Scavenging Processes Research Articles

Dissolved rare earth elements in the North Pacific Subtropical Gyre: Lithogenic sources and water mass mixing control

In the North Pacific Subtropical Gyre, which is one of the largest oligotrophic regions, there is a lack of information regarding the sources and transport of trace metals through water mass mixing. Rare earth elements (REEs) are essential for tracing lithogenic sources and water mass transport. In this study, we present dissolved REE concentrations and the factors controlling their distributions in the northwest Pacific during a GEOTRACES cruise (GP09). In the surface water along 11°N, we observed input signals from the Philippine and the Hawaiian Islands, characterized by positive Eu anomalies and slightly elevated REE concentrations. By incorporating our data and published REE data from the northwest Pacific to the southeast Pacific (40°N–40°S), we demonstrated that the REE concentrations and Yb/Nd ratios can distinguish North Pacific Intermediate Water (NPIW), Antarctic Intermediate Water (AAIW), and modified AAIW. By estimating the ratio of water mass mixing, we suggest that heavy REEs are predominantly contributed by water mass mixing (e.g., 93 % ± 4% for Yb) and can be used as semi-conservative tracers to quantify the mixing of NPIW and modified AAIW at the potential density of 27.2 kg/m3. At ∼800 m depth at stations K12, K13, and K14, weak negative Ce anomalies (>0.1) were observed, indicating the lateral transport of water masses imprinted with sediment signals from the Philippine Islands. In the deep waters (>1500 m) at the Luzon Strait (station K1), we propose that the weak Ce negative anomalies (>0.08) and low Yb/Nd ratios (<5), combined with the low beam transmission, are the result of particle resuspension and release. In deep water (>2000 m), combining high-resolution REE measurements with water mass analysis, our research reveals that dissolved REEs (except Ce) are dominantly controlled by water mass mixing (e.g., 80 %∼100 % for Yb and 70 %∼100 % for Nd). For the non-conservative behavior, which is not explained by water mass mixing, the residual fraction of heavy REEs (<20 % for Yb) originates from release of sinking particles (organic matter and siliceous particles), while the remaining concentrations of light REEs (<30 % for Nd) may be influenced by a combination of particle release and scavenging processes. These findings highlight valuable information about lithogenic sources and the proportions of REE distributions that are controlled by physical and biogeochemical processes. Moreover, it emphasizes the applicability of heavy REEs as effective tracers for understanding basin-scale water mass mixing in the northwest Pacific.

Simulation methodology and numerical comparison of boxer and opposed free piston linear generator configuration in 0D/1D environment

Free Piston Linear Generators (FPLGs) are thermal machines suitable for both stationary power generation unit (PU) and vehicle propulsion. They convert chemical energy from the fuel into electric energy to charge a battery using a linear electric generator. Due to the reduction of friction losses and the ability to work with different compression ratios, FPLGs are potentially characterized by high overall global efficiency with respect to a conventional alternative internal combustion engine. Like conventional internal combustion engines, FPLGs have several configurations: single piston, dual piston, opposed piston and boxer are the configurations considered in this work. Two configurations are compared in this paper from a functional and energetic perspective: opposed piston (Opposed) and Boxer. This is done with the aim to highlights pro and cons of these configurations. They are modelled using the 0D/1D modelling coupling GT-Power® and Simulink®. The comparison between the two configurations was done modelling the architecture with the same size and in two-strokes operating mode. The comparison of the two configurations highlights differences between them in terms of scavenging process, thermodynamic efficiency and global energy efficiency, putting in evidence what aspects need to be improved for each configuration and what are their advantageous features. Boxer configuration can provide less power due to lower volumetric efficiency compared to the Opposed configuration. Boxer configuration can provide 102.2 kW while Opposed can provide 110.0 kW at full load with a frequency of 20 Hz (equivalent to 1200 rpm). The Opposed configuration results in lower heat loss but higher energy lost at the exhaust. The final balance shows that Boxer configuration has a slightly higher brake efficiency (equal to 28.9 %) compared to the value found for Opposed (27.6 %).

Chemical Data Assimilation With Aqueous Chemistry in WRF‐Chem Coupled With WRFDA (V4.4.1)

AbstractThis study introduces a new chemistry option in the Weather Research and Forecasting model data assimilation (WRFDA) system, coupled with the WRF‐Chem model (Version 4.4.1), to incorporate aqueous chemistry (AQCHEM) in the assimilation of ground‐level chemical measurements. The new DA capability includes the integration of aqueous‐phase aerosols from the Regional Atmospheric Chemistry Mechanism (RACM) gas chemistry, the Modal Aerosol Dynamics Model for Europe (MADE) aerosol chemistry, and the Volatility Basis Set (VBS) for secondary organic aerosol production. The RACM‐MADE‐VBS‐AQCHEM scheme facilitates aerosol‐cloud‐precipitation interactions by activating aerosol particles in cloud water during the model simulation. With the goal of enhancing air quality forecasting in cloudy conditions, this new implementation is demonstrated in the weakly coupled three‐dimensional variational data assimilation (3D‐Var) system through regional air quality cycling over East Asia. Surface particulate matter (PM) concentrations and four gas species (SO2, NO2, O3, and CO) are assimilated every 6 hr for the month of March 2019. The results show that including aqueous‐phase aerosols in both the analysis and forecast can represent aerosol wet removal processes associated with cloud development and rainfall production. During a pollution event with high cloud cover, simulations without aerosols defined in cloud water exhibit significantly higher values for liquid water path, and surface PM10 (PM2.5) concentrations are overestimated by a factor of 10 (3) when wet scavenging processes dominate. On the contrary, AQCHEM proves to be helpful in simulating the wet deposition of aerosols, accurately predicting the evolution of surface PM concentrations without such overestimation.

Carcass provisioning and intra-guild risk avoidance between two sympatric large carnivores

Apex carnivores that rely primarily on predation play a central but complex role within scavenging ecology by potentially suppressing intra-guild competitors, but also facilitating them by providing a reliable supply of carrion. We investigated the competitive relationship between sympatric wolves (Canis lupus) and wolverines (Gulo gulo) in Norway across three seasons. We deployed remote cameras at fresh wolf kills (n = 29) and built Bayesian generalized linear mixed models (GLMMs) to explore the use of fresh wolf-killed prey by sympatric wolves and wolverines. Our results showed that wolves facilitated wolverines by providing scavenging opportunities. Biomass available from wolf kills was influenced by seasonal wolf prey preference and group size. Wolverines visited 100% of wolf kills in fall and winter, whereas only 18% in summer. We found that in winter, wolverines visited wolf kills 3.6 and 6.7 times more often than single wolves and wolf groups revisited their kills, and spent 10 and 25 times as much time at carcasses compared to single wolves and groups of wolves. Thus, wolverines played an important role in the depletion of wolf-killed prey, with potential effects on the scavenging behavior of other guild members. Understanding how globally threatened top predators may function as key species in scavenging processes is important to conservation as this may have community-wide cascading effects and support important ecosystem functions and services.Significance statementLarge carnivores serve a central role within scavenging ecology through the suppression and facilitation of intraguild competitors. The wolf, as an apex obligate predator, can provide a reliable supply of carrion, that can serve as an important resource to facultative scavengers. However, while facultative behavior helps to mitigate the effects of limited prey for scavengers, it can also increase exposure to competition and intraguild predation. Across three seasons, we explored the use of fresh wolf-killed prey by sympatric wolves and wolverines. Our findings reveal that wolves facilitate wolverines by providing scavenging opportunities, where biomass available from kills is influenced by wolves’ prey preference and group size. Wolverines, like wolves, utilized kills heavily during winter, when increased access to food is important to wolverine reproductive rates. Wolverines exhibited caching behavior, possibly reducing exposure to interspecific competition, while serving an important role in the depletion of carrion biomass.

Wet scavenging of multi-mode 137Cs aerosols following the Fukushima accident: Size-resolved microphysics modeling with observed diameters

Wet scavenging was critical in the atmospheric transport of 137Cs aerosols following the Fukushima accident. The aerosol size diversity and related microphysical processes produce complex behaviors during wet scavenging. Such behaviors are difficult to investigate using traditional simplified size distributions, resulting in inaccurate modeling. This study establishes an improved size-resolved wet scavenging model that considers the activation process. Using this model, five monodisperse simulations with five representative observed diameters with realistic solubility setting are performed to investigate the spatiotemporal wet scavenging behaviors of 137Cs aerosols. One polydisperse simulation with an empirical size distribution is also validated against the observation. The results reveal that 137Cs aerosols with diameters of 0.6 and 2.0 μm are mainly subject to below-cloud scavenging, which makes a significant contribution to low-deposition areas (<300 kBq/m2). For 137Cs aerosols with diameters of 6.4, 15, and 30 μm, in-cloud scavenging dominates, and the resulting depositions make significant contributions in high-deposition areas. The polydisperse results satisfy the criteria for good performance and better agree with the size, and deposition observations than the five monodisperse simulations, whereas for the concentration, the results show a similar RANK2 with the best mono1 and mono2 cases and reach the satisfactory criteria. These findings reveal the complex behavior and wet scavenging process of multi-mode 137Cs aerosols, improving our understanding and modeling.

Atmospheric fallout of 7Be in bulk precipitation at the Adriatic coast, Croatia

ABSTRACT Atmospheric fallout of naturally occurring cosmic radionuclide 7Be was monitored in bulk precipitation over a year (July 2018 to June 2019) at a coastal station (Martinska) of the Adriatic Sea, Croatia. The monthly depositional fluxes varied between 25.08 and 78.97 Bq m−2 month−1 (average: 49.18 ± 19.17 Bq m−2 month−1) and showed a significant correlation with precipitation (r = 0.92). The highest seasonal flux observed in winter (172 ± 4.31 Bq m−2 season−1) coincides with the highest amount of precipitation (190 mm), suggesting an important role of precipitation in the scavenging process of 7Be deposition to the surface. The monthly volume-weighted activities of 7Be varied from 0.63 to 5.74 Bq L−1 (average: 1.96 ± 1.7 Bq L−1) with the highest value corresponding to the summer season. The precipitation-normalised enrichment factor (α) indicates a higher depositional flux of 7Be in the summer season than the desired value due to the stratosphere-troposphere exchange and the contribution of dry deposition. The annual bulk depositional flux of 7Be was 590 Bq m−2 y−1, which is comparable with several Mediterranean coastal stations. The annual bulk depositional fluxes of 7Be in the 30°N - 50°N latitude band showed a good correlation with precipitation and established that the atmospheric fallout of this radionuclide is mainly governed by precipitation in that given latitude band.

Low emission stepped piston engine for marine outboard motor application

Separating the scavenging process from the lubrication methodology in conventional two-stroke engines is an effective method of reducing emissions. Segregation of scavenging by use of stepped pistons is one such method providing significant improvements in engine durability, and reduced lubricant consumption, together with reduced production cost. The study discusses the approaches used together with those applied to conventional engines. This paper focusses on a marine outboard motor application and cross-comparisons with a comparable four-stroke outboard motor are drawn within the study. One-dimensional computational fluid dynamics models of the engine types have allowed performance and emissions simulations. Where possible, data from experimental dynamometer testing is compared with the theoretical models. A reasonable level of correlation in terms of performance has been observed. Two-stroke cycle engines are able to demonstrate reduced oxides of nitrogen emissions when compared with conventional four-stroke engines. Models of the stepped piston engine have confirmed the lower NOx emission evident with operation on the two-stroke cycle.

Free radical scavenging behaviour of the plant-beneficial secondary metabolite 2,4-diacetylphloroglucinol derivatives under physiological conditions: A joint experimental and theoretical study

Undoubtedly, natural products (NPs) offer a crucial foundation for crafting novel biologically relevant scaffolds. Among these, 2,4-diacetylphloroglucinol (DAPG) stands out as a polyketide compound produced by Pseudomonads spp, showcasing substantial antimicrobial activity. This study focuses on synthesising derivatives of DAPG and delving into their structural characteristics, tautomerism, and antiradical properties. Through density functional theory (DFT) calculations at the B3LYP/def2-SVP level, we examined the thermodynamic parameters governing the double H+/e−radical trapping processes. These investigations encompassed both gas phase and physiological environments (lipid-like and aqueous solution media). Comparative analyses were conducted with its analogue (2,4-diisobutyrylphloroglucinol, DBPG), its parent compound (phloroglucinol, PG), and a commercial antioxidant standard (2-butylated hydroxyanisole, 2-BHA). This study unveils that DAPG exhibits a preference for double-sequential proton loss electron transfer (dSPLET) as the favoured mechanism within physiological environments. Additionally, we computed redox potentials and equilibrium constants to discuss the effectiveness of the overall scavenging process against diverse reactive oxygen, nitrogen, and sulphur species (ROS, RNS, and RSS). Further insights were gained through molecular docking studies, evaluating the potential inhibition against several ROS-generating enzymes such as xanthine oxidase (XO), lipoxygenase (LO), CYP2C9 (CP450), and NADPH-oxidase (NO). Comprehensive discussions regarding the effects of modifications on PG rings were also conducted. In addition, bioinformatic POM (Petra/Osiris/Molinspiration) analyses were reported to aid in clarifying the experimental data and DFT calculations. Ultimately, this study advocates for the development of potent acyl phloroglucinols (ACPLs)-based antiradical agents, shedding light on how structural characteristics influence their radical scavenging potential.

Study on the influence principle and application law of intake wall thickness on uniflow scavenging opposed-piston engine

Energy efficient utilization is an important research direction of energy conversion systems. Uniflow scavenging opposed-piston engine has the potential to achieve higher thermal efficiency than classic engines. The lack of valve mechanism leads to the poor scavenging performance of uniflow scavenging opposed-piston engines. Many studies have been conducted to improve scavenging performance by optimizing intake structure. However, the critical influence of intake wall thickness has not been considered. Therefore, a three-dimensional simulation model of intake wall thickness was established and validated. Then the detailed influence of intake wall thickness was explored. Last, the influence law of intake wall thickness under different application conditions is explored. According to the simulated results, intake wall thickness significantly affects the scavenging process by influencing exhaust gas backflow and changing the scavenging passage; the vital influence of intake wall thickness should be considered in optimizing other intake structures. Thicker intake wall thickness increases the backflow resistance and retains more exhaust gas backflow in the intake port, which is conducive to orderly cleaning backflow exhaust gas. The thinner intake wall thickness should be selected at small intake pressure, and the thicker intake wall thickness should be selected at large intake pressure.

Theoretical model for high-altitude gas exchange process in multi-fuel poppet valves two-stroke aircraft engine

Under the demand of global aviation carbon reduction, the multi-fuel poppet valves two-stroke (MF-PV2S) aircraft engine exhibits advantages such as lower lubricant consumption and the flexibility to high-altitude valve timing adjustment, which position it to play a more significant role in general aviation aircraft and unmanned aerial vehicle propulsion systems. High-altitude gas exchange performance is a critical factor in the thermal efficiency and power characteristics of two-stroke aircraft engines. However, the applicability and accuracy of existing models in predicting the gas exchange process for PV2S engines remain insufficiently discussed. Recognizing discrepancies in the predictions of PV2S gas exchange processes by existing models, a theoretical model applicable to high-altitude gas exchange in an MF-PV2S aircraft engine is established. The modified model adjusts the exhaust composition during the second and third phases of the scavenging process, and a novel model characteristic coefficient, designated as b3, is incorporated to signify the proportion of mixed gas in the exhaust gases at a given moment. Moreover, the model characteristic coefficients b1 and b2, are determined with nonlinearity, based on appropriate relationships that account for the characteristics of the PV2S gas exchange process. The model calculates gas exchange characteristics under different operating conditions and fuels, comparing these results with simulations and tracer gas-based experiments. The findings demonstrate that the model successfully captures the characteristics of early appearance and prolonged duration of fresh charge loss during PV2S gas exchange, significantly enhancing the predictive accuracy. Through adjustments of model coefficients based on specific conditions, the model predicts and describes the variation process of PV2S gas exchange performance parameters under different conditions, including various speeds, different intake-exhaust pressure differences at different altitudes, valve overlaps, and fuel types. The maximum relative errors between model predictions and experimental trapping efficiency, delivery ratio and charging efficiency are 2.58 %, 4.33 %, and 3.89 % respectively. The model can be used for rapid and accurate prediction of gas exchange characteristics under different conditions for the MF-PV2S aircraft engine. Also, it serves as an alternative model of three-dimensional simulation models that can be coupled into the one-dimensional thermodynamic cycle simulation.

Effect of dietary antioxidants on free radical damage in dogs and cats.

Alpha-tocopherol (vitamin E) is an antioxidant that is largely involved in immune defense and enhancing the ability of biological systems to respond to oxidative stress. During the process of free radical scavenging, vitamin C supports the regeneration of vitamin E. Although the functions of antioxidants and their importance have been widely studied, the intricate interplay between antioxidants has yet to be fully elucidated, especially in dogs and cats. As such, the objective of the present study was to determine the effect of a combination of dietary antioxidants on DNA damage and antioxidant status in dogs and cats. Forty adult mixed-breed dogs and 40 adult domestic shorthair cats were randomly assigned to one of four treatment groups per species. Dogs and cats remained in these groups for the 84-d duration of the study. The food differed in antioxidant supplementation with the control food meeting all of the Association of American Feed Control Officials requirements for complete and balanced nutrition, including sufficient vitamin E to exceed the published minimum. The treatment diets were targeted to include either 500, 1,000, or 1,500 IU vitamin E/kg as well as 100ppm of vitamin C and 1.5ppm of β-carotene in the food. The effect of vitamin E supplementation level on serum vitamin E concentration, DNA damage, and total antioxidant power was evaluated. Feeding diets enriched with antioxidants resulted in an increased (P < 0.05) circulating vitamin E concentration, increased (P < 0.05) immune cell protection, reduced (P < 0.05) DNA damage in dogs, and an improved (P < 0.05) antioxidant status. Overall, these data demonstrated that feeding a dry kibble with an antioxidant blend inclusive of vitamin E, vitamin C, and β-carotene enhanced cell protection and improved antioxidant status in dogs and cats.

Selenium‐Based Catalytic Scavengers for Concurrent Scavenging of H2S and Reactive Oxygen Species

AbstractHydrogen sulfide (H2S) is an endogenous gasotransmitter that plays important roles in redox signaling. H2S overproduction has been linked to a variety of disease states and therefore, H2S‐depleting agents, such as scavengers, are needed to understand the significance of H2S‐based therapy. It is known that elevated H2S can induce oxidative stress with elevated reactive oxygen species (ROS) formation, such as in H2S acute intoxication. We explored the possibility of developing catalytic scavengers to simultaneously remove H2S and ROS. Herein, we studied a series of selenium‐based molecules as catalytic H2S/H2O2 scavengers. Inspired by the high reactivity of selenoxide compounds towards H2S, 14 diselenide/monoselenide compounds were tested. Several promising candidates such as S6 were identified. Their activities in buffers, as well as in plasma‐ and cell lysate‐containing solutions were evaluated. We also studied the reaction mechanism of this scavenging process. Finally, the combination of the diselenide catalyst and photosensitizers was used to achieve light‐induced H2S removal. These Se‐based scavengers can be useful tools for understanding H2S/ROS regulations.

Selenium-Based Catalytic Scavengers for Concurrent Scavenging of H2 S and Reactive Oxygen Species.

Hydrogen sulfide (H2 S) is an endogenous gasotransmitter that plays important roles in redox signaling. H2 S overproduction has been linked to a variety of disease states and therefore, H2 S-depleting agents, such as scavengers, are needed to understand the significance of H2 S-based therapy. It is known that elevated H2 S can induce oxidative stress with elevated reactive oxygen species (ROS) formation, such as in H2 S acute intoxication. We explored the possibility of developing catalytic scavengers to simultaneously remove H2 S and ROS. Herein, we studied a series of selenium-based molecules as catalytic H2 S/H2 O2 scavengers. Inspired by the high reactivity of selenoxide compounds towards H2 S, 14 diselenide/monoselenide compounds were tested. Several promising candidates such as S6 were identified. Their activities in buffers, as well as in plasma- and cell lysate-containing solutions were evaluated. We also studied the reaction mechanism of this scavenging process. Finally, the combination of the diselenide catalyst and photosensitizers was used to achieve light-induced H2 S removal. These Se-based scavengers can be useful tools for understanding H2 S/ROS regulations.

Theoretical insight of reactive oxygen species scavenging mechanism in lignin waste depolymerization products.

Apart from natural products and synthesis, phenolic compounds can be produced from the depolymerization of lignin, a major waste in biofuel and paper production. This process yields a plethora of aryl propanoid phenolic derivatives with broad biological activities, especially antioxidant properties. Due to its versatility, our study focuses on investigating the antioxidant mechanisms of several phenolic compounds obtained from renewable and abundant resources, namely, syringol (Hs), 4-allylsyringol (HAs), 4-propenylsyringol (HPns), and 4-propylsyringol (HPs). Employing the density functional theory (DFT) approach in conjunction with the QM-ORSA protocol, we aim to explore the reactivity of these compounds in neutralizing hydroperoxyl radicals in physiological and non-polar media. Kinetic and thermodynamic parameter calculations on the antioxidant activity of these compounds were also included in this study. Additionally, our research utilizes the activation strain model (ASM) for the first time to explain the reactivity of the HT and RAF mechanisms in the peroxyl radical scavenging process. It is predicted that HPs has the best rate constant in both media (1.13 × 108 M-1 s-1 and 1.75 × 108 M-1 s-1, respectively). Through ASM analysis, it is observed that the increase in the interaction energy due to the formation of intermolecular hydrogen bonds during the reaction is an important feature for accelerating the hydrogen transfer process. Furthermore, by examining the physicochemical and toxicity parameters, only Hs is not suitable for further investigation as a therapeutic agent because of potential toxicity and mutagenicity. However, overall, all compounds are considered potent HOO˙ scavengers in lipid-rich environments compared to previously studied antioxidants.

A dual-purpose separator employing phosphine oxide with metal hydroxide incorporation onto polyethylene matrix to improve interfacial stability and safety of high nickel concentration lithium-ion batteries

In recent years, there has been considerable interest in high nickel concentration oxide batteries, typically denoted as high-Ni NMC, thanks to the substantial specific capacity (≤200 mAhg-1) and energy density. Nevertheless, the high-Ni NMC battery often encounters challenges related to interfacial problems and fire concerns stemming from the reduction of nickel (Ni) during electrochemical cycling. Herein, a dual-purpose separator incorporating Mg(OH)2 into dimethoxymethyl phosphine oxide (C3H9O3P) on a polyethylene (PE) matrix is proposed for high-Ni NMC batteries. A noteworthy property of the dual-purpose separator is its ability to form a thin and uniform cathode electrolyte interphase (CEI) with approximately 2 nm, primarily composed of robust LiF, on charge-discharge. As a result, the electrochemical stability is improved, demonstrating a high and stable Coulombic efficiency of ∼99.8% with a reduced impedance from ∼155.8 Ω to ∼60.3 Ω. Also, the capacity degradation decreases from 15% to 0.7% for 100 cycles (at C-rate). Another key property of the dual-purpose separator is the strong thermal stability and flame-retardant performance. During combustion test, any flames that appeared are rapidly extinguished in less than 1.0 s due to the combined flame retardant capability from the water release by heat decomposition of Mg(OH)2 and the radical (e.g. OH∙ and H∙) scavenging process by C3H9O3P. Overall, the dual-purpose separator effectively addresses the interfacial challenges and fire safety associated with high-Ni NMC batteries, concurrently, thanks to the synergetic effects between the constituents.

Experimental investigation of the influence of pre-chamber structural parameters on combustion and emission characteristics of a high compression ratio SI engine

The passive pre-chamber exhibits great potential for practical applications in the internal combustion engine due to its simple structure. However, it faces difficulties in scavenging process, making optimization of pre-chamber structure particularly important. In this study, the effects of pre-chamber ignition systems with different structures and original spark ignition were conducted on a high compression ratio direct-injection SI engine to investigate the combustion, performance, and emission characteristics. The results show that the increase in pre-chamber volume weakens the in-cylinder combustion process and engine performance, while increasing the pre-chamber orifice diameter can enhance the combustion stability at medium to high loads, but will weaken the engine performance at low load. Compared to spark ignition, pre-chamber ignition results in an earlier 50% combustion position, a shorter combustion duration and lower COVIMEP, with these effects becoming stronger as load increases. At high load, the pre-chamber ignition (PC1) advances the 50% combustion position by 5.6°CA and shortens the combustion duration by 16.7%. In addition, the indicated thermal efficiency of the pre-chamber ignition achieves an increase of 0.84% at the optimal point and 2.5% at high load. Overall, using the smaller orifice diameter and volume in the pre-chamber can improve in-cylinder combustion process and increase thermal efficiency across the load range. For emission analysis, the pre-chamber ignition leads to an increase in NOx and HC emissions due to the influence of in-cylinder combustion temperature and quenching effect, while the CO emissions are similar to spark ignition.

Comparison of radiation protection effects between epigallocatechin gallate and ascorbic acid

Ionizing radiation can originate from naturally occurring radiation sources on the earth or it can be from man-made sources. When interacting with cells and living organisms, ionizing radiation produces free radicals, impacting biological molecules such as proteins, lipids, and DNA in the cell nucleus and membrane, leading to cell death or causing cell mutations. Epigallocathecin gallate (EGCG) and ascorbic acid (AA) are well-known natural antioxidants that have been studied and applied as potential radical scavengers. In this study, the radiation protection effects in the presence of EGCG and AA via the scavenging process of free radicals (mainly hydroxyl radicals) were examined. Saccharomyces cerevisiae yeast cells were grown in YDP liquid medium containing yeast extract, peptone, and dextrose/glucose that supplemented with EGCG and AA at different concentrations. Then, the cell cultures were irradiated with both low (gamma) and high (helium ion beam) linear energy transfer (LET) radiations to evaluate the radiation effect on the survival of the yeast cell. Both of EGCG and AA play effectively important roles as radiation-protective agent for yeast cells and the effectiveness in radiation protection of EGCG and AA at the same concentration was almost the same between these two additives.

Simulations of 7Be and 10Be with the GEOS-Chem global model v14.0.2 using state-of-the-art production rates

Abstract. The cosmogenic radionuclides 7Be and 10Be are useful tracers for atmospheric transport studies. Combining 7Be and 10Be measurements with an atmospheric transport model can not only improve our understanding of the radionuclide transport and deposition processes but also provide an evaluation of the transport process in the model. To simulate these aerosol tracers, it is critical to evaluate the influence of radionuclide production uncertainties on simulations. Here we use the GEOS-Chem chemical transport model driven by the Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2) reanalysis to simulate 7Be and 10Be with the state-of-the-art production rate from the CRAC:Be (Cosmic Ray Atmospheric Cascade: Beryllium) model considering realistic spatial geomagnetic cutoff rigidities (denoted as P16spa). We also perform two sensitivity simulations: one with the default production rate in GEOS-Chem based on an empirical approach (denoted as LP67) and the other with the production rate from the CRAC:Be but considering only geomagnetic cutoff rigidities for a geocentric axial dipole (denoted as P16). The model results are comprehensively evaluated with a large number of measurements including surface air concentrations and deposition fluxes. The simulation with the P16spa production can reproduce the absolute values and temporal variability of 7Be and 10Be surface concentrations and deposition fluxes on annual and sub-annual scales, as well as the vertical profiles of air concentrations. The simulation with the LP67 production tends to overestimate the absolute values of 7Be and 10Be concentrations. The P16 simulation suggests less than 10 % differences compared to P16spa but a significant positive bias (∼18 %) in the 7Be deposition fluxes over East Asia. We find that the deposition fluxes are more sensitive to the production in the troposphere and downward transport from the stratosphere. Independent of the production models, surface air concentrations and deposition fluxes from all simulations show similar seasonal variations, suggesting a dominant meteorological influence. The model can also reasonably simulate the stratosphere–troposphere exchange process of 7Be and 10Be by producing stratospheric contribution and 10Be/7Be ratio values that agree with measurements. Finally, we illustrate the importance of including the time-varying solar modulations in the production calculation, which significantly improve the agreement between model results and measurements, especially at mid-latitudes and high latitudes. Reduced uncertainties in the production rates, as demonstrated in this study, improve the utility of 7Be and 10Be as aerosol tracers for evaluating and testing transport and scavenging processes in global models. For future GEOS-Chem simulations of 7Be and 10Be, we recommend using the P16spa (versus default LP67) production rate.

Early Steps in the O2 Scavenger Process in the Aqueous Phase: Hydrazine vs DEHA.

We investigate the first direct proton abstraction reactions from reducing agents (RAHs) hydrazine and diethyl hydroxylamine (DEHA), toward dioxygen (O2) in the aqueous phase, spanning ambient to high-temperature conditions. Quantum chemistry methods and molecular dynamics simulations are employed in this study. Quantum chemistry methods are used to analyze the quasi-equilibrium between a reactive conformation and a transition state in the [RAH,O2] cluster. On the other hand, molecular dynamics simulations estimate the probability of observing a reactive conformation of the [RAH,O2] cluster in the solution. In this study, we assume that the energy barrier of the quasi-equilibrium is sufficiently high for the RAH/O2 association process to be at equilibrium. Our findings indicate that the first proton abstraction process from a reactive conformation cluster by DEHA is energetically favored compared to hydrazine. Conversely, the association process of hydrazine and O2 in solution is more favorable than that of DEHA. Consequently, the rate constant for the first proton abstraction process is similar for both hydrazine and DEHA, particularly at high temperatures, with activation energies of approximately 21.5 ± 1.5 kcal mol-1 for both compounds. These results align with recent experiments investigating the complete O2 scavenger process in liquid water with hydrazine and DEHA. Therefore, our findings support the assumption that first proton abstraction reactions are the rate-determining steps in O2 scavenger processes in the aqueous phase.

Kinetic analysis of free radical scavenging in sonochemistry

As an advanced oxidation process, high-power ultrasound produces free radicals in aqueous solution through acoustic cavitation. Whereas radical production inside the cavitation bubble is well understood, radical scavenging outside the bubble is still unexplored quantitatively. In this study, we modeled the behavior of radicals in the scavenging process by solving the diffusion-advection-reaction equations. Using terephthalate as the scavenger, the principal reaction pathways of hydroxyl radicals are identified and the scavenging efficiency is quantified. The analysis shows that among the various reactions competing for hydroxyl radicals, the scavenging by terephthalate is in disadvantage for the small mass diffusivity. It limits the replenishment of scavengers to the reaction zone and compromises radical trapping efficiency. A parametric study puts the maximum radical trapping efficiency below 30%. Our study elucidates the key factor limiting the utilization of ultrasound-induced radicals and paves the way for future efforts to maximize the sonochemical effects.