Cement-based composites (CBCs) are essential in the construction sector due to their cost-effectiveness, availability, and versatility, but they struggle with low tensile strength and poor heat resistance. Recent advancements have highlighted the potential of nanomaterials, particularly graphene oxide (GO), in enhancing the mechanical, thermal, and electrical properties of CBCs. This study aims to provide a comprehensive review of the incorporation of GO into cementitious composites, examining its impact on microstructure, mechanical properties, rheology, and durability; thus, a bibliometric review and scientometric analysis were conducted to thoroughly evaluate the existing literature. A total of 263 studies were selected for thorough study. It can be concluded that GO content acts as a pore filler, decreasing porosity by 23% and average pore size by 22%, while boosting compressive strength by up to 15% at a 0.05% concentration. It also enhances workability, stability, and resistance to chloride ingress, sulfate attack, alkali–silica reaction, and carbonation. Incorporating GO reduces cement consumption and carbon footprint, leading to more durable structures and supporting sustainable construction by efficiently utilizing waste materials. The optimal GO concentration for these benefits ranges from 0.03% to 0.1% by weight of cement, as higher concentrations may cause agglomeration. GO-modified cementitious materials are well suited for high-performance and durable applications, particularly in environments with chemical and mechanical stresses.
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