotope techniques to assess the effectiveness and service life of 18 rock and masonry check dams that were constructed in the 1930s for controlling sediment fluxes in an 11 ha mountainous watershed in southern Arizona. All of the dams are currently filled with sediment resulting in reduction of local channel gradients by 35 to 71% to between 0.04 and 0.28 depending on location within the reach. Sedimentation occurred over multiple decades at a relatively slow average rate of 0.59 t ha−1 y−1 indicating low instantaneous retention efficiency. The smaller headwater dams were filled soon after construction; however, their share of the overall storage capacity was minor. Although evaluation of 137Cs was an effective method for dating sediment, the 210Pb dating method was not satisfactory because of sediment sorting effects and complex deposition patterns. The abundance of similar control structures in the region points to the opportunity to better understand the process impacts of check dams over multiple decades to inform planning and design of their use in future mitigation projects.

Analysing the performance of the NARX model for forecasting the water level in the Chikugo River estuary, Japan

Estuaries are dynamic environments which are driven by various natural processes like river discharge, tides, waves, influx of saline water and sediments, etc. These ecosystems are the most sensitive to sea level rise and fluctuations in river discharge associated with climate change. A direct response of sea level rise and river discharge can be observed in the water level of estuaries. However, existing models have not considered these parameters for forecasting water level. This paper focuses on developing a water level forecast model for the Chikugo River estuary in Japan using Nonlinear Autoregressive with Exogenous inputs (NARX Model). NARX neural network was used to do the one-step-ahead prediction of water level considering the various parameters that can very well be influenced by climate change: previous water level, river discharge, and salinity. Accordingly, three models were developed: (i) Model I considering previous water level; (ii) Model II additionally considering river discharge; and (iii) Model III additionally considering salinity. All the models showed appreciable performance in forecasting the water level. Model III had the best correlation with the water level with a cross-correlation value of 0.6030, while the river discharge had only a cross-correlation of 0.1113 indicating that the Chikugo River estuary is tide-dominated. The model was trained using different combinations of available data - previous water level, river discharge, and salinity. Cross-correlation results showed a better correlation between water level and salinity than various other combinations trained. Therefore, tidal intrusion influences the water level in the estuary, thereby depicting that sea level rise can affect the water level, and its influence can be well predicted by the developed model. The water level significantly affects the flora and fauna and the predictability of future estuarine floods can help in taking necessary mitigation strategies.

Modelling mass accumulation rates and 210Pb rain rates in the Skagerrak: lateral sediment transport dominates the sediment input

Sediment fluxes to the seafloor govern the fate of elements and compounds in the ocean and serve as a prerequisite for research on elemental cycling, benthic processes and sediment management strategies. To quantify these fluxes over seafloor areas, it is necessary to scale up sediment mass accumulation rates (MAR) obtained from multiple sample stations. Conventional methods for spatial upscaling involve averaging of data or spatial interpolation. However, these approaches may not be sufficiently precise to account for spatial variations of MAR, leading to poorly constrained regional sediment budgets. Here, we utilize a machine learning approach to scale up porosity and 210Pb data from 145 and 65 stations, respectively, in the Skagerrak. The models predict the spatial distributions by considering several predictor variables that are assumed to control porosity and 210Pb rain rates. The spatial distribution of MAR is based on the predicted porosity and existing sedimentation rate data. Our findings reveal highest MAR and 210Pb rain rates to occur in two parallel belt structures that align with the general circulation pattern in the Skagerrak. While high 210Pb rain rates occur in intermediate water depths, the belt of high MAR is situated closer to the coastlines due to lower porosities at shallow water depths. Based on the spatial distributions, we calculate a total MAR of 34.7 Mt yr-1 and a 210Pb rain rate of 4.7 · 1014 dpm yr-1. By comparing atmospheric to total 210Pb rain rates, we further estimate that 24% of the 210Pb originates from the local atmospheric input, with the remaining 76% being transported laterally into the Skagerrak. The updated MAR in the Skagerrak is combined with literature data on other major sediment sources and sinks to present a tentative sediment budget for the North Sea, which reveals an imbalance with sediment outputs exceeding the inputs. Substantial uncertainties in the revised Skagerrak MAR and the literature data might close this imbalance. However, we further hypothesize that previous estimates of suspended sediment inputs into the North Sea might have been underestimated, considering recently revised and elevated estimates on coastal erosion rates in the surrounding region of the North Sea.

Influences of sources and weather dynamics on atmospheric deposition of Se species and other trace elements

Abstract. Atmospheric deposition is an important source of the micronutrient selenium for terrestrial ecosystems and food chains. However, the factors determining the total concentrations and chemical forms (speciation) of selenium in atmospheric deposition remain poorly understood. Here, aerosol samples were collected weekly over 5 years at Pic du Midi Observatory (French Pyrenees), alongside highly temporally resolved samples of aerosols, precipitation, and cloud water taken during a 2-month campaign. Firstly, measurements of selenium, other elements, and water isotopes were combined with sophisticated modelling approaches (aerosol–chemistry–climate SOCOL-AERv2 model and air parcel backward trajectories and Lagrangian moisture source analyses). Aerosol selenium measurements agreed well with SOCOL-AERv2-predicted values, and interestingly, higher fluxes of selenium and other elements were associated with deep convective activity during thunderstorms, highlighting the importance of local cloud dynamics in high deposition fluxes. Our results further indicate the coupling of element and water cycles from source to cloud formation, with decoupling during precipitation due to below-cloud scavenging. Secondly, selenium speciation was investigated in relation to sulfur speciation, organic composition, and moisture sources. While in the 5-year aerosol series, selenite (SeIV) was linked to anthropogenic source factors, in wet deposition it was related to pH and Atlantic moisture sources. We also report an organic selenium fraction, tracing it back to a marine biogenic source in both aerosols and wet deposition. With a comprehensive set of observations and model diagnostics, our study underscores the role of weather system dynamics alongside source contributions in explaining the atmospheric supply of trace elements to surface environments.

Quantifying denudation rates and sediment recycling of low-relief, high-elevation landscapes using in-situ and meteoric cosmogenic nuclides

Quantifying Earth’s surface denudation rates is crucial for estimating sediment flux and its role in regulating global climate change. The inability of in-situ cosmogenic 10Bein to quantify denudation rates in quartz–free environment has prompted the need for a new proxy–the ratio of meteoric 10Bemet to mineral-weathered 9Be in reactive phase (precipitated in or adsorbed onto secondary minerals). This study utilized 10Bein–26Alin, 10Bemet/9Be, and major element analyses of reactive and mineral phases of bedload sediments to infer basin-wide denudation rates and sediment recycling (reworking of deeply buried sediments) in the Three River Source Region (TRSR) of the central Tibetan Plateau. Results from 10Bein-26Alin analysis of bedload sediments and bedrock samples (quartz grain, 250–500 μm) suggest that the sediments underwent burial events since at least 0.54 ± 0.16 million years ago. Combining paleoclimate records in the central Tibetan Plateau, we interpret the “Great Burial” as most likely the result of climate-controlled deglaciation and denudation at the termination of Naynayxungla glaciation during the MIS 13–15 period. This event marks the first widespread deglaciation on the Tibetan Plateau. The 10Bein-26Alin derived paleo–denudation rates range from 4.2-0.8+0.9 to 151-32+37 mm/kyr, consistent with previous 10Bein–derived modern denudation rates of 10–117 mm/kyr in TRSR. These rates show a moderate positive correlation with regional topography, particularly channel steepness, indicating a decrease in both relief and denudation rates from lower to upper streams. This spatial discrepancy is likely due to enhanced river headward incision and active neotectonic activities in the southeast. Denudation rates derived from the 10Bemet/9Be proxy range from 13 to 248 mm/kyr, alongside a chemical weathering intensity ranging from 43 % to 67 %. These denudation rates are strongly correlated with, but about 1.5 times higher than, the 10Bein–26Alin derived paleo–denudation rates from the same watershed. This suggests that the 10Bemet/9Be extracted from fine grains (<64 μm) may reflect a different sediment recycling pattern compared to 10Bein–26Alin in quartz sediments. Alternatively, the 10Bemet/9Be ratio could indicate a mixture of carbonate rock with a high denudation rate and silicate rock with a lower denudation rate, whereas 10Bein–26Alin reflects a single silicate denudation signal.

Comprehensive insight into mercury contamination in atmospheric, terrestrial and aquatic ecosystems surrounding a typical antimony-coal mining district

This study comprehensively investigated mercury (Hg) contents of various environmental compartments in a typical antimony-coal mining area with intensive industrial activities over the past 120 years to analyze Hg environmental behaviors and evaluate Hg risks. The total mercury (THg) contents in river water, sediments, soils, PM10, dust falls, vegetables and corns were 1.16 ± 0.63 µg/L, 2.01 ± 1.64 mg/kg, 1.87 ± 3.88 mg/kg, 7.87 ± 18.68 ng/m3, 13.01 ± 14.53 mg/kg, 0.30 ± 0.34 mg/kg and 3.11 ± 0.51 µg/kg, respectively. The δ202Hg values in soils and dust falls were − 1.58 ∼ 0.12‰ and 0.25 ∼ 0.30‰, respectively. Environmental samples affected by industrial activities in the Xikuangshan (XKS) presented higher THg and δ202Hg values. Binary mixing model proved that atmospheric deposition with considerable Hg deposition flux (0.44 ∼ 6.40, 3.12 ± 2.20 mg/m2/y) in the XKS significantly contributed to Hg accumulations on surface soils. Compared with soils, sediments with more frequent paths and higher burst probabilities presented higher dynamic Hg risks. Children were faced higher health risk of multiple Hg exposure than adults. Furthermore, the health risk of THg by consuming leaf vegetables deserved more attention. These findings provided scientific basis for managing Hg contamination.

A new process-based and scale-aware desert dust emission scheme for global climate models – Part II: Evaluation in the Community Earth System Model version 2 (CESM2)

Abstract. Desert dust is an important atmospheric aerosol that affects the Earth's climate, biogeochemistry, and air quality. However, current Earth system models (ESMs) struggle to accurately capture the impact of dust on the Earth's climate and ecosystems, in part because these models lack several essential aeolian processes that couple dust with climate and land surface processes. In this study, we address this issue by implementing several new parameterizations of aeolian processes detailed in our companion paper in the Community Earth System Model version 2 (CESM2). These processes include (1) incorporating a simplified soil particle size representation to calculate the dust emission threshold friction velocity, (2) accounting for the drag partition effect of rocks and vegetation in reducing wind stress on erodible soils, (3) accounting for the intermittency of dust emissions due to unresolved turbulent wind fluctuations, and (4) correcting the spatial variability of simulated dust emissions from native to higher spatial resolutions on spatiotemporal dust variability. Our results show that the modified dust emission scheme significantly reduces the model bias against observations compared with the default scheme and improves the correlation against observations of multiple key dust variables such as dust aerosol optical depth (DAOD), surface particulate matter (PM) concentration, and deposition flux. Our scheme's dust also correlates strongly with various meteorological and land surface variables, implying higher sensitivity of dust to future climate change than other schemes' dust. These findings highlight the importance of including additional aeolian processes for improving the performance of ESM aerosol simulations and potentially enhancing model assessments of how dust impacts climate and ecosystem changes.

A comprehensive observation of organic and inorganic nitrogen in gases, particulate matter and precipitation in the northern suburb of Nanjing, East China, with an emphasis on size-resolved particulate nitrogen

China is considered one of the nitrogen deposition hotspots in the world. Measurements to date have focused mainly on inorganic nitrogen, organic nitrogen and the size distribution of particulate nitrogen has yet to be studied. Lack of dry deposition observations imposes a reliance on models, resulting in a much larger uncertainty relative to wet deposition which is routinely measured. In this study, dry and wet organic and inorganic nitrogen deposition were comprehensively measured in Nanjing in 2019, and nitrogen species in size-segregated particles were investigated. Total annual nitrogen deposition flux was up to 29.96 kg N ha−1 yr−1 in Nanjing, with wet deposition contributed slightly more (51.90%) to total deposition than dry deposition (48.10%). Observations revealed that reduced nitrogen (NHx = NH3 + NH4+) contributed 65.49% of the total inorganic nitrogen deposition budget, which implied that the control of reduced N in urban environments is needed to improve local air quality. Dry deposition of ammonia played an especially key role in dry deposition, contributing from 18.17% to 55.91% in different seasons. The deposition flux of water-soluble organic nitrogen (WSON) dominated by wet deposition, with the wet WSON about 4.6 times higher than that of dry deposition and contributed 41.18% of the wet nitrogen deposition. The wet N deposition in summer was significantly higher than in the other three seasons. The seasonal patterns in dry deposition were driven mostly by seasonal concentration patterns. The highest deposition of ammonia occurred in summer, while the deposition of nitrogen dioxide, particulate ammonium and nitrate peaked in winter. The maximum dry and wet WSON deposition appeared in autumn. Higher NH4+ concentration almost distributed in each size bin and centered in ranges of 0.18–1.0 μm, while higher NO3− concentration scattered in particle size ranges of 1.8–5.6 μm and 0.18–1.0 μm.

Predicting soil erosion and sediment delivery in large, data‐sparse, mountainous basins

AbstractIntense hydroelectric exploitation requires information on sediment flux to prevent the potential siltation of cascade reservoirs. As the main sediment source for the Yangtze River, the lower Jinsha River Basin (LJRB) lacks data on its sediment budget, which urges a thorough investigation to provide reliable estimates. This paper proposed a modelling framework to study soil erosion, sediment delivery, and sediment yield in this critical area with an emphasis on analyzing the underlying controls. Over the past 50 years, basin average erosion rates decreased from 26.5 to 23.7 t ha−1 a−1, with erosion hotspots (&gt;50 t ha−1 a−1) comprising only 21.1% of the basin area but contributing 69.5% of the gross erosion. Local steepness and sparse landcover conditions were found to be directly responsible for high erosions, rather than precipitation or soils. With a dimensionality reduction strategy to remove redundant factors, the optimal variables for modelling sediment delivery ratio (SDR) were identified as Specific Catchment Area, Maximum Elevation, and Drainage Area. These three variables all had a positive correlation with SDR, and the established model can explain 86% of the SDR variation. Further modelling revealed regionalised SDRs ranging from 0.07 to 0.38 for 39 subbasins, about 30% of which were no less than 0.35. Regionalised specific sediment yield (SSY) ranged from 1.3 to 16.9 t ha−1 a−1 with 38% of the high SSYs (above 8 t ha−1 a−1) concentrating in the reservoir area from Wudongde to Xiluodu that poses siltation risks. This study addressed the scarcity of sediment budget knowledge in the LJRB, and the coupled model of erosion and sediment delivery has been validated with satisfactory predictions. Therefore, the modelling framework proposed may be adopted to diverse river basins for its low parameter requirements and solid modelling performance.

High-power impulse magnetron sputter deposition of TiBx thin films: Effects of pulse length and peak current density

We report on a systematic study of the effect of pulse length (ton=25−200μs), and peak target current density (JT,peak=0.25−2.0A/cm2) during HiPIMS deposition of AlB2-phase TiBx thin films from a TiB2 target at a pressure of pAr=1.33Pa(10mTorr) and substrate temperature Ts=500°C. All films are under-stoichiometric with B/Ti = 1.36–1.89, with the higher values corresponding to longer pulses and higher JT,peak values. While the deposition flux, including both ions and neutrals, in general increases with increasing ton and JT,peak, the Ti+ ion flux saturates, resulting in the higher B/Ti values under these conditions. Thus, the relative amount of Ti ionization, and the degree to which these ions are guided toward the substrate by magnetic fields, are main modulators determining the composition of TiBx thin films.

ELEMENTAL COMPOSITION OF BOTTOM SEDIMENTS AND PERMAFROST DEPOSITS FROM THE BUOR-KHAYA BAY (LAPTEV SEA)

The paper summarizes data on the lithological and elemental composition of bottom sediments and permafrost from boreholes 1D-14, 3D-14 and 1D-15 drilled in Buor-Khaya Bay in 2014-2015. Based on the results of determining the percentage content of SiO2, Al2O3, Fe2O3, TiO2, MgO, Na2O, K2O, CaO, MnO, P2O5, Cl, Cr, S, Ni, Cu, Zn, Rb, Sr, Ba, Y, Zr, organic carbon in sediments, lithochemical modules values were calculated and comparative analysis of the lithological and geochemical composition was performed. Principal differences between near-continental (1D-14 and 3D-14) and relatively distant from land (1D-15) strata were established, which is explained by spatial and temporal variability in sedimentary fluxes and weathering crust activity in the studied area of the Laptev Sea. The results of the study allowed to conclude that the basis of the petrofund of the studied deposits are most likely sedimentary rocks of the Kharaulakh ridge of the Verkhoyansk mountain system (sandstones, siltstones and mudstones). The contribution of igneous and metamorphic rocks to the sedimentary supply in the strata uncovered by drilling was insignificant.

Atmospheric deposition of dicamba herbicide can cause injury to sensitive soybean

ABSTRACT The herbicide dicamba has injured millions of hectares of sensitive plant species in the United States since 2017. This injury has coincided with the commercialization of dicamba-resistant soybean [Glycine max (L.) Merr.] and cotton (Gossypium hirsutum L.). We quantified atmospheric deposition and mass flux of dicamba in 12 soybean production regions of Missouri. Dicamba was routinely detected in weekly deposition samples collected during agriculturally-intensive spray periods. Observed concentrations were indicative of both local (&lt;1 km) and long-distance transport (&gt;1 km) of air-borne dicamba. High deposition events (&gt;100 µg m-2) occurred annually in southeast Missouri, and peak dicamba deposited at these sites (12.5-84.0 µg m-2) was sufficient to injure non-dicamba resistant soybean. Adoption rate of dicamba-resistant crops and atmospheric stability explained much of the variance, and it is difficult for a herbicide product label to address these variables. Overall, these results demonstrated that dicamba was commonly deposited from the atmosphere during the growing season and observed concentrations and fluxes were strongly related to the timing and magnitude of rainfall events, and the amount of dicamba usage near collection sites.

Current and future roles of meltwater–groundwater dynamics in a proglacial Alpine outwash plain

Abstract. Glacierized alpine catchments are rapidly evolving due to glacier retreat and consequent geomorphological and ecological changes. As more terrain becomes ice-free, reworking of exposed terrain by the river as well as thawing of the top layer may lead to an increase in surface and subsurface water exchanges, leading to potential changes in water storage and release, which in turn may impact ecological, geomorphological and hydrological processes. In this study, we aim to understand the current and future hydrological functioning of a typical outwash plain in a Swiss Alpine catchment. As with many other fluvial aquifers in alpine environments, this outwash plain is located at the valley bottom, where catchment-wide water and sediment fluxes tend to gather from multiple sources, may store water and provide specific habitats for alpine ecosystems. Their dynamics are however rarely studied in post Little Ice Age proglacial zones. Based on geophysical investigations as well as year-round stream and groundwater observations, we developed a simplified physically based 3D MODFLOW model and performed an optimized automatic calibration using PEST HP. We highlight the strong interactions between the upstream river and the aquifer, with stream infiltration being the dominant process of recharge. Groundwater exfiltration occurs in the lower half of the outwash plain, balancing out the amount of river infiltration at a daily timescale. We show that hillslope contributions from rain and snowmelt have little impact on groundwater levels. We also show that the outwash plain acts as a bedrock-dammed aquifer and can maintain groundwater levels close to the surface during dry periods lasting months, even in the absence of glacier meltwater, but may in turn provide only limited baseflow to the stream. Finally, we explore how new outwash plains may form in the future in this catchment due to glacier recession and discuss from a hydrological perspective which cascading impacts the presence of multiple outwash plains may have. For this case study, we estimate the total dynamic storage of future outwash plains to be about 20 mm, and we demonstrate their limited capacity to provide more stream water than that which they infiltrate upstream, except for very low river flows (&lt;150 to 200 L s−1). Below this limit, they can provide limited baseflow on timescales of weeks, thus maintaining moisture conditions that may be beneficial for proglacial ecosystems. Their role in attenuating floods also appears limited, as less than 0.5 m3 s−1 of river water can be infiltrated. The studied outwash plain appears therefore to play an important role for alpine ecosystems but has a marginal hydrological effect on downstream river discharge.

Event-scale suspended sediment fluxes in a dryland environment valley-bottom wetland: Implications for downstream sediment and phosphorous fluxes

Suspended fine sediment in rivers and small streams contributes to fluvial pollution loads because of its association with anthropogenically introduced heavy metals, pesticides / herbicides, and nutrients, including phosphorous (P). By acting as sinks for suspended sediment, wetlands located along drainage lines have considerable potential in reducing downstream sediment and nutrient fluxes. The aim of this research was to document downstream sediment fluxes within a single valley-bottom wetland to establish the effectiveness of this common wetland type in retaining P attached to sediment. The study was accomplished by conducting a topographic survey (dGPS and 0.5 m Lidar-derived DEM) with surface and sub-surface sediment sampling to establish long-term (decades to centuries) processes of erosion and deposition within the wetland, as well as consider storage of P. This was paired with event-based suspended sediment sampling at eight positions within the wetland over a wet season, as well as time-averaged suspended sediment sampling at a seasonal-scale at the wetland inlet and outlet. Sediment samples were characterised in terms of organic content, total phosphorous and particle size, which were determined using loss-on-ignition, ICP-AES following aqua regia extraction, and a combination of dry sieving and settling, respectively.Over the wet season, average suspended sediment concentrations increased to a maximum value of 0.26 g.L−1 and then declined, potentially because of the exhaustion of locally available sediment. The total P concentration of incoming sediment was 2174 mg/kg compared to 800 mg/kg at the wetland outlet. However, when considering the seasonal flux for the single year sampled, it was found that the wetland was a net downstream contributor of sediment (11 g of sample were retained at the inlet, relative to 19 g at the outlet). Despite this, the wetland retained ∼37 % of the total P supplied to it from upstream sources, with the remainder passing through the wetland as a result of sediment reworking in reforming channels. Thus, while wetlands may be effective at retaining some sediment and nutrients, they are not an alternative to more formal water treatment works.

Distributions, spatial patterns and source identification of n-alkanes in air and bulk deposition in the eastern coastal areas of China: Fluxes and removal efficiency of bulk deposition

Normal alkanes (n-alkanes) are crucial components of organic carbon in the atmosphere. Low-carbon number n-alkanes act as precursors for secondary organic aerosols, while long-chain alkanes are difficult to degrade after deposition, posing risks to human health and garnering widespread attention. However, their environmental partitioning, chemical composition, removal efficiency by bulk deposition, and sources in the eastern coastal areas of China remain understudied. To address this, this study investigated n-alkanes (C11 to C40) in the air and bulk deposition. This investigation was conducted by applying passive sampling-gas chromatography-mass spectrometry analysis technology in Qingdao from December 2019 to October 2020. The mean concentrations of n-alkanes in the atmosphere and bulk deposition were 160 ng/m3 and 15.6 μg/m2/d, respectively, throughout the year. Deposition fluxes followed this order: background site > suburban > rural > urban, while atmospheric n-alkanes showed the reverse trend. Plant sources contributed more to n-alkanes in bulk deposition than in the atmosphere. N-alkanes with medium to high-carbon numbers (C20–C36) were more efficiently removed from the atmosphere during summer-autumn. Based on carbon preference index (CPI) and positive matrix factorization (PMF) analysis, the main contributors to n-alkanes in air and bulk deposition were fossil fuel combustion, emissions from higher plants, and motor vehicle exhaust.