Seawater Reverse Osmosis Brine Research Articles

Evaluation of enhanced nanofiltration membranes for improving magnesium recovery schemes from seawater/brine: Integrating experimental performing data with a techno-economic assessment

The global demand for valuable metals and minerals necessitates the exploration of alternative, sustainable approaches to mineral recovery. Seawater mining has emerged as a promising option, offering a vast reserve of minerals and an environmentally friendly alternative to land-based mining. Among the various techniques, Nanofiltration (NF) has gained significant attention as a preliminary treatment step in Minimum Liquid Discharge (MLD) and Zero Liquid Discharge (ZLD) schemes. This study focused on the potential of two underexplored commercial polyamide based NF membranes, Synder NFX and Vontron VNF1, with enhanced divalent over monovalent separation factors, in optimizing the extraction of magnesium hydroxide (Mg(OH)2) from seawater and seawater reverse osmosis (SWRO) brines. The research encompassed a thorough characterization of the membranes utilizing advanced physic-chemical analytical techniques, followed by rigorous experimental assessments using synthetic seawater and SWRO brine in concentration configuration. The findings highlighted the superior selectivity of NFX for magnesium recovery from SWRO brine and the promising concentration factors of VNF1 for seawater treatment. Cross-validation of experimental data with a mathematical model demonstrated the model's reliability as a process design tool in predicting membrane performance. A comprehensive techno-economic evaluation demonstrates the potential of NFX, operating optimally at 23 bar pressure and 70% permeate recovery rate, to yield an estimated annual revenue of 5.683 M€/yr through Mg(OH)2 production from SWRO brine for a plant with a nominal capacity of 0.8 Mm3/y. This research shed light on the promising role of NF membranes in enhancing mineral recovery taking benefit of their separation factors and emphasizes the economic viability of leveraging NF technology for maximizing magnesium recovery from seawater and SWRO brines.

Environmentally Friendly Photothermal Membranes for Halite Recovery from Reverse Osmosis Brine via Solar-Driven Membrane Crystallization.

Modern society and industrial development rely heavily on the availability of freshwater and minerals. Seawater reverse osmosis (SWRO) has been widely adopted for freshwater supply, although many questions have arisen about its environmental sustainability owing to the disposal of hypersaline rejected solutions (brine). This scenario has accelerated significant developments towards the hybridization of SWRO with membrane distillation-crystallization (MD-MCr), which can extract water and minerals from spent brine. Nevertheless, the substantial specific energy consumption associated with MD-MCr remains a significant limitation. In this work, energy harvesting was secured from renewables by hotspots embodied in the membranes, implementing the revolutionary approach of brine mining via photothermal membrane crystallization (PhMCr). This method employs self-heating nanostructured interfaces under solar radiation to enhance water evaporation, creating a carefully controlled supersaturated environment responsible for the extraction of minerals. Photothermal mixed matrix photothermal membranes (MMMs) were developed by incorporating graphene oxide (GO) or carbon black (CB) into polyvinylidene fluoride (PVDF) solubilized in an eco-friendly solvent (i.e., triethyl phosphate (TEP)). MMMs were prepared using non-solvent-induced phase separation (NIPS). The effect of GO or GB on the morphology of MMMs and the photothermal behavior was examined. Light-to-heat conversion was used in PhMCr experiments to facilitate the evaporation of water from the SWRO brine to supersaturation, leading to sodium chloride (NaCl) nucleation and crystallization. Overall, the results indicate exciting perspectives of PhMCr in brine valorization for a sustainable desalination industry.

Impacts of Desalination Brine Discharge on Benthic Ecosystems.

Seawater reverse osmosis (SWRO) desalination facilities produce freshwater and, at the same time, discharge hypersaline brine that often includes various chemical additives such as antiscalants and coagulants. This dense brine can sink to the sea bottom and creep over the seabed, reaching up to 5 km from the discharge point. Previous reviews have discussed the effects of SWRO desalination brine on various marine ecosystems, yet little attention has been paid to the impacts on benthic habitats. This review comprehensibly discusses the effects of SWRO brine discharge on marine benthic fauna and flora. We review previous studies that indicated a suite of impacts by SWRO brine on benthic organisms, including bacteria, seagrasses, polychaetes, and corals. The effects within the discharge mixing zones range from impaired activities and morphological deformations to changes in the community composition. Recent modeling work demonstrated that brine could spread over the seabed, beyond the mixing zone, for up to several tens of kilometers and impair nutrient fluxes from the sediment to the water column. We also provide a possible perspective on brine's impact on the biogeochemical process within the mixing zone subsurface. Desalination brine can infiltrate into the sandy bottom around the discharge area due to gravity currents. Accumulation of brine and associated chemical additives, such as polyphosphonate-based antiscalants and ferric-based coagulants in the porewater, may change the redox zones and, hence, impact biogeochemical processes in sediments. With the demand for drinking water escalating worldwide, the volumes of brine discharge are predicted to triple during the current century. Future efforts should focus on the development and operation of viable technologies to minimize the volumes of brine discharged into marine environments, along with a change to environmentally friendly additives. However, the application of these technologies should be partly subsidized by governmental stakeholders to safeguard coastal ecosystems around desalination facilities.

Direct CO2 mineralization using seawater reverse osmosis brine facilitated by hollow fiber membrane contactor

The urgent demand for sustainable water management has given rise to widespread seawater desalination, leading to significant brine waste and a substantial carbon footprint resulting from extensive energy consumption. To address this challenge, we propose the utilization of hollow fiber membrane contactors (HFMCs) for direct CO2 mineralization. By mimicking lotus leaf surfaces, HFMs are successfully modified to possess superhydrophobic and antifouling properties, resulting in enhanced operational stability, as evidenced by a marginal 3.5 % flux decline after 10 days. Moreover, HFMCs incorporating these modified membranes achieve remarkable CO2 removal (up to 94 %) and selective mineral carbonation of Ca2+ and Mg2+ through staged pH swing. A techno-economic analysis highlights the superiority of our system compared to traditional amine scrubbing, with a 35 % reduction in CO2 capture costs and the generation of valuable products. This innovative application of HFMCs presents a promising solution for CO2 management, transforming seawater reverse osmosis brine into a valuable resource.

Efficient lithium recovery from simulated brine using a hybrid system: Direct contact membrane distillation (DCMD) and electrically switched ion exchange (ESIX)

Seawater reverse osmosis (SWRO) brine is a readily available resource hub in many countries, fulfilling the country's freshwater need by SWRO, yet lower in a concentration of high-demand elements like Li. This study outlines developing a novel hybrid system that combines direct contact membrane distillation (DCMD) and electrically switched ion exchange (ESIX) to facilitate simultaneous SWRO brine enrichment followed by selective Li recovery. The DCMD process concentrates the SWRO brine utilizing electrospun nanofiber membranes (ENMs) composed of polyvinylidene fluoride (PVDF). Incorporating reduced graphene oxide (rGO) nanoparticles augments the morphological, thermal, and mechanical stability of the PVDF ENMs. The water contact angle (WCA) of the 1-rGO/PVDF ENM stands at 142.08°, a testament to an enhanced hydrophobic property which resulted in a 12 % freshwater recovery from simulated SWRO brine and a 2.4-fold increase in Li+ concentration. The durability of the 1-rGO/PVDF ENM is evident in its minimal 11 % reduction in WCA after 15 h of brine concentration. In the context of hybrid operation, a Li-selective LiAlO2 electrode, coupled with an activated carbon counter electrode, demonstrated remarkable Li recovery for Li capture solutions enriched by the rGO-PVDF membrane in the DCMD phase. Compared to the Li concentration in the DCMD feed, sequential Li capture and release cycles recovered 91.8 % of Li, thereby underlining the critical role of the hybrid mode operation in concentrating Li from simulated brine solutions.

Polyelectrolyte multilayers modification of nanofiltration membranes to improve selective separation of mono- and multivalent cations in seawater brine

Nowadays, brine produced in the Reverse Osmosis (RO) seawater desalination plants is a significant and largely untapped source of critical minerals and metals, which is usually discharged into the seas as wastewater. As a front face stage in the brine mining process, nanofiltration (NF) membranes can be used to separate brine stream into monovalent and multivalent ion-rich streams. Since high separation factors are required in seawater RO brine, polyelectrolyte multilayers with Layer-by-Layer (LbL) technique were used in this study to modify commercial polyamide NF membranes and improve their performance. Two common polyelectrolytes, poly(diallyldimethylammonium chloride) (PDADMAC) and poly(sodium 4-styrenesulfonate) (PSS) were coated onto two poly-piperazine polyamide NF membranes (NF270 and Desal-5 DL). The effects of the bilayers number and the outer layer charge on membranes’ performance were studied using two crossflow filtration setups with two different membrane sizes to find the membrane with the higher monovalent/multivalent separation factor. Desal-5 DL membrane coated with 5.5 bilayers provided the highest selectivity factors for mono/multivalent cations (> 21), the highest average rejection of multivalent cations group (about 95.7%) for short-term experiments. Another interesting result was the increase in water permeance of the Desal-5 DL membrane after it was coated with 5.5 bLs (indicating more than 20% improvement in pure water permeance). In addition, the stability test with brines at 20 bar showed that this membrane was stable over an extended period of filtration (22 hours) with an even higher selectivity factor of 34 and multivalent cations rejection of 97.7% on average.

Techno-economic analysis of seawater reverse osmosis brines treatment using nanofiltration modelling tools

The management of seawater desalination (SWD) brine presents environmental and economic challenges. However, according to the circular economy approach, this residue offers an interesting source of resources. While nanofiltration (NF) has been extensively studied experimentally, few modelling tools exist for scaling up this process due to its performance dependence on solution composition, membrane characteristics, and operational parameters.In this study, the Solution-Electro-Diffusion-Film model was used to conduct a techno-economic analysis for scaling up NF in the treatment of SWD brine, with a focus on resource recovery. Three commercial membranes, NF270, PROXS2, and Fortilife XC-N, were subjected to technical and economic evaluations. Initially, permeate flux, selectivity factors, and scaling potential were determined as a function of applied pressure and permeate recovery. An economic evaluation was conducted considering energy consumption, capital expenditures, and operational expenditures.Results indicated that the NF270 membrane exhibited the highest permeate flux and the lowest rejections, suggesting a low scaling potential. However, this membrane also demonstrated the lowest selectivity factors. In contrast, the PROXS2 and Fortilife XC-N membranes exhibited the highest selectivity factors, particularly at high operational pressures. Regarding economic aspects, it was observed that increasing permeate recovery and reducing pressure led to decrease energy consumption (0.5–1.5 kWh/m3).

Design of a New Phthalocyanine-Based Ion-Imprinted Polymer for Selective Lithium Recovery from Desalination Plant Reverse Osmosis Waste.

In this study, a novel technique is introduced that involves the combination of an ion-imprinted polymer and solid-phase extraction to selectively adsorb lithium ions from reverse osmosis brine. In the process of synthesizing ion-imprinted polymers, phthalocyanine acrylate acted as the functional monomer responsible for lithium chelation. The structural and morphological characteristics of the molecularly imprinted polymers and non-imprinted polymers were assessed using Fourier transform infrared spectroscopy and scanning electron microscopy. The adsorption data for Li on an ion-imprinted polymer showed an excellent fit to the Langmuir isotherm, with a maximum adsorption capacity (Qm) of 3.2 mg·g-1. Comprehensive chemical analyses revealed a significant Li concentration with a higher value of 45.36 mg/L. Through the implementation of a central composite design approach, the adsorption and desorption procedures were systematically optimized by varying the pH, temperature, sorbent mass, and elution volume. This systematic approach allowed the identification of the most efficient operating conditions for extracting lithium from seawater reverse osmosis brine using ion-imprinted polymer-solid-phase extraction. The optimum operating conditions for the highest efficiency of adsorbing Li+ were determined to be a pH of 8.49 and a temperature of 45.5 °C. The efficiency of ion-imprinted polymer regeneration was evaluated through a cycle of the adsorption-desorption process, which resulted in Li recoveries of up to 80%. The recovery of Li from the spiked brine sample obtained from the desalination plant reverse osmosis waste through the ion-imprinted polymer ranged from 62.8% to 71.53%.

Valorization of Seawater Reverse Osmosis Brine by Monovalent Ion-Selective Membranes through Electrodialysis.

This paper proposes the use of monovalent selective electrodialysis technology to concentrate the valuable sodium chloride (NaCl) component present in seawater reverse osmosis (SWRO) brine for direct utilization in the chlor-alkali industry. To enhance monovalent selectivity, a polyamide selective layer was fabricated on commercial ion exchange membranes (IEMs) through interfacial polymerization (IP) of piperazine (PIP) and 1,3,5-Benzenetricarbonyl chloride (TMC). The IP-modified IEMs were characterized using various techniques to investigate changes in chemical structure, morphology, and surface charge. Ion chromatography (IC) analysis showed that the divalent rejection rate was more than 90% for IP-modified IEMs, compared to less than 65% for commercial IEMs. Electrodialysis results demonstrated that the SWRO brine was successfully concentrated to 14.9 g/L NaCl at a power consumption rate of 3.041 kWh/kg, indicating the advantageous performance of the IP-modified IEMs. Overall, the proposed monovalent selective electrodialysis technology using IP-modified IEMs has the potential to provide a sustainable solution for the direct utilization of NaCl in the chlor-alkali industry.

Evaluation of the nanofiltration of brines from seawater desalination plants as pre-treatment in a multimineral brine extraction process

Many materials essential to the European Union's (EU) economy lack primary resources, and the major suppliers of these materials are non-EU nations. It has been determined that seawater reverse osmosis (SWRO) desalination brines are a circular answer for the supply of critical elements. SWRO desalination brines, however, are distinguished by high concentrations of elements with negligible economic worth. (e.g., Na, Cl) compared to critical elements present in very low concentrations (e.g. Mg, B, Sc, V, In, Ga, Li, Mo, Rb). Therefore, an efficient separation pre-treatment is necessary to maximize the recovery efficiency in a brine extraction process. Nanofiltration (NF) was proposed as pre-treatment stage to separate monovalent from divalent ions and it was investigated if a Ca(II) removal stage was necessary before the NF to avoid scaling. The performances of three polyamide commercial membranes (NF270, Fortilife XC-N and PRO-XS2) treating SWRO brine (brine 1) and Ca(II)-free SWRO brine (after Ca(II) removal with sodium bicarbonate - brine 2) were evaluated in a closed circuit configuration as a function of the applied pressure from 6 to 30 bar.Results showed that NF was an efficient process to separate target elements present in seawater desalination brine into two different streams. Moreover, removal of Ca(II) before the NF step (brine 2) increased the selectivity between multivalent and monovalent species (higher rejection of multivalent and lower rejection of monovalent species compared to brine 1) for all the membranes tested, reaching the highest selectivity at 20 bar. At 20 bar, the polyamide membrane PRO-XS2 presented rejections of 71% for Ca(II) and 89% for Mg(II) and the highest selectivity in experiments with brine 2, being recommended for this application. In addition, the transport of species was characterized by membrane permeances by using the Solution-Electro-Diffusion-Film model. The scaling assessment at the membrane surface showed a lower scaling potential if Ca(II) was removed before the NF stage.

Selective lithium separation from desalination concentrates via the synergy of extractant mixtures

Seawater reverse osmosis (SWRO) desalination plants generate high volumes of concentrates, which contain, in addition to major salts, some elements of growing interest in minor concentrations. This is the case of lithium, highly demanded in the battery industry. In this work, the separation of Li+ from model SWRO brines has been evaluated by obtaining Li+ extraction curves with the combination of extractants DBM•TOPO and FDOD•TOPO, proving that both mixtures are capable of extracting Li+ under basic pH conditions, due to the keto-enolic tautomerism of the β-diketones. Li+ extraction values of 95.4 % for DBM•TOPO (pH = 12.2) and 100 % for FDOD•TOPO (pH = 9.0) were achieved. This behaviour was verified by the FT-IR analysis of the sample before and after the Li+ extraction. Finally, the selective separation of Li+ against other cations, such as Na+, K+, Mg2+, Ca2+ and Sr2+, present in the model brines at higher concentrations, was determined. Under mentioned experimental conditions, these cations are not extracted, reaching to Li+ selective separation close to 100 %. This study shows the first results on the selective extraction of lithium in complex SWRO brines, fostered through promising extractants mixtures showing a synergic effect towards Li+ in such multicomponent matrices.

Selective lithium extraction from diluted binary solutions using metal-organic frameworks (MOF)-based membrane capacitive deionization (MCDI)

The increasing demand for lithium (Li) calls for exploring efficient and environmental-friendly methods to extract Li from brine. Capacitive deionization (CDI) as an emerging technology is of interest for resource recovery because of its rapid adsorption rate, limited energy consumption, and low environmental impact. However, Na and K in seawater and seawater reverse osmosis (SWRO) brine and Mg and Ca in inland brine challenge the feasibility of selective Li extraction. Herein, CDI was integrated with deposition-coated ZIF-8-PDA membranes to extract Li from binary solutions containing Li and M (M representing Na, K, Mg, and Ca). MCDI tests were conducted under a series of voltages (±0.5 V, ±1.0 V, and ±1.5 V) to investigate the influence of applied potentials on Li extraction performances. The results indicated advantages for Li extraction when coexisting cations were monovalent than divalent. Additionally, a lower voltage of 0.5 V could provide superior Li selectivity, charge efficiency (CE), and energy normalized to Li (ENL) than higher voltages. Especially, Li selectivity of 1.50 and 1.85 was achieved in Li/Na and Li/K feeds under 0.5 V, 37 % and 74 % higher than those under 1.5 V, respectively, illuminating the potential of MCDI for Li extraction from seawater and SWRO brine with low energy input.

Novel LiAlO2 Material for Scalable and Facile Lithium Recovery Using Electrochemical Ion Pumping

In this study, α-LiAlO2 was investigated for the first time as a Li-capturing positive electrode material to recover Li from aqueous Li resources. The material was synthesized using hydrothermal synthesis and air annealing, which is a low-cost and low-energy fabrication process. The physical characterization showed that the material formed an α-LiAlO2 phase, and electrochemical activation revealed the presence of AlO2* as a Li deficient form that can intercalate Li+. The AlO2*/activated carbon electrode pair showed selective capture of Li+ ions when the concentrations were between 100 mM and 25 mM. In mono salt solution comprising 25 mM LiCl, the adsorption capacity was 8.25 mg g-1, and the energy consumption was 27.98 Wh mol Li-1. The system can also handle complex solutions such as first-pass seawater reverse osmosis brine, which has a slightly higher concentration of Li than seawater at 0.34 ppm.

Electrodialysis with Bipolar Membranes for the Sustainable Production of Chemicals from Seawater Brines at Pilot Plant Scale.

Environmental concerns regarding the disposal of seawater reverse osmosis brines require the development of new valorization strategies. Electrodialysis with bipolar membrane (EDBM) technology enables the production of acid and base from a salty waste stream. In this study, an EDBM pilot plant with a membrane area of 19.2 m2 was tested. This total membrane area results much larger (i.e., more than 16 times larger) than those reported in the literature so far for the production of HCl and NaOH aqueous solutions, starting from NaCl brines. The pilot unit was tested both in continuous and discontinuous operation modes, at different current densities (200-500 A m-2). Particularly, three different process configurations were evaluated, namely, closed-loop, feed and bleed, and fed-batch. At lower applied current density (200 A m-2), the closed-loop had a lower specific energy consumption (SEC) (1.4 kWh kg-1) and a higher current efficiency (CE) (80%). When the current density was increased (300-500 A m-2), the feed and bleed mode was more appropriate due to its low values of SEC (1.9-2.6 kWh kg-1) as well as high values of specific production (SP) (0.82-1.3 ton year-1 m-2) and current efficiency (63-67%). These results showed the effect of various process configurations on the performance of the EDBM, thereby guiding the selection of the most suitable process configuration when varying the operating conditions and representing a first important step toward the implementation of this technology at industrial scale.

Industrial scale thin-film composite membrane modules for salinity-gradient energy harvesting through pressure retarded osmosis

The current work highlights development of novel thin-film composite hollow fiber membranes for pressure retarded osmosis applications to harvest salinity gradient energy. The membranes were developed with a specific target of harnessing the salinity gradient energy between wastewater reverse osmosis retentate and seawater reverse osmosis brine via osmotic mixing. The hollow fiber membranes were prepared by coating a polyethersulfone substrate with a thin-film composite polyamide layer via interfacial polymerization, which were assembled into modules of different diameters for lab scale and pilot scale evaluation. As the module size increased from 1-in. to 2-in., and 4-in., the water permeability, tested against a 1000 mg/L sodium chloride solution at 15 bar, decreased from 2.6 L m−2 h−1 bar−1 to 2.0 L m−2 h−1 bar−1, and 1.2 L m−2 h−1 bar−1, respectively. The power density, measured in the lab-scale unit using 1 M sodium chloride draw solution, and DI water feed solution, also decreased from 9.1 W/m2 to 5.3 W/m2 with increasing module size. Pilot scale evaluation of the 4-and 8-in. modules on a 24 m3/day unit resulted in lower power densities of 2.5 W/m2 and 1.5 W/m2 which translated to 0.024 kWh/m3 and 0.05 kWh/m3 of salinity-gradient energy harvested, respectively.

The recovery of strontium ions from seawater reverse osmosis brine using novel composite materials of ferrocyanides modified roasted date pits

In this study, three types of adsorbents were used to remove and recover strontium ions (Sr2+) from aqueous and brine solution of seawater reverse osmosis (SWRO), namely roasted date pits (RDP) and RDP modified using copper and nickel salts of potassium hexacyanoferrates to obtain RDP–FC–Cu, and RDP–FC–Ni, respectively. Additionally, the influence of various parameters, including pH, temperature, initial concentration, and co-existing ions was also evaluated. The results revealed that pH 10 was the optimum pH in which the maximum Sr2+ ions were adsorbed. Additionally, all adsorbents had a high adsorption capacity (99.9 mg/g) for removing Sr2+ ions at the highest concentration (100 mg/L) and a temperature of 45 °C was found to be the optimum temperature. A scanning electron microscopy for the adsorbents before and after the adsorption of strontium showed the remarkable pore filling onto the active sites of all adsorbents. The thermodynamics parameter demonstrated that the adsorption occurred in an endothermic environment, and that, the reaction was spontaneous, and favorable at all the temperatures investigated. According to isotherm studies, the Langmuir model was the best-fit isotherm model; indicating that strontium adsorption involved the formation of monolayers and multilayers at higher temperatures (45 °C). Furthermore, high desorption percentages (above 90%) were achieved for all the adsorbents when an HCl concentration of 0.5 M was used. This showed the high reusability of the adsorbents. Lastly, the adsorption of strontium from the SWRO brine containing a number of metal ions was extremely sufficient as all the adsorbents were efficient to adsorb a high amount of Sr2+ despite the presence of other competing ions.

Technical and Environmental Feasibilities of the Commercial Production of NaOH from Brine by Means of an Integrated EDBM and Evaporation Process.

Electrodialysis with bipolar membranes (EDBMs) is a technology that offers a great potential for the introduction of the principles of a circular economy in the desalination industry, by providing a strategy for the recovery of HCl and NaOH from brine via the process of seawater reverse osmosis (SWRO). Both chemicals are widely employed in desalination facilities, however NaOH presents a special interest due to its higher requirements and cost. Nevertheless, the standard commercial concentrations that are commonly employed in the facilities cannot be obtained using the state of the art EDBM technology itself. Therefore, the aim and main purpose of this work is to prove the technical and environmental feasibilities of a new approach to produce commercial NaOH (50%wt.) from SWRO brine by means of an integrated process of EDBMs followed by a triple effect evaporation. The global process has been technically evaluated in terms of the specific energy consumption (SEC) (kWh·kg−1 NaOH) and the environmental sustainability performance has been analyzed by its carbon footprint (CF) (kg CO2-eq.·kg−1 NaOH). The influence of the current density, and the power source in the EDBM stage have been evaluated on a laboratory scale while the influence of the feed stream concentration in the evaporation stage has been obtained through simulations using Aspen Plus. The lowest SEC of the integrated process (SECOV), 31.1 kWh·kg−1 NaOH, is obtained when an average current density of 500 A·m−2, provided by a power supply (grid mix), is applied in the EDBM stage. The environmental burdens of the integrated process have been quantified by achieving reductions in the CF by up to 54.7% when solar photovoltaic energy is employed as the power source for EDBMs, with a value of 5.38 kg CO2-eq.·kg−1 NaOH. This study presents a great potential for the introduction of the principles of a circular economy in the water industry through the recovery of NaOH from the high salinity waste stream generated in SWRO facilities and opens the possibility of the reuse of NaOH by its self-supply in the desalination plant.

Valorisation of SWRO brines in a remote island through a circular approach: Techno-economic analysis and perspectives

Nowadays, small remote islands rely heavily on desalination technologies to overcome freshwater scarcity. Unfortunately, these technologies are accompanied by the production of brines which can affect the receiving water bodies i.e., the aquatic ecosystem. Yet, it is extremely appealing how such brines constitute an abundant source of valuable raw materials (such as magnesium). In this work, a novel hybrid system is introduced to capture the value of seawater reverse osmosis (SWRO) brines produced in the minor Sicilian island of Pantelleria. The “Minimal Liquid Discharge” (MLD) process consists of: (i) Nanofiltration NF (separation of bivalent from monovalent ions), (ii) Mg Reactive Crystallizer MRC (selective recovery of magnesium and calcium), (iii) Multi-Effect Distillation MED (freshwater production) and (iv) NaCl Thermal Crystallizer NTC (sodium chloride recovery). The economic and environmental performances of the process have been evaluated by implementing and integrating the techno-economic models of each unit in a simulation platform called RCE (Remote Component Environment). Results revealed important economic benefits in comparison to conventional brine disposal methods. In addition, the proposed MLD chain turned out to be an attractive alternative for the production of high purity minerals/salts, achieving lower selling prices than the current market price.

A Zero-Brine Discharge Seawater Desalination Using a Pilot-Scale Membrane Distillation System Integrated with Crystallizer.

The management of brines generated from reverse osmosis operation remains a critical challenge requiring new approaches and processes to limit the impact of brine discharge onto ecosystems and to enhance both water and valuable resource recovery. The treatment of real seawater reverse osmosis (SWRO) brines (45,000 ppm TDS) obtained from a local Singaporean desalination plant with a crystallizer integrated pilot-scale membrane distillation unit (MDC) was studied. Commercial STOMATE® hollow fiber membranes were used in vacuum membrane distillation (VMD) configuration, leading to an average flux of around 3.7 L/m2-h at a permeate vacuum of 80 kPa and an average feed temperature of 65 °C. Consistent separation operations were achieved for the treatment of real SWRO brine over a period of 280 h; this led to a water recovery of >95% and to the collection of salt slurries, containing up to ~10–20 wt% of moisture, from the crystallizer. This approach demonstrates the potential of MDC systems to achieve zero brine discharge efficiently from seawater desalination systems, providing an environmentally friendly alternative to manage brines by increasing water recovery and generating salt slurries of economic value.

Development of a novel tailored ion-imprinted polymer for recovery of lithium and strontium from reverse osmosis concentrated brine

This study aims to prepare ion-imprinted polymer (IIP) with the benefit of a metal-based sorbent, which is fabricated to selectively adsorb lithium (Li+) from aqueous solutions, and in an attempt to remove strontium (Sr2+). The adsorption processes were carried out at different pH values, initial concentrations, and temperatures, to optimize the experimental conditions, with the use of response surface methodology (RSM). The seawater reverse osmosis (SWRO) brine was physically and chemically characterized, and the physicochemical characterization of the prepared IIP before and after adsorption was also performed using different spectroscopic methods. The adsorption capacity for Li+ and Sr2+ from SWRO brine was evaluated, and the reusability of IIP was investigated using adsorption–desorption cycles. The results showed that the IIP was efficient to remove Li+ but not Sr2+, and it follows Freundlich adsorption isotherms models. The analysis revealed a significant concentration of minerals in the brine sample It also revealed a low concentration of trace metals, like Ba (0.16 mg/L), Zn (0.845 mg/L), Fe (1.31 mg/L), Cu (1.165 mg/L), Pb (1.505 mg/L), and V (3.88 mg/L), except Li and Sr which shows a higher concentration of 43.32 mg/L and 16.93 mg/L respectively. pH 10 was selected to be the optimum pH for the adsorption isotherm experiments, as it was the highest efficient pH to adsorb Li+ and Sr2+. The thermodynamics study revealed that the adsorption of Li+ on the IIP favored exothermic conditions. It was noticed that the maximum adsorption capacity (Qm) was increased as the temperature rise from 714.3 mg/g at 25 °C to 2500 mg/g at 45 °C. The Li+ desorption results show that 94.03% − 94.71% of the ions were recovered, while the Sr2+ desorption results show that 96.35% − 96.56% of the ions were recovered. The efficiency of IIP to adsorb lithium and strontium from brine shows that the adsorption removal% of Li+ was between 84.21% and 84.68%, while the adsorption removal% of Sr2+ was between 3.83% and 10%. The cost analysis for IIP preparation was 2 USD/g.