Industrial control systems (ICS) are a collection of control systems and associated instrumentation for controlling and monitoring industrial processes. Critical infrastructure relies on supervisory control and data acquisition (SCADA), a subset of ICS specifically designed for monitoring and controlling industrial processes over large geographic areas. Cyberattacks like the Colonial Pipeline ransomware case have demonstrated how an adversary may compromise critical infrastructure. The Colonial Pipeline ransomware attack led to a week’s pipeline shutdown, causing a gas shortage in the United States. As existing vulnerability assessment tools cannot be used in the context of ICS systems, vulnerability datasets specified for ICSs are needed to evaluate the security weaknesses. Our secondary metadata, ICS-LTU2022, consists of multiple features that can be used for vulnerability assessment and risk evaluation in industrial control systems. A description of the dataset, its characteristics, and data analysis are also presented in this paper. Vulnerability analysis was conducted based on the top 10 vulnerabilities in terms of severity, frequency by year, impact, components of the ICS, and common weaknesses. The ICS-LTU2022 vulnerabilities dataset is updated biannually. Our proposed dataset provides security researchers with the most recent ICS critical vulnerabilities.