The GaoFen6 (GF6) satellite is an optical remote sensing satellite in China’s GaoFen series that combines the imaging abilities of high resolution and wide field of view (WFV). The WFV camera, equipped on the GF6, can obtain an image 800 km in width and with a resolution of 16 m, which represents the highest level of observation swath width among similar satellites in the world. Guaranteeing the high geometric quality of the imagery obtained by the WFV camera for subsequent remote sensing applications is a prominent problem that must be solved. This paper presents the key geometry processing method for the WFV camera, in which the parameters relative determination method based on two selected reference bands and the sensor correction based on virtual collinear complementary metal oxide semiconductor (CMOS) with distortion are proposed. To overcome the challenge of matching the tie points between different bands with large radiation differences, two bands—rather than traditional one band—were chosen as the reference bands for the WFV camera to perform the parameters relative determination. The geometric influence of the virtual CMOS is fully analyzed in the along- and across-track directions. Then, the virtual CMOS with a real calibrated distortion was designed; based on this design, a sensor correction was applied to stitch the whole image generated by single images in each band. This experiment verified the effectiveness of the proposed parameters relative determination and sensor correction methods in improving the internal relative accuracy and the registration accuracy; moreover, the mosaicking accuracy is also guaranteed.