Urban estuaries are dynamic environments that hold high ecological and economic value. Yet, their optical complexity hinders accurate satellite retrievals of important biogeochemical variables, such as chlorophyll-a (Chl-a) biomass. Approaches based on a limited number of satellite spectral bands often fail to capture seasonal transitions and sharp spatial gradients in estuarine Chl-a concentrations, inhibiting integration of satellite data into water quality monitoring and conservation programs. We propose a novel approach that utilizes the wide range of spectral information captured by the Ocean and Land Color Instrument (OLCI) to retrieve estuarine Chl-a. To validate our approach, we used measurements in Long Island Sound (LIS), a highly urbanized estuary increasingly susceptible to anthropogenic stressors and climate change. Hyperspectral remote sensing reflectance (Rrs) and Chl-a data representing the spatiotemporal diversity of LIS were used to assess the ideal atmospheric correction approach for OLCI and develop a multi-spectral multiple linear regression (MS-MLR) Chl-a algorithm. POLYMER derived Rrs proved to be the preferred atmospheric correction approach. Evaluation of MS-MLR performance in retrieving Chl-a with in situ Rrs showed good agreement with field measurements. Application to OLCI-retrieved Rrs showed significant improvement (20%-30%) in common error metrics relative to other algorithms assessed. The MS-MLR approach successfully captured seasonal cycles and spatial gradients in Chl-a concentration. Application of this method to urban estuaries and coasts enables accurate, high resolution Chl-a observations at the ecosystem scale and across a range of conditions, as needed for conservation and ecosystem management efforts.
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