Sediment Flux Research Articles

Evidence of Secondary Bedform Controls on River Dune Migration

AbstractIn rivers worldwide, multiple scales of dunes coexist. It is unknown how the larger, primary dunes interact with secondary bedforms that are superimposed. We test the hypothesis that streamwise variability in the sediment flux inferred from the downstream migration of secondary bedforms explains migration of the host dune, based on bathymetric data from a lowland, sand‐bedded river. Results indicate that transport estimated from secondary bedform migration increases along the host dune stoss, eroding the stoss slope. When the superimposed bedforms disintegrate at the primary lee slopes, results indicate that all sediment transport associated to secondary bedform migration is arrested in the lee of the host dune, explaining migration of the host dune. When secondary dunes persist however, only part of the sediments transport linked to secondary dunes contributes to the migration of the host dune. This study gives novel insight into the fundamental mechanisms controlling the kinematics of compound dunes.

Rates of Evacuation of Bedload Sediment From an Alpine Glacier Control Proglacial Stream Morphodynamics

AbstractProglacial forefields commonly include highly dynamic fluvial systems associated with the fundamental instability between topography, flow hydraulics and sediment transport. However, there is limited knowledge of how these systems respond to changing subglacial hydrology and sediment supply. We investigated this relationship using the first continuous field‐collected data sets for both suspended and bedload sediment export and proglacial river dynamics for an Alpine glacier forefield, the Glacier d’Otemma, Switzerland. The results show a strong sensitivity of fluvial morphodynamics to the balance between sediment transport capacity and supply. When subglacial bedload export rates exceeded fluvial transport capacity, we found bar construction leading to net forefield aggradation and surficial coarsening, especially on bar heads. This intensified braiding buffered the downstream transport of coarse sediment. When subglacial bedload export rates were lower than transport capacity, incision occurred, with reduced braiding intensity, net erosion and important amounts of bedload leaving the proglacial system. We found a net fining of surficial deposits except for very isolated coarsening patterns on bar heads. Thus, proglacial forefield morphodynamics are strongly conditioned by subglacial hydrology and sediment supply, but this conditioning is also influenced by the response of the forefield itself. Proglacial forefields have an important influence on the longitudinal connectivity of sediment flux in regions sensitive to climate change, such as recently deglaciated high mountain areas. The linkages we report between subglacial processes and river morphodynamics are critical for understanding the development of embryonic forefield ecosystems.

Constraining Mean Landslide Occurrence Rates for Non‐Temporal Landslide Inventories Using High‐Resolution Elevation Data

AbstractConstraining landslide occurrence rates can help to generate landslide hazard models that predict the spatial and temporal occurrence of landslides. However, most landslide inventories do not include any temporal data due to the difficulties of dating landslide deposits. Here we introduce a method for estimating the mean landslide occurrence rate of deep‐seated rotational and translational slides derived solely from high‐resolution (≤3 m) elevation data and globally available estimates of the diffusion coefficient for sediment flux. The method applies a linear diffusion model to the roughest landslide deposits until they reach a representative non‐landslide roughness distribution. This estimates the time for a landslide deposit to be unrecognizable in high‐resolution digital elevation data, which we term the mean lifetime of the landslide. Using the mean lifetime and number of landslides within an area of interest, we can estimate the mean occurrence rate of landslides over that domain. We validate this approach using a comprehensive temporal inventory of landslides in western Oregon created using age‐roughness curves that are calibrated with high‐resolution elevation data and radiocarbon data. We find good agreement between our diffusion method and the existing age‐roughness‐derived estimates, producing mean lifetimes of 4500 and 5200 years (4% difference), respectively. Hazard maps produced using the two methodologies generally agree, with the maximum differences in landslide probability reaching 0.1. Due to the relative abundance of high‐resolution elevation data compared with age‐dated landslides, our method could help constrain landslide occurrence rates in areas previously considered unfeasible.

Analysis of long-term and short-term bankline stability prediction considering seasonal variations: A study in lower Ganga Basin, India

River bank instability in the lower Ganga plain has been a major concern since the early 1850s due to its huge catchment flux and transboundary character, especially in the districts of Malda and Murshidabad. This study examines the seasonal dynamics of banklines in the upper and lower Farakka regions. The study assesses seasonal changes in the lower Ganga regions over 68 years (1955–2022) and projects trends for the next 22 years (2022–2044) using a GIS-based Digital Shoreline Analysis System (DSAS) approach. Long-term erosion prevails on the left bank at −19.38 ± 2.83 m yr^-1 (LRR method), with 38.61 % of transects showing a significant (p < 0.05) erosional rate, covering 58.85 % of total erosional transects. The right bank experiences accretion at a rate of 6.82 ± 2.83 m yr^-1, with 27.66 % of transects showing a significant erosional rate, covering 46.10 % of total erosional transects. Short-term fluctuations show erosion-accretion values surpassing the 50 % threshold, highlighting dominant erosion in 1975–1980 and 1985–2015. The non-cyclic erosion-accretion nature unveils erosional processes in 1975–2000 and 2010–2015 and accretional processes in 2000–2010 and 2015–2021 on the right bank during the monsoon season. The dynamics of the projected bank lines exhibit an accretional tendency over the right bank and an erosional trend over the left. Moreover, a strong correlation between the actual and expected bank lines is shown by the R2 value surpassing 0.95 for all seasons on both the left and right banks. The erosional trends are evident in Chachunda at a rate of −152.45 ± 198.92 m yr^-1, while Loharpur and Shikdarpur exhibit erosional rates of −237.88 ± 211.30 m yr^-1 and −243.59 ± 207.91 m yr^-1, respectively, in the lower Farakka. The seasonal long-term and short-term analyses are influenced by various forcing mechanisms like high sediment flux, enormous discharge, and drastic anthropogenic intervention that drives changing foci of erosion and accretion.

Evaluation of sedimentation processes in riverbank water reservoir

Abstract Reservoirs are vital for human development, aiding agriculture, energy, industry, and the economy. This study delves into the pressing issue of muddy flooding in reservoirs. Field experiments aimed to identify sedimentation causes in the Chartak reservoir and assess its volume efficiency. Utilizing mathematical and statistical methods alongside river surveyor tools, sediment processes were analyzed. Findings reveal a loss of 9.08 million.m3 in Chartak Reservoir due to sedimentation, impacting efficiency and water balance. Maximum sedimentation influx from natural flow was 0.6 kg/m3, attributed to leaching. Mathematical analysis indicates one third of the reservoir’s useful volume filled with mud over half a century. These insights shed light on the challenges posed by sedimentation, emphasizing the need for proactive measures to mitigate its adverse effects on reservoir functionality and environmental balance.

Geomorphic assessment of sediment storage potential and mobilisation on the hillslopes of a mountain catchment: An example from Pranmati catchment, NW Himalaya

Sediment budgeting within a landscape is useful in understanding landscape evolution, and hazard prediction and assessment. It has been observed that only a fraction of the total volume of sediment produced within the system gets exported, implying that a part of the total volume of sediment is stored within the system. This sediment mass gets arrested and stored in compartments within the system and is mobilised during extreme stochastic events. These sediment storage compartments are poorly connected with the channel network and hence, do not supply sediment at steady rates. We have evaluated sediment connectivity and conducted field validation within a 93 km2 mountainous river basin (Pranmati catchment) in the NW Himalayas. This assessment relies on the Index of Connectivity (IC), computed through two methods: one employing the original framework and the C-factor from RUSLE, and the other utilizing a multiple flowpath model that incorporates Manning's roughness coefficient. We developed a storage potential index (SPI) by modifying the basic framework of index of connectivity; SPI indicates the potential of a point on the hillslope to arrest sediment flux and store it. Based on the difference of normalised IC and SPI, we have developed a sediment evacuation susceptibility index (ESIS) that indicates the susceptibility of various parts of the hillslope to get evacuated. Using ESIS, a sediment evacuation susceptibility zonation map was prepared that delineates areas on the basis of their stability.Our study indicates that sediment flux gets arrested at the (1) junction of land use and land cover units that have contrasting sediment transporting capacity, (2) grassland/barren land pockets surrounded by forests, (3) croplands, and (4) landslide debris deposits. The parts of the hillslope in the vicinity of the channel network and areas around steep surfaces are highly susceptible to sediment evacuation. Gentle sloped surfaces away from the channel network are relatively stable. Landslide debris are highly stable units of sediment storage.

In situ three-dimensional reconstruction and gradient-induced design of ultrastable Zn metal anodes in Zn-Se batteries

Zinc-selenium batteries have high specific and volumetric capacities, but practical development faces key challenge in achieving stable zinc metal anodes, and avoiding zinc dendrite growth, hydrogen evolution reaction (HER) and corrosion. Here, a zinc foam substrate is employed to fabricate three-dimensional gradient electrodes Zn foam@Cu@CuSe2 (ZFCCS) with gradient change of zincophilicity and conductivity. Experimental observations and simulations collectively confirm that the three-dimensional structure and gradient design effectively homogenize interfacial ion flux and diminish local current density. This optimization of the zinc deposition path synergistically fosters high flux and deep deposition of zinc metal while simultaneously preventing dendrite growth. The results demonstrate that the developed ZFCCS electrode produces an excellent Coulombic efficiency of 99.5 % over 1000 plating/stripping cycles, and the corresponding symmetric cell provides an ultra-long dendrite-free cycle life of 800 h at 5 mA cm−2 and 2 mAh cm−2 with a low overpotential of 27.4 mV. In addition, the Zn-Se full cell based on the designed ZFCCS composite anode exerts superior stable cycle life (358.1 mAh g−1 at 2 A g−1 after 1000 cycles). Therefore, the gradient design strategy based on 3D electrodes will be a reference for high performance energy storage devices.

Provenance shift of the abyssal plains in the Southwest sub-basin of the South China Sea at ∼ 8 Ma: Tectonics & climate changes implication

Tectonic processes and climatic changes are recognized as two major drivers of erosion along the southeastern margin of the Tibetan Plateau and consequently are the main factors controlling depositional patterns along the margins of the South China Sea. However, the role of tectonics and climate in governing the types and patterns of sedimentation in the abyssal plains is relatively little known. The results of International Ocean Discovery Program (IODP) drilling in the abyssal plains of the Southwest sub-basin of the South China Sea show that the multi-trace element and rare earth element (REE) character of sediments older than ∼8 Ma are in disorder. εNd(0) and 87Sr/86Sr values exhibit large fluctuations, which implies temporally variable sediment sources during the early post-spreading stage of the South China Sea. High εNd(0) and low 87Sr/86Sr values and abundant Cenozoic (13–35 Ma) zircon grains in the sediments suggest relatively juvenile sources for their origins, such as the Cagayan Ridge and Palawan Block in the south before ∼8 Ma. Multi-trace element and REE patterns of sediments younger than ∼8 Ma are more uniform. Low εNd(0) and high 87Sr/86Sr values of the sediments indicate that more continentally-derived sediments were transported to the abyssal plain. Coastal rivers in SE Vietnam, and the Mekong and Red Rivers in the west gradually became the major detrital sources of abyssal sediments in the Southwest sub-basin after ∼8 Ma. The switching of the sediment sources from the south to the west is consistent with the progressive uplift of the Vietnamese Central Highlands (VCH) and the SE Tibetan Plateau margin during the Late Miocene. The strengthened summer monsoon since ∼5 Ma affected not only the marginal basins, but also the deep abyssal basins. We argue that the regional tectonics shaped and controlled the shift of provenance and sediment routing system, whereas the East Asian monsoon affected the sediment flux to the abyssal plains of the Southwest sub-basin in the South China Sea.

Role of tidal range and coastline morphology on the evolution of two macrotidal sand spits

AbstractThe present study examines the stratigraphy of two sandspits that both appeared and developed since the middle of the 17th century during the Little Ice Age. The Arçay spit is located along the macrotidal Atlantic coast in South‐West France with a maximum tidal range of 6.5 m. The Pointe du Banc in the English Channel, North‐West France, is located in a hypertidal coastal setting with a tidal range of up to 14 m. The evolution of the two spit systems has been compared using historical maps, ground penetrating radar data and facies analysis and geochronological data from sediment cores. The Pointe du Banc spit developed between 1650 and 1750 CE, in a dominant seaward direction while the main mode of construction of the Arçay spit was in a longshore direction. It is proposed that this difference relates to sediment supply and coastline morphology. At the Pointe du Banc spit, the large tidal range causes a long wind fetch and sustained aeolian sediment supply. Moreover, the spit is located at the apex of a large‐scale embayment where sediment transport from north and south converges. Combined, these factors result in a positive sediment budget and seaward shoreline progradation. At the Arçay spit, high wave obliquity results in a large littoral drift and sustained longshore spit construction. At both locations, low gradient shorefaces may have favoured a net landward‐directed sediment flux that supply sand to the foreshore.

Exploring the Transport Path of Oceanic Microplastics in the Atmosphere.

Microplastics (MP) have been recognized as an emerging atmospheric pollutant, yet uncertainties persist in their emissions and concentrations. With a bottom-up approach, we estimate 6-hourly MP fluxes at the ocean-atmosphere interface, using as an input the monthly ocean surface MP concentrations simulated by the global oceanic model (NEMO/PISCES-PLASTIC, Nucleus for European Modeling of the Ocean, Pelagic Interaction Scheme for Carbon and Ecosystem Studies), a size distribution estimate for the MP in the micrometer range, and a sea salt emission scheme. The atmospheric dispersion is then simulated with the Lagrangian model FLEXPART. We identify hotspot sources in the tropical regions and highlight the seasonal variability of emissions, atmospheric concentrations, and deposition fluxes both on land and ocean surfaces. Due to the variability of MP concentration during the year, the MP flux from the sea surface appears to follow a seasonality opposite to that of sea salt aerosol emissions. The comparison with existing observations of MP in the marine atmosphere suggests an underestimation of one to 2 orders of magnitude in our current knowledge of the MP in the oceans' surface. In addition, we show that the MP in the micrometer range is transported efficiently around the globe and can penetrate and linger in the stratosphere over time scales of months. The interaction of these particles with the chemistry and physics of the atmosphere is still mostly unknown and deserves to be further investigated.

Balancing the oceanic Zn isotope budget: The key role of deep-sea pelagic sediments

Abstract Oxygenated deep-sea pelagic sediments with Fe-Mn–oxide particles represent a key oceanic oxic sink for transition metals in the modern ocean. However, the isotopic composition of authigenic Zn in the pelagic zone remains poorly constrained, which hampers our understanding of the global budget of Zn isotopes. Here, we analyzed the Zn isotopic compositions of two deep-sea pelagic sediment columns collected from the Pacific Ocean. The results show that authigenic Zn in deep-sea sediments is primarily hosted by the Fe-Mn (oxyhydr)oxides. The light Zn isotopic signatures (δ66Zn: −0.02‰ to 0.34‰, n = 42; computed as the per mille deviation of the 66Zn/64Zn ratio from the JMC-Lyon standard) observed in deep-sea sediments are completely different from the previously assumed values of ~1.0‰ based on the Zn isotopic compositions of Fe-Mn crusts and nodules. Based on this observation (Zn flux of deep-sea sediments = 5.3 × 108 mol yr–1), we propose a new, balanced global budget for Zn isotopes.

Impacts of glacial discharge on the primary production in a Greenlandic fjord

Subglacial discharge from marine-terminating glaciers in Greenland injects large volumes of freshwater and suspended sediment into adjacent fjord environments. Although the discharge itself is nutrient poor, the formation of meltwater plumes can enhance marine biological production by stimulating upwelling of nutrient-rich fjord water. Despite the importance of meltwater discharge to marine ecosystems, little is known of the quantitative impact of discharge processes on phytoplankton growth, including the effects of local plumes, fjord-wide stirring and mixing, and suspended sediments on net primary production (NPP). Here, we report simulations of Bowdoin Fjord in northwestern Greenland using coupled non-hydrostatic ocean circulation and lower-trophic level ecosystem models, developed using field data. Our findings demonstrate that subglacial discharge plays a crucial role in NPP by stirring and mixing the entire fjord water system, which has a greater effect on NPP than local plume upwelling. Sensitivity tests suggest a 20% increase in NPP under conditions of enhanced discharge anticipated in the future. However, if glacier discharge and retreat exceed critical levels, NPP is predicted to decline by 88% relative to present values. This pattern reflects the negative impact of increased sediment flux on photosynthesis and weakened fjord stirring and mixing resulting from shallower outlet depths.

Atmospheric deposition of microplastics in an urban conglomerate near to the foothills of Indian Himalayas: Investigating the quantity, chemical character, possible sources and transport mechanisms

The global apprehension regarding the ubiquitous presence of microplastics (MPs) and their associated health risks underscore a significant challenge. However, our understanding on the occurrence and characteristics of this emerging class of pollutants in the different environmental compartments remains limited. For instance, despite housing approximately 20–25% of the global population, the evidence of the atmospheric MPs in Indian Subcontinent is exceedingly rare. Hence, we for the first-time present data on the depositional flux, chemical composition, morphological features of the atmospheric MPs collected from the foothills of Indian Himalayas. The total number of MPs for the collected samples ranged from 65 to 752 particles, with an average of 317 ± 171 particles count. The average flux of atmospheric MPs was 2256 ± 1221 particles/m2/day and varied significantly from 462 particles/m2/day to 5346 particles/m2/day. The highest deposition (5346 particles/m2/day) of atmospheric MPs was recorded during the 3rd week of sampling, coinciding with the Diwali festival. Based on the visual characteristics, we determined that the size of MPs ranged from 67 to 2320 μm, with a predominant presence of smaller particles (<1200 μm), primarily composed of fragments and films/sheets. Raman spectroscopy indicated that the analyzed MPs were mainly composed of 4 different polymer types, including PE (46.8 ± 7.2 %), PP (20.9 ± 7.4 %), PS (15.6 ± 3.8 %) and PET (16.7 ± 9.9 %). We further highlighted the extent to which climate variables control the deposition of atmospheric MPs in this urban conglomerate located in the foothills of Himalayas. Our Lagrangian parcel tracking approach showed that the greater frequencies are of local origin and clustered near to the studied region. We also speculate that atmospheric microplastics can be transported along the westerly winds. Though we did not observe any significant relation (p > 0.05) between meteorological parameters and the quantity of atmospheric MPs.

Polycrystalline silicon, a molecular dynamics study: I. Deposition and growth modes

Polycrystalline silicon (poly-Si) significantly expands the properties of the ICT miracle material, silicon (Si). Depending on the grain size and shape and grain boundary structure, the properties of poly-Si exceed what single-crystal (c-Si) and amorphous (a-Si) silicon can offer, especially for radio frequency (RF) applications in microelectronics. Due to its wide range of applications and, on the one hand, its theoretically and technologically challenging microstructure, poly-Si research is the most timely (Ding et al 2020 Mater. Charact. 161 110174; Zhao and Li 2019 Acta Mater. 168 52–62). In this report, we describe how we simulate and analyse the phenomena and mechanisms that control the effect of poly-Si deposition parameters on the structure of the deposited poly-Si films using classical molecular dynamics simulations. The grain shape and size, degree of crystallinity, grain boundary structure and the stress of poly-Si films are determined depending on the growth temperature, temperature distribution in the growing film, deposition flux, flux variation and the energy transferred to the film surface due to the deposition flux. The main results include: (i) the dependence of the crystallinity profile of the deposited poly-Si films on the stress, temperature and the different parameters of the deposition flux, (ii) growth modes at the early stages of the deposition, (iii) interaction and stability of seed crystallites at the early stage of the deposition of poly-Si films and the transition from the isolated crystallite growth to the poly-Si growth, (iv) interplay of the temperature, crystallinity, crystal shape and heath conductivity of different Si phases, (v) four different stages of crystallite growth are described: nucleation, growth, disappearance and retardation.

Time-lapse surveys reveal patterns and processes of erosion by exceptionally powerful turbidity currents that flush submarine canyons: A case study of the Congo Canyon

The largest canyons on Earth occur on the seafloor, and seabed sediment flows called turbidity currents play a key role in carving these submarine canyons. However, the processes by which turbidity currents erode submarine canyons are very poorly documented and understood. Here we analyse the first detailed time-lapse bathymetric surveys of a large submarine canyon, and its continuation as a less-deeply incised channel. These are also the most comprehensive time-lapse surveys before and after a major canyon-channel flushing turbidity current. These unique field data come from the Congo Submarine Fan offshore West Africa, where canyon flushing turbidity currents between 2019 and 2020 eroded ~2.65 km3 of seabed sediment, as they travelled for over 1100 km at speeds of 5–8 m/s. This eroded sediment volume is equivalent to ~19–33 % of global sediment flux from all rivers to the oceans. The time-lapse surveys cover 40 % of the 1100 km long submarine canyon-channel. They show that erosion was predominantly (94 %) along the canyon-channel axis, with only 6 % from failures along canyon or channel flanks. However, erosion along the canyon-channel floor was very patchy; some areas were eroded to depths of 10–20 m, whilst intervening areas showed no significant change. Knickpoints with up-slope migrating headscarps account for 22 % of the total eroded volume. One knickpoint in the deep-sea channel migrated by 21 km in one year, making it the fastest moving submarine knickpoint yet documented. Most (62 %) eroded sediment was in zones extending across the canyon or channel floor, without distinct headscarps as is the case for knickpoints. Erosion restricted to outer bends only comprised 10 % of the total, suggesting processes of erosion differ significantly from meandering rivers in which outer bend erosion is more important. Patchy seabed erosion appears to be mainly due to flow-bed processes (e.g. knickpoints), but spatial variations in seabed sediment properties may also play a role. The irregular seabed erosion occurs despite near-uniform flow speeds observed between moorings and submarine cable breaks with spacing of tens to hundreds of kilometers. Patchy and localised erosion has important implications for assessing hazards to seabed telecommunication cables, which are more likely to break in areas of deep erosion, and for creating appropriate numerical models of seabed erosion and turbidity current behaviour, or how to interpretate ancient submarine canyons and channels in rock outcrops.

Source-resolved atmospheric metal emissions, concentrations, and deposition fluxes into the East Asian seas

Source-resolved atmospheric metal emissions, concentrations, and deposition fluxes into the East Asian seas

Phytoavailability, translocation, and accompanying isotopic fractionation of cadmium in soil and rice plants in paddy fields

Rice consumption is a major pathway for human cadmium (Cd) exposure. Understanding Cd behavior in the soil-rice system, especially under field conditions, is pivotal for controlling Cd accumulation. This study analyzed Cd concentrations and isotope compositions (δ114/110Cd) in rice plants and surface soil sampled at different times, along with urinary Cd of residents from typical Cd-contaminated paddy fields in Youxian, Hunan, China. Soil water-soluble Cd concentrations varied across sampling times, with δ114/110Cdwater lighter under drained than flooded conditions, suggesting supplementation of water-soluble Cd by isotopically lighter Cd pools, increasing Cd phytoavailability. Both water-soluble Cd and atmospheric deposition contributed to rice Cd accumulation. Water-soluble Cd’s contribution increased from 28‐52% under flooded to 58‐87% under drained conditions due to increased soil Cd phytoavailability. Atmospheric deposition’s contribution (12‐72%) increased with potential atmospheric deposition flux among sampling areas. The enrichment of heavy Cd isotopes occurred from root-stem-grain to prevent rice Cd accumulation. The different extent of enrichment of heavy isotopes in urine indicated different Cd exposure sources. These findings provide valuable insights into the speciation and phytoavailability changes of Cd in the soil-rice system and highlight the potential application of Cd isotopic fingerprinting in understanding the environmental fate of Cd.

Atmospheric bulk depositions: state-of-the-art and European legislative framework with focus on Italy.

The determination of total atmospheric deposition (bulk) is an essential tool to assess the state of environmental contamination and the consequent exposure of the population to persistent organic pollutants (POPs) through the intake of contaminated food. Over the past 20years, international authorities and the European Union through various pieces of legislation have emphasised the importance of conducting monitoring and studies on depositions to better understand their impact on the environment and human health without setting reference values. Despite the absence of such values, several European countries, through national laws, have adopted limit values and/or guideline values for the deposition fluxes of some organic (dioxins, furans, polychlorinated biphenyls and polycyclic aromatic hydrocarbons) and inorganic persistent pollutants (metals). The aim of this review is both to summarise the present European legislation on depositions both to discuss the different legislations adopted by the various member states. Furthermore, a focus of this paper will be dedicated to the Italian legislation, where there is currently no specific guideline values for POPs in atmospheric deposition. In any case, some national authorities in Italy, such as the National Institute of Health (ISS) and the Regional Environmental Protection Agencies (ARPA), have conducted numerous monitoring activities on depositions, providing the scientific community and policymakers with numerous data on which to establish national reference values.

Organophosphate flame retardants in air from formal e-waste recycling workshops in China: Size-distribution, gas-particle partitioning and exposure assessment

In order to understand the organophosphate flame retardants (OPFRs) pollution and evaluate the inhalation exposure risk in formal e-waste recycling facilities, the air concentrations, particle size distribution and gas-particle partitioning of OPFRs in four typical workshops were investigated. The total Σ15OPFR concentrations inside workshops were in the range of 64.7–682 ng/m3, with 5.80–23.4 ng/m3 in gas phase and 58.8–658 ng/m3 in particle phase. Triphenyl phosphate (TPHP) and tris(2-chloroisopropyl) phosphate (TCIPP) were main analogs, both of which contributed to 49.0–85.7% of total OPFRs. In the waste printed circuit boards thermal treatment workshop, the OPFRs concentration was the highest, and particle-bound OPFRs mainly distributed in 0.7–1.1 μm particles. The proportions of TPHP in different size particles increased as the decrease of particle size, while TCIPP presented an opposite trend. The gas-particle partitioning of OPFR analogs was dominated by absorption process, and did not reach equilibrium state due to continuous emission of OPFRs from the recycling activities. The deposition fluxes of OPFRs in respiratory tract were 65.7–639 ng/h, and the estimated daily intake doses of OPFRs were 8.52–76.9 ng/(kg·day) in four workshops. Inhalation exposure was an important exposure pathway for e-waste recycling workers, and deposition fluxes of size-segregated OPFRs were mainly in head airways region.

Decadal-scale decay of landslide-derived fluvial suspended sediment after Typhoon Morakot

Abstract. Landslides influence fluvial suspended sediment transport by changing sediment supply and grain size, which alter suspended sediment concentrations and fluxes for a period of time after landsliding. To investigate the duration and scale of altered suspended sediment transport due to landsliding, we analyzed suspended sediment concentration and water discharge measurements at 87 gauging stations across Taiwan over an 11-year period after Typhoon Morakot, which generated nearly 20 000 landslides in 2009. At each gauging station, we computed annual rating curves to quantify changes over time in the sensitivity of suspended sediment concentrations to water discharge. Among the 40 stations in basins that were impacted by landsliding, the discharge-normalized rating curve coefficient ã was higher than that before Morakot by a factor of 5.1±1.1 (mean ± standard error) in 2010, the first year after Morakot. The rating curve exponent b did not decrease at most stations until a year later (2011), when the average b value was lower than that before Morakot by 0.25±0.05. Across the compilation of gauging stations, post-Morakot changes in discharge-normalized sediment concentration (ã) were positively correlated with landslide intensity for 7 years after Morakot, while post-Morakot changes in the exponent of the discharge–concentration relationship (b) were negatively correlated with landslide intensity from 2011 to 2014. This reflects a tendency for larger changes in ã and b to occur in basins with more intense landsliding. At 26 of these 40 stations, elevated values of ã declined after the initial post-Morakot peak, consistent with a gradual return to pre-Morakot suspended sediment transport conditions. Exponential regressions to these ã values reveal a median characteristic decay time of 8.8 years (interquartile range: 5.7–14.8 years). Values of ã increased more and declined faster in basins with more intense landsliding, with a mean characteristic decay time of 6 years in the basins hit hardest by landsliding. Furthermore, changes in ã and b tended to be larger in basins with more intense landsliding. At stations that were not impacted or only minimally impacted by landsliding, neither ã nor b exhibited systematic responses to Morakot. To quantify the effect of landsliding on sediment discharge, we compared the measured sediment discharges after Morakot to the hypothetical sediment discharges that would have occurred if Morakot had induced no landslides, calculated by applying each station's pre-Morakot rating curve to its post-Morakot water discharge history. This analysis suggests that Morakot-induced landsliding increased sediment discharge by as much as &gt; 10-fold in some basins in the 1–2 years after Morakot. Together, these results indicate that the influence of Morakot-induced landsliding on rating curves was large shortly after Morakot but diminished in less than a decade in most of the study rivers and will be imperceptible in another few decades in all of the study rivers. To the extent that these results are applicable to other landscapes, this suggests that periods of elevated sediment transport efficiency after landsliding should persist for years to decades, even if the landslide deposits persist for centuries to millennia.