Sea Breeze Research Articles

Nocturnal Ozone Enhancement Induced by Sea-Land Breezes During Summertime in Northern Coastal City Qingdao, China

This study investigated the influence of sea–land breezes on nocturnal spatial and temporal distribution of ozone (O3) and its potential effects on particulate nitrate formation in Qingdao, a coastal city in northern China. Observation campaigns were conducted to measure surface air pollutants and meteorological factors during a typical sea–land breezes event from 22 to 23 July 2022. A coherent Doppler lidar (CDL) system was employed to continuously detect three-dimensional wind fields. The results revealed that nocturnal ozone levels were enhanced by a conversion of sea–land breezes. Initially, the prevailing northerly land breeze transported high concentrations of O3 and other air pollutants from downtown to the Yellow Sea. As the sea breeze developed in the afternoon, the sea breeze front advanced northward, resulting in a flow of high O3 concentrations back into inland areas. This penetration of the sea breeze front led to a notable spike in O3 concentrations between 16:00 on 22 July and 02:00 on 23 July across downtown areas, with an average increase of over 70 μg/m3 within 10 min. Notably, a time lag in peak O3 concentration was observed with southern downtown areas peaking before northern rural areas. During this period, combined pollution of O3 and PM2.5 was also observed. These findings indicated that the nighttime increase in O3 concentrations, coupled with enhanced atmospheric oxidation, would likely promote the secondary conversion of gaseous precursors into PM2.5.

Understudied High-Pollution Band along Long Island’s South Coastline Caused by the Interaction of New York City Urban Plumes and a Stagnant Sea Breeze Front

Understudied High-Pollution Band along Long Island’s South Coastline Caused by the Interaction of New York City Urban Plumes and a Stagnant Sea Breeze Front

Observed Variability in Convective Cell Characteristics and Near-Storm Environments across the Sea- and Bay-Breeze Fronts in Southeast Texas

Abstract During the DOE Atmospheric Radiation Measurement (ARM) Tracking Aerosol Convection Interactions Experiment (TRACER) IOP spanning June–September 2022, two fixed ARM sites and a mobile team concurrently sampled the airmass heterogeneity across sea- and bay-breeze fronts around the greater Houston metropolitan region. Here, we quantify the spatiotemporal variability between maritime (coastal/bay side of breeze fronts) and continental (inland side of breeze fronts) air masses over 15 IOP days characterized by strong sea-breeze forcing. We analyze environmental profile data from 177 radiosondes and use S- and C-band radar data to track and quantify the variability in attributes of more than 2300 shallow and transitioning cells across different air masses. The composite analysis of environmental profiles indicates that during the early afternoon, the sea-breeze maritime air mass exhibits lower convective available potential energy (CAPE) than the bay-breeze maritime air mass. As the sea breeze advances inland with time, CAPE within the maritime air mass exceeds that of the continental air mass to the north of the breeze fronts. In general, maritime cells have a larger mean composite reflectivity and cell widths than continental cells; however, the response varies between shallow and transitioning cells. Mean composite 20-dBZ echo-top heights, however, are similar across air masses for both shallow and transitioning cells. The continental and maritime inflow air mass for transitioning cells has significantly different mean values for mixed-layer entrainment CAPE, lifted condensation level, level of free condensation, boundary layer depth, and diluted equilibrium level. For shallow cells, only total precipitable water shows a significant difference. Significance Statement The greater Houston metropolitan area is a natural laboratory for understanding the individual impacts of background meteorology and aerosols on convective clouds. Due to its proximity to the Gulf Coast and Galveston Bay, the Houston region experiences a diurnal precipitation cycle in the summer, driven by convection triggered from sea- and bay-breeze fronts. These fronts act as a boundary between air masses with distinct thermodynamic and environmental characteristics. Convergence along these fronts and interactions between storm outflow and the fronts facilitate convection initiation in different mesoscale air masses. This study quantifies the heterogeneity among these air masses while investigating their influence on cloud microphysics. We find that the effect of airmass heterogeneity is more pronounced for the bulk microphysical properties in shallow clouds.

Long-term climate characteristics of sea breeze phenomena over Sriharikota using met-tower observations and ERA-5 reanalysis dataset

Long-term climate characteristics of sea breeze phenomena over Sriharikota using met-tower observations and ERA-5 reanalysis dataset

Evaluating MPAS-A Performance for Mesoscale Simulation in a Tropical Region: A Case Study of Extreme Heat in Jakarta, Indonesia

The Model for Prediction Across Scales–Atmosphere (MPAS-A) has been widely used for larger scale simulations, but its performance in mesoscale, particularly in tropical regions, is less evaluated. This study aimed to assess MPAS-A in simulating extreme surface air temperature in Jakarta during the hot spells of October 2023 with eight different simulation setups. Several validation metrics were applied to near-surface meteorological variables, land surface temperature (LST), and vertical atmospheric profile. From the eight simulations, MPAS-A captured diurnal patterns of the near-surface variables well, except for wind direction. The model also performed well in LST simulations. Moreover, the biases in the vertical profiles varied with height and were sensitive to the initial/boundary conditions used. Simulations with modified terrestrial datasets showed higher LST and air temperatures over the sprawling urban areas. MPAS-A successfully simulated the extreme event, showing higher air temperatures in southern Jakarta (over 36 °C) compared to the northern part. Negative temperature advection by sea breeze helped lower air temperature in the northern area. This study highlights the role of sea breezes as natural cooling mechanisms in coastal cities. Additionally, MPAS-A is feasible for several applications for urban climate studies and climate projection, although further development is needed.

Effects of sea-land breeze on air pollutant dispersion in street networks with different distances from coast using WRF-CFD coupling method

A WRF-CFD coupled model with high-temporal resolution is employed to investigate pollutant dispersions during a sea-land breeze (SLB) day in an identical building block configuration at three locations in Shanghai, China, and the blocks are set at the coast (L1), downtown (L2) and inland (L3). The results show that the localized wind speed drops below 1 m/s during the sea-land-breeze collision period (SLBCP), which leads to pollutant accumulation. The closer the block is to the coast, the earlier occurrence and longer duration of SLBCP, and Blocks L1, L2, and L3 experience SLBCPs during the morning peak traffic period (MPTP), low-traffic-volume period (at midday), and evening peak traffic period (EPTP), with durations of 2.5 h, 2 h, and 1 h, respectively. Due to the low wind speeds of both land breezes and sea breezes during the overlap of MPTP and SLBCP, the pollutant concentration in Block L1 is significantly elevated, and the peak concentration is two times higher than that in the non-coastal blocks (L2 and L3). Block L2 shows a peak concentration during the midday low-traffic-volume period, while no evident peak concentration is found in L3 in EPTP. The mean concentrations in Blocks L1, L2, and L3 during EPTP are 72 %, 57 %, and 31 % lower than those during MPTP, respectively. This suggests that SLB has significantly different effects on wind fields and pollutant dispersion in building blocks with different distances from the coast and can provide reference data for transport planning in coastal cities.

Impacts of Local Circulations on Ozone Pollution in the New York Metropolitan Area: Evidence From Three Summers of Observations

AbstractElevated surface ozone levels are often detected in the New York metropolitan area during summertime. Moreover, surface ozone in this region exhibits sharp spatial gradients and distinctive diurnal cycles under the influence of complex boundary layer circulations induced by the intricate coastal geometry. This study examines how surface ozone is impacted by local circulations spatially and temporally under different temperature scenarios (all summer days, hot summer days, and extreme heat days) with the help of cluster‐based meteorological conditions during the summertime of 2017–2019. The most polluted days are found to be highly associated with hot sea breeze days with weak background flow. When sea breeze development in the New York Bight is delayed and its penetration north is intercepted by the dominant westerlies during hot summer days, daily maximum 8‐hr average ozone (DMA8) in some ozone hot spots of New York City (NYC) and the south shore of Connecticut (CT) typically drops 9–10 ppb under comparable temperature levels. The average regional decrease of DMA8 for NYC and coastal CT is 6.7 and 8.3 ppb, respectively. Furthermore, we conclude that a change in early morning meridional wind direction is the most critical meteorological characteristic in controlling sea breeze onset type and helping modulate ozone exceedances in the region during extreme hot days when ozone exceedances are expected to be very common. The conclusion is further demonstrated with two case studies during the Long Island Sound Tropospheric Ozone Study 2018 field campaign.

RIME-CNN-BiLSTM: A novel optimized hybrid enhanced model for significant wave height prediction in the Gulf of Mexico

Accurate prediction of SWH in the ocean is critical to the development of ocean energy technologies. However, existing forecasting models have limitations in accuracy and reliability, which directly affect the efficiency of ocean energy utilization. To address this problem, this paper proposes a new ocean SWH prediction model, RIME-CNN-BiLSTM, for predicting 1, 6, 12, and 24 h SWH at three buoy observing stations in the Gulf of Mexico. The model combines the RIME algorithm, CNN, and BiLSTM to comprehensively capture multiple parameters that affect wave heights, such as sea breeze, waves, barometric pressure, and temperature. The parameters of the CNN-BiLSTM model are optimized by the RIME algorithm, which significantly improves the prediction accuracy and generalization ability. Compared with the traditional model, RIME-CNN-BiLSTM captures the nonlinear features more accurately, has better prediction ability for outliers, and shows stronger generalization performance in different sea areas of the Gulf of Mexico. In terms of predicting the wave height in the next 24 h, the improvements are 7.065%, 3.646% and 5.186%, respectively. The results show that the RIME-CNN-BiLSTM model performs well in all prediction time periods, significantly outperforms other benchmark models, and is able to accurately capture nonlinear features and effectively predict outliers.

TAMU TRACER: Targeted Mobile Measurements to Isolate the Impacts of Aerosols and Meteorology on Deep Convection

Abstract Difficulty in using observations to isolate the impacts of aerosols from meteorology on deep convection often stems from the inability to resolve the spatiotemporal variations in the environment serving as the storm’s inflow region. During the U.S. Department of Energy (DOE) Tracking Aerosol Convection interactions Experiment (TRACER) in June–September 2022, a Texas A&M University (TAMU) team conducted a mobile field campaign to characterize the meteorological and aerosol variability in air masses that serve as inflow to convection across the ubiquitous mesoscale boundaries associated with the sea and bay breezes in the Houston, Texas, region. These boundaries propagate inland over the fixed DOE Atmospheric Radiation Measurement (ARM) sites. However, convection occurs on either or both the continental or maritime sides or along the boundary. The maritime and continental air masses serving as convection inflow may be quite distinct, with different meteorological and aerosol characteristics that fixed-site measurements cannot simultaneously sample. Thus, a primary objective of TAMU TRACER was to provide mobile measurements similar to those at the fixed sites, but in the opposite air mass across these moving mesoscale boundaries. TAMU TRACER collected radiosonde, lidar, aerosol, cloud condensation nuclei (CCN), and ice nucleating particle (INP) measurements on 29 enhanced operations days covering a variety of maritime, continental, outflow, and prefrontal air masses. This paper summarizes the TAMU TRACER deployment and measurement strategy, instruments, and available datasets and provides sample cases highlighting differences between these mobile measurements and those made at the ARM sites. We also highlight the exceptional TAMU TRACER undergraduate student participation in high-impact learning activities through forecasting and field deployment opportunities.

Lev Gutman—A Pioneer in Theoretical Mesoscale Meteorology

Abstract On 5 March 2023, Professor Lev Gutman would have been 100 years old. This article describes Professor Gutman’s legacy in the field of dynamic mesoscale meteorology and numerical weather prediction. Gutman developed his career as a mathematician and meteorologist in the Soviet Union, where he built a school of specialists in mesoscale meteorology from the 1950s through the 1970s. He primarily worked on analytical methods to solve complex nonlinear problems, such as the structure of sea breezes, mountain–valley circulations, and thermal convection over heated terrain. Gutman pioneered the development of theories of cumulus clouds, tornadoes, and other atmospheric phenomena. In the 1960s, he carried out numerous research investigations on these topics with his doctoral students and collaborators at the High-Altitude Geophysical Institute in Nalchik in the northern Caucasus and later at the Siberian Scientific Center near Novosibirsk. Gutman compiled the results from these studies into a monograph titled “Introduction to the Nonlinear Theory of Mesoscale Meteorological Processes,” which was published in Russian in 1969 and later translated into English, Chinese, and Japanese. This monograph became a major textbook for specialists in mesoscale meteorology, remaining relevant to this day. After Professor Gutman immigrated to Israel in 1978, his collaborations expanded to include Israeli and western scientists from Europe and the United States. Gutman did not receive the recognition he deserved due to the political realities of the time. His book and his seminal analytical solutions should still be useful for early career scientists in mesoscale meteorology and atmospheric dynamics.

An air quality and boundary layer dynamics analysis of the Los Angeles basin area during the Southwest Urban NOx and VOCs Experiment (SUNVEx)

Abstract. The NOAA Chemical Sciences Laboratory (CSL) conducted the Southwest Urban NOx and VOCs Experiment (SUNVEx) to study emissions and the role of boundary layer (BL) dynamics and sea-breeze (SB) transitions in the evolution of coastal air quality. The study presented utilizes remote sensing and in situ observations in Pasadena, California. Separate analyses are conducted on the synoptic conditions during ozone (O3) exceedance (>70 ppb) and non-exceedance (<70 ppb) days, as well as the fine-structure variability of in situ chemistry measurements during BL growth and SB transitions. Diurnal analyses spanning August 2021 revealed a markedly different wind direction during evenings preceding O3 exceedance (northerly) versus non-exceedance (easterly) days. Increased O3 occurred simultaneously with warmer and drier conditions, a reduction in winds, and an increase in volatile organic compounds (VOCs) and fine particulate matter (PM2.5). While the average BL height was lower and surface pressure was higher, the day-to-day variability of these quantities led to an overall weak statistical relationship. Investigations focused on the fine-structure variability of in situ chemistry measurements superimposed on background trends were conducted using a novel multivariate spectral coherence mapping (MSCM) technique that combined the spectral structure of two or more independent measurements through a wavelet analysis as reported by maximum-normalized scaleograms. A case study was chosen to illustrate the MSCM technique, where the dominant peaks in scaleograms were identified and compared to BL height during the growth phase. The temporal widths of peaks (τmax) derived from VOC and nitrogen oxide (NOx) scaleograms, as well as scaleograms combining VOCs, NOx, and variations in BL height, indicated a broadening with respect to time as the BL increased in depth. A separate section focused on comparisons between τmax and BL height during August 2021 revealed uncorrelated or weakly correlated scatter, except in the case of VOCs when really large τmax and relatively deep BL heights were ignored. Instances of large τmax and relatively deep BL heights occurred near sunrise and as onshore flow entered Pasadena, respectively. Wind transitions likely influenced both the dynamical evolution of the BL and tracer advection and thus offer additional challenges when separating factors contributing to the fine structure. Other insights gained from this work include observations of descending wind jets from the San Gabriel Mountains that were not resolved by the High-Resolution Rapid Refresh (HRRR) model and the derivation of intrinsic properties of oscillations observed in NOx and O3 during the interaction between an SB and enhanced winds above the BL that flowed in opposition to the SB.

Continental scale spatial temporal interpolation of near-surface air temperature: do 1 km hourly grids for Australia outperform regional and global reanalysis outputs?

Near-surface air temperature is an essential climate variable for the study of many biophysical phenomena, yet is often only available as a daily mean or extrema (minimum, maximum). While many applications require sub-diurnal dynamics, temporal interpolation methods have substantial limitations and atmospheric reanalyses are complex models that typically have coarse spatial resolution and may only be periodically updated. To overcome these issues, we developed an hourly air temperature product for Australia with spatial interpolation of hourly observations from 621 stations between 1990 and 2019. The model was validated with hourly observations from 28 independent stations, compared against empirical temporal interpolation methods, and both regional (BARRA-R) and global (ERA5-Land) reanalysis outputs. We developed a time-varying (i.e., time-of-day and day-of-year) coastal distance index that corresponds to the known dynamics of sea breeze systems, improving interpolation performance by up to 22.4% during spring and summer in the afternoon and evening hours. Cross-validation and independent validation (n = 24/4 OzFlux/CosmOz field stations) statistics of our hourly output showed performance that was comparable with contemporary Australian interpolations of daily air temperature extrema (climatology/hourly/validation: R2 = 0.99/0.96/0.92, RMSE = 0.75/1.56/1.78 °C, Bias = -0.00/0.00/-0.03 °C). Our analyses demonstrate the limitations of temporal interpolation of daily air temperature extrema, which can be biased due to the inability to represent frontal systems and assumptions regarding rates of temperature change and the timing of minimum and maximum air temperature. Spatially interpolated hourly air temperature compared well against both BARRA-R and ERA5-Land, and performed better than both reanalyses when evaluated against the 28 independent validation stations. Our research demonstrates that spatial interpolation of sub-diurnal meteorological fields, such as air temperature, can mitigate the limitations of alternative data sources for studies of near-surface phenomena and plays an important ongoing role in supporting numerous scientific applications.

Spatiotemporal Distribution Characteristics of Ground-level-ozone and Its Relationship with Meteorological Conditions in a Representative City in the Bohai Rim from 2017 to 2022

In recent years, ground-level-ozone（O3） pollution in urban areas in the Bohai Rim has attracted wide attention. Based on the analysis of the spatiotemporal distribution characteristics of O3 concentration in Dongying, a representative city in the Bohai Rim from 2017 to 2022, the effects of meteorological factors and sea-land breeze circulation on O3 concentration were evaluated. The results showed that： ① From 2017 to 2022, the annual assessment value of O3 concentration in Dongying showed a fluctuating upward trend, and the pollution days with O3 as the primary pollutant increased. O3 pollution mainly occurred in spring, summer, and autumn, with the most severe O3 pollution episodes typically occurring in May and June, and the duration of O3 pollution season tended to be longer. The monthly variation in the daily maximum 8-h average ozone （MDA8 O3） presented a bimodal distribution, with significant increases in the 5th and 25th percentiles, and the spatial distribution was "high in the north and south, low in the middle." In addition, the nocturnal O3 concentration in recent years in Dongying also showed a significant increase trend. ② Meteorological factors greatly influenced O3 concentration in Dongying. When the temperature was greater than 30℃, the relative humidity was less than 50%, and the wind direction was south-southwest or east-northeast, a high O3 value was more likely to occur. Meteorological factors contributed 30% of the MDA8 O3 variation in Dongying during the study period. In the case of moderate and severe O3 pollution, the contribution of meteorological factors to the change in MDA8 O3 could be as high as 40%. ③ To some extent, sea-land breeze contributed to the occurrence of MDA8 O3 exceeding the secondary standard limit value of the National Ambient Air Quality Standard. In the afternoon, the hourly concentration of O3 during the sea-land breeze days was approximately 20 μg·m-3 higher than that during the non-sea-land breeze days. On the days of moderate and severe O3 pollution, the O3 concentration during the sea-land breeze days from 10：00 to 16：00 was higher than that during non-sea-land breeze days, and the O3 concentration was also at a high level from 20：00 to 23：00 on sea-land breeze days. In the O3 pollution season, the sea-land breeze could significantly affect the O3 level in coastal cities, which could bring significant challenges for O3 pollution prevention and control in this region. In the future, cities in the Bohai Rim need to further strengthen regional joint prevention and control of O3 pollution and increase emission reduction efforts of nitrogen oxides and volatile organic compounds. This strategy could effectively lower pollutant concentrations within the land breeze air mass, consequently reducing the impact of the sea breeze air mass on air quality in cities in the Bohai Rim.

Unusual inland intrusion of nocturnal sea breeze in the North China plain during summer

Unusual inland intrusion of nocturnal sea breeze in the North China plain during summer

Sensitivity of Coastal Squall-Line Evolution to Numerical Sea-Breeze Initialization Method

Abstract This study employs 3D idealized numerical experiments to investigate the physical processes associated with coastal convection initiation (CI) as an offshore-moving squall line traverses a mountainous coastal region. A squall line can propagate discretely as convection initiates over the lee slope downstream of the primary storm as the cold pool collides with a sea breeze. Intensity of the initiating convection, thus the downstream squall line, is sensitive to the sea-breeze numerical initialization method, since it influences sea-breeze and cold pool characteristics, instability and vertical wind shear in the sea-breeze environment, and ultimately the vertical acceleration of air parcels during CI. Here, sea breezes are generated through four commonly used numerical methods: a cold-block marine atmospheric boundary layer (MABL), a prescribed surface sensible heat flux function, a prescribed surface sensible plus latent heat flux functions, and radiation plus surface-layer parameterization schemes. For MABL-initialized sea breezes, shallow weak sea-breeze flow in a relatively low instability environment results in weak CI. For the remainder, deeper stronger sea-breeze flow in an environment of enhanced instability supports more robust CI. In a subset of experiments, however, the vertical trajectory of air parcels is suppressed leading to weaker convection. Downward acceleration forms due to the horizontal rotation of the sea-breeze flow. Accurate simulations of coastal convective storms rely on an accurate representation of sea breezes. For idealized experiments such as the present simulations, a combination of initialization methods likely produces a more realistic representation of sea breeze and the associated physical processes.

Diurnal and seasonal dynamics of the canopy‐layer urban heat island of Kuwait

AbstractThis study examines the temporal and spatial variability of near‐surface air temperature and the canopy layer urban heat island (UHICL) of Kuwait City. Observations collected at 12 locations across the country of Kuwait and for the period 2010–2022 are analysed on an hourly and 3‐hourly basis to provide monthly and diurnal insights of the city's UHICL characteristics. Research on Kuwait's UHICL was first conducted by Nasrallah et al. (International Journal of Climatology, 10, 401–405). Results presented here have been afforded the benefit of additional stations and more extensive data compared with the earlier study. Mean positive UHICL intensities, ranging from 1.1°C to 3.8°C at night, are observed consistently across all months, owing to the prevalence of clear skies from winter to summer. Negative UHICL intensities, indicating a typical daytime urban cool island (UCICL), are most prominent on summer days, exhibiting a mean hourly magnitude range between 0.6°C and 2.6°C that extends into the early parts of the evening. Heat and cool island effects are maintained up to wind speeds approaching 10 m s−1 at the urban periphery. A coastal site near the city demonstrates strong influences of the Arabian Gulf temperatures and associated sea and land breeze effects on UHICL development. The results can be used for comparison with other desert locales, in the evaluation of urban climate models, for urban planning policies and improving local weather forecasts. This study honours in memoriam Dr. Hassan Nasrallah, who produced the first UHICL study in the Arab World.

Seasonality of Retreat Rate of a Wave‐Exposed Marsh Edge

AbstractWave‐driven erosion of marsh boundaries is a major cause of marsh loss, but little research has captured the effect of seasonal differences on marsh‐edge retreat rates to illuminate temporal patterns of when the majority of this erosion is occurring. Using five surface models captured over a study year of a marsh with a steep escarped boundary in South San Francisco Bay, we find a pronounced seasonal signal, where rapid marsh retreat in the spring and summer is driven by a strong sea breeze but little change is found in the marsh‐edge position in the fall and winter. We found accretion in the mudflat transition region close to the marsh boundary in the calmer seasons however, suggesting intertwined morphodynamics of mudflats and the eroding marsh‐scarp. We observed large spatial heterogeneity in retreat rates within seasons, but less on longer (annual and decadal) timescales. The relationship between marsh‐edge retreat rates and properties of the wave field nearby is explored and contextualized against extant relationships, but our results speak to the difficulty in addressing spatial erosion/accretion variability on short (seasonal) timescales with simple models.

Climatology of sea breeze over Jiangsu coast: An overview from the ERA5 reanalysis

AbstractThe sea breeze characteristics for 30 years of summer (1981–2010) in the coastal region of Jiangsu Province were analysed in this study, using the four‐step filter method based on ECMWF Fifth‐Generation Reanalysis (ERA5) data. The results showed that the filtering method reasonably identified three types of sea breeze. Additionally, approximately 23% of the total summer days remained; the corkscrew type dominates the three types of sea breeze; and the backdoor sea breeze was the least common. Except for the type of backdoor sea breeze, the other two types had relatively fixed dominant weather types on three coastlines. The synoptic weather patterns in the 500‐hPa level corresponding to each sea breeze type were different. Further, the details of the diurnal cycle of lower tropospheric circulation indicated the strength of the onshore wind and the location of the large potential temperature gradient at noon being influenced by sea breeze type and coastal location. The wind strength for the three types of sea breeze on the middle coastline was stronger than that on the other two coastlines. On the three coastlines, strong onshore winds were concentrated in areas near the coastline, where they reached their maximum strengths around noon. On the southern coastline, strong onshore winds moved further inland.

Multiparameter Detection of Summer Open Fire Emissions: The Case Study of GAW Regional Observatory of Lamezia Terme (Southern Italy)

In Southern Mediterranean regions, the issue of summer fires related to agriculture practices is a periodic recurrence. It implies a significant increase in carbon dioxide (CO2) emissions and other combustion-related gaseous and particles compounds emitted into the atmosphere with potential impacts on air quality and global climate. In this work, we performed an analysis of summer fire events that occurred on August 2021. Measurements were carried out at the permanent World Meteorological Organization (WMO)/Global Atmosphere Watch (GAW) station of Lamezia Terme (Code: LMT) in Calabria, Southern Italy. The observatory is equipped with greenhouse gases and black carbon analyzers, an atmospheric particulate impactor system, and a meteo-station for atmospheric parameters to characterize atmospheric mechanisms and transport for land and sea breezes occurrences. High mole fractions of carbon monoxide (CO) and carbon dioxide (CO2) coming from quadrants of inland areas were correlated with fire counts detected via the MODIS satellite (GFED-Global Fire Emissions Database) at 1 km of spatial resolution. In comparison with the typical summer values, higher CO and CO2 were observed in August 2021. Furthermore, the growth in CO concentration values in the tropospheric column was also highlighted by the analyses of the L2 products of the Copernicus SP5 satellite. Wind fields were reconstructed via a Weather Research and Forecasting (WRF) output, the latter suggesting a possible contribution from open fire events observed at the inland region near the observatory. So far, there have been no documented estimates of the effect of prescribed burning on carbon emissions in this region. This study suggested that data collected at the LMT station can be useful in recognizing and consequently quantifying emission sources related to open fires.

Daytime and nighttime aerosol soluble iron formation in clean and slightly polluted moist air in a coastal city in eastern China

Abstract. Photocatalytic reactions during the daytime, alongside aqueous-phase reactions occurring during both daytime and nighttime, are identified as the two primary processes facilitating the conversion of aerosol iron (Fe) from the insoluble state to the soluble state within the atmospheric environment. This study investigated the levels of total Fe (FeT) and soluble Fe (FeS) in PM2.5 samples collected during daytime and nighttime in Qingdao, a coastal city in eastern China, evaluating the distinctive roles of these two pathways in enhancing aerosol Fe solubility (%FeS, defined as the ratio of FeS to FeT). Under clean and humid conditions, characterized by prevailing sea breezes and a relative humidity (RH) typically above 80 %, an average daytime %FeS of 8.7 % was observed, which systematically exceeded the nighttime %FeS (6.3 %). Photochemical conversions involving oxalate contributed to the higher %FeS observed during daytime. Conversely, in scenarios where air masses originated from inland areas and exhibited slightly polluted, daytime %FeS (3.7 %) was noted to be lower than the nighttime %FeS (5.8 %). This discrepancy was attributable to the variations in RH, with nighttime RH averaging around 77 %, conducive to the more efficient generation of acidic compounds, thereby accelerating FeS production compared to the daytime, when RH was only about 62 %. Furthermore, the oxidation rates of sulfur (SOR) displayed a strong correlation with RH, particularly when RH fell below 75 %. A 10 % increase in RH corresponded to a 7.6 % rise in SOR, which served as the primary driver of the higher aerosol acidity and %FeS at night. These findings highlight the RH-dependent activation of aqueous-phase reactions and the augmentation of daytime photocatalysis in the formation of FeS in the coastal moist atmosphere.