Seawater δ18O Research Articles

Stable carbon and oxygen isotope-based sclerochronology of bivalve mollusk shells from the Upper Cretaceous (upper Campanian) Coon Creek Formation in Tennessee, USA: Implications for paleoecology and paleoenvironment

Stable carbon and oxygen isotope-based sclerochronology was carried out on well-preserved fossil shells of bivalve mollusks Crassatella vadosa and Cucullaea vulgaris from the Upper Cretaceous (upper Campanian) Coon Creek Formation in Tennessee, USA, to reconstruct their life-history traits and sedimentary settings on an intra-annual time scale. The δ13CShell values along with the shell growth showed the cyclic variation with downward convex to lower value, likely reflecting the seasonal cycle of ambient seawater dissolved inorganic carbon (DIC) or metabolism of the bivalve or both. The δ13CShell cycles were largely associated with the strong growth disturbance lines, supporting hypothesis that the growth lines were formed annually. We estimated the ages of the shells based on both δ13C cycle or the growth cessation line. The modeled relationship between age and shell growth showed that Cr. vadosa and Cu. vulgaris grew up to about 40 mm at 7 years old and about 65 mm at 10 years old, respectively. The paleotemperatures estimated from the δ18OShell profiles of the examined specimens ranged from 16.2 °C to 24.2 °C and from 18.8 °C to 27.0 °C when assuming the bottom seawater δ18O to be −1.00‰ and −0.46‰ (VSMOW), respectively, and showed no clear seasonal cycle. The bottom seawater temperatures reconstructed from the specimens of the two bivalve species were lower than the near-surface seawater temperatures (29.0–30.6 °C) estimated from the planktic foraminiferal δ18O. We inferred that the benthic bivalve habitat of the Coon Creek Formation was at least 10 m or deeper below the thermocline.

Resolving and correcting for kinetic biases on methane seep paleotemperature using carbonate ∆47/∆48 analysis.

Methane-derived authigenic carbonate often constitutes the sole remaining record of relic methane seeps. The clumped (∆47) and oxygen isotopic composition of seep carbonates often yield inaccurate temperatures, attributed to kinetic isotope effects and modification of seawater isotope composition by hydrate water. Here, we analyzed the dual-clumped isotope (∆47/∆48) composition of authigenic carbonate from a modern methane seep. We demonstrate that aragonite forms closest to isotopic equilibrium such that its ∆47 can directly yield the correct formational temperature, whereas calcite is unambiguously biased by kinetic isotope effects. Numerical models show that the observed bias in the isotopic composition arises from rate-limiting dehydration/dehydroxylation of HCO3- alongside diffusive fractionation, which can be corrected for with analysis of carbonate ∆47/∆48 values. We demonstrate the utility of dual-clumped isotope analysis for studying seep carbonates, as it reveals the origin and magnitude of kinetic biases and can be used to reconstruct paleotemperature and seawater δ18O.

High-resolution carbon and oxygen isotopic compositions of cultured brachiopods: Effect of pH, temperature and growth

Brachiopod shells are ubiquitous since the Early Cambrian up to now. As they secrete a shell made of low-magnesium calcite, more resistant to diagenesis than biocarbonates richer in Mg, their geochemical signatures are generally considered a powerful tool for paleo-environmental and paleo-climatic reconstructions. However, gaps in knowledge still remain on the underlying controls of the shell chemistry, in particular at a high spatial resolution. In this study, in situ oxygen and carbon isotope measurements by SIMS (Secondary Ion Mass Spectrometry) were performed in brachiopod shells of the cold-temperate water species Magellania venosa, constituted of a primary and a secondary layer. The individual specimens studied here grew under controlled conditions mimicking the natural environment and in experiments under low-pH (high pCO2) and high-temperature conditions. Transversal carbon and oxygen profiles showed a “brachiopod pattern” typical of extant two-layered brachiopods, with the primary layer depleted in 18O and 13C relative to equilibrium and the secondary layer showing a gradual increasing trend until reaching a near-equilibrium plateau. Overall, shells cultured at low pH were found to have δ18O and δ13C values closer to equilibrium when compared to shells from the control experiment. These near-equilibrium values may reflect a decrease in shell precipitation rate, leading to less kinetic effects, and/or a more rapid kinetics for the equilibration between DIC species and water. By close pairing of seawater δ18O and δ13C to that of shell microstructure, our study enables us to derive layer-specific C and O enrichment factors, which show the extent of pH and temperature effects superimposed on the seawater δ18O and DIC δ13C signal inherited. Finally, we show that during brachiopod shell growth, newly precipitated calcite is added to the calcite already existing, thus empirically validating the conceptual accretionary growth model proposed by Ackerly (1989).

Shallow-water temperature seasonality in the middle Cretaceous mid-latitude northwestern Pacific

Temperature seasonality during the middle Cretaceous provides vital information about climate dynamics and ecological traits of organisms under the conditions of the “supergreenhouse” Earth. However, sub-annual scale paleotemperature records in the mid-latitude region remain limited. In this study, sclerochronological and stable oxygen isotope (δ18O) analyses of bivalve fossils from the northwestern Pacific (paleolatitude: 44°N) were used to estimate their life history and sub-annual scale temperature patterns of the middle Cretaceous. The materials studied included Cucullaea (Idonearca) delicatostriata and Aphrodina pseudoplana recovered from middle Turonian (middle Cretaceous) shallow marine deposits in Hokkaido, northern Japan. Growth increment width and shell δ18O of C. (I.) delicatostriata revealed that the growth rate was temporally maximized and then minimized, which can be interpreted as representing spring and winter growth, respectively. Approximately 25 fortnightly growth increments occurred within that cycle, suggesting that shell formation proceeded continuously throughout the year. Based on shell δ18O values, shallow-water temperatures from 28°C to 35°C with 7°C seasonality were estimated, under the assumption that seawater δ18O values were annually invariant at −1‰ relative to VSMOW. This temperature seasonality in the middle Cretaceous is more than 5°C smaller than the seasonality of modern shallow-water environments at the same latitudes. These findings, taken together with previous studies of other oceanic regions, suggest that the Northern Hemisphere had low seasonal shallow-water temperature variation of up to 10°C in the middle Cretaceous.

The variability of Intermediate water intrusion into the South China Sea during the last deglaciation

Millennial-scale variations of the intermediate water in the South China Sea (SCS) have not been well understood due to limited data. Here we investigate the temperature and δ18O of seawater (δ18Osw, a proxy of salinity) evolution history of the intermediate water during the last deglaciation by analyzing Mg/Ca and oxygen isotopes of planktonic foraminifera Globorotalia inflata in the southern SCS. The results indicate that intermediate water was warm and salty during the Heinrich 1 (H1) and Younger Dryas (YD) cold events, while it was cold and fresh during the Bølling-Alleød (B-A) warm event in the southern SCS. By comparison with other paleorecords, we find that there was a weak intrusion of the low-salinity intermediate water from the western Pacific into the SCS during H1 and YD, whereas the opposite occurred during the B-A. Our study reveals that the variability in the intrusion intensity of intermediate water into the SCS from the western Pacific was primarily influenced by the changes in winter wind intensity during the last deglaciation.

Meteoric water and glacial melt in the southeastern Amundsen Sea: a time series from 1994 to 2020

Abstract. Ice sheet mass loss from Antarctica is greatest in the Amundsen Sea sector, where “warm” modified Circumpolar Deep Water moves onto the continental shelf and melts and thins the bases of ice shelves hundreds of meters below the sea surface. We use nearly 1000 paired salinity and oxygen isotope analyses of seawater samples collected on seven expeditions from 1994 to 2020 to produce a time series of glacial meltwater inventory for the southeastern Amundsen Sea continental shelf. Deep water column salinity–δ18O relationships yield freshwater end-member δ18O values from -31.3±1.0‰ to -28.4±1.0‰, consistent with the isotopic composition of local glacial ice. We use a two-component meteoric water end-member approach that accounts for precipitation in the upper water column, and a pure glacial meteoric water end-member is employed for the deep water column. Meteoric water inventories are comprised of nearly pure glacial meltwater in deep shelf waters and of >74 % glacial meltwater in the upper water column. Total meteoric water inventories range from 8.1±0.7 to 9.6±0.8 m and exhibit greater interannual variability than trend over the study period, based on the available data. The relatively long residence time in the southeastern Amundsen Sea allows changes in mean meteoric water inventories to diagnose large changes in local melt rates, and improved understanding of regional circulation could produce well-constrained glacial meltwater fluxes. The two-component meteoric end-member technique improves the accuracy of the sea ice melt and meteoric fractions estimated from seawater δ18O measurements throughout the entire water column and increases the utility for the broader application of these estimates.

Oxygen isotope ensemble reveals Earth’s seawater, temperature, and carbon cycle history

Earth’s persistent habitability since the Archean remains poorly understood. Using an oxygen isotope ensemble approach—comprising shale, iron oxide, carbonate, silica, and phosphate records—we reconcile a multibillion-year history of seawater δ 18 O, temperature, and marine and terrestrial clay abundance. Our results reveal a rise in seawater δ 18 O and a temperate Proterozoic climate distinct to interpretations of a hot early Earth, indicating a strongly buffered climate system. Precambrian sediments are enriched in marine authigenic clay, with prominent reductions occurring in concert with Paleozoic and Cenozoic cooling, the expansion of siliceous life, and the radiation of land plants. These findings support the notion that shifts in the locus and extent of clay formation contributed to seawater 18 O enrichment, clement early Earth conditions, major climate transitions, and climate stability through the reverse weathering feedback.

Multidecadal-to-interannual modulations of Late Holocene climate variations reconstructed from oxygen isotope ratios of a 237-year-long lived fossil coral in Kikai Island, southwestern Japan

For this study, to elucidate the East Asian monsoon variations on seasonal, interannual, and decadal timescales during the Late Holocene, we generated a 237-year-long time series of bimonthly resolved oxygen isotope ratios (δ18O) from a 3.5–3.2 ka Porites coral in Kikai Island, southwestern Japan. The coral data clearly show seasonal-to-interdecadal variations reflecting seawater temperature and salinity variations for 237 years, which can be a robust benchmark with respect to subtropical Pacific climate variability during the Late Holocene. Along with modern and fossil coral records published earlier from Kikai Island and Okinawa Island, the time-weighted δ18O averages for overlapped 14C ages demonstrate that the annual and summer values had slightly increased by <0.2‰ for 6–3 ka and that the winter values had increased by ∼0.2‰ for 6–5 ka and decreased by ∼0.2‰ for 5–3 ka. The result indicates that the mean climate state around the island had been almost stable on a centennial-to-millennium timescale throughout the transition from the Middle to Late Holocene, but with several short-term cooling excursions of ∼1 °C at 4–3 ka. On interdecadal-to-interannual timescales, amplitudes of the fossil coral δ18O variations for winter and summer were similar or larger at 3.5–3.2 ka relative to today, revealing significant periodicities at 36–38 years, 20–21 years, 6–9 years, and 3–4 years by spectral analysis at 95% confidence intervals. Furthermore, winter and summer coral δ18O time series of the respective periodic components indicate that interannual variations of SST (and/or seawater δ18O) around the island have changed on interdecadal and decadal timescales, which have been modulated on a multidecadal timescale of approximately 60–90 years/cycle. These results imply that the relationships of the East Asian winter and summer monsoon to the El Niño/Southern Oscillation and Pacific Decadal Oscillation dominant in the North Pacific might have been modulated by or associated with the Atlantic Multidecadal Oscillation dominant in the North Atlantic during the Late Holocene.

Contrasting Central Equatorial Pacific Oxygen Isotopic Signatures of the 2014/2015 and 2015/2016 El Niño Events

AbstractPaleoclimate reconstructions of El Niño/Southern Oscillation (ENSO) behavior often rely on oxygen isotopic records from tropical corals (δ18O). However, few reef‐based observations of physical conditions during El Niño events exist, limiting our ability to interpret coral δ18O. Here we present physical and geochemical measurements from Palmyra Atoll (5.9°N, 162.1°W) from 2014–2017, along with a data assimilation product using the isotope‐enabled Regional Ocean Modeling System (isoROMS). Coral δ18O signals are comparably strong in 2014–2015 and 2015–2016; notably, over 50% of the signal is driven by seawater δ18O, not temperature. If a constant seawater δ18O:salinity relationship were present, this would imply a comparable salinity anomaly during both events. However, salinity changes are much larger during 2014–2015, indicating a highly nonstationary relationship. isoROMS then shows that advection strongly influences δ18O during both the 2014–2015 and 2015–2016 El Niño, driving differences in the salinity/seawater δ18O relationship. This demonstrates the need for considering ocean dynamics when interpreting coral δ18O.

Revisiting Oxygen‐18 and Clumped Isotopes in Planktic and Benthic Foraminifera

AbstractForaminiferal isotopes are widely used to study past oceans, with different species recording conditions at different depths. Their δ18O values record both seawater oxygen‐18 and temperature according to species‐specific fractionation factors, while their Δ47 signatures likely depend only on temperature. We describe an open‐source framework to collect/combine data relevant to foraminiferal isotopes, by constraining species‐specific oxygen‐18 fractionation factors (18α) based on culture experiments, stratified plankton tows or core‐top sediments; compiling stratified plankton tow constraints on living depths for planktic species; extracting seawater temperature, δ18O, and chemistry from existing databases for any latitude, longitude, and depth‐range; inferring calcification temperatures based on the above data. We find that although 18α differs between species, its temperature sensitivity remains indistinguishable from inorganic calcite. Based on &gt; 2,600 observations we show that, although most planktic δ18O values are consistent with seawater temperature and δ18O over their expected living depths, a sizable minority (12%–24%) have heavier‐than‐predicted δ18O, best explained by calcification in deeper waters. We use this framework to revisit three recent Δ47 calibration studies of planktic/benthic foraminifera, confirming that planktic Δ47 varies systematically with oxygen‐18‐derived temperature estimates, even for samples whose δ18O disagrees with assumed climatological conditions, and demonstrating excellent agreement between planktic foraminifera and modern, largely inorganic Δ47 calibrations. Benthic foraminifera remain ambiguous: modern benthic Δ47 values appear offset from planktic ones, yet applying equilibrium Δ47 calibration to the Cenozoic benthic foraminifer record of Meckler et al. (2022, https://doi.org/10.1126/science.abk0604) largely reconciles it with δ18O‐derived temperatures, with discrete Δ47/δ18O discrepancies persisting in the Late Paleocene/Eocene/Plio‐Pleistocene.

Isotopic disequilibrium in brachiopods disentangled with dual clumped isotope thermometry

The stable oxygen and clumped isotope composition of brachiopod calcite are important proxies for the reconstruction of Phanerozoic seawater temperatures and δ18O values. The utility of brachiopods as a temperature archive is nonetheless challenged by indications that their shells precipitate out of isotopic equilibrium with ambient seawater, though the origin of disequilibrium effects has remained elusive. Here, we apply the recently developed dual clumped isotope thermometer (i.e., the simultaneous measurement of Δ47 and Δ48 values in CO2 derived from the acid digestion of carbonates) to modern and fossil brachiopods to investigate disequilibrium signatures recorded in brachiopod calcite. We present evidence that disequilibrium signatures are derived from the combination of two rate-limiting processes: the hydration/hydroxylation of CO2, and, potentially, the diffusion of HCO3−/CO32− in water. An empirical correction for clumped isotope disequilibrium is presented, based on correlation between measured disequilibrium offsets in the Δ47 and Δ48 values of modern brachiopods (Δ47disequilibrium = –0.88 × Δ48disequilibrium + 0.02). Dual clumped isotope thermometry of Eocene age brachiopods from Seymour Island (∼65 °S) yields temperatures in agreement with previously reported Δ47 derived temperatures from coeval bivalves. In contrast, uncorrected Δ47 derived temperatures from the same brachiopods are 6–11 °C colder. Measurement of dual clumped isotope composition alongside δ18O values of brachiopod carbonate should also enable more accurate reconstruction of seawater-δ18O. In comparison with group-specific Δ47-temperature calibrations, which correct for an average kinetic bias in Δ47, dual clumped isotope thermometry accounts for the magnitude of disequilibrium inherent to an individual sample, facilitating more reliable paleotemperature and seawater-δ18O reconstructions.

Transient Deep Ocean Cooling in the Eastern Equatorial Pacific Ocean at the Eocene‐Oligocene Transition

AbstractAt the Eocene‐Oligocene Transition (EOT), approximately 34 million years ago, Earth abruptly transitioned to a climate state sufficiently cool for Antarctica to sustain large ice sheets for the first time in tens to hundreds of millions of years. Oxygen isotope records from deep‐sea benthic foraminifera (δ18Ob) provide the foundation of our understanding of this pivot point in Cenozoic climate history. A deeper insight, however, is hindered by the paucity of independent deep‐sea temperature reconstructions and the ongoing challenge of deconvolving the temperature and continental ice volume signals embedded in δ18Ob records. Here we present records of deep‐sea temperature change from the eastern equatorial Pacific for the EOT using clumped isotope thermometry, which permits explicit temperature reconstructions independent of seawater chemistry and continental ice volume. Our records suggest that the deep Pacific Ocean cooled markedly at the EOT by 4.7 ± 0.9°C. This decrease in temperature represents the first direct and robust evidence of deep‐sea cooling associated with the inception of major Cenozoic glaciation. However, our data also indicate that this major cooling of the deep Pacific Ocean at the EOT was short‐lived (∼200 kyrs), with temperatures rebounding to values close to pre‐EOT levels by 33.6 Ma. Our calculated record of seawater δ18O suggests that this rebound in ocean temperature occurred despite the continued presence of a large‐scale Antarctic ice sheet. This finding suggests a degree of decoupling between deep ocean temperatures in the eastern equatorial Pacific Ocean and the behavior of the newly established Antarctic ice sheet.

Coral Paleoclimate Perspectives Support the Role of Low‐Latitude Forcing on the 4.2 ka BP Event

AbstractThe 4.2 ka BP Event is an abrupt climate change that might have contributed to the collapse of ancient civilizations and marks the transition between the mid‐ and late‐Holocene. Despite considerable research on this event, our understanding remains primarily based on terrestrial paleoclimate reconstructions, leaving a significant gap in understanding the role of the ocean in this event. Here, we present paired sea surface temperature (SST) and seawater δ18O reconstructions based on four fossil corals from the South China Sea. Our results demonstrate that the climate during the event was cooler, and there were meridional dry‐wet patterns in East Asia, indicating a weakened summer monsoon. Furthermore, our examination of additional coral records from the Pacific and Indian Oceans suggests that low‐latitude forcing (i.e., SST anomalies in the tropical Pacific) plays a crucial role in driving hydrology shifts in East Asia over the 4.2 ka BP interval.

Modulation of East Asian monsoon strength by ENSO during the warm periods of the late Holocene: Evidence from Porites corals in the northern South China Sea

As a gauge for ocean precipitation conditions, sea surface salinity (SSS) is suspected to be an excellent indicator for variations in the global hydrological cycle. The SSS conditions in the South China Sea (SCS) are closely related to precipitation changes of the East Asian monsoon. However, the characteristics and driving mechanisms of the meridional pattern of East Asian monsoon rainfall during the warm periods of the late Holocene are not well understood because of a lack of high-resolution proxies from the SCS. Here, we present three precise chronologies of monthly stable coral skeleton oxygen isotopes (δ18O) and pair them with established composite strontium/calcium (Sr/Ca) records from the Xisha Islands to obtain a continuous reconstruction of the residual δ18O (Δδ18O, regarded as seawater δ18O) during 1980–2007 CE (Common Era), 1149–1205 CE, and 2070–2011 a BP (years before 1950 CE). The results confirm that coral Δδ18O is a good tracer for reconstructing SSS and precipitation changes in the northern SCS on seasonal and interannual timescales, with higher Δδ18O values implying more saline conditions and less precipitation. The mean value of fossil coral Δδ18O for 1149–1205 CE was higher than that of modern coral, suggesting the existence of salty surface waters and notable dry climate episodes in the northern SCS during the late Medieval Climate Anomaly (MCA). In contrast, the average coral Δδ18O for 2070–2011 a BP was significantly lighter by about 0.404‰ compared to that of recent decades, indicating that less saline and more humid conditions occurred in the northern SCS during the early Roman Warm Period (RWP). Synthesizing our coral records with other published precipitation reconstructions from eastern China suggested a meridional dipole spatial pattern of moisture variation over East Asia during the historical warm periods of the Holocene. During the MCA, drier conditions generally prevailed in the region south of the Yangtze River, and more humid conditions in the north. This may be closely related to the contemporaneous strong El Niño activity occurring at this time, which probably enhanced the East Asian summer monsoon (EASM) and caused a northward shift of the intertropical convergence zone (ITCZ), possibly inducing increased water vapor transport from the SCS to North China. During the RWP, the relatively weak El Niño–Southern Oscillation (ENSO) variability may weaken the intensity of the EASM and shift the ITCZ southward, possibly resulting in a spatial pattern of “wet south and dry north” in East Asia.

Disentangling multiproxy temperature reconstructions from the subtropical North Atlantic

Reliable reconstruction of past sea surface temperature (SST) is of prime importance for understanding the Earth’s sensitivity to external forcing. Yet, it remains a major challenge in paleoceanography because comparison between SST estimates from different proxies reveals mismatches and raise the question as to what the contrasting proxies actually record. A better understanding of these mismatches in the light of seasonal occurrence of the proxy bearing organisms (archives) and water mass changes help to assess climate models. Here, we analyze data from the last deglaciation using a sediment core site situated at the northern boundary of the North Atlantic subtropical gyre influenced by fast latitudinal migrations of the subtropical Azores Front (AF) and resulting changes in water masses that may affect the SST records. Differences between the SST estimates from different deglacial SST reconstructions obtained from (1) Mg/Ca in planktic foraminifer tests, (2) alkenone UK′37, and (3) planktic foraminifer assemblages (SIMMAX), are assumed to result from the ecology of the proxy bearing organisms, and are assessed for the impact on different SST reconstructions from local seawater δ18O (δ18Ow) reconstructions. The general trends of SSTs from all four proxies confirm the well-known deglacial succession of warm and cold events. Mismatches between amplitudes of temperature changes are explained by differences in the phenology of the proxy-bearing organisms and local changes in hydrography. The combination of δ18O SST from the three different archives of δ18Ow reconstructions may cause offsets that exceed the climate driven signals.

Multi-proxy assessment of brachiopod shell calcite as a potential archive of seawater temperature and oxygen isotope composition

Abstract. Most of our knowledge of past seawater temperature history is based on δ18O values of calcium carbonate fossil shells. However, the determination of past temperatures using this proxy requires the knowledge of past seawater δ18O values, which is generally poorly constrained. Other paleothermometers using carbonate archives, such as Mg/Ca ratios and clumped isotopes (Δ47), have been developed to allow for paleotemperatures to be estimated independently and to allow past ocean δ18O values to be calculated using various groups of calcifying organisms. Articulated brachiopod shells are some of the most commonly used archives in studies of past oceanic geochemistry and temperature. They are abundant in the fossil record since the Cambrian, and for decades, their low Mg–calcite mineralogy has been considered relatively resistant to diagenetic alteration. Here, we investigate the potential of brachiopod shells as recorders of seawater temperatures and seawater δ18O values using new brachiopod shell geochemical data by testing multiple well-established or suggested paleothermometers applied to carbonate archives. Modern articulated brachiopod shells covering a wide range of temperatures (−1.9 to 25.5 ∘C), depths (5 to 3431 m) and salinities (33.4 to 37.0 PSU) were analysed for their stable isotope compositions (δ13C, δ18O and Δ47) and their elemental ratios (Mg/Ca, Sr/Ca, Na/Ca and Li/Ca). Our data allowed us to propose a revised oxygen isotope fractionation equation between modern-brachiopod shell calcite and seawater: (1) T = - 5.0 ( ± 0.2 ) ( δ 18 O c - δ 18 O sw ) + 19.4 ( ± 0.4 ) , where δ18Oc is in ‰ VPDB, δ18Osw is in ‰ VSMOW, and T is in ∘C. Our results strongly support the use of clumped isotopes as an alternative temperature proxy but confirm significant offsets relative to the canonical relationship established for other biogenic and abiogenic calcium carbonate minerals. Brachiopod shell Mg/Ca ratios show no relationship with seawater temperatures, indicating that this ratio is a poor recorder of past changes in temperatures, an observation at variance with several previous studies. Despite significant correlations with brachiopod living temperature, brachiopod shell Sr/Ca, Na/Ca and Li/Ca values indicate the influence of environmental and biological factors unrelated to temperature, which undermines their potential as alternative temperature proxies. Kinetic effects (growth rates) could explain most of the deviation of brachiopod shell calcite from expected isotopic equilibrium with seawater and part of the distribution of Sr/Ca, Na/Ca and Li/Ca ratios.

A 600 kyr reconstruction of deep Arctic seawater δ18O from benthic foraminiferal δ18O and ostracode Mg ∕ Ca paleothermometry

Abstract. The oxygen isotopic composition of benthic foraminiferal tests (δ18Ob) is one of the pre-eminent tools for correlating marine sediments and interpreting past terrestrial ice volume and deep-ocean temperatures. Despite the prevalence of δ18Ob applications to marine sediment cores over the Quaternary, its use is limited in the Arctic Ocean because of low benthic foraminiferal abundances, challenges with constructing independent sediment core age models, and an apparent muted amplitude of Arctic δ18Ob variability compared to open-ocean records. Here we evaluate the controls on Arctic δ18Ob by using ostracode Mg/Ca paleothermometry to generate a composite record of the δ18O of seawater (δ18Osw) from 12 sediment cores in the intermediate to deep Arctic Ocean (700–2700 m) that covers the last 600 kyr based on biostratigraphy and orbitally tuned age models. Results show that Arctic δ18Ob was generally higher than open-ocean δ18Ob during interglacials but was generally equivalent to global reference records during glacial periods. The reduced glacial–interglacial Arctic δ18Ob range resulted in part from the opposing effect of temperature, with intermediate to deep Arctic warming during glacials counteracting the whole-ocean δ18Osw increase from expanded terrestrial ice sheets. After removing the temperature effect from δ18Ob, we find that the intermediate to deep Arctic experienced large (≥1 ‰) variations in local δ18Osw, with generally higher local δ18Osw during interglacials and lower δ18Osw during glacials. Both the magnitude and timing of low local δ18Osw intervals are inconsistent with the recent proposal of freshwater intervals in the Arctic Ocean during past glaciations. Instead, we suggest that lower local δ18Osw in the intermediate to deep Arctic Ocean during glaciations reflected weaker upper-ocean stratification and more efficient transport of low-δ18Osw Arctic surface waters to depth by mixing and/or brine rejection.

In‐Situ and Triple Oxygen Isotope Characterization of Seafloor Drilled Cherts: Marine Diagenesis and Its Bearing on Seawater Reconstructions

AbstractCherts are used to reconstruct the evolution of seawater δ18O and temperature over geological time. However, given the influence of marine diagenesis, reconstructing seawater from the isotope composition of cherts is not straightforward, resulting in ambiguity of interpretation. Here, we present a detailed isotope and petrographic investigation of deep‐sea drilled 135–40 Ma cherts with focus on the effects of marine diagenesis. We combined triple O‐isotope data with in‐situ δ′18O‐16OH/16O measurements using secondary ion mass spectrometry (SIMS). We also provide electron microprobe maps, traditional δ′18O measurements from petrographically diverse domains, and δD and H2O wt.% values. The bulk δ′18O values range between 29‰ and 38‰ in our collection, while SIMS δ′18O data reveal significant intra‐sample heterogeneities up to 6‰ related to distinct petrographic features (e.g., filled radiolarian tests) and to micrometer‐scale variations in silica forms. Further, the δ′18O—Δ′17O values of these seafloor‐drilled cherts plot near and under equilibrium curve. Both triple‐O and SIMS δ′18O results reflect diagenesis in presence of marine pore waters at temperatures higher than ambient seawater, which is especially appreciable in cherts deposited on young oceanic crust. Despite the relatively constant δ18O seawater values over last 135 Ma, the marine silica spanning between 0 and 135 Ma occupies a wide compositional space in the δ′18O—Δ′17O rather than an equilibrium curve. The δ′18O values of cherts from modern‐seafloor positively correlate with the oceanic crustal age at the time of deposition, hinting at the importance of the heat flux in the diagenetic recrystallization of marine silica.

Equatorial Undercurrent Influence on Surface Seawater δ18O Values in the Galápagos

AbstractStable isotopes of oxygen (δ18O) in seawater reflect the combined influences of ocean circulation and atmospheric moisture balance. However, it is difficult to disentangle disparate ocean and atmosphere influences on modern seawater δ18O values, partly because continuous time series of seawater δ18O are rare. Here we present a nearly nine‐year, continuous record of seawater δ18O values from the Galápagos. Seawater δ18O values faithfully track sea surface salinity and salinity along the equator at 50 m depth. Zonal current velocity within the Equatorial Undercurrent (EUC), directly west of the Galápagos, is strongly correlated with Galápagos surface seawater δ18O values with a 1‐month lag. Reconstructions of Galápagos seawater δ18O values could thus provide a window into past variations in the strength of the EUC, an important influence on large‐scale tropical Pacific climate.

Large freshwater-influx-induced salinity gradient and diagenetic changes in the northern Indian Ocean dominate the stable oxygen isotopic variation in Globigerinoides ruber

Abstract. The application of stable oxygen isotopic ratio of surface-dwelling planktic foraminifera Globigerinoides ruber (white variety; δ18Oruber) to reconstruct past hydrological changes requires a precise understanding of the effect of ambient parameters on δ18Oruber. The northern Indian Ocean, with its huge freshwater influx and being a part of the Indo-Pacific Warm Pool, provides a unique setting to understand the effect of both the freshwater-influx-induced salinity and temperature on δ18Oruber. Here, we use a total of 400 surface samples (252 from this work and 148 from previous studies), covering the entire salinity end-member region, to assess the effect of freshwater-influx-induced seawater salinity and temperature on δ18Oruber in the northern Indian Ocean. The analysed surface δ18Oruber mimics the expected δ18O calcite estimated from the modern seawater parameters (temperature, salinity, and seawater δ18O) very well. We report a large diagenetic overprinting of δ18Oruber in the surface sediments, with an increase of 0.18 ‰ per kilometre increase in water depth. The freshwater-influx-induced salinity exerts the major control on δ18Oruber (R2=0.63) in the northern Indian Ocean, with an increase of 0.29 ‰ per unit increase in salinity. The relationship between temperature- and salinity-corrected δ18Oruber (δ18Oruber−δ18Osw) in the northern Indian Ocean [T=-0.59⋅(δ18Oruber-δ18Osw)+26.40] is different than reported previously, based on the global compilation of plankton tow δ18Oruber data. The revised equations will help create a better palaeoclimatic reconstruction from the northern Indian Ocean by using the stable oxygen isotopic ratio. The entire data set (newly generated and previously published) used in this work is available both as a Supplement to this article and at PANGAEA (https://doi.org/10.1594/PANGAEA.945401; Saraswat et al., 2022).